JPS5827966A - Heat treatment of high strength electrically conductive copper alloy - Google Patents
Heat treatment of high strength electrically conductive copper alloyInfo
- Publication number
- JPS5827966A JPS5827966A JP12521981A JP12521981A JPS5827966A JP S5827966 A JPS5827966 A JP S5827966A JP 12521981 A JP12521981 A JP 12521981A JP 12521981 A JP12521981 A JP 12521981A JP S5827966 A JPS5827966 A JP S5827966A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- heat treatment
- alloy
- electrically conductive
- high strength
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910000881 Cu alloy Inorganic materials 0.000 title claims abstract description 8
- 238000010438 heat treatment Methods 0.000 title claims description 24
- 238000005097 cold rolling Methods 0.000 claims abstract description 10
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 8
- 239000000956 alloy Substances 0.000 claims abstract description 8
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 7
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 5
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 5
- 239000012535 impurity Substances 0.000 claims abstract description 4
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 3
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 3
- 229910052718 tin Inorganic materials 0.000 claims abstract description 3
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 abstract description 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 2
- 229910001369 Brass Inorganic materials 0.000 description 3
- 239000010951 brass Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910000906 Bronze Inorganic materials 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000010974 bronze Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- MOFOBJHOKRNACT-UHFFFAOYSA-N nickel silver Chemical compound [Ni].[Ag] MOFOBJHOKRNACT-UHFFFAOYSA-N 0.000 description 2
- 239000010956 nickel silver Substances 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 101100410782 Arabidopsis thaliana PXG1 gene Proteins 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Heat Treatment Of Nonferrous Metals Or Alloys (AREA)
Abstract
Description
【発明の詳細な説明】 本発明は後記する銅合金を最終冷間圧延後。[Detailed description of the invention] In the present invention, the copper alloy described later is subjected to final cold rolling.
２００〜５００℃で２〜２０時間熱処理し、伸び、ばね
限界値、導電率を向上させるに際し。Heat treatment at 200-500°C for 2-20 hours to improve elongation, spring limit value, and electrical conductivity.
引張強さを低下させずに伸び、導電率、特にはね限界値
を著しく向上させることが可能な熱処理条件に関するも
のである。The present invention relates to heat treatment conditions that make it possible to significantly improve elongation and electrical conductivity, particularly the spring limit value, without reducing tensile strength.
従来、スイッチ、コネクター等のばね材としては安価な
黄銅或いは優れたばね性を有する洋白、シん青銅が用い
られているが、黄銅はばね性が劣シかつ応力腐食割れが
生ずる欠点を有しておシ、またりん青銅、洋白は高価で
あ如電気伝導度が匠い欠点を有している。そこで１本出
願人は先にばね性に優れ、安価で耐食性の合金を開発し
た。（特許５４−１６７５１７ ）この合金については
、出願明細書の中に最終冷間圧延後、熱処理を施すこと
により強度、ばね性を向上させることを一部述べたが１
本発明は、該合金の優れた性質を最大限に発揮させるた
めには、熱処理条件を厳密に調整する必要があり２本発
明に定められる条件においてのみ最も優れた性質の発現
が可能にな石ことを見出した。Conventionally, inexpensive brass, nickel silver, and silver bronze, which have excellent spring properties, have been used as spring materials for switches, connectors, etc. However, brass has the disadvantage of poor spring properties and stress corrosion cracking. However, phosphor bronze and nickel silver are expensive and have poor electrical conductivity. Therefore, the present applicant first developed an alloy that has excellent spring properties, is inexpensive, and has corrosion resistance. (Patent No. 54-167517) Regarding this alloy, it was partially stated in the application specification that the strength and springiness were improved by applying heat treatment after final cold rolling.
The present invention shows that in order to maximize the excellent properties of the alloy, it is necessary to strictly adjust the heat treatment conditions. I discovered that.
そして本発明は、ニッケル０４〜８重量−２けい素０１
〜３重量％、亜鉛１０〜３５重量−及びそれに付随する
不純物と残部銅からなる高力導電銅合金を最終冷間圧延
後、２００〜５００℃で２〜２０時間熱処理し、伸び、
ばね限界値。And the present invention uses nickel 04-8 weight-2 silicon 01
After final cold rolling, a high-strength conductive copper alloy consisting of ~3% by weight of zinc, 10-35% by weight of zinc, impurities accompanying it, and the balance copper is heat-treated at 200-500°C for 2-20 hours to elongate it.
Spring limit value.
導電率を向上させる熱処理方法および前記合金に、副成
分としてリン０．００１〜α１重′Ｊｉｉ：優。The heat treatment method for improving electrical conductivity and the alloy include phosphorus from 0.001 to α1 weight as a subcomponent: Excellent.
ヒ素α００１〜ＬＩＬ１重量−，チタン０．０１〜１重
量％、クロム［１Ｌ０１〜１重量−、スズＣＬＯ１〜１
！Ｊｉ％、マグネシウム０．０１〜１重量−から成る群
より選択した１１ｉ！ｉもしくは２種以上を総量で１０
０１〜２重量係添加した高力導電鋼合金を最終冷間圧延
後、２００〜５００℃で２〜２０時間熱処理１／ ｌ伸
び、ばね限界値５導電率を向上させる熱処理方法に関す
る。Arsenic α001~LIL1wt-, titanium 0.01~1wt%, chromium [1L01~1wt-, tin CLO1~1
! 11i selected from the group consisting of Ji%, magnesium 0.01-1 wt. i or 2 or more types in total 10
This invention relates to a heat treatment method for improving the conductivity of a high-strength conductive steel alloy with a weight ratio of 01 to 2, after final cold rolling, at 200 to 500°C for 2 to 20 hours to improve elongation of 1/l and spring limit value of 5.
これＫより１本発明の熱処理後、第１図乃至に３図に示
すように、引張り強度を低下させずに、伸び、ばね限界
値および導電率を著しく向上させることができた。After the heat treatment of the present invention, as shown in FIGS. 1 to 3, the elongation, spring limit value, and electrical conductivity were significantly improved without decreasing the tensile strength.
前記熱処理温度を２００℃〜５００℃に限定したのは、
２００℃未満では熱処理効果が現われず、また５００℃
を越える温度では短時間で軟化してしまい所定の強度が
得られないためである。そして最も好ましい熱処理温度
は３００℃〜４００℃である。The heat treatment temperature was limited to 200°C to 500°C because
The heat treatment effect does not appear below 200℃, and below 500℃
This is because if the temperature exceeds 1000 yen, the material will soften in a short period of time and the desired strength will not be obtained. The most preferable heat treatment temperature is 300°C to 400°C.
また熱処理時間を２〜２０時間に限定したのは、２時間
未満では材料特性が安定せず、２０時間を越える熱処理
時間では経済的価値がなくなるからである。The reason why the heat treatment time is limited to 2 to 20 hours is because the material properties will not be stabilized if the heat treatment time is less than 2 hours, and the economic value will be lost if the heat treatment time exceeds 20 hours.
次に１本発明の詳細な説明する。Next, one aspect of the present invention will be explained in detail.
実施例
第１表に示した組成の合金を溶解し、厚さ１００ｇ１Ｍ
の鋳塊を得た。次に鋳塊を約８００℃で熱間圧延し厚さ
Ｚ５■の条件にした後表面を面側する。そして冷間圧延
で厚さ１５−にした後、８００℃で１分間の熱処理を施
し、最終冷間圧延で厚さ０７簡にし３５０℃で４時間熱
処理する。この試料を５重量−の硫酸で約１０秒間酸洗
し引張強さ、伸び、ばね限界値、導電率を測定し第２表
を得た。Example An alloy having the composition shown in Table 1 was melted to a thickness of 100g1M.
An ingot was obtained. Next, the ingot was hot-rolled at about 800°C to a thickness of Z5cm, and then the surface was side-faced. Then, after cold rolling to a thickness of 15 -, heat treatment is performed at 800°C for 1 minute, and final cold rolling is performed to a thickness of 07°, followed by heat treatment at 350°C for 4 hours. This sample was pickled with 5 weight of sulfuric acid for about 10 seconds, and the tensile strength, elongation, spring limit value, and electrical conductivity were measured, and Table 2 was obtained.
この第２表よ如熱処理後２％に伸び、ばね限界値が著し
く犬きくなシ、また導電率も高くなっている。Table 2 shows that after heat treatment, the elasticity increased by 2%, the spring limit value became significantly sharper, and the electrical conductivity also increased.
第１表 化学組成 単位；重ＢＳ
５−
以上の実施例および第１．２．５図より本発明の熱処理
方法で、特に伸び、ばね限界値、導電率が向上し、黄銅
の代替として電気機器用ばねや端子、コネクター等に使
用できる。Table 1 Chemical composition Unit: Heavy BS 5- From the above examples and Figure 1.2.5, the heat treatment method of the present invention improves elongation, spring limit value, and electrical conductivity, and can be used as a substitute for brass in electrical equipment. Can be used for springs, terminals, connectors, etc.
第１図は、熱処理前後の引張強さと伸びの関係を表わす
グラフ、第２図は、熱処理前後の引張強さとばね限界値
を表わすグラフ、第３図は。
熱処理前後の引張強さと導電率を表わすグラフを示して
いる。
特許出願人 日本鉱業株式会社
代理人 弁理士（７５６９）並川啓志
第２図
１泰か理崩′皮ａ５１５り執０１４゛わ限η僧の開イ姐
懺（、＠、に＠炙（り、Ｗｌ、５灸吏玖ざヒ贋轢びヤク
ル肖１本ご１脹旗さく鵠／ｍｍ２）
手続補正１゛（方式）
昭和５７年２月１タ日
特許庁長官 島 １）春 樹 殿
１、事件の表示
昭和５６年特許願第１２５２１９号
２、発明の名称
高力導電銅合金の熱処理方法
３、補正をする者
事件との関係 特許出願人
住所 東京都港区虎ノ門二丁目１０番１号名称 日本鉱
業株式会社
代表者 佐々木 陽 信
４、代 理 人 〒１０５電話５８２−２１１１住所
東京都港区虎ノ門二丁目１０番１号５、補正命令の日付
昭和５７年１月５日（昭和５７年１月２６日発送）６、
補正の対象
図面
Ｚ補正の内容
別紙のとおシ
５１５１ｔＲさ （ｋｇ／ｍｍ２）FIG. 1 is a graph showing the relationship between tensile strength and elongation before and after heat treatment, FIG. 2 is a graph showing the tensile strength and spring limit value before and after heat treatment, and FIG. 3 is a graph showing the spring limit value. A graph showing tensile strength and electrical conductivity before and after heat treatment is shown. Patent applicant Nippon Mining Co., Ltd. Agent Patent attorney (7569) Keishi Namikawa Wl, 5. Forgery of Yakuru Portraits (1 bottle, 1 flag, 1 mm2) Procedural amendment 1゛ (Method) February 1, 1980 Commissioner of the Japan Patent Office Shima 1) Haruki Tono 1, Case Indication of Patent Application No. 125219 No. 125219 of 1981 2, Name of the invention Heat treatment method for high strength conductive copper alloy 3, Relationship to the case of the person making the amendment Patent applicant address 2-10-1 Toranomon, Minato-ku, Tokyo Name Japan Mining Co., Ltd. Representative Yoshin Sasaki 4, Agent Address: 105 Phone: 582-2111
2-10-1-5 Toranomon, Minato-ku, Tokyo, date of amendment order: January 5, 1982 (shipped on January 26, 1981) 6.
Drawing Z subject to correction Contents of correction Attached sheet 5151tR (kg/mm2)
Claims (2)
３重量％、亜鉛１０〜３５重量％及びそれに付随する不
純物と残部銅からなる高力導電銅合金を最終冷間圧延後
、２００〜５００℃で２〜２０時間熱処理し、伸び、ば
ね限界値、導電率を向上させる熱処理方法。(1) Nickel 0.4~8% by weight, silicon 0.1~
After final cold rolling, a high-strength conductive copper alloy consisting of 3% by weight of zinc, 10-35% by weight of zinc and accompanying impurities, and the balance copper is heat-treated at 200-500°C for 2-20 hours to improve elongation, spring limit value, Heat treatment method to improve electrical conductivity.
チ、亜鉛１０〜３５重量％及びそれに付随する不純物と
残部銅から成る合金に副成分として。 リ ン ｏ、ｏｏ １〜
ｏ、［ｔｉｆＬ ％ヒ 素
０．００１〜ｌ１１ 重ｉチチ タ ン
［１０１〜１ 重−７％り ロ ム
０．０１ 〜１ 重量％ス ズ
０．０１〜１ 重量％マグネシウム
１０１〜１重量％から成る群より選択された１種もしく
は２種以上を総量で０．００１〜２重量嗟添加した高力
導電銅合金を最終冷間圧延後、２００〜５００℃で２〜
２０時間熱処理し、伸び、ばね限界値。 導電率を向上させる熱処理方法。(2) As a subcomponent in an alloy consisting of 0.4 to 8% by weight of nickel, 01 to 3 layers of silicon, 10 to 35% by weight of zinc, impurities associated therewith, and the balance copper. Rin o, oo 1~
o, [tifL% arsenic
0.001～l11 Heavy titanium
[101~1 weight -7% rom
0.01 to 1% by weight tin
0.01-1 wt% magnesium
After final cold rolling, a high-strength conductive copper alloy containing one or more selected from the group consisting of 101 to 1% by weight in a total amount of 0.001 to 2% by weight is heated at 200 to 500°C.
Heat treated for 20 hours, elongation and spring limit values. Heat treatment method to improve electrical conductivity.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12521981A JPS5827966A (en) | 1981-08-12 | 1981-08-12 | Heat treatment of high strength electrically conductive copper alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12521981A JPS5827966A (en) | 1981-08-12 | 1981-08-12 | Heat treatment of high strength electrically conductive copper alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5827966A true JPS5827966A (en) | 1983-02-18 |
Family
ID=14904795
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12521981A Pending JPS5827966A (en) | 1981-08-12 | 1981-08-12 | Heat treatment of high strength electrically conductive copper alloy |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5827966A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60115506U (en) * | 1984-01-13 | 1985-08-05 | 株式会社クボタ | Sediment basin machinery and equipment |
| JPS61109812A (en) * | 1984-11-01 | 1986-05-28 | Kintaro Kurita | Cleaner for river |
| JPS61238948A (en) * | 1985-04-15 | 1986-10-24 | Furukawa Electric Co Ltd:The | Manufacture of copper alloy material for lead frame |
| JPS6421024A (en) * | 1987-07-16 | 1989-01-24 | Furukawa Electric Co Ltd | Bending-resisting cable conductor |
| US5977859A (en) * | 1997-01-13 | 1999-11-02 | Pacific Engineering Company | Multielectrode type fuse element and multielectrode type fuse using the same |
-
1981
- 1981-08-12 JP JP12521981A patent/JPS5827966A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60115506U (en) * | 1984-01-13 | 1985-08-05 | 株式会社クボタ | Sediment basin machinery and equipment |
| JPS61109812A (en) * | 1984-11-01 | 1986-05-28 | Kintaro Kurita | Cleaner for river |
| JPS61238948A (en) * | 1985-04-15 | 1986-10-24 | Furukawa Electric Co Ltd:The | Manufacture of copper alloy material for lead frame |
| JPS6421024A (en) * | 1987-07-16 | 1989-01-24 | Furukawa Electric Co Ltd | Bending-resisting cable conductor |
| US5977859A (en) * | 1997-01-13 | 1999-11-02 | Pacific Engineering Company | Multielectrode type fuse element and multielectrode type fuse using the same |
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