JPS582306A - ポリオレフインの製造方法 - Google Patents
ポリオレフインの製造方法Info
- Publication number
- JPS582306A JPS582306A JP57104073A JP10407382A JPS582306A JP S582306 A JPS582306 A JP S582306A JP 57104073 A JP57104073 A JP 57104073A JP 10407382 A JP10407382 A JP 10407382A JP S582306 A JPS582306 A JP S582306A
- Authority
- JP
- Japan
- Prior art keywords
- magnesium
- reaction
- temperature
- formula
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title description 6
- 229920000098 polyolefin Polymers 0.000 title description 6
- 239000003054 catalyst Substances 0.000 claims description 33
- 238000006116 polymerization reaction Methods 0.000 claims description 32
- 239000007787 solid Substances 0.000 claims description 26
- 239000007795 chemical reaction product Substances 0.000 claims description 22
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 229930195733 hydrocarbon Natural products 0.000 claims description 17
- 150000002430 hydrocarbons Chemical class 0.000 claims description 16
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 10
- 239000011541 reaction mixture Substances 0.000 claims description 10
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 9
- 239000011777 magnesium Substances 0.000 claims description 9
- 229910052749 magnesium Inorganic materials 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 150000001348 alkyl chlorides Chemical class 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 5
- 230000000737 periodic effect Effects 0.000 claims description 4
- 230000000379 polymerizing effect Effects 0.000 claims description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims 2
- -1 polyethylene Polymers 0.000 description 46
- 239000004698 Polyethylene Substances 0.000 description 39
- 229920000573 polyethylene Polymers 0.000 description 39
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 28
- 239000005977 Ethylene Substances 0.000 description 28
- 239000000843 powder Substances 0.000 description 23
- 239000010936 titanium Substances 0.000 description 23
- 239000002283 diesel fuel Substances 0.000 description 19
- 229920000642 polymer Polymers 0.000 description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
- 239000000203 mixture Substances 0.000 description 14
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 13
- 238000009826 distribution Methods 0.000 description 13
- 229910052719 titanium Inorganic materials 0.000 description 13
- 239000006185 dispersion Substances 0.000 description 12
- 239000007789 gas Substances 0.000 description 12
- 239000000725 suspension Substances 0.000 description 11
- 229910052782 aluminium Inorganic materials 0.000 description 10
- 230000035484 reaction time Effects 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 238000010557 suspension polymerization reaction Methods 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000010992 reflux Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- CRGZYKWWYNQGEC-UHFFFAOYSA-N magnesium;methanolate Chemical compound [Mg+2].[O-]C.[O-]C CRGZYKWWYNQGEC-UHFFFAOYSA-N 0.000 description 4
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 4
- 239000012299 nitrogen atmosphere Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 235000011089 carbon dioxide Nutrition 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 150000002902 organometallic compounds Chemical class 0.000 description 3
- 239000002685 polymerization catalyst Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000010414 supernatant solution Substances 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- 150000003682 vanadium compounds Chemical class 0.000 description 3
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 2
- SXSVTGQIXJXKJR-UHFFFAOYSA-N [Mg].[Ti] Chemical compound [Mg].[Ti] SXSVTGQIXJXKJR-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910021570 Manganese(II) fluoride Inorganic materials 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 101100219264 Petunia hybrida C4H2 gene Proteins 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910021552 Vanadium(IV) chloride Inorganic materials 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 238000004737 colorimetric analysis Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- CTNMMTCXUUFYAP-UHFFFAOYSA-L difluoromanganese Chemical compound F[Mn]F CTNMMTCXUUFYAP-UHFFFAOYSA-L 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- ULYZAYCEDJDHCC-UHFFFAOYSA-N isopropyl chloride Chemical compound CC(C)Cl ULYZAYCEDJDHCC-UHFFFAOYSA-N 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- LMHHRCOWPQNFTF-UHFFFAOYSA-N s-propan-2-yl azepane-1-carbothioate Chemical compound CC(C)SC(=O)N1CCCCCC1 LMHHRCOWPQNFTF-UHFFFAOYSA-N 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- CMWCOKOTCLFJOP-UHFFFAOYSA-N titanium(3+) Chemical compound [Ti+3] CMWCOKOTCLFJOP-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3124223.5 | 1981-06-20 | ||
| DE19813124223 DE3124223A1 (de) | 1981-06-20 | 1981-06-20 | "verfahren zur herstellung eines polyolefins und katalysator hierfuer" |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS582306A true JPS582306A (ja) | 1983-01-07 |
| JPH0415806B2 JPH0415806B2 (enExample) | 1992-03-19 |
Family
ID=6134984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57104073A Granted JPS582306A (ja) | 1981-06-20 | 1982-06-18 | ポリオレフインの製造方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4447587A (enExample) |
| EP (1) | EP0068257B1 (enExample) |
| JP (1) | JPS582306A (enExample) |
| AR (1) | AR244715A1 (enExample) |
| AU (1) | AU550824B2 (enExample) |
| BR (1) | BR8203592A (enExample) |
| CA (1) | CA1207498A (enExample) |
| DE (2) | DE3124223A1 (enExample) |
| ES (1) | ES8304163A1 (enExample) |
| IN (1) | IN157122B (enExample) |
| ZA (1) | ZA824319B (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6131401A (ja) * | 1984-07-24 | 1986-02-13 | Ube Ind Ltd | エチレンの重合法 |
| JP2008530323A (ja) * | 2005-02-16 | 2008-08-07 | バーゼル・ポリオレフィン・ゲーエムベーハー | １−オレフィン（コ）ポリマーの製造方法 |
| JP2012072229A (ja) * | 2010-09-28 | 2012-04-12 | Japan Polyethylene Corp | チーグラー・ナッタ触媒の改質方法および改質されたチーグラー・ナッタ触媒、並びにそれを用いたオレフィンの重合方法および得られたオレフィン系重合体 |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3538099A1 (de) * | 1985-10-26 | 1987-04-30 | Ruhrchemie Ag | Verfahren zur homo- und mischpolymerisation von olefinen |
| US4698323A (en) * | 1986-09-29 | 1987-10-06 | Stauffer Chemical Company | Transition metal catalyst component containing magnesium alkoxy alkoxides |
| DE3918646A1 (de) * | 1989-06-08 | 1990-12-13 | Hoechst Ag | Verfahren zur herstellung eines poly-l-olefins |
| US5286694A (en) * | 1991-12-11 | 1994-02-15 | Phillips Petroleum Company | Lanthanide halide catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
| DE19945980A1 (de) | 1999-09-24 | 2001-03-29 | Elenac Gmbh | Polyethylen Formmasse mit verbesserter ESCR-Steifigkeitsrelation und Schwellrate, Verfahren zu ihrer Herstellung und daraus hergestellte Hohlkörper |
| DE10122111B4 (de) * | 2001-05-08 | 2007-03-01 | Ticona Gmbh | Verfahren zur Herstellung von Olefinpolymeren, sowie ausgewählte Katalysatoren |
| KR20050088310A (ko) * | 2002-12-19 | 2005-09-05 | 바젤 폴리올레핀 게엠베하 | 소형 콘테이너 생산을 위한 폴리에틸렌 취입 성형 조성물 |
| DE60306811T2 (de) * | 2002-12-24 | 2007-02-22 | Basell Polyolefine Gmbh | Polyethylen Formmasse zum Herstellen von Behältern durch Blasformen und damit hergestellte L-Ring-Conrainer |
| JP2006512474A (ja) * | 2002-12-24 | 2006-04-13 | バーゼル・ポリオレフィン・ゲーエムベーハー | ジェリー缶を製造するためのポリエチレン吹込成形用組成物 |
| KR20050088113A (ko) * | 2002-12-24 | 2005-09-01 | 바젤 폴리올레핀 게엠베하 | 대형 콘테이너를 위한 폴리에틸렌 취입 성형 조성물 |
| CN100349413C (zh) * | 2004-11-15 | 2007-11-14 | 华为技术有限公司 | 智能网中的业务调用方法 |
| DE102004055587A1 (de) | 2004-11-18 | 2006-05-24 | Basell Polyolefine Gmbh | Polyethylen Formmasse für die äußere Ummantelung von Elektrokabeln |
| DE102004055588A1 (de) | 2004-11-18 | 2006-05-24 | Basell Polyolefine Gmbh | Polyethylen Formmasse für die Beschichtung von Stahlrohren |
| DE102005009896A1 (de) | 2005-03-01 | 2006-09-07 | Basell Polyolefine Gmbh | Polyethylen Formmasse zum Herstellen von Blasfolien mit verbesserten mechanischen Eigenschaften |
| DE102005009916A1 (de) | 2005-03-01 | 2006-09-07 | Basell Polyolefine Gmbh | Polyethylen Formmasse zum Herstellen von Blasfolien mit verbesserten mechanischen Eigenschaften |
| DE102005009895A1 (de) * | 2005-03-01 | 2006-09-07 | Basell Polyolefine Gmbh | Polyethylen Formmasse zum Herstellen von Blasfolien mit verbesserten mechanischen Eigenschaften |
| DE102005030941A1 (de) * | 2005-06-30 | 2007-01-11 | Basell Polyolefine Gmbh | Polyethylen Formmasse zur Herstellung von spritzgegossenen Fertigteilen |
| DE102005040390A1 (de) * | 2005-08-25 | 2007-03-01 | Basell Polyolefine Gmbh | Multimodale Polyethylen Formmasse zur Herstellung von Rohren mit verbesserten mechanischen Eigenschaften |
| KR101229632B1 (ko) * | 2005-09-28 | 2013-02-05 | 고에키자이단호진 고쿠사이카가쿠 신고우자이단 | 분위기 제어된 접합 장치, 접합 방법 및 전자 장치 |
| WO2010139419A2 (en) | 2009-06-03 | 2010-12-09 | Basell Polyolefine Gmbh | Polyethylene composition and finished products made thereof |
| ES2421297T3 (es) | 2009-06-30 | 2013-08-30 | Basell Polyolefine Gmbh | Composición para el moldeo de polietileno |
| US8728970B2 (en) | 2009-08-06 | 2014-05-20 | Basell Polyolefine Gmbh | Catalyst component for the polymerization of olefins |
| BR112012009515A2 (pt) * | 2009-10-22 | 2017-02-21 | Basell Polyolefine Gmbh | "componentes catalíticos para a polimerização de olefinas e catalisadores obtidos a partir dos mesmos" |
| KR20120095454A (ko) | 2009-12-23 | 2012-08-28 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 올레핀 중합용 촉매 성분 및 이로부터 수득되는 촉매 |
| US11214633B2 (en) | 2019-09-10 | 2022-01-04 | Braskem America, Inc. | Ziegler-Natta catalyst systems and methods of controlling particle size |
| TWI877448B (zh) * | 2021-02-01 | 2025-03-21 | 大陸商中國石油化工科技開發有限公司 | 乙烯聚合物及其製備方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57158204A (en) * | 1981-03-25 | 1982-09-30 | Mitsui Petrochem Ind Ltd | Modification of titanium catalytic component and modified titanium catalytic component |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3644318A (en) * | 1968-08-21 | 1972-02-22 | Hoechst Ag | Process for the polymerization of olefins |
| GB1275641A (en) * | 1969-01-06 | 1972-05-24 | Solvay | Catalysts for the polymerisation and copolymerisation of olefins |
| DE2830929A1 (de) * | 1978-07-14 | 1980-01-24 | Basf Ag | Verfahren zum herstellen einer titan-komponente fuer polymerisationskatalysatoren des ziegler-natta-typs |
-
1981
- 1981-06-20 DE DE19813124223 patent/DE3124223A1/de not_active Withdrawn
-
1982
- 1982-06-14 ES ES513076A patent/ES8304163A1/es not_active Expired
- 1982-06-14 EP EP82105165A patent/EP0068257B1/de not_active Expired
- 1982-06-14 US US06/388,023 patent/US4447587A/en not_active Expired - Lifetime
- 1982-06-14 IN IN682/CAL/82A patent/IN157122B/en unknown
- 1982-06-14 DE DE8282105165T patent/DE3263246D1/de not_active Expired
- 1982-06-18 JP JP57104073A patent/JPS582306A/ja active Granted
- 1982-06-18 CA CA000405526A patent/CA1207498A/en not_active Expired
- 1982-06-18 BR BR8203592A patent/BR8203592A/pt not_active IP Right Cessation
- 1982-06-18 AU AU84993/82A patent/AU550824B2/en not_active Ceased
- 1982-06-18 ZA ZA824319A patent/ZA824319B/xx unknown
- 1982-06-18 AR AR82289719A patent/AR244715A1/es active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57158204A (en) * | 1981-03-25 | 1982-09-30 | Mitsui Petrochem Ind Ltd | Modification of titanium catalytic component and modified titanium catalytic component |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6131401A (ja) * | 1984-07-24 | 1986-02-13 | Ube Ind Ltd | エチレンの重合法 |
| JP2008530323A (ja) * | 2005-02-16 | 2008-08-07 | バーゼル・ポリオレフィン・ゲーエムベーハー | １−オレフィン（コ）ポリマーの製造方法 |
| JP4916454B2 (ja) * | 2005-02-16 | 2012-04-11 | バーゼル・ポリオレフィン・ゲーエムベーハー | １−オレフィン（コ）ポリマーの製造方法 |
| JP2012072229A (ja) * | 2010-09-28 | 2012-04-12 | Japan Polyethylene Corp | チーグラー・ナッタ触媒の改質方法および改質されたチーグラー・ナッタ触媒、並びにそれを用いたオレフィンの重合方法および得られたオレフィン系重合体 |
Also Published As
| Publication number | Publication date |
|---|---|
| US4447587A (en) | 1984-05-08 |
| BR8203592A (pt) | 1983-06-14 |
| IN157122B (enExample) | 1986-01-18 |
| AU550824B2 (en) | 1986-04-10 |
| CA1207498A (en) | 1986-07-08 |
| EP0068257B1 (de) | 1985-04-24 |
| JPH0415806B2 (enExample) | 1992-03-19 |
| DE3124223A1 (de) | 1982-12-30 |
| ES513076A0 (es) | 1983-03-01 |
| ZA824319B (en) | 1983-04-27 |
| EP0068257A1 (de) | 1983-01-05 |
| ES8304163A1 (es) | 1983-03-01 |
| DE3263246D1 (en) | 1985-05-30 |
| AR244715A1 (es) | 1993-11-30 |
| AU8499382A (en) | 1983-01-06 |
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