JPS5816536A - Manufacture of semiconductor device - Google Patents
Manufacture of semiconductor deviceInfo
- Publication number
- JPS5816536A JPS5816536A JP11444081A JP11444081A JPS5816536A JP S5816536 A JPS5816536 A JP S5816536A JP 11444081 A JP11444081 A JP 11444081A JP 11444081 A JP11444081 A JP 11444081A JP S5816536 A JPS5816536 A JP S5816536A
- Authority
- JP
- Japan
- Prior art keywords
- film
- layer
- sio2
- bsg
- grown
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004065 semiconductor Substances 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title claims description 11
- 238000005229 chemical vapour deposition Methods 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000000758 substrate Substances 0.000 claims abstract description 8
- 229910052796 boron Inorganic materials 0.000 claims abstract description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000001681 protective effect Effects 0.000 claims abstract description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 3
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 3
- 229920005591 polysilicon Polymers 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 22
- 229910052681 coesite Inorganic materials 0.000 abstract description 11
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 11
- 239000000377 silicon dioxide Substances 0.000 abstract description 11
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 11
- 229910052682 stishovite Inorganic materials 0.000 abstract description 11
- 229910052905 tridymite Inorganic materials 0.000 abstract description 11
- 238000009792 diffusion process Methods 0.000 abstract description 4
- 238000000059 patterning Methods 0.000 abstract description 3
- 239000012535 impurity Substances 0.000 abstract description 2
- 239000005380 borophosphosilicate glass Substances 0.000 description 12
- 238000005530 etching Methods 0.000 description 10
- 230000007547 defect Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- 101100130497 Drosophila melanogaster Mical gene Proteins 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 101100345589 Mus musculus Mical1 gene Proteins 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 102220043690 rs1049562 Human genes 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000001947 vapour-phase growth Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Local Oxidation Of Silicon (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
- Formation Of Insulating Films (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は半導体装置の製造方法に係り、特にポリシリコ
ン等の配線層を有する素子表面にCVD法によりBPS
G膜を始めとする保護膜が形成されているMO8型半導
体装置の製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for manufacturing a semiconductor device, and in particular to a method for manufacturing a semiconductor device, in particular, BPS is applied to the surface of an element having a wiring layer such as polysilicon by a CVD method.
The present invention relates to a method of manufacturing an MO8 type semiconductor device in which a protective film such as a G film is formed.
一般に集積回路等の半導体装置の製造においては、熱酸
化法に代えて製造条件に余裕度のめるCVD法(Che
mical Vapour Deposition
化学反応を用いた気相成長法)により各種酸化膜を形
成することが多用されはじめている。ところでCVD法
により酸化膜を形成する場合、酸化膜中にヒロックと称
する突起物が成長することがある。Generally, in the manufacture of semiconductor devices such as integrated circuits, the CVD method (CVD method), which allows for a certain degree of leeway in the manufacturing conditions, is used instead of the thermal oxidation method.
Mical Vapor Deposition
Formation of various oxide films by a vapor phase growth method using chemical reactions has begun to be frequently used. By the way, when forming an oxide film by the CVD method, protrusions called hillocks may grow in the oxide film.
特に半導体基板上にゲートとなるポリシリコン(以下P
−8iと称す)層を有するMO8型半導体装置では、素
子表面を滑らかな形状とするためのメルト用のBPSG
膜(ボロンと燐を含むSiOzm)を比較的厚く成長さ
せる必要があってヒロックが発生し易い。そのため塗布
したレジストがヒロックのところで薄くなった9、マス
クの損傷によりマスク欠陥が発生して不必要な開孔が生
じ、しかもヒロックとBPSG膜との界面はエツチング
液が浸透し易いのでその開孔は5PSG膜の下層の深い
所まで及ぶ。In particular, polysilicon (hereinafter P
In MO8 type semiconductor devices having a layer (referred to as -8i), BPSG for melting is used to make the element surface smooth.
It is necessary to grow the film (SiOzm containing boron and phosphorus) relatively thickly, and hillocks are likely to occur. As a result, the applied resist became thinner at the hillocks9, and mask defects occurred due to damage to the mask, resulting in unnecessary openings.Moreover, etching solution easily penetrates the interface between the hillocks and the BPSG film, so the openings extends deep into the lower layer of the 5PSG film.
例えば第1図はMO8型トランジスタを示したもので、
ゲートとなるp−s;5.1上にtJmされた5102
膜2.5PSG膜3はCVD法により形成されており、
エツチングによって5P8Gl1% 3の生長時に発生
したヒロックが原因となった欠陥孔4が開孔されている
。そのため基板5のドレイン(またはソースノとなる拡
散層6にコンタクトするkl配線層7によって拡散層6
とP−8i層1とが接続され素子機能が損なわれている
。なお6′はソース(またはドレイン)となる拡散層、
7′は拡散層6′にコンタクトとするAl配線層、8は
P二S1層1を基板5と絶縁する5I02膜である。For example, Figure 1 shows an MO8 type transistor.
p-s to be the gate; 5102 with tJm on 5.1
Film 2.5PSG film 3 is formed by CVD method,
Defect holes 4 caused by hillocks generated during the growth of 5P8Gl1%3 are opened by etching. Therefore, the diffusion layer 6 can be
and P-8i layer 1 are connected, and the device function is impaired. Note that 6' is a diffusion layer that becomes a source (or drain);
Reference numeral 7' is an Al interconnection layer that contacts the diffusion layer 6', and 8 is a 5I02 film that insulates the P2S1 layer 1 from the substrate 5.
このようにMO8型半導体装置ではP−8i層による表
面段差構造を解消するためにCVD法によりBPSG膜
を形成することが行なわれるので、BP8G膜生長時に
発生するヒロックを原因とする欠陥孔により配線ショー
トが生じ製造歩留りが低下していた。In this way, in MO8 type semiconductor devices, a BPSG film is formed by the CVD method in order to eliminate the surface step structure caused by the P-8i layer. Short circuits occurred and manufacturing yields decreased.
本発明はかかる従来の難点に鑑みなされたもので、その
特徴とするところはP−8i層とBPSG膜との間にS
in、膜の代りにB8′G膜を形成し、該BSG 膜の
エツチング速度が遅いことを利用してBPSG膜にヒロ
ックが存在しても不必要な欠陥孔が下層のP−8i層ま
で到達しないようにし、Al配線層によってP−8i層
と、半導体領域との電気的接触が生ずるのを防止した点
にある。The present invention was made in view of such conventional difficulties, and its feature is that S
In, a B8'G film is formed instead of the BSG film, and by taking advantage of the slow etching rate of the BSG film, even if there are hillocks in the BPSG film, unnecessary defect holes can reach the underlying P-8i layer. This is to prevent electrical contact between the P-8i layer and the semiconductor region due to the Al wiring layer.
以下本発明を図面に基づいて実施例につき詳細に説明す
る。The present invention will be described in detail below with reference to the drawings.
本発明においてはP−8i層を含む素子表面を保護する
膜として、CVD法によりBSG膜(ポロンを含む5i
n2膜)を形成し、次いでBPSG膜を形成するもので
ある。これは素子表面構造を平滑にするためのBPSG
膜成長時にヒロックが発生してもBSG膜のエツチング
速度が遅いため、BPSG膜に半導体領域とのコンタク
ト用の穴を開孔する際のヒロック部分からのエツチング
液の浸透を小さくできるためである。通常BP8G膜に
コンタクト穴を開孔するに先立って乾燥N2中で約10
00℃、10分程度の熱処理を施すメルトを行なうが、
この熱処理後のエッチング1速度についていえば、容積
比HF:NH,F :H20=6 : 40 : 54
の25°Cのエツチング液に対してBPSG膜、5in
2膜では約1400A/分程度であるのに対しBSGj
良(ポロン濃度約5 X 10”/c++! )では約
1oooX/分とエツチング速度が遅い。In the present invention, a BSG film (5i containing poron
n2 film) and then a BPSG film. This is BPSG for smoothing the element surface structure.
This is because even if hillocks occur during film growth, the etching rate of the BSG film is slow, so that it is possible to reduce penetration of the etching solution from the hillock portions when forming holes in the BPSG film for contact with the semiconductor region. Typically, prior to drilling contact holes in the BP8G membrane, approximately 10
Melting is performed by heat treatment at 00℃ for about 10 minutes.
Regarding the etching rate after this heat treatment, the volume ratio HF:NH,F:H20=6:40:54
BPSG film, 5in.
BSGj
At a good etching rate (Poron concentration of about 5 x 10''/c++!), the etching rate is about 1 oooX/min.
まずSi基板90表面にSiO2層10を形成し、次い
でこの上にP−8i層を成長させたのちバターニングを
行ないゲート用P−8i層11を形成する(第2図)。First, a SiO2 layer 10 is formed on the surface of a Si substrate 90, and then a P-8i layer is grown thereon, followed by patterning to form a P-8i layer 11 for a gate (FIG. 2).
次に数10OA程度のSiO2膜12をP−8i層11
の周囲に形成したのち、CVD法によりB10膜を成長
させバターニングを行なってB8G膜13およびSin
、、膜10に第1回目のコンタクト穴14.14′を開
孔する(第3図)。この5102膜12は以後の工程で
の熱処理によってBSGS電膜からポロンがP−8i層
11へ拡散するのを防止するために設けるものである。Next, a SiO2 film 12 of approximately several tens of OA is applied to the P-8i layer 11.
After forming around the B8G film 13 and the Sin
,, a first contact hole 14, 14' is drilled in the membrane 10 (FIG. 3). This 5102 film 12 is provided to prevent poron from diffusing from the BSGS electrical film into the P-8i layer 11 during heat treatment in subsequent steps.
次いでCVD法によってBPSG膜15を成長させたの
ち乾燥N2中で1000°Cの熱処理を約10公租度加
え、BPSG膜をメルトして表面を平滑にし、次いでバ
ターニングを行なってBPSG膜15に第2回目のコン
タクト16.16′を開孔する(第4図)。このときB
PSG膜15の成長に伴なってヒロックが発生し、コン
タクト穴16.16′の開孔に使用するエツチング液に
よってヒロックの部分から不要な欠陥孔17が形成され
ることがあるが、BSGS電膜のエツチング速度が遅い
ため欠陥孔17がP−8i層11に達するのを容易に防
げる。続いて基板9に不純物を拡散してドレイン18、
ソース18′を形成したのちAlを蒸着してドレイン1
8、ソース18′にそれぞれコンタクトするAl配線層
19.19′を形成するとMO8型トランジスタができ
(第5図)、Al配線層19によるドレイン18とP−
8i層11との間の電気的接触は生じない。Next, the BPSG film 15 is grown by the CVD method, and then heat treated at 1000°C in dry N2 for about 10 degrees to melt the BPSG film and smooth the surface. A second contact 16.16' is drilled (Fig. 4). At this time B
Hillocks may occur as the PSG film 15 grows, and unnecessary defective holes 17 may be formed from the hillocks by the etching solution used to open the contact holes 16 and 16'. Since the etching speed is slow, defect holes 17 can be easily prevented from reaching the P-8i layer 11. Subsequently, impurities are diffused into the substrate 9 to form the drain 18,
After forming the source 18', Al is deposited to form the drain 1.
8. By forming Al wiring layers 19 and 19' in contact with the source 18', an MO8 type transistor is formed (Fig. 5), and the drain 18 and P-
No electrical contact occurs with the 8i layer 11.
以上の説明ではSi基板上にP−8iの配線層が形成さ
れたMO8型半導体装置について述べたが、本発明はこ
れに限られるものではなく、P−8iの代りに隅温に耐
え得る配線材料であるモリブデン等の金属を用いた場合
にも適用でき、この場合にはボロ/拡散防止用の5in
2膜12が省略できる。In the above explanation, an MO8 type semiconductor device in which a P-8i wiring layer is formed on a Si substrate has been described, but the present invention is not limited to this. It can also be applied when using a metal such as molybdenum as a material, and in this case, a 5 inch
2 membranes 12 can be omitted.
以上説明したように本発明によれば、P−8i等の配線
層を含む素子表面にCVD法により順次BSG膜、BP
SG膜を形成しているので、BPSG膜成長時にヒロッ
クが発生しても不必要な欠陥孔が深く開孔されることを
防止でき、その後のAl配線により半導体領域とP−8
’>等の配線層との間に電気的接続が生じることが防げ
、装置の製造歩留りが向上する。As explained above, according to the present invention, a BSG film and a BP film are sequentially formed on the surface of an element including a wiring layer such as P-8i by the CVD method.
Since the SG film is formed, even if hillocks occur during the growth of the BPSG film, unnecessary defect holes can be prevented from being drilled deeply.
It is possible to prevent electrical connection from occurring between wiring layers such as '>, etc., and improve the manufacturing yield of the device.
第1図は従来のMO8型トランジスタの断面図、第2図
〜第5図は本発明方法によるMO8型トランジスタの製
造を説明するためのy面図である。
9・・・・・・Si基板
10・・・・・SiO2膜
11・・・・・・P−8i配線層
13・・・・・・BSG腺
15・・・・・・BPSG、膜
(7’317)代理人 弁理士 則 ユ1ヱ 尉 ?
f5(ほか1名)
第 l 図
第 2 図
第 3 図
第4 図
第 6 図
んFIG. 1 is a sectional view of a conventional MO8 type transistor, and FIGS. 2 to 5 are y-plane views for explaining the manufacture of the MO8 type transistor by the method of the present invention. 9...Si substrate 10...SiO2 film 11...P-8i wiring layer 13...BSG gland 15...BPSG, film (7 '317) Agent Patent Attorney Rule Yu1e Lieutenant?
f5 (1 other person) Figure l Figure 2 Figure 3 Figure 4 Figure 6
Claims (1)
線層を形成し、次いでこの上に保護膜を形成する半導体
装置の製造方法において、前記保護膜を、CVD法によ
りボロンを含むS iO,膜、ボロンと燐とを含むSN
O2膜を順次成長させて形成することを特徴とする半導
体装置の製造方法。In a method for manufacturing a semiconductor device in which a wiring layer such as polysilicon is formed on a Si substrate via an 8i02 film, and then a protective film is formed on the wiring layer, the protective film is formed by a CVD method using an SiO film containing boron. , SN containing boron and phosphorus
A method for manufacturing a semiconductor device, characterized in that an O2 film is sequentially grown.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11444081A JPS5816536A (en) | 1981-07-23 | 1981-07-23 | Manufacture of semiconductor device |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11444081A JPS5816536A (en) | 1981-07-23 | 1981-07-23 | Manufacture of semiconductor device |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5816536A true JPS5816536A (en) | 1983-01-31 |
Family
ID=14637782
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11444081A Pending JPS5816536A (en) | 1981-07-23 | 1981-07-23 | Manufacture of semiconductor device |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5816536A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6376459A (en) * | 1986-09-15 | 1988-04-06 | ワトキンズ‐ジョンソン コムパニー | Boron silicate glass film for multilayer metallic structure in semiconductor device and manufacture of the same |
-
1981
- 1981-07-23 JP JP11444081A patent/JPS5816536A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6376459A (en) * | 1986-09-15 | 1988-04-06 | ワトキンズ‐ジョンソン コムパニー | Boron silicate glass film for multilayer metallic structure in semiconductor device and manufacture of the same |
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