JPS5735537A - Preparation of hexachloroacetone - Google Patents

Preparation of hexachloroacetone

Info

Publication number
JPS5735537A
JPS5735537A JP11038680A JP11038680A JPS5735537A JP S5735537 A JPS5735537 A JP S5735537A JP 11038680 A JP11038680 A JP 11038680A JP 11038680 A JP11038680 A JP 11038680A JP S5735537 A JPS5735537 A JP S5735537A
Authority
JP
Japan
Prior art keywords
chlorine
chlorinated
acetone
phosphine
average
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP11038680A
Other languages
Japanese (ja)
Other versions
JPS6116255B2 (en
Inventor
Yasuo Hibino
Akira Negishi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Central Glass Co Ltd
Original Assignee
Central Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Central Glass Co Ltd filed Critical Central Glass Co Ltd
Priority to JP11038680A priority Critical patent/JPS6116255B2/ja
Priority to IT2346881A priority patent/IT1138147B/en
Priority to FR8115641A priority patent/FR2488602B1/en
Priority to DE19813131895 priority patent/DE3131895C2/en
Priority to GB8124769A priority patent/GB2082180B/en
Publication of JPS5735537A publication Critical patent/JPS5735537A/en
Publication of JPS6116255B2 publication Critical patent/JPS6116255B2/ja
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/63Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms

Abstract

PURPOSE: To obtain the titled compound useful as an intermediate for a medicine, agricultural chemical, etc. in high yield and purity efficiently, by reacting a low chlorinated acetone with chlorine under heating in the presence of a phosphine or its mixture with an organic base as a catalyst.
CONSTITUTION: Acetone is catalytically reacted with chlorine in the vapor phase at 70W100°C, and the formed acetone chlorinated to 1.6W1.8 substituent chlorine atoms on an average is absorbed in an organic solvent to react with excess chlorine. The resultant chlorinated acetone containing 2W2.5 chlorine atoms on an average is then chlorinated with chlorine in the presence of a catalyst consisting of a phosphine, e.g. tri-n-butylphosphine or diphenylphosphine (except triphenylphosphine), alone or its mixture with an organic base, e.g. an amine such as pyridine or quinoline, under heating at 60W150°C to give hexachloroacetone.
USE: A raw material for preparing trichloroacetic acid and chloroform, a raw material for preparing hexafluoroacetone, etc.
COPYRIGHT: (C)1982,JPO&Japio
JP11038680A 1980-08-13 1980-08-13 Expired JPS6116255B2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP11038680A JPS6116255B2 (en) 1980-08-13 1980-08-13
IT2346881A IT1138147B (en) 1980-08-13 1981-08-11 PROCEDURE FOR THE PREPARATION OF HEXACLOROACETONE USING A PHOSPHINE CATALYST TO COMPLETE THE CHLORURATION
FR8115641A FR2488602B1 (en) 1980-08-13 1981-08-12 PROCESS FOR THE PREPARATION OF HEXACHLOROACETONE
DE19813131895 DE3131895C2 (en) 1980-08-13 1981-08-12 Process for the production of hexachloroacetone
GB8124769A GB2082180B (en) 1980-08-13 1981-08-13 Process of preparing hexachloroacetone using phosphine catalyst to complete chlorination

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11038680A JPS6116255B2 (en) 1980-08-13 1980-08-13

Publications (2)

Publication Number Publication Date
JPS5735537A true JPS5735537A (en) 1982-02-26
JPS6116255B2 JPS6116255B2 (en) 1986-04-28

Family

ID=14534484

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11038680A Expired JPS6116255B2 (en) 1980-08-13 1980-08-13

Country Status (5)

Country Link
JP (1) JPS6116255B2 (en)
DE (1) DE3131895C2 (en)
FR (1) FR2488602B1 (en)
GB (1) GB2082180B (en)
IT (1) IT1138147B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015105078A1 (en) * 2014-01-08 2015-07-16 旭硝子株式会社 Production method for hexachloroacetone

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2453615T3 (en) 2007-12-03 2014-04-08 Asahi Glass Company, Limited Procedure for the production of a carbonate compound
EP2218708B1 (en) 2007-12-03 2014-06-25 Asahi Glass Company, Limited Method for producing carbonate compound
RU2012120335A (en) 2009-11-17 2013-12-27 Асахи Гласс Компани, Лимитед. METHOD FOR PRODUCING POLYCARBONATE
SG11201500988VA (en) 2012-08-10 2015-04-29 Asahi Glass Co Ltd Method for producing carbonate compound and method for producing aromatic polycarbonate
ES2664979T3 (en) 2012-12-06 2018-04-24 Asahi Glass Company, Limited Method to produce carbonate compound

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2635117A (en) * 1949-05-12 1953-04-14 Allied Chem & Dye Corp Preparation of polychloroacetones
US3265740A (en) * 1962-07-11 1966-08-09 Du Pont Process for chlorinating acetone and acetylacetone
US3988369A (en) * 1974-09-26 1976-10-26 Pearson Donald E Process and reactant for halogenating organic compounds

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015105078A1 (en) * 2014-01-08 2015-07-16 旭硝子株式会社 Production method for hexachloroacetone
JPWO2015105078A1 (en) * 2014-01-08 2017-03-23 旭硝子株式会社 Method for producing hexachloroacetone
US9745241B2 (en) 2014-01-08 2017-08-29 Asahi Glass Company, Limited Production method for hexachloroacetone

Also Published As

Publication number Publication date
IT8123468D0 (en) 1981-08-11
DE3131895A1 (en) 1982-03-25
FR2488602B1 (en) 1985-07-05
GB2082180A (en) 1982-03-03
DE3131895C2 (en) 1984-10-31
GB2082180B (en) 1984-07-11
JPS6116255B2 (en) 1986-04-28
FR2488602A1 (en) 1982-02-19
IT1138147B (en) 1986-09-17

Similar Documents

Publication Publication Date Title
JPS5867647A (en) Preparation of malonic diester
JPS5735537A (en) Preparation of hexachloroacetone
JPS56139436A (en) Preparation of hexachloroacetone
JPS5772921A (en) Preparation of acetylenic ketone
JPH01106835A (en) Method for synthesizing p-tertiary-butoxystyrene
JPS58206564A (en) Preparation of beta-chloropyridine compound
JPS63145262A (en) Production of trifluoromethylbenzonitrile
JPS59139329A (en) Preparation of 4-fluorobenzotrifluoride
JPS5791982A (en) Preparation of 5-methylfurfural
JPS5559121A (en) 1-halo-3-decyne compound
JPH0217163A (en) Production of diaminomaleonitrile and diaminoacrylonitrile derivative
JPS6067454A (en) Production of polychlorobenzonitrile
JPS61155350A (en) Production of fatty acid chloride and aromatic acid chloride
JPS60188349A (en) Preparation of 2,3-dichloro-6-nitrophenol
JPH03178973A (en) Production of isocumarins
JPS6445A (en) Production of 2-chloropropionaldehyde
JPH04108745A (en) Production of trifluorohydrocarbon compound
JPS56115776A (en) Preparation of 2-bromo-trifluoromethylpyridine
JPS6219541A (en) Production of fluorobenzene
JPS5659727A (en) Preparation of substituted phenol
JPS5649324A (en) Preparation of acetylene derivative
JPH01121267A (en) Production of pyridine polyhalide
JPS5959643A (en) Preparation of perfluoroacyl chloride
JPS6054336A (en) Preparation of 8-methyl-trans-6-nonenoic acid
JPH03170450A (en) Production of alkynylketone derivative