JPS5735537A - Preparation of hexachloroacetone - Google Patents

Preparation of hexachloroacetone

Info

Publication number
JPS5735537A
JPS5735537A JP11038680A JP11038680A JPS5735537A JP S5735537 A JPS5735537 A JP S5735537A JP 11038680 A JP11038680 A JP 11038680A JP 11038680 A JP11038680 A JP 11038680A JP S5735537 A JPS5735537 A JP S5735537A
Authority
JP
Japan
Prior art keywords
chlorine
chlorinated
acetone
phosphine
average
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP11038680A
Other languages
Japanese (ja)
Other versions
JPS6116255B2 (en
Inventor
Yasuo Hibino
Akira Negishi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Central Glass Co Ltd
Original Assignee
Central Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Central Glass Co Ltd filed Critical Central Glass Co Ltd
Priority to JP11038680A priority Critical patent/JPS5735537A/en
Priority to IT23468/81A priority patent/IT1138147B/en
Priority to DE3131895A priority patent/DE3131895C2/en
Priority to FR8115641A priority patent/FR2488602B1/en
Priority to GB8124769A priority patent/GB2082180B/en
Publication of JPS5735537A publication Critical patent/JPS5735537A/en
Publication of JPS6116255B2 publication Critical patent/JPS6116255B2/ja
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/63—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To obtain the titled compound useful as an intermediate for a medicine, agricultural chemical, etc. in high yield and purity efficiently, by reacting a low chlorinated acetone with chlorine under heating in the presence of a phosphine or its mixture with an organic base as a catalyst.
CONSTITUTION: Acetone is catalytically reacted with chlorine in the vapor phase at 70W100°C, and the formed acetone chlorinated to 1.6W1.8 substituent chlorine atoms on an average is absorbed in an organic solvent to react with excess chlorine. The resultant chlorinated acetone containing 2W2.5 chlorine atoms on an average is then chlorinated with chlorine in the presence of a catalyst consisting of a phosphine, e.g. tri-n-butylphosphine or diphenylphosphine (except triphenylphosphine), alone or its mixture with an organic base, e.g. an amine such as pyridine or quinoline, under heating at 60W150°C to give hexachloroacetone.
USE: A raw material for preparing trichloroacetic acid and chloroform, a raw material for preparing hexafluoroacetone, etc.
COPYRIGHT: (C)1982,JPO&Japio
JP11038680A 1980-08-13 1980-08-13 Preparation of hexachloroacetone Granted JPS5735537A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP11038680A JPS5735537A (en) 1980-08-13 1980-08-13 Preparation of hexachloroacetone
IT23468/81A IT1138147B (en) 1980-08-13 1981-08-11 PROCEDURE FOR THE PREPARATION OF HEXACLOROACETONE USING A PHOSPHINE CATALYST TO COMPLETE THE CHLORURATION
DE3131895A DE3131895C2 (en) 1980-08-13 1981-08-12 Process for the production of hexachloroacetone
FR8115641A FR2488602B1 (en) 1980-08-13 1981-08-12 PROCESS FOR THE PREPARATION OF HEXACHLOROACETONE
GB8124769A GB2082180B (en) 1980-08-13 1981-08-13 Process of preparing hexachloroacetone using phosphine catalyst to complete chlorination

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11038680A JPS5735537A (en) 1980-08-13 1980-08-13 Preparation of hexachloroacetone

Publications (2)

Publication Number Publication Date
JPS5735537A true JPS5735537A (en) 1982-02-26
JPS6116255B2 JPS6116255B2 (en) 1986-04-28

Family

ID=14534484

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11038680A Granted JPS5735537A (en) 1980-08-13 1980-08-13 Preparation of hexachloroacetone

Country Status (5)

Country Link
JP (1) JPS5735537A (en)
DE (1) DE3131895C2 (en)
FR (1) FR2488602B1 (en)
GB (1) GB2082180B (en)
IT (1) IT1138147B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015105078A1 (en) * 2014-01-08 2015-07-16 旭硝子株式会社 Production method for hexachloroacetone

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5458891B2 (en) 2007-12-03 2014-04-02 旭硝子株式会社 Method for producing carbonate compound
KR101556421B1 (en) 2007-12-03 2015-10-01 아사히 가라스 가부시키가이샤 Method for producing carbonate compound
BR112012011814A2 (en) 2009-11-17 2019-09-24 Asahi Glass Co Ltd polycarbonate production process
IN2015DN01009A (en) 2012-08-10 2015-06-12 Asahi Glass Co Ltd
JP6229663B2 (en) 2012-12-06 2017-11-15 旭硝子株式会社 Method for producing carbonate compound

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2635117A (en) * 1949-05-12 1953-04-14 Allied Chem & Dye Corp Preparation of polychloroacetones
US3265740A (en) * 1962-07-11 1966-08-09 Du Pont Process for chlorinating acetone and acetylacetone
US3988369A (en) * 1974-09-26 1976-10-26 Pearson Donald E Process and reactant for halogenating organic compounds

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015105078A1 (en) * 2014-01-08 2015-07-16 旭硝子株式会社 Production method for hexachloroacetone
JPWO2015105078A1 (en) * 2014-01-08 2017-03-23 旭硝子株式会社 Method for producing hexachloroacetone
US9745241B2 (en) 2014-01-08 2017-08-29 Asahi Glass Company, Limited Production method for hexachloroacetone

Also Published As

Publication number Publication date
IT8123468A0 (en) 1981-08-11
GB2082180A (en) 1982-03-03
FR2488602A1 (en) 1982-02-19
FR2488602B1 (en) 1985-07-05
DE3131895A1 (en) 1982-03-25
DE3131895C2 (en) 1984-10-31
JPS6116255B2 (en) 1986-04-28
GB2082180B (en) 1984-07-11
IT1138147B (en) 1986-09-17

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