JPS57171949A - Preparation of p-isocyanatobenzoyl chloride - Google Patents
Preparation of p-isocyanatobenzoyl chlorideInfo
- Publication number
- JPS57171949A JPS57171949A JP5796981A JP5796981A JPS57171949A JP S57171949 A JPS57171949 A JP S57171949A JP 5796981 A JP5796981 A JP 5796981A JP 5796981 A JP5796981 A JP 5796981A JP S57171949 A JPS57171949 A JP S57171949A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- reacting
- thionyl chloride
- phosphorus pentachloride
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To prepare the titled compound useful as a synthetic raw material of pharmaceuticals, polymers, etc., in high efficiency, by reacting p-{N-(alkoxycarbonyl)-amino}benzoic acid with phosphorus pentachloride or thionyl chloride.
CONSTITUTION: The compound of formula II can be prepared by reacting 1mol of the compound of formulaI(R is alkyl or aralkyl) with ≥2mol of phosphorus pentachloride or thionyl chloride at 80W110°C in the absence of solvent, or preferably in an inert organic solvent such as benzene. The amount of phosphorus pentachloride or thionyl chloride is preferably 2.1W2.5mol or 15W20mol per 1mol of the compound of formulaIto improve the yield. The compound of formulaIused as a starting raw material can be prepared easily by reacting p-aminobenzoic acid with chloroformic acid ester in an alkaline aqueous solution.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5796981A JPS57171949A (en) | 1981-04-17 | 1981-04-17 | Preparation of p-isocyanatobenzoyl chloride |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5796981A JPS57171949A (en) | 1981-04-17 | 1981-04-17 | Preparation of p-isocyanatobenzoyl chloride |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS57171949A true JPS57171949A (en) | 1982-10-22 |
Family
ID=13070835
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5796981A Pending JPS57171949A (en) | 1981-04-17 | 1981-04-17 | Preparation of p-isocyanatobenzoyl chloride |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57171949A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62116592A (en) * | 1985-10-17 | 1987-05-28 | イミユノメデイツクス、インコ−ポレイテツド | Difunctional linker |
US4873232A (en) * | 1986-10-29 | 1989-10-10 | Syntex | Novel use for carbamoyl benzoates |
-
1981
- 1981-04-17 JP JP5796981A patent/JPS57171949A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62116592A (en) * | 1985-10-17 | 1987-05-28 | イミユノメデイツクス、インコ−ポレイテツド | Difunctional linker |
US4873232A (en) * | 1986-10-29 | 1989-10-10 | Syntex | Novel use for carbamoyl benzoates |
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