JPS5686154A - Preparation of indole or its derivative - Google Patents

Preparation of indole or its derivative

Info

Publication number
JPS5686154A
JPS5686154A JP16162879A JP16162879A JPS5686154A JP S5686154 A JPS5686154 A JP S5686154A JP 16162879 A JP16162879 A JP 16162879A JP 16162879 A JP16162879 A JP 16162879A JP S5686154 A JPS5686154 A JP S5686154A
Authority
JP
Japan
Prior art keywords
phosphate
aniline
derivative
silver
ethylene glycol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP16162879A
Other languages
Japanese (ja)
Other versions
JPS6251267B2 (en
Inventor
Fujio Matsuda
Kozo Kato
Original Assignee
Mitsui Toatsu Chem Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Toatsu Chem Inc filed Critical Mitsui Toatsu Chem Inc
Priority to JP54161628A priority Critical patent/JPS6251267B2/ja
Publication of JPS5686154A publication Critical patent/JPS5686154A/en
Publication of JPS6251267B2 publication Critical patent/JPS6251267B2/ja
Expired legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

PURPOSE: To obtain the high-purity titled compound by one step, by reacting an inexpensive aniline with ethylene glycol as raw materials in a gas phase in the presence of a catalyst selected from the group consisting of cadmium phosphate, zinc phosphate, aluminum phosphate, boron phosphate, and silver.
CONSTITUTION: In the presence of one or more catalysts selected from the group consisting of cadmium phosphate, zinc phosphate, aluminum phosphate, boron phosphate, and silver, 1mol of an aniline (e.g., aniline, p-toluidine, etc.) is reacted with 0.05W2mol ethylene glycol at 250W400°C in a gas phase to give indole or its derivative (e.g., 5-methylindole, etc.).
EFFECT: A very small amount of by-products occurs, and the selectivity is superior.
USE: A raw material for synthesizing spice and an amino acid.
COPYRIGHT: (C)1981,JPO&Japio
JP54161628A 1979-12-14 1979-12-14 Expired JPS6251267B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP54161628A JPS6251267B2 (en) 1979-12-14 1979-12-14

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP54161628A JPS6251267B2 (en) 1979-12-14 1979-12-14

Publications (2)

Publication Number Publication Date
JPS5686154A true JPS5686154A (en) 1981-07-13
JPS6251267B2 JPS6251267B2 (en) 1987-10-29

Family

ID=15738790

Family Applications (1)

Application Number Title Priority Date Filing Date
JP54161628A Expired JPS6251267B2 (en) 1979-12-14 1979-12-14

Country Status (1)

Country Link
JP (1) JPS6251267B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5846067A (en) * 1981-09-14 1983-03-17 Mitsui Toatsu Chem Inc Preparation of indole
JPS5955869A (en) * 1982-09-22 1984-03-31 Mitsui Toatsu Chem Inc Preparation of indole compound
US4474997A (en) * 1982-07-06 1984-10-02 E. I. Du Pont De Nemours And Company Oxidation process and catalyst therefor
US4937353A (en) * 1982-06-24 1990-06-26 Mitsui Toatsu Chemicals, Incorporated Preparation process for indoles

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5846067A (en) * 1981-09-14 1983-03-17 Mitsui Toatsu Chem Inc Preparation of indole
JPH0243738B2 (en) * 1981-09-14 1990-10-01 Mitsui Toatsu Chemicals
US4937353A (en) * 1982-06-24 1990-06-26 Mitsui Toatsu Chemicals, Incorporated Preparation process for indoles
US4474997A (en) * 1982-07-06 1984-10-02 E. I. Du Pont De Nemours And Company Oxidation process and catalyst therefor
JPS5955869A (en) * 1982-09-22 1984-03-31 Mitsui Toatsu Chem Inc Preparation of indole compound
JPH0347263B2 (en) * 1982-09-22 1991-07-18 Mitsui Toatsu Chemicals

Also Published As

Publication number Publication date
JPS6251267B2 (en) 1987-10-29

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