JPS5625133A - Preparation of fluorine-containing carboxylic acid ester - Google Patents
Preparation of fluorine-containing carboxylic acid esterInfo
- Publication number
- JPS5625133A JPS5625133A JP9982979A JP9982979A JPS5625133A JP S5625133 A JPS5625133 A JP S5625133A JP 9982979 A JP9982979 A JP 9982979A JP 9982979 A JP9982979 A JP 9982979A JP S5625133 A JPS5625133 A JP S5625133A
- Authority
- JP
- Japan
- Prior art keywords
- carboxylic acid
- acid ester
- formula
- fluorine
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To link a carboxylic acid ester group to the difficulty linkable carbon atom in the α- or β-position to the ether oxygen, by the reaction of an α,β-unsaturated ether compound containing a fluorine atom with an ester of a halogenized formic acid, in the presence of a fluoride.
CONSTITUTION: (a) An α,β-unsaturated ether compound containing a fluorine atom, preferably having a structure of formula I (A, B, and E are Fs, or trifluoromethyls) in the molecule, e.g. CF2=CF-O-C3H7, is reacted with (b) an ester of a halogenized formic acid or an acid halogenide having a carboxylic acid ester group, that is, a compound of formula II or III (X is halogen; R1 is 1W12C alkyl, etc.), e.g. FOC-COOCH3, in the presence of a fluoride, e.g. cesium fluoride, preferably at 80W170°C, to give the object compound of formula IV, etc.
USE: An intermediate for synthesis, etc.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9982979A JPS5625133A (en) | 1979-08-07 | 1979-08-07 | Preparation of fluorine-containing carboxylic acid ester |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9982979A JPS5625133A (en) | 1979-08-07 | 1979-08-07 | Preparation of fluorine-containing carboxylic acid ester |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5625133A true JPS5625133A (en) | 1981-03-10 |
JPS626701B2 JPS626701B2 (en) | 1987-02-13 |
Family
ID=14257700
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP9982979A Granted JPS5625133A (en) | 1979-08-07 | 1979-08-07 | Preparation of fluorine-containing carboxylic acid ester |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5625133A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5991932A (en) * | 1982-11-17 | 1984-05-26 | 松下電器産業株式会社 | Cutter for cooker |
JPH0646721U (en) * | 1992-12-03 | 1994-06-28 | パラマウントベッド株式会社 | Frame structure in bed |
US11535579B2 (en) | 2017-12-13 | 2022-12-27 | 3M Innovative Properties Company | Hydrofluoroolefin ethers, compositions, apparatuses and methods for using same |
US11551827B2 (en) | 2017-12-13 | 2023-01-10 | 3M Innovative Properties Company | Perfluorinated 1-alkoxypropenes in dielectric fluids and electrical devices |
US11673861B2 (en) | 2017-12-13 | 2023-06-13 | 3M Innovative Properties Company | Perfluorinated 1-alkoxypropenes, compositions, and methods and apparatuses for using same |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01155026U (en) * | 1988-04-08 | 1989-10-25 |
-
1979
- 1979-08-07 JP JP9982979A patent/JPS5625133A/en active Granted
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5991932A (en) * | 1982-11-17 | 1984-05-26 | 松下電器産業株式会社 | Cutter for cooker |
JPH0646721U (en) * | 1992-12-03 | 1994-06-28 | パラマウントベッド株式会社 | Frame structure in bed |
US11535579B2 (en) | 2017-12-13 | 2022-12-27 | 3M Innovative Properties Company | Hydrofluoroolefin ethers, compositions, apparatuses and methods for using same |
US11551827B2 (en) | 2017-12-13 | 2023-01-10 | 3M Innovative Properties Company | Perfluorinated 1-alkoxypropenes in dielectric fluids and electrical devices |
US11673861B2 (en) | 2017-12-13 | 2023-06-13 | 3M Innovative Properties Company | Perfluorinated 1-alkoxypropenes, compositions, and methods and apparatuses for using same |
Also Published As
Publication number | Publication date |
---|---|
JPS626701B2 (en) | 1987-02-13 |
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