JPS5622325A - Production of polymerizable organopolysiloxane - Google Patents
Production of polymerizable organopolysiloxaneInfo
- Publication number
- JPS5622325A JPS5622325A JP9758779A JP9758779A JPS5622325A JP S5622325 A JPS5622325 A JP S5622325A JP 9758779 A JP9758779 A JP 9758779A JP 9758779 A JP9758779 A JP 9758779A JP S5622325 A JPS5622325 A JP S5622325A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- group
- monovalent hydrocarbyl
- acid
- hydrocarbyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001296 polysiloxane Polymers 0.000 title abstract 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 3
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 2
- 125000003700 epoxy group Chemical group 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- -1 alkali metal salt Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 230000009257 reactivity Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Landscapes
- Macromonomer-Based Addition Polymer (AREA)
- Silicon Polymers (AREA)
Abstract
PURPOSE: To obtain, in high purity and yield, a polymerizable organopolysiloxane without using an organic solvent, by reacting an epoxy group-containing organopolysiloxane with (meth)acrylic acid in the presence of a metal salt of the acid.
CONSTITUTION: A polymerizable organopolysiloxane represented by formula III, wherein R2 is H or methyl, B is a monovalent hydrocarbyl group or a group of formula IV, is prepared by reacting acrylic acid or methacrylic acid with an epoxy group-containing organopolysiloxane represented by formula I, wherein R1 is a monovalent hydrocarbyl group, A is a monovalent hydrocarbyl group or a group of formula II, a is 0, 1 or 2, n is 1W5, and m is 1W4, in the presence of an alkali metal salt of acrylic or methacrylic acid. It is preferred from a point of reactivity, yield, etc., that R1 in said formula I is a 1W4C alkyl or phenyl.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP54097587A JPS6017377B2 (en) | 1979-07-31 | 1979-07-31 | Method for producing polymerizable organopolysiloxane |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP54097587A JPS6017377B2 (en) | 1979-07-31 | 1979-07-31 | Method for producing polymerizable organopolysiloxane |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5622325A true JPS5622325A (en) | 1981-03-02 |
JPS6017377B2 JPS6017377B2 (en) | 1985-05-02 |
Family
ID=14196361
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP54097587A Expired JPS6017377B2 (en) | 1979-07-31 | 1979-07-31 | Method for producing polymerizable organopolysiloxane |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6017377B2 (en) |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58213024A (en) * | 1982-05-06 | 1983-12-10 | ゼネラル・エレクトリツク・カンパニイ | Epoxy and/or acryl functional group-containing ultraviolet ray hardenable silicone releasing composition |
JP2004507513A (en) * | 2000-08-28 | 2004-03-11 | アプリリス,インコーポレイテッド | Holographic storage media containing polyfunctional epoxy monomers capable of performing cationic polymerization |
JP2005023011A (en) * | 2003-07-01 | 2005-01-27 | Toray Ind Inc | Method for refining silicone agent |
JP2005170827A (en) * | 2003-12-10 | 2005-06-30 | Toray Ind Inc | Method for manufacturing silicone compound and silicone agent |
WO2005090364A1 (en) | 2004-02-27 | 2005-09-29 | Toray Industries, Inc. | Silicone compound and process for producing the same |
JP2005272459A (en) * | 2004-02-27 | 2005-10-06 | Toray Ind Inc | Silicone compound and its production method |
WO2010024372A1 (en) * | 2008-08-28 | 2010-03-04 | 日油株式会社 | Silicone monomer and manufacturing method and usage thereof |
WO2010082659A1 (en) * | 2009-01-19 | 2010-07-22 | 日油株式会社 | Silicone monomer |
US8053539B2 (en) * | 2006-06-30 | 2011-11-08 | Johnson & Johnson Vision Care Inc. | Siloxanyl materials for molded plastics |
US8080622B2 (en) | 2007-06-29 | 2011-12-20 | Johnson & Johnson Vision Care, Inc. | Soluble silicone prepolymers |
CN105085562A (en) * | 2006-09-29 | 2015-11-25 | 庄臣及庄臣视力保护公司 | Process of producing hydrolysis-resistant polysilicone compounds |
JP2016153390A (en) * | 2009-09-02 | 2016-08-25 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | Silicone modified fatty acids, method of preparation and usage thereof |
WO2019107117A1 (en) | 2017-11-29 | 2019-06-06 | 信越化学工業株式会社 | Siloxane compound and method for producing same |
WO2020246313A1 (en) | 2019-06-06 | 2020-12-10 | 信越化学工業株式会社 | Siloxane and method for producing same |
JP2021161091A (en) * | 2020-04-02 | 2021-10-11 | 信越化学工業株式会社 | Silicone compound production method |
WO2022196721A1 (en) | 2021-03-17 | 2022-09-22 | 信越化学工業株式会社 | Siloxane compound and method for producing same |
WO2022196720A1 (en) | 2021-03-17 | 2022-09-22 | 信越化学工業株式会社 | Siloxane compound and method for producing same |
-
1979
- 1979-07-31 JP JP54097587A patent/JPS6017377B2/en not_active Expired
Cited By (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0427254B2 (en) * | 1982-05-06 | 1992-05-11 | Gen Electric | |
JPS58213024A (en) * | 1982-05-06 | 1983-12-10 | ゼネラル・エレクトリツク・カンパニイ | Epoxy and/or acryl functional group-containing ultraviolet ray hardenable silicone releasing composition |
JP2004507513A (en) * | 2000-08-28 | 2004-03-11 | アプリリス,インコーポレイテッド | Holographic storage media containing polyfunctional epoxy monomers capable of performing cationic polymerization |
JP4720072B2 (en) * | 2003-07-01 | 2011-07-13 | 東レ株式会社 | Method for purifying silicone agent and silicone agent |
JP2005023011A (en) * | 2003-07-01 | 2005-01-27 | Toray Ind Inc | Method for refining silicone agent |
JP2005170827A (en) * | 2003-12-10 | 2005-06-30 | Toray Ind Inc | Method for manufacturing silicone compound and silicone agent |
JP4507580B2 (en) * | 2003-12-10 | 2010-07-21 | 東レ株式会社 | Method for producing silicone compound and silicone agent |
WO2005090364A1 (en) | 2004-02-27 | 2005-09-29 | Toray Industries, Inc. | Silicone compound and process for producing the same |
JP2005272459A (en) * | 2004-02-27 | 2005-10-06 | Toray Ind Inc | Silicone compound and its production method |
US7683206B2 (en) * | 2004-02-27 | 2010-03-23 | Toray Industries, Inc. | Silicone compound and process for producing the same |
US8053539B2 (en) * | 2006-06-30 | 2011-11-08 | Johnson & Johnson Vision Care Inc. | Siloxanyl materials for molded plastics |
CN105085562A (en) * | 2006-09-29 | 2015-11-25 | 庄臣及庄臣视力保护公司 | Process of producing hydrolysis-resistant polysilicone compounds |
US8080622B2 (en) | 2007-06-29 | 2011-12-20 | Johnson & Johnson Vision Care, Inc. | Soluble silicone prepolymers |
WO2010024372A1 (en) * | 2008-08-28 | 2010-03-04 | 日油株式会社 | Silicone monomer and manufacturing method and usage thereof |
JP5402934B2 (en) * | 2008-08-28 | 2014-01-29 | 日油株式会社 | Silicone monomer, its production method and use |
WO2010082659A1 (en) * | 2009-01-19 | 2010-07-22 | 日油株式会社 | Silicone monomer |
US8481608B2 (en) | 2009-01-19 | 2013-07-09 | Nof Corporation | Silicone monomer |
JP5505313B2 (en) * | 2009-01-19 | 2014-05-28 | 日油株式会社 | Silicone monomer |
JP2016153390A (en) * | 2009-09-02 | 2016-08-25 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | Silicone modified fatty acids, method of preparation and usage thereof |
WO2019107117A1 (en) | 2017-11-29 | 2019-06-06 | 信越化学工業株式会社 | Siloxane compound and method for producing same |
KR20200089692A (en) | 2017-11-29 | 2020-07-27 | 신에쓰 가가꾸 고교 가부시끼가이샤 | Siloxane compound and its manufacturing method |
WO2020246313A1 (en) | 2019-06-06 | 2020-12-10 | 信越化学工業株式会社 | Siloxane and method for producing same |
JP2020200365A (en) * | 2019-06-06 | 2020-12-17 | 信越化学工業株式会社 | Siloxane and method for producing the same |
CN113906037A (en) * | 2019-06-06 | 2022-01-07 | 信越化学工业株式会社 | Siloxane and preparation method thereof |
JP2021161091A (en) * | 2020-04-02 | 2021-10-11 | 信越化学工業株式会社 | Silicone compound production method |
WO2022196721A1 (en) | 2021-03-17 | 2022-09-22 | 信越化学工業株式会社 | Siloxane compound and method for producing same |
WO2022196720A1 (en) | 2021-03-17 | 2022-09-22 | 信越化学工業株式会社 | Siloxane compound and method for producing same |
Also Published As
Publication number | Publication date |
---|---|
JPS6017377B2 (en) | 1985-05-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS5622325A (en) | Production of polymerizable organopolysiloxane | |
JPS5378298A (en) | Preparation of curable resin | |
JPS543007A (en) | Preparation of glycidyl (meth)acrylate | |
JPS5232999A (en) | Process for preparing unsaturated epoxy esters having improved curabil ity | |
JPS5517307A (en) | Preparation of glycidyl ester of acrylic or methacrylic acid | |
JPS57146786A (en) | Optically active borane compound and preparation of optically active compound using the same | |
JPS5750953A (en) | Preparation of hydroxybenzonitriles | |
JPS5334714A (en) | Preparation of dialkylaminoalkyl acrylate and dialkylaminoalkyl methacrylate | |
JPS5212125A (en) | Process for preparation of oligoester (meth)acrylate emulsion | |
JPS56104851A (en) | Preparation of tertiary-butylaminoethyl methacrylate | |
JPS5412326A (en) | Preparation of trimethylgallium | |
JPS5419911A (en) | Preparation of dialkylaminoethyl ester of acrylic acid or methacrylic acid | |
JPS5424846A (en) | Preparation of substituted phenylacetic acid | |
JPS51127080A (en) | A process for preparing quisqualic acid. | |
JPS5783526A (en) | Preparation of polycarbonate | |
JPS5459223A (en) | Preparation of azo compounds | |
JPS51133228A (en) | Process for preparation of beta-methylglycidyl ester | |
JPS549233A (en) | Preparation of curable unsaturated compounds | |
JPS5377042A (en) | Preparation of optically active organic thiophosphotic acid | |
JPS57192345A (en) | Preparation of iminodiacetic acid ester | |
JPS53135922A (en) | Synthesis of 2-chloro-2-hydroxyiminoacetic acid alkyl ester | |
JPS54144320A (en) | Preparation of ureidomethylene malonic ester | |
JPS5412320A (en) | Preparation of 2-acetyl-3, 3-dimethyl-4-pentenoic acid ester | |
JPS57142960A (en) | Novel optically active 3-organosulfonyloxycarboxylic acid or its ester, and their preparation | |
JPS53147019A (en) | Preparation of fatty acid glycidyl ester |