JPS5549368A - Production of 2, 5-furandicarboxyaldehyde - Google Patents

Production of 2, 5-furandicarboxyaldehyde

Info

Publication number
JPS5549368A
JPS5549368A JP12323278A JP12323278A JPS5549368A JP S5549368 A JPS5549368 A JP S5549368A JP 12323278 A JP12323278 A JP 12323278A JP 12323278 A JP12323278 A JP 12323278A JP S5549368 A JPS5549368 A JP S5549368A
Authority
JP
Japan
Prior art keywords
furfral
hydroxymethyl
oxidized
organic solvent
dinitrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP12323278A
Other languages
Japanese (ja)
Inventor
Shunichi Morikawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Noguchi Institute
Original Assignee
Noguchi Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Noguchi Institute filed Critical Noguchi Institute
Priority to JP12323278A priority Critical patent/JPS5549368A/en
Publication of JPS5549368A publication Critical patent/JPS5549368A/en
Pending legal-status Critical Current

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  • Furan Compounds (AREA)

Abstract

PURPOSE: 5-Hydroxymethyl-2-furfral is oxidized with nitrogen oxides in an organic solvent to produce title compound useful as an intermediate of drug, agricultural chemical, perfume and furan resin readily in high yield with industrial advantage.
CONSTITUTION: 5-Hydroxymethyl-2-furfral readily obtained by dehydration of hexose under heating in the presence of an acidic catalyst is oxidized with an nitrogen oxide as dinitrogen tetraoxide, dinitrogen trioxide, nitric acid, nitrous acid, preferably dinitrogen tetraoxide, in an organic solvent as dimethyl sulfoxide or dimethoxyethane, preferably with dimethyl solfixide then nitric acid, to convert the primary alcohol selectively into aldehyde. The reaction temperature is 60W180, preferably 80W120°C and the amount of the oxidant used is more than 1.0, preferably 1.2W2.5 moles per mole of the starting material.
COPYRIGHT: (C)1980,JPO&Japio
JP12323278A 1978-10-06 1978-10-06 Production of 2, 5-furandicarboxyaldehyde Pending JPS5549368A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12323278A JPS5549368A (en) 1978-10-06 1978-10-06 Production of 2, 5-furandicarboxyaldehyde

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12323278A JPS5549368A (en) 1978-10-06 1978-10-06 Production of 2, 5-furandicarboxyaldehyde

Publications (1)

Publication Number Publication Date
JPS5549368A true JPS5549368A (en) 1980-04-09

Family

ID=14855462

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12323278A Pending JPS5549368A (en) 1978-10-06 1978-10-06 Production of 2, 5-furandicarboxyaldehyde

Country Status (1)

Country Link
JP (1) JPS5549368A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2669636A1 (en) * 1990-11-22 1992-05-29 Furchim Process for the manufacture of furan-2,5-dicarboxaldehyde
US6706900B2 (en) 2001-09-17 2004-03-16 E. I. Du Pont De Nemours And Company Process for preparing 2,5-diformylfuran from carbohydrates
JP2008162919A (en) * 2006-12-27 2008-07-17 Canon Inc Method for producing furan ring compound
US7700788B2 (en) 2006-10-31 2010-04-20 Battelle Memorial Institute Hydroxymethyl furfural oxidation methods
US7956203B2 (en) 2000-03-27 2011-06-07 E. I. Du Pont De Nemours And Company Oxidation of 5-(hydroxymethyl) furfural to 2,5-diformylfuran and subsequent decarbonylation to unsubstituted furan
DE102010030991A1 (en) * 2010-07-06 2012-01-12 Evonik Degussa Gmbh Process for the preparation of 2,5-diformylfuran and its derivatives
CN103113327A (en) * 2013-01-24 2013-05-22 四川大学 Method for synthesizing furan-2,5-dicarbaldehyde through one-step catalysis of carbohydrate

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2669636A1 (en) * 1990-11-22 1992-05-29 Furchim Process for the manufacture of furan-2,5-dicarboxaldehyde
US8524923B2 (en) 2000-03-27 2013-09-03 E I Du Pont De Nemours And Company Processes for preparing diacids, dialdehydes and polymers
US8785667B2 (en) 2000-03-27 2014-07-22 E I Du Pont De Nemours And Company Processes for preparing diacids, dialdehydes and polymers
US7956203B2 (en) 2000-03-27 2011-06-07 E. I. Du Pont De Nemours And Company Oxidation of 5-(hydroxymethyl) furfural to 2,5-diformylfuran and subsequent decarbonylation to unsubstituted furan
US8748637B2 (en) 2000-03-27 2014-06-10 E I Du Pont De Nemours And Company Processes for preparing diacids, dialdehydes and polymers
US8129550B2 (en) 2000-03-27 2012-03-06 E. I. Du Pont De Nemours And Company Oxidation of 5-(hydroxymethyl) furfural to 2,5 diformylfuran and subsequent decarbonylation to unsubstituted furan
US8748638B2 (en) 2000-03-27 2014-06-10 E I Du Pont De Nemours And Company Processes for preparing diacids, dialdehydes and polymers
US8575299B1 (en) 2000-03-27 2013-11-05 E I Du Pont De Nemours And Company Processes for preparing diacids, dialdehydes and polymers
US6706900B2 (en) 2001-09-17 2004-03-16 E. I. Du Pont De Nemours And Company Process for preparing 2,5-diformylfuran from carbohydrates
US7700788B2 (en) 2006-10-31 2010-04-20 Battelle Memorial Institute Hydroxymethyl furfural oxidation methods
US8193381B2 (en) 2006-10-31 2012-06-05 Battelle Memorial Institute Hydroxymethyl furfural oxidation methods
US8193382B2 (en) 2006-10-31 2012-06-05 Battelle Memorial Institute Hydroxymethyl furfural oxidation methods
JP2008162919A (en) * 2006-12-27 2008-07-17 Canon Inc Method for producing furan ring compound
DE102010030991A1 (en) * 2010-07-06 2012-01-12 Evonik Degussa Gmbh Process for the preparation of 2,5-diformylfuran and its derivatives
CN103113327A (en) * 2013-01-24 2013-05-22 四川大学 Method for synthesizing furan-2,5-dicarbaldehyde through one-step catalysis of carbohydrate

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