JPS55338A - Preparation of diacetoxybutene - Google Patents

Preparation of diacetoxybutene

Info

Publication number
JPS55338A
JPS55338A JP7389478A JP7389478A JPS55338A JP S55338 A JPS55338 A JP S55338A JP 7389478 A JP7389478 A JP 7389478A JP 7389478 A JP7389478 A JP 7389478A JP S55338 A JPS55338 A JP S55338A
Authority
JP
Japan
Prior art keywords
butadiene
effected
oxygen
acetic acid
catalytic activity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP7389478A
Other languages
Japanese (ja)
Other versions
JPS6146464B2 (en
Inventor
Takeshi Onoda
Akihisa Ono
Junzo Haji
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Kasei Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Priority to JP7389478A priority Critical patent/JPS55338A/en
Publication of JPS55338A publication Critical patent/JPS55338A/en
Publication of JPS6146464B2 publication Critical patent/JPS6146464B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: The reaction between 1,3-butadiene, oxygen, and acetic acid is effected in the presence of a solid catalyst obtained by adding at least one selected from Sb, As, and Tl to Rh, thus preventing the reduction of the catalytic activity and producing title compound that is used for the starting material of 1,4-butanediol with great advantage.
CONSTITUTION: In the presence of a Rh solid catalyst, the acetoxylation of 1,3- butadiene with oxygen and acetic acid is effected to produce diacetoxybutene, in which the Rh catalyst includes at least one selected from Sb, As, and Tl as the essential component. For example, rhodium acetate, antimony trioxide, arsenic oxide and thallium oxide are employed and the use of activated carbon or silica as a carrier is preferred. Calculated as the elements, the amount of Rh used is 0.5W5 wt%, Sb, As, or Tl is 0.1W5 wt%. Further, the reductive treatment after supporting each component on the carrier increases the catalytic activity.
EFFECT: The elucidation of Rh into the reaction mixture can be inhibited to minimum.
COPYRIGHT: (C)1980,JPO&Japio
JP7389478A 1978-06-19 1978-06-19 Preparation of diacetoxybutene Granted JPS55338A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7389478A JPS55338A (en) 1978-06-19 1978-06-19 Preparation of diacetoxybutene

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7389478A JPS55338A (en) 1978-06-19 1978-06-19 Preparation of diacetoxybutene

Publications (2)

Publication Number Publication Date
JPS55338A true JPS55338A (en) 1980-01-05
JPS6146464B2 JPS6146464B2 (en) 1986-10-14

Family

ID=13531357

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7389478A Granted JPS55338A (en) 1978-06-19 1978-06-19 Preparation of diacetoxybutene

Country Status (1)

Country Link
JP (1) JPS55338A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04117333A (en) * 1990-05-31 1992-04-17 Daikin Ind Ltd Production of 1-chloro-1,2,-trifluoroethylene and 1,2,2-trifluoroethylene

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52125106A (en) * 1976-04-13 1977-10-20 Asahi Chem Ind Co Ltd Production of diacyloxybutenes

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52125106A (en) * 1976-04-13 1977-10-20 Asahi Chem Ind Co Ltd Production of diacyloxybutenes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04117333A (en) * 1990-05-31 1992-04-17 Daikin Ind Ltd Production of 1-chloro-1,2,-trifluoroethylene and 1,2,2-trifluoroethylene

Also Published As

Publication number Publication date
JPS6146464B2 (en) 1986-10-14

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