JPS5479275A - 3-acyl-thiazolidine-2-thione and its preparation - Google Patents

3-acyl-thiazolidine-2-thione and its preparation

Info

Publication number
JPS5479275A
JPS5479275A JP14544877A JP14544877A JPS5479275A JP S5479275 A JPS5479275 A JP S5479275A JP 14544877 A JP14544877 A JP 14544877A JP 14544877 A JP14544877 A JP 14544877A JP S5479275 A JPS5479275 A JP S5479275A
Authority
JP
Japan
Prior art keywords
thione
compound
salt
thiazolidine
formulai
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP14544877A
Other languages
Japanese (ja)
Other versions
JPS564558B2 (en
Inventor
Mitsuaki Mukoyama
Toshio Izawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Kasei Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Priority to JP14544877A priority Critical patent/JPS5479275A/en
Publication of JPS5479275A publication Critical patent/JPS5479275A/en
Publication of JPS564558B2 publication Critical patent/JPS564558B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Thiazole And Isothizaole Compounds (AREA)

Abstract

NEW MATERIAL:3-Acylthiazolidine-3-thione of formulaI: (R1 is hydrocarbon group which may have an inert substituent).
EXAMPLE: 3-Benzoylthiazolidine-2-thione.
USE: Useful as an intermediate for synthesis because the compound can be readily led to an aldehyde by reduction with an organoaluminum monohalide or its complex compound, and by hydrolysis in a high yield.
PROCESS: A corboxylic acid of formula II is reacted with thiazolidine-2-thione of formula III in the presence of a tertiary amine and a quaternary ammonium salt of a heterocyclic compound wherein a halogen atom is bonded to the carbon atom adjacent to the nitrogen atom, e.g. 2-halobenzoxaxonium salt, such as a 2-halopyridinium salt, 2-chloro-3-methylbenzoxazonium chloride, etc. to give the compound of formulaI.
COPYRIGHT: (C)1979,JPO&Japio
JP14544877A 1977-12-03 1977-12-03 3-acyl-thiazolidine-2-thione and its preparation Granted JPS5479275A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14544877A JPS5479275A (en) 1977-12-03 1977-12-03 3-acyl-thiazolidine-2-thione and its preparation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14544877A JPS5479275A (en) 1977-12-03 1977-12-03 3-acyl-thiazolidine-2-thione and its preparation

Publications (2)

Publication Number Publication Date
JPS5479275A true JPS5479275A (en) 1979-06-25
JPS564558B2 JPS564558B2 (en) 1981-01-30

Family

ID=15385449

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14544877A Granted JPS5479275A (en) 1977-12-03 1977-12-03 3-acyl-thiazolidine-2-thione and its preparation

Country Status (1)

Country Link
JP (1) JPS5479275A (en)

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS=S5504ZZD CHEMISTRY LETTER=1975 *

Also Published As

Publication number Publication date
JPS564558B2 (en) 1981-01-30

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