JPS5470294A - Cephalosporin derivative and its preparation - Google Patents
Cephalosporin derivative and its preparationInfo
- Publication number
- JPS5470294A JPS5470294A JP13493977A JP13493977A JPS5470294A JP S5470294 A JPS5470294 A JP S5470294A JP 13493977 A JP13493977 A JP 13493977A JP 13493977 A JP13493977 A JP 13493977A JP S5470294 A JPS5470294 A JP S5470294A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- compound
- cephalosporin
- derivative
- antibiotic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Cephalosporin Compounds (AREA)
Abstract
PURPOSE: The halogenation of a novel silyl derivative of cephalosporin is conducted to form a novel halogen derivative, which is then hydrolyzed or reacted with a hydrazine to prepare cephalosporin derivative useful as an antibiotic in high yield.
CONSTITUTION: The silylation product of a compound of formula I (R1 is H, lower alkoxy; R2 is amino, acylamino, imide) is subjected to halogenaton with molecular chlorine or bromine to form a compound of formula II. The hydrolysis of the product of formula II is conducted in a solvent of dioxane or acetone to obtain the compound of formula III. Or a compound of formula II is reacted with a compound of formula IV (Y is O,S, imino that may be substituted; B is H, OH, amino, hydrocarbyl) to produce the compound of formula V. USE;The compound of formula III is an antibiotic that is effective against bacteria resisting penicillin. The compound of formula II is useful as an intermeadiate for synthesizing a variety of cephalosporin derivatives.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13493977A JPS5470294A (en) | 1977-11-09 | 1977-11-09 | Cephalosporin derivative and its preparation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP13493977A JPS5470294A (en) | 1977-11-09 | 1977-11-09 | Cephalosporin derivative and its preparation |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5470294A true JPS5470294A (en) | 1979-06-05 |
JPS636551B2 JPS636551B2 (en) | 1988-02-10 |
Family
ID=15140078
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP13493977A Granted JPS5470294A (en) | 1977-11-09 | 1977-11-09 | Cephalosporin derivative and its preparation |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5470294A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996035692A1 (en) * | 1995-05-11 | 1996-11-14 | Biochemie Gesellschaft Mbh | Antibacterial cephalosporins |
-
1977
- 1977-11-09 JP JP13493977A patent/JPS5470294A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996035692A1 (en) * | 1995-05-11 | 1996-11-14 | Biochemie Gesellschaft Mbh | Antibacterial cephalosporins |
Also Published As
Publication number | Publication date |
---|---|
JPS636551B2 (en) | 1988-02-10 |
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