JPS54112820A - Insectidal perhaloalkylvinyl cyclopropane carboxylates and their intermediates - Google Patents

Insectidal perhaloalkylvinyl cyclopropane carboxylates and their intermediates

Info

Publication number
JPS54112820A
JPS54112820A JP347779A JP347779A JPS54112820A JP S54112820 A JPS54112820 A JP S54112820A JP 347779 A JP347779 A JP 347779A JP 347779 A JP347779 A JP 347779A JP S54112820 A JPS54112820 A JP S54112820A
Authority
JP
Japan
Prior art keywords
perhaloalkylvinyl
insectidal
intermediates
cyclopropane carboxylates
cyclopropane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP347779A
Other languages
English (en)
Other versions
JPS6217583B2 (ja
Inventor
Furanshisu Enjieru Jiyon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FMC Corp
Original Assignee
FMC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FMC Corp filed Critical FMC Corp
Publication of JPS54112820A publication Critical patent/JPS54112820A/ja
Publication of JPS6217583B2 publication Critical patent/JPS6217583B2/ja
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C61/16—Unsaturated compounds
    • C07C61/40—Unsaturated compounds containing halogen
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/26—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton
    • C07C17/263—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions
    • C07C17/2635—Preparation of halogenated hydrocarbons by reactions involving an increase in the number of carbon atoms in the skeleton by condensation reactions involving a phosphorus compound, e.g. Wittig synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C07C29/52—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only in the presence of mineral boron compounds with, when necessary, hydrolysis of the intermediate formed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/22—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system
    • C07C35/23—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system with hydroxy on a condensed ring system having two rings
    • C07C35/32—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring polycyclic, at least one hydroxy group bound to a condensed ring system with hydroxy on a condensed ring system having two rings the condensed ring system being a (4.3.0) system, e.g. indenols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/30—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings
    • C07C57/38—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings polycyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C07F9/5442—Aromatic phosphonium compounds (P-C aromatic linkage)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • Environmental Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
JP347779A 1978-01-20 1979-01-18 Insectidal perhaloalkylvinyl cyclopropane carboxylates and their intermediates Granted JPS54112820A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US87097378A 1978-01-20 1978-01-20
US92719878A 1978-07-24 1978-07-24

Publications (2)

Publication Number Publication Date
JPS54112820A true JPS54112820A (en) 1979-09-04
JPS6217583B2 JPS6217583B2 (ja) 1987-04-18

Family

ID=27128180

Family Applications (1)

Application Number Title Priority Date Filing Date
JP347779A Granted JPS54112820A (en) 1978-01-20 1979-01-18 Insectidal perhaloalkylvinyl cyclopropane carboxylates and their intermediates

Country Status (30)

Country Link
US (1) US4263319A (ja)
EP (1) EP0003336B1 (ja)
JP (1) JPS54112820A (ja)
AR (1) AR231431A1 (ja)
AT (1) AT367391B (ja)
AU (1) AU535346B2 (ja)
BR (1) BR7900361A (ja)
CA (1) CA1251801A (ja)
CS (1) CS209913B2 (ja)
DD (2) DD151444A5 (ja)
DE (1) DE2966699D1 (ja)
DK (1) DK159260C (ja)
DO (1) DOP1979002732A (ja)
EG (1) EG13725A (ja)
ES (1) ES8205492A1 (ja)
GR (1) GR67601B (ja)
HK (1) HK43387A (ja)
IE (1) IE48309B1 (ja)
IL (1) IL56340A (ja)
IN (1) IN150399B (ja)
IT (1) IT1111011B (ja)
MX (1) MX6173E (ja)
MY (1) MY8800115A (ja)
NL (1) NL971028I2 (ja)
NZ (1) NZ189438A (ja)
PL (1) PL125296B1 (ja)
SG (1) SG15887G (ja)
SU (1) SU1344244A3 (ja)
TR (1) TR21071A (ja)
YU (1) YU8679A (ja)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5589248A (en) * 1978-07-15 1980-07-05 Bayer Ag Fluoroalkenyllsubstituted cyclopropanecarboxylic esters*their manufacture and their use as insecticide
JPS58185541A (ja) * 1982-04-05 1983-10-29 インペリアル・ケミカル・インダストリ−ズ・ピ−エルシ− 殺虫・殺ダニ方法
JPH0285234A (ja) * 1988-07-07 1990-03-26 Presidenza Del Consiglio Dei Ministri Ufficio Del Ministro Coordinament Iniziativ Ric Sci & Tecnolo ２，２―ジメチルシクロプロパンカルボン酸のエステル
JP2004504290A (ja) * 2000-07-18 2004-02-12 シンジェンタ　リミテッド 鏡像異性体的に純粋なピレトロイド殺虫剤の調製のための方法

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BG48333A3 (en) * 1978-02-28 1991-01-15 Montedison Spa Method for preparing of 2, 2- dimethyl cyclopropane carbonic acid derivatives
DE2842541A1 (de) * 1978-09-29 1980-05-22 Bayer Ag Fluoralkenylsubstituierte cyclopropancarbonsaeureester und ihre verwendung als insektizide
US4333950A (en) * 1979-05-24 1982-06-08 Fmc Corporation (+)-4-Substituted-2-indanol insecticidal ester derivatives
GB2093831B (en) * 1981-02-24 1985-09-25 Fmc Corp 4-substituted-2-indanols and insecticidal ester derivatives
US4402973A (en) * 1980-10-02 1983-09-06 Fmc Corporation Insecticidal (1,1'-biphenyl)-3-ylmethyl esters
IT1131883B (it) * 1980-07-02 1986-06-25 Montedison Spa Processo per la sintesi stereoselettiva di ciclopropancarbossilati intermaedi per piretroidi
US4339457A (en) * 1980-10-20 1982-07-13 Fmc Corporation 3-(Pyrrol-1-yl)phenylmethyl esters and intermediates
US4368205A (en) * 1980-10-31 1983-01-11 Fmc Corporation 4-Heterocyclic-substituted-2-indanyl alcohols and insecticidal ester derivatives
US4417078A (en) * 1980-12-31 1983-11-22 Fmc Corporation Process for producing (+)-4-substituted-2-indanols
US4423255A (en) * 1980-12-31 1983-12-27 Fmc Corporation (+)-4-Substituted-2-indanols
US4429149A (en) 1980-12-31 1984-01-31 Fmc Corporation 4-Phenyl-2-indanyl esters of 1R,cis-3-(2-halo-3,3,3-trifluoropropenyl)-2,2-dimethylcyclopropanecarboxylic acid
DE3171352D1 (en) * 1981-01-21 1985-08-14 Ici Plc Halobenzyl esters of haloalkenylcyclopropane acids, their preparation, compositions and method of combating insect pests therewith
US4362744A (en) * 1981-03-19 1982-12-07 Fmc Corporation Trans-3-substituted-1-indanol insecticidal ester derivatives
US4415748A (en) * 1981-08-06 1983-11-15 Fmc Corporation Intermediates for insecticidal synthetic pyrethroids
EP0073566A1 (en) * 1981-08-27 1983-03-09 Imperial Chemical Industries Plc Methods and compositions for combating soil pests
FR2515176A1 (fr) * 1981-10-23 1983-04-29 Roussel Uclaf Nouveaux esters d'alcools aromatiques ou heteroaromatiques, leur procede de preparation et leur application a la lutte contre les parasites
FR2534918A2 (fr) * 1982-10-26 1984-04-27 Roussel Uclaf Nouveaux esters d'alcools aromatiques et heteroaromatiques, leur procede de preparation et leur application a la lutte contre les parasites
USH49H (en) 1983-01-10 1986-04-01 Fmc Corporation Process for producing 3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethylcyclopropanecarboxylates
DK113384A (da) * 1983-03-11 1984-09-12 Fmc Corp Difluorethenylcyclopropancarboxylater, insecticide og acaricide midler og fremgangsmaade til bekaempelse af insekter og acarider
US4552892A (en) * 1983-03-11 1985-11-12 Fmc Corporation Acaricidal difluoroethenylcyclopropanecarboxylates
FR2628103B1 (fr) * 1988-03-03 1991-06-14 Roussel Uclaf Nouveaux esters pyrethrinoides portant un noyau indanyle, leur procede de preparation et leur application comme pesticides
DE3907069A1 (de) * 1989-03-04 1990-09-06 Basf Ag Substituierte 2-phenyl-alk(en)yl-1-yl-cyclopropancarbonsaeurebenzylester, verfahren zu ihrer herstellung und ihre verwendung zur bekaempfung von schaedlingen
GB9100654D0 (en) * 1991-01-11 1991-02-27 Ici Plc Process for preparing halogenated compounds
FR2686602B1 (fr) * 1992-01-28 1994-03-11 Roussel Uclaf Nouveaux derives de l'acide 2,2-dimethyl 3-[(2,2-difluorocyclopropylidene methyl] cyclopropane carboxylique, leur procede de preparation et leur application comme pesticides.
FR2708930B1 (fr) * 1993-08-10 1995-09-08 Roussel Uclaf Nouveaux esters dérivés de l'acide 2,2-diméthyl 3-(3,3,3-trifluoro-1-propényl) cyclopropane carboxylique, leur procédé de préparation et leur application comme pesticides.
US6048892A (en) * 1997-12-30 2000-04-11 Sumitomo Chemical Company, Limited Ester compound pesticide containing thereof
AU753585B2 (en) * 1998-09-15 2002-10-24 Sumitomo Chemical Company, Limited Ester compound and pesticide containing thereof
KR20140133601A (ko) * 2012-03-13 2014-11-19 레드엑스 파마 리미티드 농약
CN104326862B (zh) * 2014-11-20 2016-08-17 西安近代化学研究所 一种2,4-二氯-1,1,1-三氟丁烷衍生物的制备方法
CN109111373A (zh) * 2018-10-09 2019-01-01 南通天泽化工有限公司 一种三氟氯氰菊酯的制备方法
CN109912386A (zh) * 2019-03-26 2019-06-21 江苏春江润田农化有限公司 一种可回收型功夫酸生产方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51141844A (en) * 1975-05-30 1976-12-07 Kuraray Co Ltd Process for preparing substituted cyclopropane-carboxylic acid esters

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3647857A (en) * 1970-03-16 1972-03-07 Procter & Gamble Novel esters of chrysanthemic acid and alcohols related to 2-indanol
US4024163A (en) * 1972-05-25 1977-05-17 National Research Development Corporation Insecticides
DE2638356A1 (de) 1976-08-26 1978-03-02 Bayer Ag Verfahren zur herstellung vinylsubstituierter cyclopropancarbonsaeureester
US4160842A (en) * 1976-08-27 1979-07-10 Fmc Corporation Insecticidal [β-(substituted-phenyl)vinyl]cyclopropanecarboxylates
US4157397A (en) * 1976-08-27 1979-06-05 Fmc Corporation Insecticidal (β-phenylvinyl)cyclopropanecarboxylates
US4183948A (en) * 1977-01-24 1980-01-15 Imperial Chemical Industries Limited Halogenated esters
GB1572669A (en) * 1977-05-26 1980-08-28 Ici Ltd Manufacture of esters

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51141844A (en) * 1975-05-30 1976-12-07 Kuraray Co Ltd Process for preparing substituted cyclopropane-carboxylic acid esters

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5589248A (en) * 1978-07-15 1980-07-05 Bayer Ag Fluoroalkenyllsubstituted cyclopropanecarboxylic esters*their manufacture and their use as insecticide
JPS6312041B2 (ja) * 1978-07-15 1988-03-17 Bayer Ag
JPS58185541A (ja) * 1982-04-05 1983-10-29 インペリアル・ケミカル・インダストリ−ズ・ピ−エルシ− 殺虫・殺ダニ方法
JPH0285234A (ja) * 1988-07-07 1990-03-26 Presidenza Del Consiglio Dei Ministri Ufficio Del Ministro Coordinament Iniziativ Ric Sci & Tecnolo ２，２―ジメチルシクロプロパンカルボン酸のエステル
JP2004504290A (ja) * 2000-07-18 2004-02-12 シンジェンタ　リミテッド 鏡像異性体的に純粋なピレトロイド殺虫剤の調製のための方法

Also Published As

Publication number Publication date
IN150399B (ja) 1982-09-25
NL971028I2 (nl) 1998-01-05
ATA38279A (de) 1981-11-15
SG15887G (en) 1987-07-17
EP0003336A2 (en) 1979-08-08
CS209913B2 (en) 1981-12-31
HK43387A (en) 1987-06-12
IL56340A (en) 1984-01-31
AU535346B2 (en) 1984-03-15
DD151444A5 (de) 1981-10-21
EP0003336B1 (en) 1984-02-22
MY8800115A (en) 1988-12-31
NZ189438A (en) 1983-04-12
EG13725A (en) 1982-06-30
IE48309B1 (en) 1984-12-12
BR7900361A (pt) 1979-08-14
TR21071A (tr) 1983-06-21
IE790009L (en) 1979-07-20
EP0003336A3 (en) 1979-11-14
ES476994A0 (es) 1982-06-16
DOP1979002732A (es) 1984-02-23
MX6173E (es) 1984-12-04
AT367391B (de) 1982-06-25
US4263319A (en) 1981-04-21
SU1344244A3 (ru) 1987-10-07
DK585078A (da) 1979-07-21
AU4350779A (en) 1979-07-26
CA1251801A (en) 1989-03-28
DE2966699D1 (en) 1984-03-29
GR67601B (ja) 1981-08-31
DD145996A5 (de) 1981-01-21
JPS6217583B2 (ja) 1987-04-18
IT1111011B (it) 1986-01-13
AR231431A1 (es) 1984-11-30
DK159260B (da) 1990-09-24
DK159260C (da) 1991-02-25
IL56340A0 (en) 1979-03-12
IT7919418A0 (it) 1979-01-18
YU8679A (en) 1983-02-28
ES8205492A1 (es) 1982-06-16
NL971028I1 (nl) 1997-10-01
PL125296B1 (en) 1983-04-30
PL212897A1 (ja) 1981-03-13

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