JPH11115333A - Aluminum alloy plate for printing plate and manufacture thereof - Google Patents

Aluminum alloy plate for printing plate and manufacture thereof

Info

Publication number
JPH11115333A
JPH11115333A JP9285866A JP28586697A JPH11115333A JP H11115333 A JPH11115333 A JP H11115333A JP 9285866 A JP9285866 A JP 9285866A JP 28586697 A JP28586697 A JP 28586697A JP H11115333 A JPH11115333 A JP H11115333A
Authority
JP
Japan
Prior art keywords
aluminum alloy
weight
plate
intermetallic compounds
alloy plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9285866A
Other languages
Japanese (ja)
Inventor
Masaki Tanigawa
正樹 谷川
Shinichiro Hosono
晋一郎 細野
Kozo Hoshino
晃三 星野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Priority to JP9285866A priority Critical patent/JPH11115333A/en
Publication of JPH11115333A publication Critical patent/JPH11115333A/en
Pending legal-status Critical Current

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  • Printing Plates And Materials Therefor (AREA)

Abstract

PROBLEM TO BE SOLVED: To realize the formation of a uniform pits without un-etched part through a short time electrolytic roughening and, at the same time, the uniform formation of roughened pits even when shallow pits are dealt. SOLUTION: This alloy plate has a composition consisting of 0.20-0.6 wt.% of Fe, 0.03-0.15 wt.% of Si, 0.005-0.05 wt.% of Ti, when necessary, 0.005-0.20 wt.% of Ni and the remainder of A and inevitable impurities. Some part or all of the elements form intermetallic compounds. Among the intermetallic compounds, the number of the intermetallic compounds, which are present at the surface of the plate and the particle side of which is 1-10 μm, lies within 1,000-8,000/mm. The percentage of the number of the intermetallic compounds, which are present at the surface of the plate and the particle size of which is 1-5 μm, is 80% or more of the number of the intermetallic compounds, which are present at the surface of the plate and the particle size of which is 1-10 μm. An aluminum alloy ingot having the above-mentioned composition is homogenized at 500-630 deg.C and then hot-rolled under the starting temperature of 400-450 deg.C.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は平版印刷版用アルミ
ニウム板及びその製造方法に関し、特に均一な電解粗面
化面を形成することができる印刷版用アルミニウム合金
板及びその製造方法に関する。
The present invention relates to an aluminum plate for a lithographic printing plate and a method for producing the same, and more particularly to an aluminum alloy plate for a printing plate capable of forming a uniform electrolytically roughened surface and a method for producing the same.

【0002】[0002]

【従来の技術】一般にオフセット印刷において、アルミ
ニウムを支持体として用いることは従来から行われてお
り、感光膜の密着性及び非画像部の保水性の点からその
表面を粗面化しておくことが必要である。
2. Description of the Related Art In offset printing, the use of aluminum as a support has been conventionally performed, and it is necessary to roughen the surface of the photosensitive film from the viewpoint of adhesion of a photosensitive film and water retention of a non-image area. is necessary.

【0003】この粗面化処理方法としては、従来から、
ボール研磨法及びブラシ研磨法等の機械的処理法がある
が、近時、塩酸又はこれを主体とする電解液、及び硝酸
を主体とする電解液を用いて板表面を電気化学的に粗面
化する電解粗面化処理法、又は上記のような機械的処理
方法と電解粗面化処理法を組み合わせた処理方法が主体
となってきている。この理由としては、電解粗面化によ
り得られた粗面板の製版適正及び印刷性能が優れている
こと並びにコイル材の連続処理に適していること等が挙
げられる。
[0003] Conventionally, as this surface roughening method,
There are mechanical treatment methods such as a ball polishing method and a brush polishing method. Recently, the plate surface is electrochemically roughened using hydrochloric acid or an electrolytic solution mainly composed of hydrochloric acid and an electrolytic solution mainly composed of nitric acid. An electrolytic surface roughening treatment method for forming a surface, or a treatment method combining the above-mentioned mechanical treatment method and the electrolytic surface roughening treatment method has been mainly used. The reasons for this include that the roughened plate obtained by electrolytic surface roughening has excellent plate making suitability and excellent printing performance, and is suitable for continuous processing of coil materials.

【0004】以上のように使用される印刷版用アルミニ
ウム合金板には粗面化処理によって均一な凹凸が形成さ
れることが要求され、このように均一な凹凸を付加する
ことにより、感光膜との密着性及び保水性が向上し、画
像鮮明性及び耐刷性が優れた印刷版が得られる。更に、
近時、粗面化処理コストを低減させるため、より短時間
又は低通電量で均一な凹凸が得られる電解粗面化効率が
優れた材料の開発が要望されている。
[0004] The aluminum alloy plate for a printing plate used as described above is required to be formed with uniform irregularities by a surface roughening treatment. Has improved adhesion and water retention, and a printing plate having excellent image clarity and printing durability can be obtained. Furthermore,
In recent years, in order to reduce the cost of the surface roughening treatment, there has been a demand for the development of a material having an excellent electrolytic surface roughening efficiency capable of obtaining uniform irregularities in a shorter time or with a smaller amount of electricity.

【0005】電解粗面化効率が優れたアルミニウム合金
板として、例えば、特開昭58−210144号公報に
は、Fe:0.2乃至1.0%、Sn、In、Ga及び
Znからなる群から選択された少なくとも1つの元素を
0.05乃至0.1%並びにCu:0.1乃至2%含有
し、化学的エッチング処理に対して優れた溶解速度を示
し、かつ均一なピットの形成を促進させるような金属間
化合物を形成させたものが開示されている。
As an aluminum alloy sheet having excellent electrolytic surface roughening efficiency, for example, Japanese Patent Application Laid-Open No. 58-210144 discloses a group consisting of Fe: 0.2 to 1.0%, Sn, In, Ga and Zn. Contains at least one element selected from the group consisting of 0.05 to 0.1% and Cu: 0.1 to 2%, exhibits an excellent dissolution rate for a chemical etching treatment, and forms uniform pits. It is disclosed that an intermetallic compound is formed so as to promote it.

【0006】また、特開平3−177528号公報に
は、組成を、Fe:0.1乃至0.5%、Si:0.0
3乃至0.30%、Cu:0.001乃至0.03%、
Ni:0.001乃至0.03%、Ti:0.002乃
至0.05%、及びGa:0.005乃至0.020%
を含有し、かつGaとTiの合計含有量が0.010乃
至0.050%の範囲とすることにより、粗面の均一性
を向上させたアルミニウム合金板が開示されている。
Japanese Patent Application Laid-Open No. 3-177528 discloses that the composition is such that Fe: 0.1 to 0.5%, Si: 0.0
3 to 0.30%, Cu: 0.001 to 0.03%,
Ni: 0.001 to 0.03%, Ti: 0.002 to 0.05%, and Ga: 0.005 to 0.020%
And the total content of Ga and Ti in the range of 0.010 to 0.050% to improve the uniformity of the rough surface is disclosed.

【0007】[0007]

【発明が解決しようとする課題】しかしながら、近時、
コスト低減のために、電解処理速度の向上が要求されて
おり、短時間の電解粗面化処理で均一なピットが形成さ
れると共に、ピットが浅い場合があっても、短時間で均
一にエッチングされ、アルミニウム板に未エッチング部
が発生しないことが要望されている。しかしながら、従
来のアルミニウム板はこのような要望を満足するもので
はなかった。
However, recently,
In order to reduce costs, there is a demand for an improvement in the electrolytic processing speed, and uniform pits are formed by a short electrolytic surface roughening treatment, and even if the pits are shallow, etching is performed uniformly in a short time. Therefore, it is demanded that an unetched portion does not occur in the aluminum plate. However, the conventional aluminum plate has not satisfied such a demand.

【0008】本発明はかかる問題点に鑑みてなされたも
のであって、短時間の電解粗面化処理で未エッチング部
がない均一なピットを形成できると共に、ピットが浅い
場合であっても粗面化ピットを均一に形成することがで
きる印刷版用アルミニウム合金板及びその製造方法を提
供することを目的とする。
The present invention has been made in view of the above-mentioned problems, and it is possible to form uniform pits having no unetched portions by a short electrolytic surface roughening treatment and to obtain a rough pit even when the pits are shallow. An object of the present invention is to provide an aluminum alloy plate for a printing plate capable of uniformly forming surface pits and a method for manufacturing the same.

【0009】[0009]

【課題を解決するための手段】本発明に係る印刷版用ア
ルミニウム合金板は、Fe:0.20乃至0.6重量
%、Si:0.03乃至0.15重量%、Ti:0.0
05乃至0.05重量%及び、必要に応じてNi:0.
005乃至0.20重量%を含有し、残部がAl及び不
可避的不純物からなる。そして、本発明の印刷版用アル
ミニウム合金板は、前記元素の一部又は全部が金属間化
合物を形成しており、前記金属間化合物のうち、表面に
存在し粒子径が1乃至10μmである金属間化合物が1
000乃至8000個/mm2であることを特徴とす
る。
The aluminum alloy plate for a printing plate according to the present invention comprises Fe: 0.20 to 0.6% by weight, Si: 0.03 to 0.15% by weight, Ti: 0.0
0.05 to 0.05% by weight and, if necessary, Ni: 0.
005 to 0.20% by weight, with the balance being Al and unavoidable impurities. In the aluminum alloy plate for a printing plate of the present invention, a part or all of the elements form an intermetallic compound, and among the intermetallic compounds, a metal present on the surface and having a particle size of 1 to 10 μm. Intermediate compound is 1
000 to 8000 / mm 2 .

【0010】本発明に係る印刷版用アルミニウム合金板
の製造方法は、Fe:0.20乃至0.6重量%、S
i:0.03乃至0.15重量%、Ti:0.005乃
至0.05重量%及び、必要に応じてNi:0.005
乃至0.20重量%を含有し、残部がAl及び不可避的
不純物からなるアルミニウム合金鋳塊に、500乃至6
30℃の温度で均質化処理する工程と、次いで開始温度
を400乃至450℃として熱間圧延する工程とを有す
る。これにより、本発明方法は、表面に粒子径1乃至1
0μmの金属間化合物が1000乃至8000個/mm
2析出した印刷版用アルミニウム合金板を得ることを特
徴とする。この場合に、前記熱間圧延の後に、順次、冷
間圧延、中間焼鈍及び最終冷間圧延を施すことができ
る。
The method for producing an aluminum alloy plate for a printing plate according to the present invention is characterized in that Fe: 0.20 to 0.6% by weight,
i: 0.03 to 0.15% by weight, Ti: 0.005 to 0.05% by weight, and if necessary, Ni: 0.005%
To 0.20% by weight, with the balance being 500 to 6 parts in an aluminum alloy ingot consisting of Al and inevitable impurities.
There is a step of homogenizing at a temperature of 30 ° C., and then a step of hot rolling at an initial temperature of 400 to 450 ° C. Thereby, the method of the present invention allows the surface to have a particle size of 1 to 1
0-μm intermetallic compound 1000-8000 / mm
(2) It is characterized in that a deposited aluminum alloy plate for a printing plate is obtained. In this case, after the hot rolling, cold rolling, intermediate annealing, and final cold rolling can be sequentially performed.

【0011】[0011]

【発明の実施の形態】以下、本発明について更に詳細に
説明する。本願発明者らは、短時間処理においても未エ
ッチング部が発生せず、且つ、均一なエッチングピット
が得られる印刷版用アルミニウム合金板を得るために、
鋭意研究した結果、アルミニウム合金板が含有する合金
元素であるFe、Si、Ti、Niを管理することに加
え、それら合金元素の一部又は全部が形成する金属間化
合物のうち、表面に存在する粒子径1乃至10μmの金
属間化合物の個数を管理することが有効であることを見
出した。金属間化合物はアルミニウムマトリクスとの間
に電位差を生じるため、電解粗面化時にイニシャルピッ
トの起点として作用し、材料のエッチング性、粗面均一
性に多大な影響を及ぼす。なかでも、表面に存在する粒
子径1乃至10μmの金属間化合物はその影響が大き
く、従って、上述のごとく表面に存在する粒子径1乃至
10μmの金属間化合物の個数を管理することが極めて
重要である。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in more detail. In order to obtain an aluminum alloy plate for a printing plate in which unetched portions are not generated even in a short-time treatment, and uniform etching pits are obtained, the present inventors have proposed:
As a result of intensive research, in addition to managing the alloy elements Fe, Si, Ti, and Ni contained in the aluminum alloy plate, some or all of these alloy elements are present on the surface among the intermetallic compounds formed It has been found that it is effective to control the number of intermetallic compounds having a particle diameter of 1 to 10 μm. Since the intermetallic compound generates a potential difference between the aluminum matrix and the aluminum matrix, the intermetallic compound acts as a starting point of initial pits during electrolytic surface roughening, and has a great effect on the etching properties and the uniformity of the rough surface of the material. Among them, intermetallic compounds having a particle diameter of 1 to 10 μm existing on the surface have a great effect, and therefore, it is extremely important to control the number of intermetallic compounds having a particle diameter of 1 to 10 μm existing on the surface as described above. is there.

【0012】上述の印刷版用アルミニウム合金板を製造
する場合は、組成を上記のものにすることに加えて、均
質化処理温度及び熱間圧延開始温度を制御して、金属間
化合物の存在数を制御することが重要である。これによ
り得られたアルミニウム合金板に電解粗面化処理を施し
た場合は、短時間処理においても未エッチング部が発生
せず、且つ粗面も均一となる。 (1)次に、本発明の成分添加理由及び組成限定理由に
ついて説明する。
When manufacturing the above-mentioned aluminum alloy plate for a printing plate, in addition to the above-mentioned composition, the number of intermetallic compounds is controlled by controlling the homogenization treatment temperature and the hot rolling start temperature. It is important to control When an electrolytic surface roughening treatment is applied to the obtained aluminum alloy plate, no unetched portion is generated even in a short time treatment, and the rough surface is uniform. (1) Next, the reasons for adding the components and the reasons for limiting the composition of the present invention will be described.

【0013】Fe:0.20乃至0.6重量% Feは純アルミニウム系合金の主要構成成分である。F
eはアルミニウム合金中ではAl−Fe系の金属間化合
物を形成する元素である。Feは再結晶粒の微細化及び
組織の均一化による機械的強度維持に効果を有する。更
に、Feは電解粗面化時のイニシャルピットの開始点と
して作用するものである。然るに、Fe含有量が0.2
0重量%未満では、金属間化合物が不足し、電解粗面化
時のイニシャルピットの形成能が不十分となる。また、
Fe含有量が0.6重量%を超える場合は、粗大化合物
の形成により、電解粗面化面が不均一となる。
Fe: 0.20 to 0.6% by weight Fe is a main component of a pure aluminum-based alloy. F
e is an element forming an Al-Fe intermetallic compound in an aluminum alloy. Fe is effective in maintaining the mechanical strength by refining the recrystallized grains and making the structure uniform. Further, Fe acts as a starting point of initial pits during electrolytic surface roughening. However, when the Fe content is 0.2
If it is less than 0% by weight, the intermetallic compound is insufficient, and the ability to form initial pits during electrolytic surface roughening is insufficient. Also,
If the Fe content exceeds 0.6% by weight, the roughened electrolytic surface becomes non-uniform due to the formation of a coarse compound.

【0014】Si:0.03乃至0.15重量% SiはAl−Fe−Si系金属間化合物を形成して、イ
ニシャルピットの形成を促進すると共に、ピットの均一
性を向上させる。Si含有量が0.03重量%未満で
は、金属間化合物が不足するため、イニシャルピットの
形成が不十分となる。一方、Si含有量が0.15重量
%を超えると、粗大化合物が形成され、電解粗面化面が
不均一となる。従って、Si含有量は0.03乃至0.
15重量%とする。
Si: 0.03% to 0.15% by weight Si forms an Al—Fe—Si based intermetallic compound to promote the formation of initial pits and to improve pit uniformity. If the Si content is less than 0.03% by weight, the formation of initial pits becomes insufficient because of insufficient intermetallic compounds. On the other hand, if the Si content exceeds 0.15% by weight, a coarse compound is formed, and the electrolytically roughened surface becomes non-uniform. Therefore, the Si content is 0.03 to 0.3.
15% by weight.

【0015】Ti:0.005乃至0.05重量% Tiは鋳造組織を微細化する元素である。Ti含有量が
0.005重量%未満では微細化効果が不十分となり、
粗面の均一性にも悪影響を及ぼす。一方、Ti含有量が
0.05重量%を超えると、Ti含有による微細化効果
が飽和してしまい、無駄であることに加えて、粗大化合
物が形成され、電解粗面化処理時に不均一なピットが生
成されやすくなってしまう。従って、Ti含有量は0.
005乃至0.05重量%とする。
Ti: 0.005 to 0.05% by weight Ti is an element for refining the cast structure. If the Ti content is less than 0.005% by weight, the refining effect becomes insufficient,
It also has an adverse effect on the uniformity of the rough surface. On the other hand, if the Ti content is more than 0.05% by weight, the effect of fineness due to the Ti content is saturated, and in addition to being wasteful, a coarse compound is formed, and non-uniformity occurs during electrolytic surface roughening treatment. Pits are easily generated. Therefore, the Ti content is 0.1.
005 to 0.05% by weight.

【0016】Ni:0.005乃至0.20重量% Niはアルミニウム合金板の化学溶解性を向上させて、
電化粗面化のエッチング性を向上させる効果を有する元
素である。また、Niはアルミニウム合金中でAl−F
e−Ni系の金属間化合物を形成し、この化合物はアル
ミニウムマトリクスとの電位差をAl−Fe系の化合物
よりさらに拡大させ、電解粗面化によるイニシャルピッ
トの形成をより促進させ、単時間で均一な粗面の形成を
可能とする。
Ni: 0.005 to 0.20% by weight Ni improves the chemical solubility of the aluminum alloy plate,
It is an element that has the effect of improving the etching properties of the electrification roughening. Ni is Al-F in an aluminum alloy.
An e-Ni-based intermetallic compound is formed. This compound further increases the potential difference from the aluminum matrix as compared with the Al-Fe-based compound, further promotes the formation of initial pits by electrolytic surface roughening, and is uniform in a single time. It is possible to form a rough surface.

【0017】然るに、Niが0.005重量%未満では
化学溶解性向上及びイニンシャルピット形成能ともに不
十分である。また、添加量が0.20重量%を超える
と、化学溶解が過剰に促進されるため、電解粗面におけ
るピットの均一性が損なわれてしまう。従って、Ni含
有量は0.005乃至0.20重量%とする。
However, if the Ni content is less than 0.005% by weight, both the improvement in chemical solubility and the ability to form initial pits are insufficient. On the other hand, if the addition amount exceeds 0.20% by weight, chemical dissolution is excessively promoted, so that the uniformity of pits on the roughened electrolytic surface is impaired. Therefore, the Ni content is set to 0.005 to 0.20% by weight.

【0018】表面に存在する粒子径1乃至10μmの金
属間化合物:1000乃至8000個/mm2 前述の如く金属間化合物はイニシャルピットの起点とし
て作用し、エッチング性及び粗面均一性に多大な効果を
有する。特に、表面に存在する粒子径1乃至10μmの
金属間化合物の効果が極めて大きい。本発明における表
面とは、圧延板の表面はもとより、機械的研磨及び化学
研磨(アルカリでの電解前処理も含む)等で現出した表
面、即ち粗面化処理を施す状態での表面をも包含するも
のである。
Gold having a particle diameter of 1 to 10 μm existing on the surface
Intergeneric compound: 1000 to 8000 / mm 2 As described above, the intermetallic compound acts as a starting point of the initial pit, and has a great effect on the etching property and the uniformity of the rough surface. In particular, the effect of the intermetallic compound having a particle diameter of 1 to 10 μm existing on the surface is extremely large. The surface in the present invention refers to not only the surface of a rolled plate but also the surface that has appeared by mechanical polishing and chemical polishing (including pretreatment with an alkali), that is, the surface that has been subjected to a surface roughening treatment. Includes

【0019】以下に表面に存在する粒子径1乃至10μ
mの金属間化合物の個数の限定理由について説明する。
表面に存在する粒子径1乃至10μmの金属間化合物が
1000個/mm2未満の場合、イニシャルピットの起
点数が不十分であり、エッチング性及び粗面化均一性が
劣る。一方、このような金属間化合物が8000個/m
2を超えると、粗大なピットが形成されやすくなり、
粗面の均一性が損なわれてしまう。従って、表面に存在
する粒子径1乃至10μmの金属間化合物個数は100
0乃至8000個/mm2とする。
The particle diameter on the surface is 1 to 10 μm
The reason for limiting the number of m intermetallic compounds will be described.
If the number of intermetallic compounds having a particle diameter of 1 to 10 μm existing on the surface is less than 1000 / mm 2, the number of starting points of initial pits is insufficient, and the etching property and the uniformity of roughening are poor. On the other hand, the number of such intermetallic compounds is 8000 / m
Beyond m 2, tends coarse pits are formed,
The uniformity of the rough surface is impaired. Therefore, the number of intermetallic compounds having a particle diameter of 1 to 10 μm existing on the surface is 100
0 to 8000 / mm 2 .

【0020】表面に存在する粒子径1乃至5μmの金属
間化合物個数の割合:表面に存在する粒子径1乃至10
μmの金属間化合物個数の80%以上 上述の如く、表面に存在する粒子径1乃至10μmの金
属間化合物はエッチング性及び粗面均一性が特に優れて
いるため、その個数を制御することが必要である。それ
に加えて、表面に存在する粒子径1乃至5μmの金属間
化合物を、表面に存在する粒子径1乃至10μmの金属
間化合物個数に対して一定割合で存在させることによっ
て、粗面均一性を更に一層向上させることができる。
Metal having a particle diameter of 1 to 5 μm existing on the surface
Ratio of the number of inter-compounds: particle diameter 1 to 10 present on the surface
80% or more of the number of intermetallic compounds having a particle diameter of 1 μm As described above , intermetallic compounds having a particle diameter of 1 to 10 μm existing on the surface are particularly excellent in etching properties and rough surface uniformity. It is. In addition, the uniformity of the rough surface is further improved by allowing the intermetallic compound having a particle diameter of 1 to 5 μm existing on the surface to be present at a fixed ratio to the number of intermetallic compounds having a particle diameter of 1 to 10 μm existing on the surface. It can be further improved.

【0021】表面に存在する粒子径1乃至5μmの金属
間化合物の個数の割合が表面に存在する粒子径1乃至1
0μmの金属間化合物の個数の80%未満の場合、粗面
均一性が劣化する。従って、表面に存在する粒子径1乃
至5μmの金属間化合物の個数の割合は表面に存在する
粒子径1乃至10μmの金属間化合物の個数の80%以
上とする。
The ratio of the number of intermetallic compounds having a particle diameter of 1 to 5 μm existing on the surface is determined by the particle diameter of 1 to 1 existing on the surface.
If it is less than 80% of the number of intermetallic compounds of 0 μm, the uniformity of the rough surface is deteriorated. Therefore, the ratio of the number of intermetallic compounds having a particle diameter of 1 to 5 μm existing on the surface is set to 80% or more of the number of intermetallic compounds having a particle diameter of 1 to 10 μm existing on the surface.

【0022】次に、本発明に係る印刷版用アルミニウム
合金板の製造方法について説明する。本発明における印
刷版用アルミニウム合金板の製造条件では、上述の化学
成分を有する合金鋳塊を使用することに加えて、均質化
処理温度及び熱間圧延開始温度を制御して、金属間化合
物の存在数を制御することが必要である。
Next, a method for producing an aluminum alloy plate for a printing plate according to the present invention will be described. In the manufacturing conditions of the aluminum alloy plate for a printing plate in the present invention, in addition to using the alloy ingot having the above-described chemical components, the homogenization treatment temperature and the hot rolling start temperature are controlled, and the intermetallic compound It is necessary to control the number.

【0023】以下、本発明に係る印刷版用アルミニウム
合金板の製造方法における均質化処理温度及び熱間圧延
開始温度の数値限定理由について説明する。
Hereinafter, the reasons for limiting the numerical values of the homogenization treatment temperature and the hot rolling start temperature in the method for producing an aluminum alloy plate for a printing plate according to the present invention will be described.

【0024】均質化処理温度:500乃至630℃ アルミニウム合金鋳塊から印刷版用アルミニウム合金板
を圧延等により製造する場合に、この鋳塊を圧延する前
に、所定温度で均質化処理することが必要である。この
均質化処理により金属間化合物を析出させ、析出した化
合物をイニシャルピットとして作用させることによっ
て、均一な電解粗面を得ることができる。均質化処理温
度が500℃未満では、均質化が不十分であることに加
え、金属間化合物の析出量が多すぎるため、電解粗面の
均一性が損なわれる。一方、均質化処理が630℃を越
えると、金属間化合物の析出量が少なくなりすぎて、イ
ニシャルピットが不足し、未エッチング部が増加すると
ともに、粗面の均一性が損なわれる。従って、均質化処
理温度は500乃至630℃とする。
Homogenization temperature: 500 to 630 ° C. When an aluminum alloy plate for a printing plate is manufactured from an aluminum alloy ingot by rolling or the like, it is necessary to homogenize the ingot at a predetermined temperature before rolling. is necessary. By this homogenization treatment, an intermetallic compound is precipitated, and the precipitated compound acts as initial pits, whereby a uniform electrolytic rough surface can be obtained. When the homogenization treatment temperature is lower than 500 ° C., the homogenization is insufficient, and the uniformity of the electrolytic rough surface is impaired because the amount of the precipitated intermetallic compound is too large. On the other hand, when the homogenization treatment exceeds 630 ° C., the precipitation amount of the intermetallic compound becomes too small, the initial pits become insufficient, the unetched portion increases, and the uniformity of the rough surface is impaired. Therefore, the homogenization temperature is set to 500 to 630 ° C.

【0025】熱間圧延開始温度:400乃至450℃ 上述の均質化処理の後、アルミニウム合金鋳塊に所定の
開始温度で熱間圧延を施す。熱間圧延開始温度が400
℃未満では、圧延中の動的再結晶が不十分であり、圧延
板の結晶組織が不均一となる。また、金属間化合物の析
出量が過少となり、イニシャルピットが不足して、電解
粗面化時に未エッチング部の増加を招くと共に、粗面の
均一性が損なわれる。一方、熱間圧延開始温度が450
℃を超えると、熱間圧延の各パス間において、結晶粒が
過剰に成長してしまうことに加え、金属間化合物の析出
量が多くなりすぎて、電解粗面の均一性が損なわれる。
従って、金属間化合物の析出量が多くなりすぎて、電解
粗面の均一性が損なわれる。従って、熱間圧延開始温度
は400乃至450℃とする。
Hot rolling start temperature: 400 to 450 ° C. After the above homogenization treatment, the aluminum alloy ingot is subjected to hot rolling at a predetermined starting temperature. Hot rolling start temperature is 400
If the temperature is lower than ℃, dynamic recrystallization during rolling is insufficient, and the crystal structure of the rolled sheet becomes non-uniform. Further, the precipitation amount of the intermetallic compound becomes too small, the initial pits become insufficient, and an unetched portion is increased at the time of electrolytic surface roughening, and the uniformity of the rough surface is impaired. On the other hand, the hot rolling start temperature is 450
If the temperature exceeds ℃, in addition to excessive growth of crystal grains between passes of hot rolling, the amount of precipitation of intermetallic compounds becomes too large, and the uniformity of the electrolytic rough surface is impaired.
Therefore, the precipitation amount of the intermetallic compound becomes too large, and the uniformity of the electrolytic rough surface is impaired. Therefore, the hot rolling start temperature is set to 400 to 450 ° C.

【0026】[0026]

【実施例】以下、本発明の実施例について、その特許請
求の範囲から外れる比較例と比較して説明する。
EXAMPLES Examples of the present invention will be described below in comparison with comparative examples that depart from the scope of the claims.

【0027】第1実施例 下記表1に示す化学組成を有する各アルミニウム合金の
鋳塊(実施例1乃至7及び比較例1乃至8)を、面削し
て厚さを470mmとし、590℃の温度で4時間の均
質化処理を施し、次いで開始温度を450℃に設定して
熱間圧延し、更に冷間圧延、中間焼鈍及び冷間圧延を順
次施して、板厚が0.3mmのアルミニウム合金板を得
た。各アルミニウム合金板の化学成分は発光分光法を使
用して測定した。また、表面に存在する粒子径1乃至1
0μmの金属間化合物の個数は、走査電子顕微鏡を用い
て、500倍の倍率で表面の反射電子線像を観察し、1
視野の面積が0.04mm2となるように25視野写真
撮影し、得られた写真から画像解析によりその個数をカ
ウントした。なお、ここでは、電子顕微鏡による表面観
察は圧延板表面及び該圧延板を40℃、10%の水酸化
ナトリウム水溶液中で10秒間溶解した後の表面の双方
で実施したが、両者はほぼ同等の数値を示したため、圧
延板表面の数値を代表値とした。
First Example An ingot of each aluminum alloy (Examples 1 to 7 and Comparative Examples 1 to 8) having the chemical composition shown in Table 1 below was face-polished to a thickness of 470 mm and a temperature of 590 ° C. The steel is subjected to a homogenization treatment at a temperature of 4 hours, and then hot-rolled with the starting temperature set at 450 ° C., and further subjected to cold rolling, intermediate annealing and cold rolling in order to obtain an aluminum sheet having a thickness of 0.3 mm. An alloy plate was obtained. The chemical composition of each aluminum alloy plate was measured using emission spectroscopy. In addition, the particle diameters 1 to 1 existing on the surface
The number of 0 μm intermetallic compounds was determined by observing a reflected electron beam image of the surface at a magnification of 500 times using a scanning electron microscope.
25 field-of-view photographs were taken so that the area of the field of view became 0.04 mm 2, and the number thereof was counted from the obtained photograph by image analysis. Here, the surface observation with an electron microscope was performed on both the surface of the rolled plate and the surface after dissolving the rolled plate in a 10% aqueous solution of sodium hydroxide at 40 ° C. for 10 seconds. Since the numerical values are shown, the numerical values on the surface of the rolled sheet were used as representative values.

【0028】次に、上述のようにして製造した各アルミ
ニウム合金板に、下記表2に示す処理条件1又は2にて
脱脂及び中和洗浄を施した後、交流電解粗面化処理を施
し、更に、電解により形成された酸化物等を除去するデ
スマット処理を施した。このデスマット処理の終了後、
各アルミニウム合金板を水洗及び乾燥させ、一定の大き
さに切り取って、これを供施材とした。
Next, each of the aluminum alloy sheets manufactured as described above was subjected to degreasing and neutralization cleaning under the processing conditions 1 or 2 shown in Table 2 below, and then subjected to AC electrolytic surface roughening treatment. Further, a desmut treatment for removing oxides and the like formed by electrolysis was performed. After the end of this desmutting process,
Each aluminum alloy plate was washed with water and dried, cut into a certain size, and used as a material to be provided.

【0029】各供試材のエッチング性及び均一性を下記
の試験により評価した。
The etching properties and uniformity of each test material were evaluated by the following tests.

【0030】エッチング性評価 各供試材の粗面化表面を、走査電子顕微鏡を使用して、
350倍の倍率で表面観察し、視野の面積が0.02m
2となるように写真を撮影した。得られた写真から、
下記数式1より未エッチング率を算出した。
Evaluation of etching properties The roughened surface of each test material was measured using a scanning electron microscope.
Observation of the surface at a magnification of 350 times, the area of the visual field is 0.02 m
The photograph was taken in such a way that m 2. From the obtained photos,
The unetched rate was calculated from the following equation (1).

【0031】[0031]

【数1】未エッチング率(%)={(粗面化されていな
い部分の面積)/(全体の面積)}×100 この算出結果から、下記基準でエッチング性を評価し
た。
## EQU1 ## Unetching rate (%) = {(area of non-roughened part) / (overall area)} × 100 From the calculation result, the etching property was evaluated based on the following criteria.

【0032】 [0032]

【0033】均一性評価 各供試材の粗面化表面を走査電子顕微鏡を使用して、5
00倍の倍率で表面観察し、写真撮影した。得られた観
察写真上に全長が100cmの線を引き、線の下のピッ
トの大きさ(直径)を測定した。最小のピットと最大の
ピットとの大きさの差異により、以下の基準で均一性を
評価した。
Evaluation of uniformity The roughened surface of each test material was measured using a scanning electron microscope for 5 minutes.
The surface was observed at a magnification of 00 and photographed. A line having a total length of 100 cm was drawn on the obtained observation photograph, and the size (diameter) of the pit below the line was measured. Based on the size difference between the smallest pit and the largest pit, uniformity was evaluated according to the following criteria.

【0034】 [0034]

【0035】表1に第1実施例の各材料のエッチング性
及び均一性に対する評価を示す。なお、各実施例及び比
較例において、処理条件1における各評価と処理条件2
における各評価とはいずれも同一であった。
Table 1 shows the evaluation of the etching property and the uniformity of each material of the first embodiment. In each example and comparative example, each evaluation under processing condition 1 and processing condition 2
All of the evaluations were the same.

【0036】[0036]

【表1】 [Table 1]

【0037】[0037]

【表2】 [Table 2]

【0038】第2実施例 下記表3に示す化学組成を有する各アルミニウム合金の
鋳塊(実施例1乃至5及び比較例1乃至10)を使用し
て、第1実施例と同様の方法でアルミニウム合金板を得
た。また、各アルミニウム合金板の化学成分及び表面に
存在する粒子径1乃至10μmの金属間化合物個数を第
1実施例と同一の方法で測定した。
Second Example An ingot of each aluminum alloy having the chemical composition shown in Table 3 below (Examples 1 to 5 and Comparative Examples 1 to 10) was used in the same manner as in the first example. An alloy plate was obtained. The chemical composition of each aluminum alloy plate and the number of intermetallic compounds having a particle diameter of 1 to 10 μm existing on the surface were measured in the same manner as in the first example.

【0039】次に、上述のようにして製造した各アルミ
ニウム合金板に、前記表2に示す処理条件1又は2にて
脱脂及び中和洗浄を施した後、交流電解粗面化処理を施
し、更に、電解により形成された酸化物等を除去するデ
スマット処理を施した。このデスマット処理の終了後、
各アルミニウム合金板を水洗及び乾燥させ、一定の大き
さに切り取って、これを供試材とした。
Next, each of the aluminum alloy sheets manufactured as described above was subjected to degreasing and neutralization cleaning under the processing conditions 1 or 2 shown in Table 2 above, and then subjected to AC electrolytic surface roughening treatment. Further, a desmut treatment for removing oxides and the like formed by electrolysis was performed. After the end of this desmutting process,
Each aluminum alloy plate was washed with water and dried, cut into a certain size, and used as a test material.

【0040】各供試材のエッチング性及び均一性を第1
実施例と同一の方法で評価した。下記表4に第2実施例
の各材料のエッチング性及び均一性に対する評価を示
す。なお、各実施例及び比較例において、処理条件1に
おける各評価と処理条件2における各評価とはいずれも
同一であった。
First, the etching property and uniformity of each test material were determined.
Evaluation was performed in the same manner as in the examples. Table 4 below shows the evaluation of the etching properties and uniformity of each material of the second embodiment. In each example and comparative example, each evaluation under processing condition 1 and each evaluation under processing condition 2 were the same.

【0041】[0041]

【表3】 [Table 3]

【0042】[0042]

【表4】 [Table 4]

【0043】第3実施例 下記表5に示す化学組織を有する各アルミニウム合金の
鋳塊(実施例1乃至9及び比較例1乃至2)を使用し
て、第1実施例と同様の方法でアルミニウム合金板を得
た。各アルミニウム合金板の組成は第1実施例と同様の
方法で測定した。また、表面に存在する金属間化合物個
数は第1実施例と同様の方法で観察し、写真撮影した
後、画像解析により、粒子径1乃至5μm、粒子径5乃
至10μmの双方の金属間化合物をカウントし、その数
値により、粒子径1乃至10μmの金属間化合物個数及
びそれらに対する粒子径1乃至5μmの金属間化合物個
数の割合を算出した。
Third Example Aluminum ingots (Examples 1 to 9 and Comparative Examples 1 and 2) having the chemical structures shown in Table 5 below were used to produce aluminum in the same manner as in the first example. An alloy plate was obtained. The composition of each aluminum alloy plate was measured by the same method as in the first embodiment. Further, the number of intermetallic compounds present on the surface was observed and photographed in the same manner as in the first example, and then, by image analysis, both intermetallic compounds having a particle diameter of 1 to 5 μm and a particle diameter of 5 to 10 μm were obtained. The number was counted, and the number was used to calculate the number of intermetallic compounds having a particle diameter of 1 to 10 μm and the ratio of the number of intermetallic compounds having a particle diameter of 1 to 5 μm to them.

【0044】次に、上述のようにして製造した各アルミ
ニウム合金板に、前記表2に示す処理条件1又は2にて
脱脂及び中和洗浄を施した後、交流電解粗面化処理を施
し、更に、電解により形成された酸化物等を除去するデ
スマット処理を施した。このデスマット処理の終了後、
各アルミニウム合金板を水洗及び乾燥させ、一定の大き
さに切り取って、これを供試材とした。
Next, each aluminum alloy plate manufactured as described above was subjected to degreasing and neutralization cleaning under the processing conditions 1 or 2 shown in Table 2 above, and then subjected to AC electrolytic surface roughening treatment. Further, a desmut treatment for removing oxides and the like formed by electrolysis was performed. After the end of this desmutting process,
Each aluminum alloy plate was washed with water and dried, cut into a certain size, and used as a test material.

【0045】各供試材のエッチング性及び均一性を第1
実施例と同一の方法で評価した。下記表6に第3実施例
の各材料のエッチング性及び均一性に対する評価結果を
示す。なお、各実施例及び比較例において、処理条件1
における各評価と処理条件2における各評価とはいずれ
も同一であった。
The etching property and uniformity of each test material were determined as follows:
Evaluation was performed in the same manner as in the examples. Table 6 below shows the evaluation results of the etching property and the uniformity of each material of the third example. In each example and comparative example, processing conditions 1
And the respective evaluations under processing condition 2 were the same.

【0046】[0046]

【表5】 [Table 5]

【0047】[0047]

【表6】 [Table 6]

【0048】第4実施例 上記表1に示す実施例1と同一の化学組成を有する各ア
ルミニウム合金鋳塊を、面削して厚さを470mmと
し、次いで下記表7に示す条件で、均質化処理及び熱間
圧延し、更に冷間圧延、中間焼鈍及び冷間圧延して、板
厚が0.3mmのアルミニウム合金板を得た。なお、各
アルミニウム合金板の化学成分及び表面に存在する粒子
径1乃至10μmの金属間化合物個数を第1実施例と同
一の方法で測定した。
Fourth Embodiment Each of the aluminum alloy ingots having the same chemical composition as in Example 1 shown in Table 1 was beveled to a thickness of 470 mm, and then homogenized under the conditions shown in Table 7 below. The aluminum alloy sheet having a thickness of 0.3 mm was obtained by performing treatment, hot rolling, and further cold rolling, intermediate annealing and cold rolling. The chemical composition of each aluminum alloy plate and the number of intermetallic compounds having a particle diameter of 1 to 10 μm existing on the surface were measured in the same manner as in the first embodiment.

【0049】次いで、上述のようにして製造した各アル
ミニウム合金板に、前記表2に示す処理条件1又は2に
て脱脂及び中和洗浄を施した後、交流電解粗面化処理を
施し、更に、電解により形成された酸化物等を除去する
デスマット処理を施した。このデスマット処理の終了
後、各アルミニウム合金板を水洗及び乾燥させ、一定の
大きさを切り取って、これを供試材とした。
Next, each of the aluminum alloy plates manufactured as described above was subjected to degreasing and neutralization cleaning under the processing conditions 1 or 2 shown in Table 2 above, and then subjected to AC electrolytic surface roughening treatment. And a desmutting treatment for removing oxides and the like formed by electrolysis. After completion of the desmutting treatment, each aluminum alloy plate was washed with water and dried, cut to a certain size, and used as a test material.

【0050】各供試材のエッチング性及び均一性を第1
実施例と同一の方法で評価した。下記表7に第4実施例
の各材料のエッチング性及び均一性に対する評価を示
す。なお、各実施例及び比較例において、処理条件1に
おける各評価と処理条件2における各評価とはいずれも
同一だった。
The etching property and uniformity of each test material were determined as follows:
Evaluation was performed in the same manner as in the examples. Table 7 below shows the evaluation of the etching property and uniformity of each material of the fourth example. In each example and comparative example, each evaluation under processing condition 1 and each evaluation under processing condition 2 were the same.

【0051】[0051]

【表7】 [Table 7]

【0052】第5実施例 上記表3に示す実施例1と同一の化学組成を有する各ア
ルミニウム合金鋳塊を、面削して厚さを470mmと
し、次いで下記表8に示す条件で、均質化処理及び熱間
圧延し、更に冷間圧延、中間焼鈍及び冷間圧延して、板
厚が0.3mmのアルミニウム合金板を得た。なお、各
アルミニウム合金板の化学成分及び表面に存在する粒子
径1乃至10μmの金属間化合物個数を第1実施例と同
一の方法で測定した。
Fifth Embodiment Each of the aluminum alloy ingots having the same chemical composition as in Example 1 shown in Table 3 above was chamfered to a thickness of 470 mm, and then homogenized under the conditions shown in Table 8 below. The aluminum alloy sheet having a thickness of 0.3 mm was obtained by performing treatment, hot rolling, and further cold rolling, intermediate annealing and cold rolling. The chemical composition of each aluminum alloy plate and the number of intermetallic compounds having a particle diameter of 1 to 10 μm existing on the surface were measured in the same manner as in the first embodiment.

【0053】次に、上述のようにして製造した各アルミ
ニウム合金板に、前記表2に示す処理条件1又は2にて
脱脂及び中和洗浄を施した後、交流電解粗面化処理を施
し、更に、電解により形成された酸化物等を除去するデ
スマット処理を施した。このデスマット処理の終了後、
各アルミニウム合金板を水洗及び乾燥させ、一定の大き
さを切り取って、これを供試材とした。
Next, each of the aluminum alloy plates manufactured as described above was subjected to degreasing and neutralization cleaning under the processing conditions 1 or 2 shown in Table 2 above, and then subjected to AC electrolytic surface roughening treatment. Further, a desmut treatment for removing oxides and the like formed by electrolysis was performed. After the end of this desmutting process,
Each aluminum alloy plate was washed with water and dried, cut to a certain size, and used as a test material.

【0054】各供試材のエッチング性及び均一性を第1
実施例と同一の方法で評価した。下記表8に第5実施例
各材料のエッチング性及び均一性に対する評価を示す。
なお、各実施例及び比較例において、処理条件1におけ
る各評価と処理条件2における各評価とはいずれも同一
だった。
The etching property and uniformity of each test material were determined as follows:
Evaluation was performed in the same manner as in the examples. Table 8 below shows the evaluation of the materials of the fifth embodiment with respect to the etching property and the uniformity.
In each example and comparative example, each evaluation under processing condition 1 and each evaluation under processing condition 2 were the same.

【0055】[0055]

【表8】 [Table 8]

【0056】[0056]

【発明の効果】以上説明したように、本発明に係る印刷
版用アルミニウム合金板は所定の化学成分に加え、表面
に粒子径1乃至10μmの金属間化合物個数が所定量存
在するため、粗面化ピットが電解粗面に均一に形成され
ると共に、各ピットの大きさが略一定となる。
As described above, in the aluminum alloy plate for a printing plate according to the present invention, in addition to a predetermined chemical component, a surface is provided with a predetermined number of intermetallic compounds having a particle diameter of 1 to 10 μm. The pits are uniformly formed on the rough electrolytic surface, and the size of each pit is substantially constant.

【0057】また、本発明に係る印刷版用アルミニウム
合金板の製造方法は、所定の化学成分を有するアルミニ
ウム合金鋳塊を所定の条件で均質化処理及び熱間圧延す
るので、表面に粒子径1乃至10μmの金属間化合物個
数が所定量存在し、粗面化ピットが電解粗面に均一に形
成されるとともに、各ピットの大きさが略一定となる印
刷版用アルミニウム合金板を得ることができる。
In the method for producing an aluminum alloy plate for a printing plate according to the present invention, an aluminum alloy ingot having a predetermined chemical composition is subjected to homogenization treatment and hot rolling under predetermined conditions, so that a particle size of 1 It is possible to obtain an aluminum alloy plate for a printing plate in which the number of intermetallic compounds of from 10 to 10 μm is present in a predetermined amount, the roughened pits are uniformly formed on the rough electrolytic surface, and the size of each pit is substantially constant. .

フロントページの続き (51)Int.Cl.6 識別記号 FI C22F 1/00 682 C22F 1/00 682 683 683 691 691B Continued on the front page (51) Int.Cl. 6 Identification code FI C22F 1/00 682 C22F 1/00 682 683 683 691 691B

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 Fe:0.20乃至0.6重量%、S
i:0.03乃至0.15重量%及びTi:0.005
乃至0.05重量%を含有し、残部がAl及び不可避的
不純物からなる組成を有し、前記元素の一部又は全部は
金属間化合物を形成しており、前記金属間化合物のう
ち、表面に存在し粒子径が1乃至10μmである金属間
化合物が1000乃至8000個/mm2であることを
特徴とする印刷版用アルミニウム合金板。
1. Fe: 0.20 to 0.6% by weight, S
i: 0.03 to 0.15% by weight and Ti: 0.005
And 0.05% by weight, with the balance having a composition consisting of Al and unavoidable impurities, and a part or all of the elements form an intermetallic compound. An aluminum alloy plate for a printing plate, wherein the number of intermetallic compounds having a particle size of 1 to 10 μm is 1000 to 8000 / mm 2 .
【請求項2】 Fe:0.20乃至0.6重量%、S
i:0.03乃至0.15重量%、Ti:0.005乃
至0.05重量%及びNi:0.005乃至0.20重
量%を含有し、残部がAl及び不可避的不純物からなる
組成を有し、前記元素の一部又は全部は金属間化合物を
形成しており、前記金属間化合物のうち、表面に存在し
粒子径が1乃至10μmである金属間化合物が1000
乃至8000個/mm2であることを特徴とする印刷版
用アルミニウム合金板。
2. Fe: 0.20 to 0.6% by weight, S
i: 0.03 to 0.15% by weight, Ti: 0.005 to 0.05% by weight, and Ni: 0.005 to 0.20% by weight, with the balance being Al and unavoidable impurities. A part or all of the elements form an intermetallic compound, and among the intermetallic compounds, 1000 of the intermetallic compounds having a particle diameter of 1 to 10 μm on the surface are present.
An aluminum alloy plate for a printing plate, wherein the number is 8000 / mm 2 .
【請求項3】 表面に存在する粒子径1乃至5μmの金
属間化合物個数の割合が、表面に存在する粒子径1乃至
10μmの金属間化合物個数の80%以上であることを
特徴とする請求項1又は2に記載の印刷版用アルミニウ
ム合金板。
3. The method according to claim 1, wherein the ratio of the number of intermetallic compounds having a particle diameter of 1 to 5 μm existing on the surface is 80% or more of the number of intermetallic compounds having a particle diameter of 1 to 10 μm existing on the surface. 3. The aluminum alloy plate for a printing plate according to 1 or 2.
【請求項4】 Fe:0.20乃至0.6重量%、S
i:0.03乃至0.15重量%及びTi:0.005
乃至0.05重量%を含有し、残部がAl及び不可避的
不純物からなるアルミニウム合金鋳塊に、500乃至6
30℃の温度で均質化処理する工程と、次いで開始温度
を400乃至450℃として熱間圧延する工程とを有
し、これにより表面に粒子径1乃至10μmの金属間化
合物が1000乃至8000個/mm2析出した印刷版
用アルミニウム合金板を得ることを特徴とする印刷版用
アルミニウム合金板の製造方法。
4. Fe: 0.20 to 0.6% by weight, S
i: 0.03 to 0.15% by weight and Ti: 0.005
To 0.05% by weight, with the balance being 500 to 6%
A step of homogenizing at a temperature of 30 ° C., and then a step of hot rolling at a starting temperature of 400 to 450 ° C., whereby 1000 to 8000 intermetallic compounds having a particle diameter of 1 to 10 μm are formed on the surface. A method for producing an aluminum alloy plate for a printing plate, comprising obtaining an aluminum alloy plate for a printing plate having a thickness of 2 mm2.
【請求項5】 Fe:0.20乃至0.6重量%、S
i:0.03乃至0.15重量%、Ti:0.005乃
至0.05重量%及びNi:0.005乃至0.20重
量%を含有し、残部がAl及び不可避的不純物からなる
アルミニウム合金鋳塊に、500乃至630℃の温度で
均質化処理する工程と、次いで開始温度を400乃至4
50℃として熱間圧延する工程とを有し、これにより表
面に粒子径1乃至10μmの金属間化合物が1000乃
至8000個/mm2析出した印刷版用アルミニウム合
金板を得ることを特徴とする印刷版用アルミニウム合金
板の製造方法。
5. Fe: 0.20 to 0.6% by weight, S
i: an aluminum alloy containing 0.03 to 0.15% by weight, Ti: 0.005 to 0.05% by weight, and Ni: 0.005 to 0.20% by weight, with the balance being Al and unavoidable impurities Subjecting the ingot to a homogenization treatment at a temperature of 500 to 630 ° C., and then to a starting temperature of 400 to 4
Hot rolling at 50 ° C. to obtain an aluminum alloy plate for a printing plate having 1000 to 8000 particles / mm 2 of intermetallic compound having a particle diameter of 1 to 10 μm deposited on the surface. Manufacturing method of aluminum alloy plate for plate.
【請求項6】 前記熱間圧延工程の後に、冷間圧延工
程、中間焼鈍工程及び最終冷間圧延工程を有することを
特徴とする請求項4又は5に記載の印刷版用アルミニウ
ム合金板の製造方法。
6. The production of an aluminum alloy plate for a printing plate according to claim 4, further comprising a cold rolling step, an intermediate annealing step, and a final cold rolling step after the hot rolling step. Method.
JP9285866A 1997-10-17 1997-10-17 Aluminum alloy plate for printing plate and manufacture thereof Pending JPH11115333A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9285866A JPH11115333A (en) 1997-10-17 1997-10-17 Aluminum alloy plate for printing plate and manufacture thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9285866A JPH11115333A (en) 1997-10-17 1997-10-17 Aluminum alloy plate for printing plate and manufacture thereof

Publications (1)

Publication Number Publication Date
JPH11115333A true JPH11115333A (en) 1999-04-27

Family

ID=17697061

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9285866A Pending JPH11115333A (en) 1997-10-17 1997-10-17 Aluminum alloy plate for printing plate and manufacture thereof

Country Status (1)

Country Link
JP (1) JPH11115333A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001219662A (en) * 2000-02-07 2001-08-14 Kodak Polychrome Graphics Japan Ltd Aluminum alloy substrate for printing plate
US6494137B2 (en) 2000-07-11 2002-12-17 Fuji Photo Film Co., Ltd. Support for lithographic printing plate and presensitized plate
EP1293579A2 (en) * 2001-09-12 2003-03-19 Fuji Photo Film Co., Ltd. Support for lithographic printing plate and presensitized plate
WO2003057934A1 (en) 2001-12-28 2003-07-17 Mitsubishi Aluminum Co., Ltd. Aluminum alloy plate for lithographic printing form and method for production thereof and lithographic printing form
JP2007131917A (en) * 2005-11-10 2007-05-31 Kobe Steel Ltd Aluminum alloy sheet for printing plate and its production method
WO2008069180A1 (en) * 2006-12-05 2008-06-12 Kabushiki Kaisha Kobe Seiko Sho High-strength aluminum alloy plate for printing plate
CN102337430A (en) * 2011-09-03 2012-02-01 乳源东阳光精箔有限公司 Aluminum alloy printing plate substrate and fabricating method thereof
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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001219662A (en) * 2000-02-07 2001-08-14 Kodak Polychrome Graphics Japan Ltd Aluminum alloy substrate for printing plate
US6494137B2 (en) 2000-07-11 2002-12-17 Fuji Photo Film Co., Ltd. Support for lithographic printing plate and presensitized plate
EP1293579A2 (en) * 2001-09-12 2003-03-19 Fuji Photo Film Co., Ltd. Support for lithographic printing plate and presensitized plate
EP1293579A3 (en) * 2001-09-12 2004-04-07 Fuji Photo Film Co., Ltd. Support for lithographic printing plate and presensitized plate
US6808864B2 (en) 2001-09-12 2004-10-26 Fuji Photo Film Co., Ltd. Support for lithographic printing plate and presensitized plate
CN1314546C (en) * 2001-09-12 2007-05-09 富士胶片株式会社 Support device for offset printing plate and offset printing plate raw sheet
WO2003057934A1 (en) 2001-12-28 2003-07-17 Mitsubishi Aluminum Co., Ltd. Aluminum alloy plate for lithographic printing form and method for production thereof and lithographic printing form
JP2007131917A (en) * 2005-11-10 2007-05-31 Kobe Steel Ltd Aluminum alloy sheet for printing plate and its production method
WO2008069180A1 (en) * 2006-12-05 2008-06-12 Kabushiki Kaisha Kobe Seiko Sho High-strength aluminum alloy plate for printing plate
CN102666940A (en) * 2009-12-25 2012-09-12 富士胶片株式会社 Insulated substrate, process for production of insulated substrate, process for formation of wiring line, wiring substrate, and light-emitting element
KR101365344B1 (en) * 2011-01-28 2014-02-20 가부시키가이샤 고베 세이코쇼 Aluminum alloy plate for printing plate and manufacturing method thereof
CN102337430A (en) * 2011-09-03 2012-02-01 乳源东阳光精箔有限公司 Aluminum alloy printing plate substrate and fabricating method thereof

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