JPH09101590A - Silver halide color photographic sensitive material and its packaged article - Google Patents

Abstract

PROBLEM TO BE SOLVED: To prevent deterioration in color development density and pressure fog occurring at the time of winding a long size of the photosensitive material and storing it at high temperature by incorporating a specified compound and a specified coupler in at least one of the layers of the photosensitive material. SOLUTION: One of the layers contains at least one kind of compounds selected from formulae I-III and a coupler represented by formula IV, and in formula I-IV, Ra1 is an alkyl or alkenyl group or the like; Ra2 is an H atom or a group as shown in Ra1 ; X is a heterocyclic group except an s-triazine ring; Rb1 is an alkyl or alkenyl group or the like; Y is a nonmetallic atomic group necessary to form a 5-membered ring together with the -N=C group through a -N(Rc1 )- or -C(Rc2 )(Rc3 )- or the like; each of Rc1 -Rc3 is an H atom or a substituent; R1 is an alkyl group or the like; and Z1 is a group to be released by reaction with the oxidation product of an aromatic primary amine color developing agent.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to a silver halide color photographic light-sensitive material and a package of the light-sensitive material. Particularly, a silver halide color photographic light-sensitive material (hereinafter, also referred to as a light-sensitive material) capable of preventing a decrease in color density and pressure fog that occur when the light-sensitive material is rolled up and stored at high temperature.
And a package of the light-sensitive material.

[0002]

2. Description of the Related Art In a silver halide color photographic light-sensitive material, especially a color light-sensitive material for photographing, it is left in various environments for a long time after the light-sensitive material is manufactured and before it is developed. There is a demand for a stable light-sensitive material in which the photographic performance does not fluctuate and the finished quality of development is always constant. As one of the methods, it is known to use a hydroxylamine compound in a photographic light-sensitive layer. For example, in U.S. Pat. Nos. 4,339,515 and 4,330,606, the use of the compound improves the storage stability of a color image formed by a coupling reaction between a coupler and an oxidized form of a developing agent. It will be disclosed. However, in these techniques, when the light-sensitive material is rolled up for a long time and stored at a high temperature, the color density is lowered or pressure fog occurs. Further, a compound having an S-triazine ring is described as a compound which improves the storage stability of the above-mentioned light-sensitive material. For example, Japanese Unexamined Patent Publication No.
No. 59-97, No. 62-546, that the storage stability of a latent image is improved by using it in combination with a compound having an active vinyl group.
No. 134 discloses that fog is reduced when used in combination with an emulsion comprising tabular silver halide grains. Also in the above technique using a compound having an S-triazine (1,3,5-triazine) ring, when the photosensitive material is rolled up for a long time and stored at a high temperature, the color density is lowered or pressure fog occurs. It was

On the other hand, Japanese Patent Application Laid-Open Nos. 57-35858 and 51-20826 disclose specific 5-pyrazolone type couplers exhibiting excellent color development. But,
The 5-pyrazolone type coupler described in this publication still has insufficient color developability, and when the light-sensitive material was rolled up for a long time and stored at high temperature, the color density was lowered and pressure fog occurred. .

[0004]

SUMMARY OF THE INVENTION Therefore, the present invention is directed to a silver halide color photographic light-sensitive material and a silver halide color photographic light-sensitive material capable of preventing a decrease in color density and pressure fog which occur when the light-sensitive material is rolled up for a long time and stored at high temperature. The purpose is to provide a package.

[0005]

As a result of earnest studies, the inventors of the present invention have found that the reduction of color density and the prevention of pressure fog that occur when a sensitive material is rolled up for a long time and stored at a high temperature are used to prevent a photosensitive material. A silver halide color photographic light-sensitive material using a specific hydroxylamine compound or hydroxamic acid compound in at least one of the light-sensitive layers on a support and using a specific 5-pyrazolone type 2-equivalent coupler. They have found that they can be improved, and that they can be improved even with a package in which the photosensitive material is stored in a specific cartridge, and have completed the present invention.

That is, the present invention includes (1) a silver halide color photographic light-sensitive material having at least one photosensitive silver halide emulsion layer and at least one light-insensitive layer on one side of a support.
The layer contains at least one compound selected from the following general formula (AI), general formula (A-II) or general formula (A-III), and a coupler represented by the following general formula (m): A silver halide color photographic light-sensitive material characterized by containing.

[0007]

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In the general formula (AI), R _a1 is an alkyl group, an alkenyl group, an aryl group, an acyl group, an alkyl or aryl sulfonyl group, an alkyl or aryl sulfinyl group, a carbamoyl group, a sulfamoyl group, an alkoxycarbonyl group or aryl. It represents an oxycarbonyl group, and R _a2 represents a hydrogen atom or a group represented by R _a1 . However, when R _a1 is an alkyl group, an alkenyl group or an aryl group, R _a2 is an acyl group, an alkyl or arylsulfonyl group, an alkyl or arylsulfinyl group,
A carbamoyl group, a sulfamoyl group, an alkoxycarbonyl group or an aryloxycarbonyl group. R _a1
And R _a2 may combine with each other to form a 5- to 7-membered ring, provided that they do not form an S-triazine ring. In formula (A-II), X represents a heterocyclic group excluding the S-triazine ring, and R _b1 represents an alkyl group, an alkenyl group or an aryl group. X and R _b1 may combine with each other to form a 5- to 7-membered ring, provided that they do not form an S-triazine ring. In the general formula (A-III), Y represents a nonmetallic atom group necessary for forming a 5-membered ring together with -N = C-. Y further represents a group of non-metal atoms necessary for forming a 6-membered ring together with the -N = C- group, and the terminal of Y bonded to the carbon atom of the -N = C- group
-N (R _c1 )-, -C (R _c2 ) (R _c3 )-, -C (R _c4 ) =, -O-, -S-
Represents a group selected from among the groups (bonded to the carbon atom of -N = C- on the left side of each group). However, it does not form an S-triazine ring. R _{c1 to} R _c4 each represent a hydrogen atom or a substituent.

[0009]

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In the formula (m), R ₁ represents an alkyl group, an aryl group, an acyl group or a carbamoyl group. Ar represents a phenyl group or a phenyl group substituted with one or more halogen atoms, an alkyl group, a cyano group, an alkoxy group, an alkoxycarbonyl group, an acylamino group, a sulfonamide group, a sulfonyl group or a sulfamoyl group. Z ₁ represents a group capable of splitting off upon reaction with an oxidized product of an aromatic primary amine color developing agent. (2) The silver halide color photographic light-sensitive material as described in (1) above, which has a magnetic recording layer containing magnetic material particles on the side opposite to the side having the emulsion layer and the support. (3) A spool 1 in which a photographic light-sensitive material 102 having an emulsion layer on a support is wound inside a cartridge body 101.
03 is rotatably accommodated, and the tip of the photographic light-sensitive material can be freely sent out of the cartridge by rotation of the spool. The cartridge body sends out the photographic light-sensitive material. In the photographic light-sensitive material package 100 having a pair of flanges 113 and 114 for holding the photographic light-sensitive material inside the both ends of the spool shaft 112 of the spool, the photographic light-sensitive material is the above-mentioned (1). ) Or (2), which is the silver halide color photographic light-sensitive material, and a photographic light-sensitive material package.

The present invention comprises at least one layer of a silver halide color photographic light-sensitive material having at least one light-sensitive silver halide emulsion layer and at least one light-insensitive layer on one side of a support. ) To (A-III) and a coupler represented by the general formula (m). Thus, the specific general formulas (AI) to (A
-When the compound represented by the formula (III) is used in combination with the specific 2-equivalent pyrazolone type coupler represented by the general formula (m), it occurs when the light-sensitive material is rolled long and stored at high temperature. The reduction in color density and pressure fog can be effectively prevented, and the object of the present invention is achieved.

In the present invention, a light-sensitive material having a magnetic layer containing magnetic particles in a back layer opposite to the emulsion layer with a support interposed therebetween is preferable. Usually, by providing a magnetic layer to a light-sensitive material, it tends to be rolled up for a long time, and the color density tends to decrease when it is stored at high temperature, and the pressure fog tends to further deteriorate. The present invention is remarkably effective in solving these problems, and solves this problem brilliantly.

Further, the specific cartridge according to the present invention shows a tendency that the color density is lowered and the pressure fog is further deteriorated when the cartridge is longly wound and stored at high temperature. The packaging body in which the sensitive material of the present invention is housed in a specific cartridge solves the above-mentioned problems that occur even in such a packaging body, and the object of the present invention can be achieved.

[0014]

BEST MODE FOR CARRYING OUT THE INVENTION The compounds represented by formulas (AI) to (A-III) will be described in more detail. The alkyl group referred to in the present invention is a linear, branched, or cyclic alkyl group, and may have a substituent. In the general formula (AI), _Ra1 is an alkyl group (preferably an alkyl group having 1 to 36 carbon atoms such as methyl, ethyl, i-propyl, cyclopropyl, butyl, isobutyl, cyclohexyl,
t-octyl, decyl, dodecyl, hexadecyl, benzyl), an alkenyl group (preferably an alkenyl group having 2 to 36 carbon atoms such as allyl, 2-butenyl, isopropenyl, oleyl, vinyl), an aryl group (preferably having a carbon number of 2 to 36) An aryl group having 6 to 40 atoms such as phenyl and naphthyl; an acyl group (preferably an acyl group having 2 to 36 carbon atoms such as acetyl, benzoyl, pivaloyl, α-
(2,4-di-tert-amylphenoxy) butyryl,
(3-Cyclohexen-1-yl) -carbonyl, myristoyl, stearoyl, naphthoyl, m-pentadecylbenzoyl, (5-norbornen-2-yl) carbonyl, isonicotinoyl), alkyl or arylsulfonyl group (preferably having 1 to 1 carbon atoms). 36 alkyl or arylsulfonyl groups such as methanesulfonyl, octanesulfonyl, benzenesulfonyl, toluenesulfonyl), alkyl or arylsulfinyl groups (preferably alkyl or arylsulfinyl groups having 1 to 40 carbon atoms such as methanesulfinyl, benzenesulfinyl), Carbamoyl group (including N-substituted carbamoyl group, preferably a carbamoyl group having 1 to 40 carbon atoms, for example, N-ethylcarbamoyl, N-phenylcarbamoyl, N, N-dimethyl Rubamoiru, N- butyl -N-
(Phenylcarbamoyl), sulfamoyl group (including N-substituted sulfamoyl group, preferably having 1 to 40 carbon atoms)
A sulfamoyl group of N-methylsulfamoyl, N, N-diethylsulfamoyl, N-phenylsulfamoyl, N-cyclohexyl-N-phenylsulfamoyl, N-ethyl-N-dodecylsulfamoyl) , An alkoxycarbonyl group (preferably having 2 to 2 carbon atoms)
36 alkoxycarbonyl groups such as methoxycarbonyl, cyclohexyloxycarbonyl, benzyloxycarbonyl, isoamyloxycarbonyl, hexadecyloxycarbonyl) or aryloxycarbonyl groups (preferably aryloxycarbonyl groups having 7 to 40 carbon atoms, such as phenoxycarbonyl). , Naphthoxycarbonyl). R _a2 is a hydrogen atom or the above R _a1
Represents a group represented by.

In the general formula (A-II), the heterocyclic group represented by X is a 5- to 7-membered S-triazine ring (1) having at least one nitrogen atom, sulfur atom, oxygen atom or phosphorus atom as a ring-constituting atom. , 3,5-triazine ring), which is a group forming a hetero ring, and the bonding position of the hetero ring (1
The position of the valence group) is preferably a carbon atom, for example 1,
2,4-triazin-3-yl, pyridin-2-yl,
Pyrazinyl, pyrimidinyl, purinyl, quinolyl, imidazolyl, 1,2,4-triazol-3-yl, benzimidazol-2-yl, thienyl, furyl, imidazolidinyl, pyrrolinyl, tetrahydrofuryl, morpholinyl, phosphinolin-2-yl. Represent. R _b1 has the same meaning as the alkyl group, alkenyl group or aryl group in R _a1 of the above general formula (AI).

In the general formula (A-III), Y is -N = C
-A group of non-metal atoms required to form a 5-membered ring with
(For example, the ring group formed is imidazolyl or benzimidazole.
Zolyl, 1,3-thiazol-2-yl, 2-imidazo
Lin-2-yl, purinyl, 3H-indole-2-i
Re). Y is a 6-membered ring together with -N = C- group
A non-metal atomic group necessary to form
The end of Y bonded to the carbon atom of the ═C-group is —N (R_C1)-, -C
(R_C2) (R_C3)-, -C (R_C4) =, -O-, -S-
Groups (bonded to the -N = C- carbon atom to the left of each group
Represents). However, S-triazine (1,3,5-to
It does not form a lyazine) ring. R_c1~ R_c4Are the same
Or a hydrogen atom or a substituent (for example,
Alkyl, alkenyl, aryl, alkoxy,
Aryloxy group, alkylthio group, arylthio group,
Alkylamino group, arylamino group, halogen atom)
Represents Where an alkyl group, an alkenyl group, an aryl
The ru group is R in the general formula (A-1). _a1An alkyl group in
Represents the same meaning as a alkenyl group or aryl group,
Alkyl of Coxy, Alkylthio and Alkylamino groups
Group, aryloxy group, arylthio group, aryl
The aryl group of the ruamino group is also represented by R of the general formula (A-1)._a1To
It has the same meaning as described above. Halogen atom
Represents, for example, chlorine, bromine or fluorine atom. By Y
Examples of the 6-membered ring group formed include quinolyl and isoquino.
Ryl, phthalazinyl, quinoxalinyl, 6H-1,2,
5-thiadiazin-6-yl is mentioned.

In the general formula (AI) or (A-II), R _a1 and R _a2 , and X and R _b1 may be bonded to each other to form a 5- to 7-membered ring, for example, a succinimide ring or a phthalimide ring. , Triazole ring, urazole ring, hydantoin ring, and 2-oxo-4-oxazolidinone ring. However, the S-triazine ring is excluded. General formula (AI)
Each group of the compounds represented by to (A-III) may be further substituted with a substituent. Examples of these substituents include an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a hydroxy group, an alkoxy group, an aryloxy group,
Alkylthio group, arylthio group, amino group, acylamino group, sulfonamide group, alkylamino group, arylamino group, carbamoyl group, sulfamoyl group, sulfo group, carboxyl group, halogen atom, cyano group, nitro group, sulfonyl group, acyl group , An alkoxycarbonyl group, an aryloxycarbonyl group, an acyloxy group, a hydroxyamino group and the like.

In the general formula (AI), R _a2 is a hydrogen atom, an alkyl group, an alkenyl group or an aryl group, and R _a1 is an acyl group, an alkyl or aryl sulfonyl group, an alkyl or aryl sulfinyl group or a carbamoyl group. , Sulfamoyl group, alkoxycarbonyl group,
It is preferably an aryloxycarbonyl group, more preferably R _a2 is an alkyl group or an alkenyl group, and R _a1 is an acyl group, an alkyl or arylsulfonyl group, a carbamoyl group, a sulfamoyl group, an alkoxycarbonyl group, or aryloxy. A compound that is a carbonyl group. Most preferably, R _a2 is an alkyl group and R _a1 is an acyl group.

In the general formula (A-II), R _b1 is preferably an alkyl group or an alkenyl group, more preferably an alkyl group. On the other hand, the general formula (A-II) is preferably represented by the following general formula (A-II-1).

[0020]

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In the general formula (A-II-1), R_b1Haichi
R in general formula (A-II)_b1Represents X ₁Is -C = N-
The non-metallic atomic group necessary to form a 5- or 6-membered ring is shown below.
I forgot. A compound represented by the general formula (A-II-1)
C, X₁Is more preferably a 5- to 6-membered heteroaromatic ring
preferable. However, it does not form an S-triazine ring.
No.

Of the compounds represented by the general formula (A-III), Y is preferably a group of non-metal atoms necessary for forming a 5-membered ring, and is bonded to a carbon atom of a -N = C- group. It is more preferable that the terminal atom of Y is a nitrogen atom. However, it does not form an S-triazine ring. Most preferably, Y forms an imidazoline ring. This imidazoline ring may be condensed with a benzene ring.

Among the compounds represented by the general formulas (AI) to (A-III), compounds having a total carbon number of 15 or less are preferable in that they act on layers other than the additive layer, and vice versa. A compound having a total carbon number of 16 or more is preferable for the purpose of acting only on the additive layer. General formula (AI)-(A-
Among the compounds represented by III), the general formula (AI),
Those represented by (A-II) are preferable, and those represented by general formula (AI) are more preferable. Specific examples of the compounds represented by formulas (AI) to (A-III) of the present invention are shown below, but the present invention is not limited thereto.

[0024]

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[0025]

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[0026]

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[0027]

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[0028]

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These compounds and the above-mentioned general formula (AI)
The correspondence with (A-III) is as follows. General formula (AI): A-1 to A-9, A-11 to A-1
8, A-33 to A-55. General formula (A-II): A-10, A-20, A-30. General formula (A-III): A-19, A-21 to A-29, A
-31, A-32. These compounds of the present invention are described in J. Org. Chem., 27, 405.
4 ('62), J. Amer. Chem. Soc., 73,2981 ('51), Japanese Patent Publication No. 4
It can be easily synthesized by the method described in 9-10692 or the like or a method similar thereto. In the present invention, the compounds represented by the general formulas (AI) to (A-III) are emulsified even if dissolved in water, a water-soluble solvent such as methanol or ethanol, or a mixed solvent thereof. It may be added by dispersion. Further, they may be added in advance during the preparation of the emulsion. When it dissolves in water, the higher or lower the pH, the higher the solubility, the pH
It may be added by dissolving it by raising or lowering.
In the present invention, two or more kinds of the compounds represented by the general formulas (AI) to (A-III) may be used in combination. For example, using both water-soluble and oil-soluble
It is advantageous in photographic performance. Compounds (A-I) to (A-III)
The coating amount of 0.01 to 0.01
100 mg / m ² is preferred. 0.1 to 50 mg / m ² is more preferable, and 1 to 20 mg / m ² is even more preferable. These compounds are used in at least one layer of the silver halide photosensitive layer, but the same compound may be used in a plurality of layers.
Different compounds may be used in each photosensitive layer.
Further, at the same time as the photosensitive layer, a non-photosensitive layer, for example, an intermediate layer,
It can also be used in a colloidal silver-containing yellow filter layer, an AH layer and a protective layer.

In the present invention, general formulas (AI) to
The compound represented by (A-III) is preferably an oil-soluble compound. It is particularly preferable to use the oil-soluble compound in the same layer containing the coupler represented by the general formula (m) described below. Furthermore, water-soluble general formulas (AI) to (A-III)
You may add the compound represented by.

By using the compounds represented by the general formulas (A-I) to (A-III) of the present invention and the coupler represented by the general formula (m) described later in combination, a light-sensitive material is rolled up in a long length. It is possible to prevent a decrease in the color density of the coupler and pressure fog that occur when stored under high temperature conditions, and the object of the present invention can be achieved. The pressure fog occurs in a portion inside the outer side of the photosensitive material. Here, the long winding means that the winding has 20 or more turns regardless of the diameter of the winding core, and particularly, the winding is more than 30 turns. Further, in the present invention, the high temperature when the light-sensitive material is stored at a high temperature means a temperature range higher than a normal room temperature, and specifically, the inside of the vehicle when the vehicle is left in the hot sun in summer. Refers to the approximate temperature.
Therefore, the high temperature is 35 ° C or higher, and the upper limit is 90 ° C.
The temperature range up to ° C.

Next, the coupler represented by formula (m) will be described in detail. In formula (m), R ₁ represents an alkyl group, an aryl group, an acyl group, or a carbamoyl group, and more specifically, an alkyl group (preferably having 1 carbon atom).
~ 32 linear or branched alkyl groups such as methyl, ethyl, propyl, isopropyl, butyl, t-butyl, 1-octyl, tridecyl), cycloalkyl groups (preferably cycloalkyl having 3 to 8 carbon atoms). An alkyl group, for example, cyclopropyl, cyclopentyl, cyclohexyl, 1-norbornyl, 1-adamantyl),
Aryl group (preferably an aryl group having 6 to 32 carbon atoms, for example, phenyl, 1-naphthyl, 2-naphthyl), an acyl group (preferably an acyl group having 1 to 32 carbon atoms, for example, formyl, acetyl, pivaloyl). , Benzoyl, tetradecanoyl) or a carbamoyl group (preferably a carbamoyl group having 1 to 32 carbon atoms, for example, carbamoyl, N, N-dibutylcarbamoyl, N-ethyl-N-octylcarbamoyl, N-propylcarbamoyl). Represents The group represented by R ₁ may further have a substituent, and as the substituent, a halogen atom (for example,
Fluorine atom, chlorine atom, bromine atom), alkyl group (preferably a linear or branched alkyl group having 1 to 32 carbon atoms, such as methyl, ethyl, propyl, isopropyl, butyl, t-butyl, 1- Octyl, tridecyl), a cycloalkyl group (preferably a cycloalkyl group having 3 to 8 carbon atoms, for example, cyclopropyl, cyclopentyl, cyclohexyl, 1-norbornyl, 1-adamantyl), an alkenyl group (preferably having 2 to 32 carbon atoms).
An alkenyl group of, for example, vinyl, allyl, 3-buten-1-yl), an aryl group (preferably an aryl group having 6 to 32 carbon atoms, for example, phenyl, 1-naphthyl, 2-naphthyl), a heterocycle A group (preferably having 1 carbon atom)
To 32 heterocyclic groups of 5 to 8 members, such as 2
-Thienyl, 4-pyridyl, 2-furyl, 2-pyrimidinyl, 1-pyridyl, 2-benzothiazolyl, 1-imidazolyl, 1-pyrazolyl, benzotriazole-2-
Yl), cyano group, silyl group (preferably having 3 to 3 carbon atoms)
2 silyl groups, for example, trimethylsilyl, triethylsilyl, tributylsilyl, t-butyldimethylsilyl, t-hexyldimethylsilyl), nitro group,

Hydroxyl group, alkoxy group (preferably alkoxy group having 1 to 32 carbon atoms, for example, methoxy, ethoxy, 1-butoxy, 2-butoxy, isopropoxy, t-butoxy, dodecyloxy), cycloalkyloxy group. (Preferably a cycloalkyloxy group having 3 to 8 carbon atoms, for example, cyclopentyloxy, cyclohexyloxy), an aryloxy group (preferably an aryloxy group having 6 to 32 carbon atoms, for example, phenoxy, 2-naphthoxy), Heterocyclic oxy group (preferably a heterocyclic oxy group having 1 to 32 carbon atoms, for example, 1-phenyltetrazole-5-oxy, 2-tetrahydropyranyloxy, 2-furyloxy), silyloxy group (preferably carbon) A silyloxy group of the number 1 to 32, for example, trimethylsilyl Xy, t-butyldimethylsilyloxy, diphenylmethylsilyloxy), an acyloxy group (preferably an acyloxy group having 2 to 32 carbon atoms, for example, acetoxy, pivaloyloxy, benzoyloxy, dodecanoyloxy), an alkoxycarbonyloxy group (preferably Is an alkoxycarbonyloxy group having 2 to 32 carbon atoms, for example, ethoxycarbonyloxy, t-butoxycarbonyloxy), cycloalkyloxycarbonyloxy (preferably a cycloalkyloxycarbonyloxy group having 4 to 9 carbon atoms, for example, Cyclohexyloxycarbonyloxy), an aryloxycarbonyloxy group (preferably an aryloxycarbonyloxy group having 7 to 32 carbon atoms, for example, phenoxycarbonyloxy), carbamoyloxy group. Group (preferably a carbamoyloxy group having 1 to 32 carbon atoms, for example, N, N-dimethylcarbamoyloxy, N-butylcarbamoyloxy), a sulfamoyloxy group (preferably sulfamoyloxy having 1 to 32 carbon atoms) Group, for example, N, N-diethylsulfamoyloxy, N-propylsulfamoyloxy), an alkanesulfonyloxy group (preferably an alkanecarbonyloxy group having 1 to 32 carbon atoms, for example, methanesulfonyloxy, Xadecanesulfonyloxy), arenesulfonyloxy (preferably an arenesulfonyloxy group having 6 to 32 carbon atoms, for example, benzenesulfonyloxy),

Acyl group (preferably an acyl group having 1 to 32 carbon atoms, such as formyl, acetyl, pivaloyl,
Benzoyl, tetradecanoyl), an alkoxycarbonyl group (preferably an alkoxycarbonyl group having 2 to 32 carbon atoms, for example, methoxycarbonyl, ethoxycarbonyl, octadecyloxycarbonyl), a cycloalkyloxycarbonyl group (preferably having 2 to 32 carbon atoms). A cycloalkyloxycarbonyl group of, for example, cyclopentyloxycarbonyl, cyclohexyloxycarbonyl), an aryloxycarbonyl group (preferably an aryloxycarbonyl group having 7 to 32 carbon atoms, for example,
Phenoxycarbonyl), a carbamoyl group (preferably a carbamoyl group having 1 to 32 carbon atoms, such as carbamoyl, N, N-dibutylcarbamoyl, N-ethyl-N).
-Octylcarbamoyl, N-propylcarbamoyl),

Amino group (preferably an amino group having 32 or less carbon atoms, for example, amino, methylamino, N, N-dioctylamino, tetradecylamino, octadecylamino), anilino group (preferably having 6 to 32 carbon atoms). Anilino group, for example, anilino, N-methylanilino),
Heterocyclic amino group (preferably a heterocyclic amino group having 1 to 32 carbon atoms, for example, 4-pyridylamino), carbonamido group (preferably a carbonamido group having 2 to 32 carbon atoms, for example, acetamide, benzamide, Tetradecanamide), ureido group (preferably having 1 to 3 carbon atoms)
2 ureido groups, for example, ureido, N, N-dimethylureido, N-phenylureido), imide groups (preferably imide groups having 10 or less carbon atoms, for example, N-succinimide, N-phthalimide), alkoxycarbonyl Amino group (preferably an alkoxycarbonylamino group having 2 to 32 carbon atoms, for example, methoxycarbonylamino, ethoxycarbonylamino, t-butoxycarbonylamino, octadecyloxycarbonylamino), an aryloxycarbonylamino group (preferably having 7 carbon atoms)
To 32 aryloxycarbonylamino groups such as phenoxycarbonylamino), sulfonamide groups (preferably C1 to C32 sulfonamide groups such as methanesulfonamide, butanesulfonamide,
Benzenesulfonamide, hexadecanesulfonamide), sulfamoylamino group (preferably having 1 to 1 carbon atoms)
32 sulfamoylamino groups, for example, N, N-dipropylsulfamoylamino, N-ethyl-N-dodecylsulfamoylamino, an azo group (preferably an azo group having 1 to 32 carbon atoms, for example, , Phenylazo, 4-methoxyphenylazo),

Alkylthio group (preferably having 1 to 3 carbon atoms)
2 alkylthio groups such as ethylthio and octylthio, arylthio groups (preferably arylthio groups having 6 to 32 carbon atoms such as phenylthio), heterocyclic thio groups (preferably heterocyclic thio groups having 1 to 32 carbon atoms). Group, for example, 2-benzothiazolylthio, 2-pyridylthio, 1-phenyltetrazolylthio), an alkylsulfinyl group (preferably an alkylsulfinyl group having 1 to 32 carbon atoms, for example, dodecanesulfinyl), arenesulfinyl ( It is preferably an arenesulfinyl group having 6 to 32 carbon atoms, for example, benzenesulfinyl), an alkanesulfonyl group (preferably having 1 to 3 carbon atoms).
2, alkanesulfonyl groups such as methanesulfonyl and octanesulfonyl), arenesulfonyl groups (preferably arenesulfonyl groups having 6 to 32 carbon atoms such as benzenesulfonyl and 1-naphthalenesulfonyl), and sulfamoyl groups (preferably carbon Sulfamoyl groups of the number 32 or less, for example, sulfamoyl, N, N
-Dipropylsulfamoyl, N-ethyl-N-dodecylsulfamoyl), sulfo group, phosphonyl group (preferably phosphonyl group having 1 to 32 carbon atoms, for example, phenoxyphosphonyl, octyloxyphosphonyl, phenylphosphonyl) ) And a phosphinoylamino group (diethoxyphosphinoylamino, dioctyloxyphosphinoylamino group).

More preferable substituents of the group represented by R ₁ are a halogen atom, an alkyl group, an alkoxy group, an aryloxy group, an alkoxycarbonyl group, a carbamoyl group, a carbonamido group, an alkoxycarbonylamino group and an aryloxy group. A carbonylamino group, a ureido group, a sulfonamide group, an imide group, an alkanesulfonyl group, an arenesulfonyl group, a phosphonyl group and a phosphinoylamino group.

Ar is substituted with a phenyl group or one or more halogen atoms having 6 to 32 carbon atoms, an alkyl group, a cyano group, an alkoxy group, an alkoxycarbonyl group, an acylamino group, a sulfonamide group, a sulfonyl group or a sulfamoyl group. Represents a phenyl group, for example, phenyl, 2,4,6-trichlorophenyl, 2,5-dichlorophenyl, 2,4-dimethyl-6-methoxyphenyl, 2,6-dichloro-4-methoxyphenyl, 2,6
-Dichloro-4-ethoxycarbonylphenyl, 2,6
-Dichloro-4-cyanophenyl, 4- [2- (2,4
-Di-t-amylphenoxy) butanamide] phenyl. The group represented by Ar may further have a substituent, and preferable substituents are the same as those listed as the substituents of the group represented by R ₁ .

R ₁ is preferably an aryl group or an acyl group. Ar is preferably a 2,4,6-trichlorophenyl group or a 2,5-dichlorophenyl group.
Z ₁ represents a coupling-off group, and the coupling-off group will be described in detail. For example, a halogen atom, an alkoxy group, an aryloxy group, an acyloxy group, a sulfonyloxy group, an amide group, an alkoxycarbonyloxy group, an aryloxycarbonyloxy group. , An alkyl, aryl or heterocyclic thio group, an imide group, a 5-membered or 6-membered nitrogen-containing heterocyclic group, an arylazo group, which are further substituted with a group allowed as a substituent for R _1. Good. More specifically, the coupling-off group represented by Z ₁ is a halogen atom (eg, fluorine atom, chlorine atom, bromine atom), an alkoxy group (eg, dodecyloxy, dodecyloxycarbonylmethoxy, methoxycarbamoylmethoxy, carboxypropyloxy, methane). Sulfonyloxy), aryloxy groups (eg methylphenoxy, 4-tert-butylphenoxy, 4-methoxyphenoxy, 4-methanesulfonylphenoxy, 4- (4-benzyloxyphenylsulfonyl) phenoxy), acyloxy groups (eg acetoxy, tetra Decanoyloxy, benzoyloxy), sulfonyloxy groups (eg methanesulfonyloxy, toluenesulfonyloxy), amide groups (eg dichloroacetylamino, methanesulfonylami) , Triphenylphosphonamide), alkoxycarbonyloxy group (eg ethoxycarbonyloxy, benzyloxycarbonyloxy), aryloxycarbonyloxy group (eg phenoxycarbonyloxy, 2,4,6-trimethylphenoxycarbonyl), alkylthio group (preferably An alkylthio group having 1 to 32 carbon atoms, for example,
Dodecylthio, tetradecylthio, hexadecylthio,
Octadecylthio, tetradecanecarboxylic acid-2-thio), an arylthio group (preferably an arylthio group having 6 to 32 carbon atoms, for example, 2-butoxy-5- (1,
1,3,3-tetramethyl-1-butyl) phenylthio, 2-pivaloylaminophenylthio, 2-phenoxycarbonylaminophenylthio, 2-tetradecanamidophenylthio, 2- (2-octyloxybenzamido) phenylthio, 2- [2- (2,4-di-t-amylphenoxy) butanamide] phenylthio, 4-
[2- (2,4-di-t-amylphenoxy) butanamide] phenylthio), a heterocyclic thio group (preferably a heterocyclic thio group having 1 to 32 carbon atoms, for example, 2-benzothiazolylthio, 2 -Pyridylthio, 1-phenyltetrazolylthio), imide group (for example, succinimide, hydantoinyl, 2,4-dioxooxazolidine-3-
Yl, 3-benzyl-4-ethoxyhydantoin-1-
5) or 6-membered nitrogen-containing heterocyclic group (1-pyrazolyl, 1-benzotriazolyl, 5-chloro-1,2,4-triazol-1-yl, 1,2-dihydro- 2-oxo-1-pyridyl), an arylazo group (for example, phenylazo, 4-methoxyphenylazo,
4-doderoxy-3-methoxyphenylazo, 4-hydroxy-3-methylphenylazo, 4-pivaloylaminophenylazo, 4-tetradecyloxy-3-methylphenylazo) and the like. In addition to these, Z ₁ may take the form of a bis-type coupler obtained by condensing a 4-equivalent coupler with an aldehyde or a ketone as a leaving group bonded via a carbon atom. Further, Z ₁ may contain a photographically useful group such as a development inhibitor or a development accelerator. Preferred Z ₁ is an alkylthio group, an arylthio group or a heterocyclic thio group, or a 5- or 6-membered nitrogen-containing heterocyclic group bonded to the coupling active position with a nitrogen atom.

Examples of the magenta coupler compound represented by formula (m) are shown below, but the invention is not limited thereto.

[0041]

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[0042]

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[0043]

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[0044]

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[0045]

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[0046]

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[0047]

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[0048]

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[0049]

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[0050]

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[0051]

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[0052]

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[0053]

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[0054]

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Among the magenta couplers represented by the general formula (m), arylthio-releasing couplers and azole-releasing couplers, which are typical two-equivalent couplers, are synthesized in JP-A-57-35858 and 51-2082, respectively.
The method described in No. 6 can be used. Other magenta couplers represented by the general formula (m) can be synthesized by
U.S. Pat. No. 3,519,429, Japanese Patent Publication No. 53-338
It can be synthesized according to the method described in Japanese Patent Publication No. 46.

The addition amount of the silver halide color photographic light-sensitive material of the coupler represented by the general formula (m) of the present invention is 3 ×.
10 ^{−5 to} 3 × 10 ⁻³ mol / m ² , preferably 3 × 10
^{-4 to} 2 × 10 ^-3 mol / m ² and 5 × 10 ^{-4 to} 1.5 × 1
0 ^-3 mol / m ² is more preferable. When the coupler represented by formula (m) of the present invention is used in a plurality of layers, the same coupler may be used in a plurality of layers, or different couplers may be used. Further, multiple couplers may be used in the same layer. The coupler represented by formula (m) of the present invention is a magenta coupler other than the present invention, for example,
1H-pyrazolo [1,5- b ] [1,2,4] triazole coupler and 1H-pyrazolo [5,1- c ] [1,
It can also be used as a 2,4] triazole coupler.

The coupler represented by the general formula (m) of the present invention is preferably used in the same layer as the compound represented by the general formulas (AI) to (A-III). Further, it is possible to prevent a decrease in color density and pressure fog, thereby achieving the object of the present invention.

Next, the magnetic recording layer used in the present invention will be described.
Will be described. The magnetic recording layer used in the present invention is a magnetic recording layer.
Aqueous or organic solvent
This is one in which a solvent-based coating solution is applied on a support. In the present invention
The magnetic particles used are γFe_TwoO_ThreeSuch as ferromagnetic oxidation
Iron, Co deposited γFe _TwoO_Three , Co-coated magnetite, Co-containing magnet
Gnetite, ferromagnetic chromium dioxide, ferromagnetic metal, ferromagnetic
Alloy, hexagonal Ba ferrite, Sr ferrite, Pb ferrite
Light, Ca ferrite, etc. can be used. Co deposited γFe_TwoO
_ThreeCo-coated ferromagnetic iron oxide such as As a shape
Needle, rice grain, sphere, cube, plate, etc.
No. S for specific surface area_BETAt 20m^Two/ g or more is preferable, and 30 m^Two
/ g or more is particularly preferable. The saturation magnetization (σs) of a ferromagnetic material is
Preferably 3.0 × 10^Four ~ 3.0 × 10^FiveA / m, especially preferred
Or 4.0 × 10^Four~ 2.5 × 10^FiveA / m. Ferromagnetic particles
In a table with silica and / or alumina or organic material
Surface treatment may be performed. Further, magnetic particles are disclosed in
Silane coupling to its surface as described in 161032
Or a titanium coupling agent. Special
Inorganic and organic on the surface described in Kaihei 4-259911 and 5-81652
Magnetic particles coated with a substance can also be used.

The binder used in the magnetic particles is a thermoplastic resin, a thermosetting resin, a radiation curable resin, a reactive resin, an acid, an alkali or a biodegradable polymer described in JP-A No. 4-219569, a natural product weight. Coalescence (cellulose derivatives, sugar derivatives, etc.) and mixtures thereof can be used. The above resin has a Tg of -40 ° C to 300 ° C and a weight average molecular weight of 2,000 to 1,000,000. Examples thereof include vinyl copolymers, cellulose diacetate, cellulose triacetate, cellulose derivatives such as cellulose acetate propionate, cellulose acetate butyrate, and cellulose tripropionate, acrylic resins and polyvinyl acetal resins, and gelatin is also preferable. Particularly, cellulose di (tri) acetate is preferable. The binder can be cured by adding an epoxy-based, aziridine-based, or isocyanate-based crosslinking agent. Examples of the isocyanate-based crosslinking agent include isocyanates such as tolylene diisocyanate, 4,4'-diphenylmethane diisocyanate, hexamethylene diisocyanate, and xylylene diisocyanate, and reaction products of these isocyanates with polyalcohol (for example, 3mol of isocyanate and 1m of trimethylolpropane
ol reaction product), and polyisocyanates formed by condensation of these isocyanates.
For example, it is described in JP-A-6-59357.

As a method of dispersing the above-mentioned magnetic material in the binder, a kneader, a pin type mill, an annular type mill, etc. are preferable and a combination thereof is also preferable, as in the method described in JP-A-6-35092. Dispersants described in JP-A-5-088283 and other known dispersants can be used. The thickness of the magnetic recording layer is 0.1 μm to 10 μm, preferably 0.2 μm to 5 μm.
m, more preferably 0.3 μm to 3 μm. The weight ratio between the magnetic particles and the binder is preferably 0.5: 100 to 60: 100.
And more preferably from 1: 100 to 30: 100. The coating amount of magnetic particles is 0.005 to 3 g / m ² , preferably 0.01 to
It is 2 g / m ² , and more preferably 0.02 to 0.5 g / m ² . The transmission yellow density of the magnetic recording layer is preferably from 0.01 to 0.50, more preferably from 0.03 to 0.20, and particularly preferably from 0.04 to 0.15. The magnetic recording layer can be provided on the entire back surface of the photographic support by coating or printing, or in a stripe shape. As a method for applying the magnetic recording layer, an air doctor, blade, air knife, squeeze, impregnation, reverse roll, transfer roll, gravure, kiss, cast, spray, dip, bar, extrusion, etc. can be used. The coating solution described in 341436 is preferred.

The magnetic recording layer has lubricating properties, curl control,
It may have functions such as antistatic, anti-adhesion and head polishing, or may be provided with another functional layer to impart these functions, and at least one kind of particles has a Mohs hardness of 5 or more. The above-mentioned non-spherical inorganic particle abrasives are preferable. As the composition of the non-spherical inorganic particles, oxides such as aluminum oxide, chromium oxide, silicon dioxide, titanium dioxide and silicon carbide, carbides such as silicon carbide and titanium carbide, and fine powders such as diamond are preferable. These abrasives may have their surfaces treated with a silane coupling agent or a titanium coupling agent. These particles may be added to the magnetic recording layer, or may be overcoated (for example, a protective layer, a lubricant layer, etc.) on the magnetic recording layer. As the binder used at this time, the above-mentioned binders can be used, and the same binder as the binder for the magnetic recording layer is preferable. For photosensitive materials having a magnetic recording layer, see US Pat.
5,229,259, 5,215,874 and EP 466,130.

In the light-sensitive material having the above-mentioned magnetic recording layer, the decrease in color density and the pressure fog which occur when the light-sensitive material is rolled up for a long time and stored at high temperature, are more prone to deterioration. The general formula (A-
In the light-sensitive material using the compounds represented by I) to (A-III) and the coupler represented by the general formula (m), the decrease in color density and the pressure fog are improved, and the object of the present invention is Can be achieved.

The structure of the photographic light-sensitive material package of the present invention (hereinafter, also referred to as "photographic film cartridge") 100 will be described below with reference to the drawings. 1 is an exploded perspective view of the photographic film cartridge, FIG. 2 is a view of the photographic film cartridge viewed from the radial direction, and FIG. 3 is a view of the photographic film cartridge viewed from the radial direction at a position different from FIG. The photographic film cartridge 100 includes a cartridge body 101 in which a spool 103 around which a photographic photosensitive material (photo film) 102 is wound is rotatably housed.
A cartridge label 104 is adhered to the outer periphery of 1.
The cartridge body (patrone body) 101 is composed of upper and lower cases 105 and 106 which are two molded parts.

An upper case 105 having a gate 150,
Photo film 1 on the front side joint with the lower case 106
A film delivery port 107 (passage) for delivering 02 is formed. A lid member 108 for preventing light from entering there is behind the film delivery port 107.
And a separation claw 109 which is arranged at the back of the separation film and separates the tip of the photographic film 102. The lid member 108 has key grooves 110,
111 is formed, and the keyway 11 is formed when loaded in the camera.
The opening / closing drive shaft on the camera side that engages with 0 and 111 is rotated between a closed position that closes the film feed opening 107 and an open position that allows entry and exit of the photographic film. FIG. 5 shows a state in which the lock pawl 144 and the lid member 108 are engaged with each other and the lid member is locked at the closed position.

The spool 103 includes a pair of lip flanges 113 and 1 on the inner sides of the spool shaft 112, respectively.
14 is attached, and a data disk is provided on the outside of one flange 113. The other flange 1
A use display member 123 is attached to the outer side of 14. A data label is attached to the data disk 115. A pair of flange engaging portions 1 with which the spool shaft 112, the data disk 115, and the respective flanges 113 and 114 are engaged.
17, 118, slit 11 for locking the rear end of the photographic film
9 and the use display member supporting portion 120 are formed integrally with each other, and when the spool 10 is mounted on the camera,
The drive shaft on the camera side is engaged with the key grooves 121 and 122 on the key holes provided at both ends of the drive shaft 3, and is rotated by the rotation of the drive shaft.

The use display member 123 includes a bearing portion 12
The four ratchet pawls 125, the gear 126, and the use display plate 127 are integrally formed, and these rotate integrally with the spool shaft 112.

The inside of the photo film cartridge 100 is
A spool lock 128 is housed so as to mesh with the gear 126. This spool lock 128 is a lid member 1.
When 08 is in the closed position, the gear 126 is engaged to lock the rotation of the spool shaft 112, prevent careless feeding of the photographic film 102, and cover member 108.
When is in the open position, it disengages from the gear 126.

The pair of flanges 113 and 114 are made of a plastic material and have a thin cup-shaped cross section. The cup-shaped bottom has a flange engaging portion 117,
Round holes 129 and 130 are rotatably engaged with 118, respectively. Also, the cup-shaped opening edge 13
1, 132 are arranged to face each other when attached to the spool shaft 112, and wrap around the outermost ends of the photographic film 102 wound between them (see FIG. 6). The opening edge portions 131 and 132 allow the rotation of the spool 103 to be transmitted to the outermost periphery of the photographic film 102 and prevent the film roll 142 from being loosened.

The flange 114 is formed with four holes 133 at a predetermined pitch so as to surround the round hole 130. These holes 133 are provided with a display member 123 for use when the spool shaft 112 rotates in the photo film feeding direction.
Ratchet claw 125 of is engaged. Ratchet claw 125
Transmits the rotation of the spool shaft 112 to the flange 114 when engaged with the hole 133, and when the spool shaft 112 rotates in the photo film winding direction, the ratchet claw 125 of the use indicating member 123 causes the hole 133 to rotate. Therefore, the rotation of the spool shaft 112 is not transmitted to the flange 114.

By the way, when the photo film 102 is fed out, the spool 103 is rotated in the film feeding direction. When the spool 103 is rotated in the film feeding direction, the tip of the photographic film 102 is separated by the separation claw 10.
9 and is separated from the part wound inside the leading edge of the photographic film. When the spool 103 is subsequently rotated, since the pair of thin flanges 113 and 114 has elasticity, the pair of flanges 113 and 114 are pushed outward by the separated film tips. The leading edge of the photographic film (143 in FIG. 3) released from the wrapping is delivered to the outside of the photographic film cartridge 100 through the film delivery port. Further, when the spool shaft 112 rotates in the photo film winding direction (the direction opposite to the photo film feeding direction), the flanges 113 and 114 do not rotate integrally with the spool shaft 112. Therefore, the photographic film 102
Since the flanges 113 and 114 do not rotate when the film is wound, a slip occurs between the opening edge portions 131 and 132 and the photographic film 102, and the photographic film 102.
Slides under the opening edges 131, 132 of the flanges to wrap the photographic film.

The data disk 115 has a large-diameter fan-shaped portion 1
34 and a notch portion 135. The barcode label 116 has a shape similar to that of the data disc 115 and is attached to the data disc.

A bar code is printed on the bar code label 116 and represents various information such as the type of the photo film 102 to be stored. This information is obtained when the spool 103 is rotated in the film feeding direction.
As shown in FIG. 5, it is read by a reading sensor provided on the camera side through an opening 136 formed on one side surface of the upper case 105 to calculate an exposure value and count the number of exposures of stored photo films. Used.

In this photo film cartridge 100,
Since even the leading edge of the photographic film 102 is stored, it is indistinguishable from the external appearance whether the unexposed photographic film or the exposed photographic film is stored. Therefore, in order to prevent the photographic film cartridge 100 containing the exposed photographic film from being reloaded into the camera and taking pictures, a post-loading prevention opening 137 is formed on one side surface of the lower case 106. There is. This one side surface is a side that is inserted toward the cartridge chamber of the camera, and a lever that enters the opening 137 is provided in the cartridge chamber.

The photographic film cartridge 100 stores the unexposed photographic film so that the large-diameter fan-shaped portion 134 is exposed in the opening 137 when the exposed photographic film is stored. If so, the stop position of the spool 103 is controlled by the drive shaft on the camera side so that the large-diameter fan-shaped portion 134 is not exposed in the opening 137. Therefore, by detecting the amount of movement of the lever, the camera side can discriminate between the exposed and unexposed photographic film.

Further, in order to allow the user to understand the appearance, the photo film cartridge 100 is
As shown in FIG. 4, on the other side surface (the side surface opposite to the side surface on which the openings 136 and 137 are provided), an opening 138 for displaying the usage state when the unexposed photo film is stored, a part thereof is photographed. When the photographic film is stored, the usage status display opening 139, when the exposed photo film that has been photographed on all is stored, the usage status display opening 140, and when the developed photographic film is stored Of the four use status display openings 138 to 141 are formed by exposing the use display plate 127 located in the back by controlling the stop position of the spool 103. The usage status of the film is displayed.

Further, the present cartridge 100 is provided with a sensitivity detection notch 145 used for detecting the sensitivity of the stored photographic film 102. This is a notch for detecting sensitivity with an inexpensive camera that does not have a bar code reader that reads the bar code written on the bar code label. When the sensitivity detecting notch 145 is provided as shown in FIG. 5, the stored photographic film 102 is IS.
The O sensitivity is 400 or more, and the ISO sensitivity is 400 or less when there is no notch.

Further, the present cartridge 100 is provided with a developed display tab showing whether or not the stored photographic film 102 has been developed. As shown in FIG.
The tab 147 is provided in an opening 146 provided on one side surface of the cartridge 100, and when the tab 147 is broken off, it means that the stored photographic film 102 has been developed.

Next, a typical example of the manufacturing method of the cartridge 100 of the present invention will be specifically described. Upper case / lower case 1
05, 106, the spool 103, and the lid member 108,
High-impact polystyrene resin (Denkastyrol HI-R-Q manufactured by Denki Kagaku Kogyo) is added with 1.0% by weight of carbon black (Mitsubishi Carbon Black # 950 manufactured by Mitsubishi Chemical) for imparting light-shielding properties, and lubricity. Silicone oil for use (Shin-Etsu Chemical Co., Ltd. Shin-Etsu Silicone KF96H-viscosity 30,000 cs) is molded by injection molding using a resin kneaded with 1.5% by weight. The use indication member 123 is made by injection molding using a resin obtained by kneading the above-mentioned high impact polystyrene resin with 0.01% by weight of the above carbon black and 3.5% by weight of titanium oxide (CR60-2 manufactured by Ishihara Sangyo). Mold.

The flanges 113 and 114 are formed by a vacuum / pneumatic method using a film having a thickness of 150 μm made from a polymer alloy of polystyrene resin and polyphenylene ether resin (Zylon X9101 manufactured by Asahi Kasei).

The patrone label 104 has a thickness of 50.
A coating for imparting printability is provided on one side of a polystyrene film containing a white pigment having a thickness of μm, an adhesive is attached to the back side thereof, and a release paper is attached to the release label to prepare an adhesive label stock. As shown in FIG. 7, on the surface of the original fabric,
Patrone ID number printing space written in numbers 15
1. A manufacturer name, a product name, a film type / sensitivity / the number of exposures, a cautionary note, and a print space 152 for a product type for printing a memo field to be filled by the user, and a bar code print space 153. First, a printing space such as a product type is printed, then half-cut processing is performed, and thereafter, a barcode and a Patrone ID number are printed to create. The bar code contains the manufacturer's name, production lot, production date, type of photo film stored, sensitivity, number of exposures,
Also, the Patrone ID number and the like are encoded and printed. The cartridge ID number is a unique number attached to each cartridge.

The bar code label 116 has a thickness of 50 μm.
A transparent vapor deposition polystyrene film with a thickness of about 400 Å is provided on one side of the transparent vapor deposition film, and an adhesive label is attached on top of it to create an adhesive label with release paper, and a bar on the opposite side of the aluminum vapor deposition layer. After printing the code, half cut the outer peripheral part, and then punch out the center to create.

The present invention is one in which the photographic light-sensitive material is housed in a package having the structure and manufacturing method exemplified above. The above object of the present invention can be achieved by the photographic light-sensitive material contained in such a package.

The light-sensitive material of the present invention may have at least one light-sensitive silver halide emulsion layer (hereinafter, also referred to as a light-sensitive layer) provided on a support. A typical example is a silver halide photographic light-sensitive material having at least one light-sensitive layer comprising a plurality of silver halide emulsion layers having substantially the same color sensitivity but different sensitivities on a support. It is. The photosensitive layer is a unit photosensitive layer having color sensitivity to any of blue light, green light, and red light, and in a multilayer silver halide color photographic material, the arrangement of the unit photosensitive layers is generally A red-sensitive layer, a green-sensitive layer, and a blue-sensitive layer are provided in this order from the support side. However, depending on the purpose, the order of installation may be reversed, or the order of installation may be such that different photosensitive layers are sandwiched between layers of the same color sensitivity. A non-light-sensitive layer may be provided between the silver halide light-sensitive layers and as the uppermost layer and the lowermost layer. These may contain a coupler, a DIR compound, a color mixing inhibitor, etc. described later. A plurality of silver halide emulsion layers constituting each unit light-sensitive layer are formed by sequentially exposing two layers, a high-speed emulsion layer and a low-speed emulsion layer, to a support as described in DE 1,121,470 or GB 923,045. It is preferable to arrange them so that the degree is low. In addition, JP-A-57-112751, 62-200350, 62-2
As described in JP-A Nos. 06541 and 62-206543, a low-speed emulsion layer may be provided on the side farther from the support, and a high-speed emulsion layer may be provided on the side closer to the support. As specific examples, from the farthest side from the support, a low-sensitivity blue-sensitive layer (BL) / a high-sensitivity blue-sensitive layer (BH) / a high-sensitivity green-sensitive layer (GH) / a low-sensitivity green-sensitive layer (GL) / High-sensitivity red-sensitive layer (RH) / low-sensitivity red-sensitive layer (RL), or BH / BL / GL / GH / RH / RL, or BH / BL / GH / GL / RL / RH And so on. Also, as described in JP-B-55-34932, the blue-sensitive layer / GH / RH / GL starts from the side farthest from the support.
/ RL can be arranged in this order. JP-A-56-2573
8, as described in JP-A-62-63936, the layers may be arranged in the order of blue-sensitive layer / GL / RL / GH / RH from the side farthest from the support. Further, as described in JP-B-49-15495, the upper layer is the silver halide emulsion layer having the highest sensitivity, the middle layer is the silver halide emulsion layer having a lower sensitivity, and the lower layer is a silver halide emulsion layer having a higher sensitivity than the middle layer. An example is an arrangement in which low silver halide emulsion layers are arranged and three layers having different sensitivities are sequentially lowered toward the support. Even when it is composed of such three layers having different sensitivities, as described in JP-A-59-202464, in the same color-sensitive layer, the medium-sensitivity emulsion layer / high-sensitivity layer is separated from the side distant from the support. You may arrange in order of a speed emulsion layer / a low speed emulsion layer. In addition, the layers may be arranged in the order of high-speed emulsion layer / low-speed emulsion layer / medium-speed emulsion layer, or low-speed emulsion layer / medium-speed emulsion layer / high-speed emulsion layer. Also, in case of 4 layers or more,
The arrangement may be changed as described above. In order to improve color reproducibility, BL, GL, described in US 4,663,271, 4,705,744, 4,707,436, JP-A-62-160448 and 63-89850, are described.
It is preferable that a donor layer (CL) having a multilayer effect having a spectral sensitivity distribution different from that of the main photosensitive layer such as RL is disposed adjacent to or close to the main photosensitive layer.

The preferred silver halide for use in the present invention is silver iodobromide, silver iodochloride, or silver iodochlorobromide containing less than about 30 mol% silver iodide. Particularly preferred is silver iodobromide or silver iodochlorobromide containing from about 2 mol% to about 10 mol% silver iodide. Silver halide grains in photographic emulsions include those having regular crystals such as cubic, octahedral and tetradecahedral, those having irregular crystal forms such as spheres and plates, twin planes, etc. Or a composite form thereof. The grain size of silver halide is about 0.2 μm or less
It may be large-sized grains up to 10 μm, and may be a polydisperse emulsion or a monodisperse emulsion. The silver halide photographic emulsion which can be used in the present invention is, for example, Research Disclosure (hereinafter abbreviated as RD) No. 17643 (December 1978), 22-2.
Page 3, "I. Emulsion preparation and type
s) ”and ibid. No. 18716 (November 1979), p. 648, ibid.
No. 307105 (November 1989), pages 863-865, and Graphide, Physics and Chemistry of Photography, published by Paul Montell (P.
Glafkides, Chemie et PhisiquePhotographique, Paul
Montel, 1967), "Photographic Emulsion Chemistry" by Duffin, published by Focal Press (GF Duffin, Photographic Emulsion
Chemistry, Focal Press, 1966), "Production and Coating of Photographic Emulsion" by Zelikmann et al., Published by Focal Press (VL Z
elikman, et al., Making and Coating Photographic E
mulsion, Focal Press, 1964) and the like.

US 3,574,628, US 3,655,394 and GB 1,4
Monodisperse emulsions described in 13,748 are also preferred. Tabular grains having an aspect ratio of about 3 or more can also be used in the present invention. Tabular grains are described in Gutof, Photographic Science and Engineering (Gutof
f, Photographic Science and Engineering), Volume 14
248-257 (1970); US 4,434,226, US 4,414,310,
It can be easily prepared by the methods described in 4,433,048, 4,439,520 and GB 2,112,157. The crystal structure may be uniform, the inside and the outside may be composed of different halogen compositions, or may have a layered structure. Silver halides having different compositions may be joined by epitaxial joining, or may be joined to a compound other than silver halide, such as, for example, silver rhodanate or lead oxide. Also, a mixture of particles of various crystal forms may be used. The above emulsion is a surface latent image type that forms a latent image mainly on the surface,
Either an internal latent image type formed inside the grain or a type having a latent image both on the surface and inside may be used, but it is necessary that the emulsion is a negative type. Of the internal latent image types, JP-A-6
The core / shell type internal latent image type emulsion described in 3-264740 may be used, and its preparation method is described in JP-A-59-133542. The thickness of the shell of this emulsion varies depending on the development process, but is preferably 3 to 40 nm, particularly preferably 5 to 20 nm.

The silver halide emulsion is usually one which has been physically ripened, chemically ripened and spectrally sensitized. The additives used in such a process are RD No.17643 and RD No.17643.
8716 and No. 307105, and the relevant parts are summarized in the table below. In the light-sensitive material of the present invention, two or more types of emulsions having at least one characteristic different from each other in the grain size, grain size distribution, halogen composition, grain shape and sensitivity of the photosensitive silver halide emulsion are mixed in the same layer. Can be used. US Pat. No. 4,082,553, the surface of which is covered with silver halide grains, US Pat.
It is preferred to apply the internally fogged silver halide grains and colloidal silver described in 214852 to the photosensitive silver halide emulsion layer and / or the substantially non-photosensitive hydrophilic colloid layer. The fogged silver halide grain inside or on the surface means a silver halide grain which enables uniform (non-imagewise) development regardless of the unexposed area and exposed area of the light-sensitive material. , Its preparation method is described in US 4,626,498 and JP-A-59-214852. The silver halide forming the internal nucleus of the core / shell type silver halide grain having the inside of the grain fogged may have a different halogen composition. As the silver halide having the inside or surface of the grain fogged, any of silver chloride, silver chlorobromide, silver iodobromide and silver chloroiodobromide can be used. The average grain size of these fogged silver halide grains is 0.01 to 0.75 μm
, Particularly preferably 0.05 to 0.6 μm. The grains may be regular grains or polydisperse emulsions, but may be monodisperse (at least the weight or the number of silver halide grains).
95% have a particle size within ± 40% of the average particle size)
It is preferred that

In the present invention, it is preferable to use a non-photosensitive fine grain silver halide. Non-photosensitive fine grain silver halide is silver halide fine grains that are not exposed during imagewise exposure to obtain a dye image and are not substantially developed in the developing process, and are preferably not fogged in advance. . The fine grain silver halide has a silver bromide content of 0 to 100 mol%, and may contain silver chloride and / or silver iodide, if necessary. Preferably, it contains 0.5 to 10 mol% of silver iodide. Fine grain silver halide has an average grain size (average value of circle equivalent diameter of projected area)
Is preferably 0.01 to 0.5 μm, more preferably 0.02 to 0.2 μm. Fine grain silver halide can be prepared by the same method as that for ordinary photosensitive silver halide. The surface of the silver halide grains does not need to be optically sensitized, and no spectral sensitization is required. However, prior to adding this to the coating solution, it is preferable to add a known stabilizer such as a triazole-based, azaindene-based, benzothiazolium-based, or mercapto-based compound or a zinc compound in advance. Colloidal silver can be contained in the layer containing fine silver halide grains. Coated silver amount of the light-sensitive material of the present invention is preferably 6.0 g / m ² or less, 4.5 g / m ² or less is most preferred.

The photographic additives that can be used in the present invention are also described in RD, and the relevant portions are shown in the following table. Type of additive RD17643 RD18716 RD307105 Chemical sensitizer page 23, page 648, right column, page 866 2. Sensitivity enhancer, page 648, right column 3. Spectral sensitizer, pages 23 to 24, page 648, right column 866 to 868, supersensitizer, page 649, right column 4. Whitening agent, page 24, page 647, right column, page 868, 5 Light absorber, pages 25 to 26, page 649, right column, page 873, filter, page 650, left column, dye, ultraviolet absorber 6. Binder, page 26, page 651, left column 873 to 874, page 7. Plasticizer, page 27, page 650, right Column 876 Lubricants 8. Coating aids, 26-27 Pages 650 Right column 875-876 Pages Surfactant 9. Static 27 pages 650 Page right columns 876-877 Inhibitors 10. Matting agents 878-879

Various dye-forming couplers can be used in the light-sensitive material of the present invention, and the following couplers are particularly preferable. Yellow couplers; couplers represented by formulas (I) and (II) of EPA 502,424A; couplers represented by formulas (1) and (2) of EP 513,496A (especially Y-28 on page 18); EP 568,037 A coupler represented by the formula (I) in claim 1 of A; a coupler represented by the general formula (I) in column 1, lines 45 to 55 of US Pat. No. 5,066,576; Couplers represented by claim 1 on page 40 of EP 498,381 A1 (especially D-35 on page 18); formulas on page 4 of EP 447,969A1
Couplers represented by (Y) (especially Y-1 (page 17), Y-54 (41
)); US 4,476,219, column 7, lines 36-58, formulas (II)-(I
V) (especially II-17, 19 (column 17), II
-24 (column 19)). Cyan coupler: CX-1,3,4,5,11,12,1 of JP-A-4-204843
4,15 (pages 14 to 16); C-7,10 (page 35) of JP-A-4-43345, 3
4,35 (page 37), (I-1), (I-17) (pages 42 to 43); JP-A-6-67385
A coupler represented by the general formula (Ia) or (Ib) according to claim 1. Polymer coupler: P-1, P-5 (p. 11) of JP-A-2-44345.

Examples of couplers in which the coloring dye has an appropriate diffusibility include US 4,366,237, GB 2,125,570, EP 96,873B,
Those described in DE 3,234,533 are preferred. Couplers for correcting unnecessary absorption of color-forming dyes are yellow colored cyan couplers represented by the formulas (CI), (CII), (CIII), and (CIV) described on page 5 of EP 456,257A1 (especially on page 84). YC-86), the EP
Yellow colored magenta coupler ExM-7 (202
), EX-1 (page 249), EX-7 (page 251), US 4,833,069
Magenta colored cyan coupler CC-9 (column
8), CC-13 (column 10), (2) of US 4,837,136 (column 8),
Colorless masking couplers of formula (A) in claim 1 of WO 92/11575 (especially the exemplified compounds on pages 36 to 45) are preferred. Examples of the compound (including a coupler) which releases a photographically useful compound residue by reacting with an oxidized developing agent include the following. Development inhibitor releasing compound: EP 37
Compounds represented by the formulas (I), (II), (III) and (IV) described on page 11 of 8,236A1 (especially T-101 (page 30), T-104 (page 31), T-113 ( 36
T-131 (p. 45), T-144 (p. 51), T-158 (p. 58)), EP436, 93
Compounds of formula (I) described on page 7 of 8A2 (particularly D-4
9 (page 51)), the compound of formula (1) of EP 568,037A (especially (23) (page 11)), and the compounds of formulas (I), (II), Compounds represented by (III) (especially I-
(1)); Bleaching accelerator releasing compounds: compounds represented by formulas (I) and (I ′) on page 5 of EP 310,125A2 (especially (60) and (6) on page 61)
1)) and the compound represented by formula (I) of claim 1 of JP-A-6-59411 (particularly (7) (page 7)); Ligand releasing compound: US
Compound represented by LIG-X described in claim 1 of 4,555,478 (especially compound on lines 21 to 41 of column 12); Leuco dye-releasing compound: compound 1 of columns 3 to 8 of US 4,749,641
~ 6; Fluorescent dye-releasing compound: C in claim 1 of US 4,774,181
Compounds represented by OUP-DYE (particularly compounds 1 to 11 in columns 7 to 10); development accelerator or fogging agent releasing compound: US
4,656,123, the compounds of formulas (1), (2) and (3) in column 3 (especially (I-22) in column 25) and EP 450,637A2
ExZK-2, p. 75, lines 36-38; Compound which releases a group which becomes a dye only when it is cleaved: Formula (I) of claim 1 of US 4,857,447
(Especially Y-1 to Y-19 in columns 25 to 36)
.

As the additives other than the coupler, the following are preferable. Dispersion medium of oil-soluble organic compound: P-3,5, JP-A-62-215272
16,19,25,30,42,49,54,55,66,81,85,86,93 (140-144
Page); Latex for impregnation of oil-soluble organic compounds: US 4,199,
Latex described in 363; Oxidized developer scavenger: a compound represented by the formula (I) in column 2, lines 54 to 62 of US Pat. ) (Column 4-
5), US Pat. No. 4,923,787, columns 5 to 10 of formula (particularly compound 1 (column 3); stain inhibitor: EP 298321A 4
Formulas (I) to (III) on page 30-33, especially I-47, 72, III-1, 27 (24
-48 pages); Anti-fading agent: A-6, 7, 20, 21, 23, 2 of EP 298321A
4,25,26,30,37,40,42,48,63,90,92,94,164 (69-118
P.), US 5,122,444, columns 25-38 II-1 to III-23, especially
III-10, EP 471347A I-1 to III-4 on pages 8 to 12, especially II-
2, US 5,139,931 columns 32-40 A-1 to 48, especially A-39,
42; Material that reduces the amount of color enhancer or color mixture inhibitor used: I-1 to II-15 on pages 5 to 24 of EP 411324A, especially I-4
6; Formalin scavenger: EP 477932A, pages 24 to 29 SCV-1 to 28, especially SCV-8; Hardener: JP-A 1-214845
Formulas in columns 13-23 of H-1,4,6,8,14, US 4,618,573 on page 17
Compounds (H-1 to 54) represented by (VII) to (XII),
214852, page 8, lower right, compound represented by formula (6) (H-1 to 7
6), especially the compound described in claim 1 of H-14, US 3,325,287; Development inhibitor precursor: P-2 of JP-A-62-168139
4,37,39 (pages 6-7); compounds as claimed in claim 1 of US 5,019,492, in particular column 7, 28,29; preservatives, fungicides: US
4,923,790 columns 3 to 15 I-1 to III-43, especially II-1,
9,10,18, III-25; Stabilizer, antifoggant: US 4,923,79
I-1 to (14) in columns 6 to 16 of 3, especially I-1,60, (2), (13), U
S 4,952,483 columns 25-32 compounds 1-65, especially 36:
Chemical sensitizer: triphenylphosphine selenide, compound 50 of JP-A-5-40324; dye: 15-18 of JP-A-3-156450
A-1 to b-20, especially a-1,12,18,27,35,36, b-5,27 to 29
Pages V-1 to 23, especially V-1, EP 445627A pages 33 to 55 FI-
1 to F-II-43, especially FI-11, F-II-8, EP 457153A 17 to 28
Pages III-1 to 36, especially III-1,3, WO 88/04794 8-26
Microcrystalline dispersion of Dye-1 to 124, compounds 1 to 22 of EP 319999A, pages 6 to 11, especially compound 1, compounds D-1 to 87 (3) represented by formulas (1) to (3) of EP 519306A. ~ Page 28), US 4,26
8,622 compounds represented by the formula (I) (columns 3 to 1)
0), compounds (1) to (4) of US Pat.
(31) (Columns 2 to 9); UV absorber: Formula of JP-A-46-3335
Compounds (18b) to (18r), 101 to 427 (6 to
9), and the compounds (3) to (6) represented by the formula (I) in EP 520938A.
6) (Pages 10 to 44) and compound HBT-1 represented by formula (III)
~ 10 (page 14), a compound represented by formula (1) in EP 521823A
(1) to (31) (columns 2 to 9).

The present invention can be applied to various color light-sensitive materials such as color negative films for general use or movies, color reversal films for slides or televisions, color papers, color positive films and color reversal papers. In addition, Japanese Patent Publication No.
Suitable for the lens-fitted film unit described in 3-39784. Suitable supports that can be used in the present invention are
For example, the RD. No. 17643, page 28, No. 18716
From page 647, right column to page 648, left column, and page 879 of the same No. 307105. In the light-sensitive material of the present invention, the total thickness of all hydrophilic colloid layers on the emulsion layer side is preferably 28 μm or less, more preferably 23 μm or less, and 18 μm or less.
m or less, more preferably 16 μm or less. Further, the film swelling speed T _1/2 is preferably 30 seconds or less, more preferably 20 seconds or less. T _1/2 is the time until the film thickness reaches 1/2 when the saturated film thickness is 90% of the maximum swollen film thickness reached when the film is processed with a color developer at 30 ° C. for 3 minutes and 15 seconds. It is defined as The film thickness means the film thickness measured at 25 ° C. and 55% relative humidity (2 days), and T _1/2 is A Green (A.Gr
een) et al., Photographic Science and Engineering (Photogr.Sci.Eng.), 19 volumes, 2,124 ~
It can be measured by using a swellometer (swelling meter) of the type described on page 129. T _1/2 can be adjusted by adding a hardening agent to gelatin as a binder or changing the aging condition after coating. The swelling rate is preferably 150 to 400%. The swelling ratio can be calculated from the maximum swelling film thickness under the conditions described above by the following formula: (maximum swelling film thickness-film thickness) / film thickness. In the light-sensitive material of the present invention, a hydrophilic colloid layer (referred to as a back layer) having a total dry film thickness of 2 μm to 20 μm is preferably provided on the side opposite to the side having the emulsion layer. The back layer preferably contains the above-mentioned light absorber, filter dye, ultraviolet absorber, antistatic agent, hardener, binder, plasticizer, lubricant, coating aid, and surfactant. The swelling ratio of the back layer is preferably from 150 to 500%.

The light-sensitive material of the present invention has the above-mentioned RD. No.176
43, pages 28 to 29, ibid. No. 18716, 651, left column to right column, and ibid., No. 307105, pages 880 to 881. Next, the processing solution for the color negative film used in the present invention will be described. The color developing solution used in the present invention is described in JP-A-4-2171.
The compounds described on page 9, upper right column, line 1 to page 11 lower left column, line 4 can be used. As a color developing agent for particularly rapid processing, 2-methyl-4- [N-ethyl-N- (2-hydroxyethyl) amino] aniline,
2-Methyl-4- [N-ethyl-N- (3-hydroxypropyl) amino] aniline, 2-methyl-4- [N-
Ethyl-N- (4-hydroxybutyl) amino] aniline is preferred. These color developing agents are preferably used in the range of 0.01 to 0.08 mol per liter of the color developing solution, particularly preferably in the range of 0.015 to 0.06 mol, more preferably 0.02 to 0.05 mol. The replenisher for the color developing solution preferably contains 1.1 to 3 times the concentration of the color developing agent, and particularly preferably 1.3 to 2.5 times the concentration.

Hydroxylamine can be widely used as a preservative for the color developing solution, but when higher preservability is required, substitution of an alkyl group, a hydroxyalkyl group, a sulfoalkyl group, a carboxyalkyl group or the like is required. A hydroxylamine derivative having a group is preferable, and specifically, N, N-di (sulfoethyl) hydroxylamine, monomethylhydroxylamine, dimethylhydroxylamine, monoethylhydroxylamine, diethylhydroxylamine, N, N-di (carboxyethyl). Hydroxylamine is preferred. Among the above, N, N-di (sulfoethyl) hydroxylamine is particularly preferred. These may be used in combination with hydroxylamine, but it is preferable to use one or more of them instead of hydroxylamine. The preservative is preferably used in the range of 0.02 to 0.2 mol per liter, particularly preferably 0.03 to 0.15 mol, and further preferably 0.04 to 0.1 mol. As in the case of the color developing agent, the replenisher preferably contains a preservative at a concentration of 1.1 to 3 times the concentration of the mother liquor (processing tank solution). The color developer contains
Sulfite is used as an anti-talling agent for oxides of color developing agents. The sulfite is preferably used in an amount of 0.01 to 0.05 mol, and particularly preferably 0.02 to 0.04 mol, per liter. In the replenisher, these 1.1 ~
It is preferable to use it at a concentration of 3 times. Further, the pH of the color developing solution is preferably in the range of 9.8 to 11.0, but particularly 10.0
˜10.5 is preferable, and in the replenisher, it is preferable to set a high value in the range of 0.1 to 1.0 from these values. In order to stably maintain such a pH, a known buffer such as carbonate, phosphate, sulfosalicylate, and borate is used.

The replenishing amount of the color developing solution is preferably 80 to 1300 ml per 1 m ² of the light-sensitive material, but is preferably smaller from the viewpoint of reducing the environmental pollution load, specifically 80 to 6
It is preferably 00 ml, more preferably 80 to 400 ml. The bromide ion concentration in the color developing solution is usually 0.01 to 1 liter / liter.
Although it is 0.06 mol, it is preferably set to 0.015 to 0.03 mol per liter for the purpose of suppressing the fog while maintaining the sensitivity, improving the discrimination, and improving the graininess. When the bromide ion concentration is set in such a range, the replenisher may contain bromide ions calculated by the following formula. However, when C becomes negative, it is preferred that the replenisher does not contain bromide ions. C = A-W / V C: Bromide ion concentration in the color developing replenisher (mol / liter) A: Target bromide ion concentration in the color developing solution (mol / liter) W: 1m ² of light-sensitive material is colored Amount of bromide ion eluted from the light-sensitive material to the color-developing solution when developed (mol) V: Replenishment amount of color-development replenisher for a light-sensitive material of 1 m ² (liter). When the bromide ion concentration is set, 1-phenyl-3-pyrazolidone or 1-phenyl-2-methyl-2 can be used as a method for increasing the sensitivity.
It is also preferable to use a development accelerator such as pyrazolidones represented by -hydroxymethyl-3-pyrazolidone and thioether compounds represented by 3,6-dithia-1,8-octanediol.

The compounds and processing conditions described in JP-A-4-125558, page 4, lower left column, line 16 to page 7, lower left column, line 6 can be applied to the processing solution having a bleaching ability in the present invention. . The bleaching agent preferably has an oxidation-reduction potential of 150 mV or more, and specific examples thereof include JP-A-5-72694 and JP-A-5-7333.
The compounds described in No. 12 are preferred, and 1,3-diaminopropanetetraacetic acid, particularly, a ferric complex salt of the compound of Specific Example 1 on page 7 of JP-A-5-73312 is preferred. In addition, in order to improve the biodegradability of the bleaching agent, JP-A-4-218845, 4-268552, EP588,
289, 591,934, and the compound ferric complex salts described in JP-A-6-208213 are preferably used as a bleaching agent. The concentration of these bleaching agents is 0.05 per liter of bleaching solution.
The amount is preferably from 0.3 to 0.3 mol, and particularly from the viewpoint of reducing the amount discharged to the environment, it is preferably designed from 0.1 to 0.15 mol. Further, when the bleaching solution is a bleaching solution, it is preferable to contain 0.2 mol to 1 mol of bromide per liter, particularly 0.3 to 0.8 mol. The replenisher for the bleaching solution basically contains the concentrations of the respective components calculated by the following formula. This allows
The concentration in the mother liquor can be kept constant. C _R = C _T × (V ₁ + V ₂ ) / V ₁ + C _P C _R : Concentration of component in replenisher C _T : Concentration of component in mother liquor (treatment tank liquid) C _P : Consumed during treatment Concentration of components V ₁ : Replenishing amount of replenisher having bleaching ability for 1 m ² of light-sensitive material (mL) V ₂ : Bring-in amount of 1 m ² of light-sensitive material from the previous bath (mL) It is preferable to contain an agent, and it is particularly preferable to contain a dicarboxylic acid having a low odor such as succinic acid, maleic acid, malonic acid, glutaric acid, and adipic acid. Also, JP-A-53-95630, RDN
It is also preferable to use known bleaching accelerators described in O. 17129, US 3,893,858. The bleaching solution is preferably replenished with 50 to 1000 ml of the bleach replenishing solution per 1 m ² of the light-sensitive material, particularly 80 to 500 ml, more preferably 100 to 300 ml. Further, it is preferable to perform aeration on the bleaching solution.

Regarding the processing liquid having fixing ability, Japanese Patent Application Laid-Open No.
The compounds and processing conditions described on page 7, lower left column, line 10 to page 8, lower right column, line 19 of 4-125558 can be applied. In particular, in order to improve the fixing speed and the homeostasis, the compounds represented by the general formulas (I) and (II) of JP-A-6-301169 are contained alone or in combination in a processing solution having fixing ability. It is preferable. In addition to the p-toluenesulfinic acid salt, the sulfinic acid described in JP-A 1-224762 can also be used.
It is preferable from the viewpoint of improving the homeostasis. It is preferable to use ammonium as a cation in a solution having a bleaching ability and a solution having a fixing ability from the viewpoint of improving desilvering ability, but from the viewpoint of reducing environmental pollution, it is preferable to reduce or eliminate ammonium. . In the bleaching, bleach-fixing and fixing steps, jet stirring described in JP-A-1-309059 is particularly preferable. The replenishing amount of the replenisher in the bleach-fixing or fixing step is 100 to 1000 ml, preferably 150 to 700 ml, and particularly preferably 200, per 1 m ² of the light-sensitive material.
~ 600 ml. In the bleach-fixing and fixing steps, it is preferable to install various silver recovery devices in-line or off-line to recover silver. By installing in-line, the processing can be carried out with a reduced silver concentration in the solution, so that the replenishment amount can be reduced. It is also preferable to recover silver off-line and reuse the remaining liquid as a replenisher. The bleach-fixing step and the fixing step can be composed of a plurality of processing tanks, and it is preferable that each tank is cascade-piped to form a multistage countercurrent system. Generally, the two-tank cascade configuration is efficient because of the balance with the size of the developing machine.
The ratio of the processing time in the front tank and the rear tank is
The range of 0.5: 1 to 1: 0.5 is preferable, and the range of 0.8: 1 to 1: 0.8 is particularly preferable. In the bleach-fixing solution or the fixing solution, it is preferable to allow a free chelating agent which is not a metal complex to be present from the viewpoint of improving the preservative property. It is preferred to use chelating agents.

Regarding the washing and stabilizing steps, the above JP-A-4-125558, page 12, lower right column, line 6 to page 13, lower right column, line 16
The contents described in the line can be preferably applied. In particular, EP 504,60 replaces formaldehyde in stabilizers.
9. Use of the azolylmethylamines described in 519,190 and N-methylolazoles described in JP-A-4-362943, and the use of an interface free of image stabilizers such as formaldehyde by dimerizing a magenta coupler. It is preferable to use a liquid of the activator from the viewpoint of preserving the working environment. Further, in order to reduce the adhesion of dust to the magnetic recording layer coated on the light-sensitive material, the stabilizing solution described in JP-A-6-289559 can be preferably used. The amount of washing and replenishment of the stabilizing solution is preferably 80 to 1000 ml / m ² of the light-sensitive material, and particularly 100 to 5 ml.
00 ml, and more preferably 150 to 300 ml, are preferable ranges from the viewpoint of ensuring the washing or stabilizing function and reducing waste liquid for environmental protection. In the treatment performed with such a supplement amount, thiabendazole, 1,2-benzisothiazolin-3one,
Known antifungal agents such as 5-chloro-2-methylisothiazolin-3-one and antibiotics such as gentamicin,
It is preferable to use water deionized with an ion exchange resin or the like. It is more effective to use deionized water in combination with antibacterial agents and antibiotics. Also, the liquid in the washing or stabilizing liquid tank is disclosed in JP-A-3-46652, JP-A-3-53246 and JP-A-3-53246.
It is also preferable to perform the reverse osmosis membrane treatment described in 55542, 3-121448, and 3-126030 to reduce the replenishment amount. In this case, the reverse osmosis membrane is preferably a low-pressure reverse osmosis membrane.

In the processing of the present invention, it is particularly preferable to carry out the evaporation correction of the processing liquid as disclosed in JIII Journal of Technical Disclosure, Japanese Patent No. 94-4992. In particular, a method of making a correction using the temperature and humidity information of the environment where the developing machine is installed is preferable based on (Equation-1) on page 2. The water used for evaporation correction is preferably collected from a replenishment tank for washing,
In that case, it is preferable to use deionized water as the replenishing water for washing.

As the treating agent used in the present invention, those described on page 3, right column, line 15 to page 4, left column, line 32 of the above-mentioned Kokai Giho are preferable. In addition, as a developing machine used for this,
The film processor described on page 3, right column, lines 22 to 28 is preferred. Specific examples of preferred processing agents, automatic processors, and evaporation correction methods for carrying out the present invention are described on page 5, right column, line 11 to page 7, right column, last line. .

The supply form of the treating agent used in the present invention is as follows:
It may be in any form, such as a liquid preparation in the form of a liquid used or a concentrated form, or granules, powders, tablets, pastes, and emulsions. As an example of such a treating agent, JP-A-63-1
7453 discloses a liquid agent contained in a container having low oxygen permeability,
19655, 4-230748, vacuum-packed powders or granules, 4-221951, granules containing a water-soluble polymer,
JP-A-51-61837 and JP-A-6-102628 have tablets and special tables
Discloses a paste-like treating agent, which can be preferably used, but from the viewpoint of simplicity at the time of use,
It is preferable to use a liquid which has been prepared in advance in a concentration at the state of use. Polyethylene, polypropylene, polyvinyl chloride, polyethylene terephthalate, nylon and the like are used alone or as a composite material in a container for containing these treatment agents. These are selected according to the required level of oxygen permeability. For an easily oxidizable liquid such as a color developing solution, a material having low oxygen permeability is preferable, and specifically, a polyethylene terephthalate or a composite material of polyethylene and nylon is preferable. These materials are used in containers having a thickness of 500 to 1500 μm, and preferably have an oxygen permeability of 20 ml / m ² · 24 hrs · atm or less.

Next, the processing solution for the color reversal film used in the present invention will be described. Regarding the processing for the color reversal film, known technology No. 6 (April 1, 1991), page 1, line 5 to page 10, line 5, and page 15, line 8 to page 24, 2 of Aztec Co., Ltd. It is described in detail in the line, and any of its contents can be preferably applied. In color reversal film processing, image stabilizers are included in either the conditioning bath or the final bath. Examples of such an image stabilizer include formalin, formaldehyde sodium bisulfite, and N-methylolazoles.
From the viewpoint of the working environment, sodium formaldehyde bisulfite or N-methylolazoles are preferable, and as N-methylolazoles, N-methyloltriazole is particularly preferable. The contents relating to the color developing solution, the bleaching solution, the fixing solution, the washing water, etc. described in the processing of the color negative film can be preferably applied to the processing of the color reversal film. A preferred color reversal film treating agent containing the above is E-manufactured by Eastman Kodak Company.
6 processing agents and CR-56 processing agents of Fuji Photo Film Co., Ltd. can be mentioned.

Next, the polyester support used in the present invention will be described. For details including sensitive materials, treatments, cartridges, and examples other than the above, open technical report, official technique number 94-6023 (Invention Society; 1994.3.15.). The polyester used in the present invention is formed by using diol and aromatic dicarboxylic acid as essential components. As aromatic dicarboxylic acids, 2,6-, 1,5-, 1,4- and 2,7-naphthalenedicarboxylic acid, terephthalic acid Examples of the acid, isophthalic acid, phthalic acid, and diol include diethylene glycol, triethylene glycol, cyclohexanedimethanol, bisphenol A, and bisphenol. Examples of the polymerized polymer include homopolymers such as polyethylene terephthalate, polyethylene naphthalate, and polycyclohexanedimethanol terephthalate. Particularly preferred is a polyester containing 50 to 100 mol% of 2,6-naphthalenedicarboxylic acid. Among them, polyethylene-2,6 is particularly preferable.
-Naphthalate. The average molecular weight ranges from about 5,000 to 200,000. Tg of the polyester of the present invention is 50 ° C.
And more preferably 90 ° C. or higher.

Next, the polyester support is subjected to a heat treatment at a heat treatment temperature of 40 ° C. or higher and lower than Tg, more preferably Tg−20 ° C. or higher and lower than Tg in order to prevent the curling tendency. The heat treatment may be performed at a constant temperature within this temperature range, or may be performed while cooling. The heat treatment time is 0.1 to 1500 hours, more preferably 0.5 to 200 hours. The heat treatment of the support may be performed in the form of a roll, or may be performed while transporting the support in the form of a web.
Surface irregularities may be imparted (for example, conductive inorganic fine particles such as SnO ₂ or Sb ₂ O ₅ may be applied) to improve the surface state. It is also desirable to take measures such as applying knurls to the ends and raising the ends only slightly to prevent cut-out of the core. These heat treatments are performed after forming the support, after surface treatment,
It may be carried out at any stage after application of the back layer (antistatic agent, slip agent, etc.) and after application of the undercoat. Preferably after application of the antistatic agent. An ultraviolet absorber may be incorporated into this polyester. Also, to prevent light piping,
The purpose can be achieved by kneading dyes or pigments commercially available for polyesters such as Diaresin manufactured by Mitsubishi Kasei and Kayaset manufactured by Nippon Kayaku.

Next, in the present invention, it is preferable to carry out a surface treatment in order to bond the support and the light-sensitive material constituting layer. Chemical treatment, mechanical treatment, corona discharge treatment, flame treatment, ultraviolet treatment, high frequency treatment, glow discharge treatment, active plasma treatment,
Surface activation treatments such as laser treatment, mixed acid treatment, ozone oxidation treatment and the like can be mentioned. Among the surface treatments, ultraviolet irradiation treatment, flame treatment, corona treatment, and glow treatment are preferable. Next, the undercoating method will be described. It may be a single layer or two or more layers. As the binder for the undercoat layer, vinyl chloride, vinylidene chloride, butadiene, methacrylic acid,
Examples include a copolymer using a monomer selected from acrylic acid, itaconic acid, maleic anhydride and the like as a starting material, polyethylene imine, epoxy resin, grafted gelatin, nitrocellulose, and gelatin. Compounds that swell the support include resorcin and p-chlorophenol. As a gelatin hardening agent for the undercoat layer, chromium salts (chrome alum, etc.), aldehydes (formaldehyde, glutaraldehyde, etc.), isocyanates, active halogen compounds (2,4-dichloro-6-) are used.
Hydroxy-S-triazine, etc.), epichlorohydrin resin, active vinyl sulfone compound and the like. SiO ₂ , TiO ₂ , inorganic fine particles or polymethylmethacrylate copolymer fine particles (0.01 to 10 μm) may be contained as a matting agent.

In the present invention, an antistatic agent is preferred.
It is used well. Carbohydrate is one of those antistatic agents.
Polymers containing acid, carboxylate and sulfonate,
Thionic polymers, ionic surfactant compounds
Can be. The most preferred antistatic agent is Z
nO, TiO_Two, SnO_Two, Al_TwoO_Three, In_TwoO_Three, SiO_Two, MgO, BaO,
MoO_Three, V_TwoO_FiveAt least one volume resistivity selected from
Is 10 ⁷Ωcm or less, more preferably 10^FiveΩcm or less
Particle size 0.001 ~ 1.0μm crystalline metal oxide
Of these composite oxides (Sb, P, B, In, S, Si, C, etc.)
Particles, sol-like metal oxides or composites thereof
These are oxide fine particles. The content in the photosensitive material should be between 5 and
500mg / m^TwoIs particularly preferably 10 to 350 mg / m^TwoIn
You. Conductive crystalline oxide or its composite oxide and vine
The ratio of the amount of the duster is preferably 1/300 to 100/1, more preferably
Or 1/100 to 100/5.

The light-sensitive material of the present invention preferably has a slip property. The slip agent-containing layer is preferably used on both the photosensitive layer surface and the back surface. A preferable slip property is a dynamic friction coefficient of 0.
It is 25 or less and 0.01 or more. The measurement at this time represents the value when the stainless steel ball with a diameter of 5 mm is transported at 60 cm / min (25
℃, 60% RH). In this evaluation, even if the surface of the photosensitive layer is replaced as the partner material, the values are almost the same level. Examples of the slip agent usable in the present invention include polyorganosiloxanes, higher fatty acid amides, higher fatty acid metal salts, esters of higher fatty acids and higher alcohols, and polyorganosiloxanes such as polydimethyl siloxane, polydiethyl siloxane, poly Styrylmethylsiloxane, polymethylphenylsiloxane, or the like can be used. The additional layer is preferably the outermost layer of the emulsion layer or the back layer. Particularly, polydimethylsiloxane or an ester having a long-chain alkyl group is preferable.

The photosensitive material of the present invention preferably contains a matting agent. The matting agent may be on either the emulsion side or the back side, but is particularly preferably added to the outermost layer on the emulsion side.
The matting agent may be soluble in the processing solution or insoluble in the processing solution, and preferably both are used in combination. For example, polymethylmethacrylate, poly (methylmethacrylate / methacrylic acid = 9/1 or 5/5 (molar ratio)), polystyrene particles and the like are preferable. The particle size is preferably 0.8 to 10 μm, and the particle size distribution is preferably narrow, and the average particle size is 0.9 to 1.
It is preferable that 90% or more of the total number of particles be contained in one time. It is also preferable to simultaneously add fine particles of 0.8 μm or less in order to enhance the matting property. Particles (0.25μm), colloidal silica (0.03μm)
Is mentioned.

Next, the film cartridge used in the present invention will be described. The main material of the patrone used in the present invention may be metal or synthetic plastic. Preferred plastic materials are polystyrene, polyethylene, polypropylene, polyphenyl ether and the like. Further, the patrone of the present invention may contain various antistatic agents, and carbon black, metal oxide particles, nonionic, anionic, cationic and betaine surfactants or polymers can be preferably used. These antistatic patrones are described in JP-A 1-312537 and JP-A 1-312538. Particularly, the resistance at 25 ° C. and 25% RH is preferably 10 ¹² Ω or less. Usually, a plastic patrone is manufactured using a plastic into which carbon black, a pigment, or the like is kneaded in order to impart light shielding properties. The size of the patrone may be 135 size at present, and for miniaturization of the camera,
It is also effective to reduce the diameter of the current 135 size 25 mm cartridge to 22 mm or less. The volume of the patrone case is preferably 30 cm ³ or less, more preferably 25 cm ³ or less. The weight of the plastic used for the patrone and the patrone case is preferably 5 g to 15 g.

Further, the cartridge used in the present invention may be a cartridge that rotates the spool to feed the film. Further, a structure may be employed in which the leading end of the film is housed in the cartridge body, and the leading end of the film is sent out from the port of the cartridge by rotating the spool shaft in the film sending direction. These are disclosed in US Pat. Nos. 4,834,306 and 5,226,613. The photographic film used in the present invention may be a so-called raw film before development, or may be a photographic film subjected to development processing. Also, raw film and developed photographic film may be stored in the same new patrone,
Different patrones may be used.

[0111]

EXAMPLES The present invention will be described in more detail with reference to the following Examples, which should not be construed as limiting the scope of the present invention. Example 1 The following comparative coupler (A) was used as a magenta coupler, and tricresyl phosphate, ethyl acetate and sodium dodecylbenzenesulfonate were added to this coupler to finely emulsify and disperse the coupler dispersion in an aqueous gelatin solution. In addition to silver halide emulsion (AgI-containing 4 mol%, average grain size 0.4 μm, cubic, multi-structure grain), poly (vinyl benzene sulfonate) as a thickener, vinyl sulfone compound as a hardener, and tetra as a stabilizer. An emulsion coating solution was prepared by adding a Zaindene compound. Subsequently, these coating solutions were uniformly coated on an undercoated cellulose triacetate film support having a thickness of 205 μm, and a surface protective layer composed mainly of an aqueous gelatin solution was coated thereon to prepare a sample. This is designated as Sample 101. At this time, the coated silver amount was 1.5 g / m ² , and the coupler coated amount was 1.0 g / m ² .
It was m ^2. The gelatin coating amount of the protective layer was 2.0 g / m ² . Sample 102 was prepared in the same manner as in Sample 101 by adding the compound (A-18) of the present invention to Sample 101. (A-18) was added to the coupler and emulsified and dispersed. The coating amount of (A-18) is 10 mg / m ² . The amount of coated silver, the amount of coated coupler, and the like are the same as in Sample 101.

Sample 103 and sample 104 are the same as sample 10
Comparative coupler (A) used in Sample No. 1 and Sample 102 was replaced with coupler (m-1) of the present invention in an equimolar amount to prepare Sample No. 101 in the same manner. At this time, the weight ratio of tricresyl phosphate / coupler was kept constant (0.5). Samples 105 to 107 were prepared by replacing the coupler (m-1) in Sample 104 with the coupler of the present invention shown in Table 1 in an equimolar amount so that the weight ratio with tricresyl phosphate was also constant. Sample 108 was prepared in the same manner as described above by adding the comparative compound (1) in place of the compound (A-18) of sample 104. Samples after Sample 109 are the following comparative couplers, couplers of the present invention, and general formula (A-
Samples 136 to 136 were produced in the same manner as described above by changing the presence or absence of the compounds represented by I) to (A-III) as shown in Table 1 and Table 2. The couplers were replaced by equimolar amounts, and the weight ratio with tricresyl phosphate was also constant. Regarding the polymer coupler, the pyrazolone mother nucleus of the constitutional unit was converted from the weight ratio and replaced by equimolar amounts. In addition,
Samples 103 to 108 are the comparative coupler (A) and Sample 11
1-115 are comparative couplers (B) and samples 118-12
0 is the same as the comparative coupler (C) and Samples 123 to 127 are the same pyrazolone mother nucleus as that of the comparative coupler (D),
Each comparative coupler is a so-called 4-equivalent coupler in which the coupling active position is unsubstituted.

[0113]

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[0114]

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The samples thus prepared were 35 mm wide and 160 mm wide.
It was cut and processed to a length of cm, and wound on a spool in the current 135 cartridge and stored. Here, the winding core diameter was 11 mm and the number of windings was 31 rounds. The following performances were evaluated using the photosensitive materials stored in these cartridges. (1) Color density One set of each light-sensitive material has a temperature of 40 ° C and a relative humidity of 60%.
Store for 0 days, another set at 5 ° C, 35% relative humidity for the same period. With respect to each of these two sets of light-sensitive materials, the outside portion in which they were caught was taken out, exposed to white light through a sensitometric wedge, and subjected to color development processing shown below. The developed sample was subjected to G concentration measurement to obtain its characteristic curve. From these characteristic curves, the maximum densities (Dmax) were read, and the ratio of the maximum densities between the presence and absence of the addition of the general formulas (AI) to (A-III) of the present invention between the same mother-nucleus couplers, The measurement was carried out at 40 ° C. and 5 ° C., respectively, on the basis of no addition of the compound of the present invention. Between the same mother-coupler couplers are samples 101 to 10 respectively.
8, Samples 109 to 115, Samples 116 to 120, Sample 1
21-127, Samples 128-138, Samples 131-13
6. As a reference, for example, in samples 101 to 108, storage of sample 101 at 5 ° C. is used as a reference (100). Samples 128 to 138 were based on the sample 101, and samples 131 to 136 were based on the sample 121.

(2) Pressure fog (ΔD) After storing one set of each light-sensitive material at 45 ° C. and 75% relative humidity for 30 days, a film sample was taken out from each cartridge and the color development shown below was performed without exposure. The first development of the processing was omitted, and the processing after the first washing in the second step was carried out. The G concentration of the magenta-colored sample was measured from the tip to the end of the sample. The samples from the results of the measurement is a density difference in the tip portion and the distal portion of the sample, the difference between the highest density value (G _H) and the lowest density value _{(D L) (ΔD = D} H
Seeking -D _L), it was examined the degree of pressure fog when stored under high temperature involving long. The samples with different densities gave high density values in the area near the spool.

The color development processing steps and processing solution compositions used in this example are shown below. Treatment process time Temperature Tank capacity Replenishment amount First development 4 minutes 38 ° C 12 liters 2200 ml / m ² First washing 2 minutes 38 ° C 4 liters 7500 ml / m ² Inversion 2 minutes 38 ° C 4 liters 1100 ml / m ² Color development Develop 6 minutes 38 ° C 12 liters 2200 ml / m ² Pre-bleaching 2 minutes 38 ° C 4 liters 1100 ml / m ² Bleach 6 minutes 38 ° C 12 liters 220 ml / m ² Settlement 4 minutes 38 ° C 8 liters 1100 ml / m 2 ² Second washing 4 minutes 38 ° C 8 liters 7500 ml / m ² Final rinse 1 minute 25 ° C 2 liters 1100 ml / m ²

The composition of each processing solution was as follows. [First developer] [Tank solution] [Replenisher] Nitrilo-N, N, N-trimethylenephosphonic acid-5 sodium salt 1.5 g 1.5 g Diethylenetriamine pentaacetic acid / 5 sodium salt 2.0 g 2.0 g Sodium sulfite 30 g 30 g Potassium hydroquinone monosulfonate 20 g 20 g Potassium carbonate 15 g 20 g Sodium bicarbonate 12 g 15 g 1-Phenyl-4-methyl-4-hydroxymethyl-3-pyrazolidone 1.5 g 2.0 g Potassium bromide 2.5 g 1.4 g Potassium thiocyanate 1.2 g 1.2 g potassium iodide 2.0 mg-diethylene glycol 13 g 15 g Water was added to 1000 ml 1000 ml pH 9.60 9.60 The pH was adjusted with sulfuric acid or potassium hydroxide.

[Reversing liquid] [Tank liquid] [Replenishing liquid] Nitrilo-N, N, N-trimethylenephosphonic acid pentasodium salt 3.0 g Same as tank liquid Stannous chloride dihydrate 1.0 g p-amino Phenol 0.1 g Sodium hydroxide 8 g Glacial acetic acid 15 ml Water was added to 1000 ml pH 6.00 pH was adjusted with acetic acid or sodium hydroxide.

[Color developer] [Tank solution] [Replenisher] Nitrilo-N, N, N-trimethylenephosphonic acid-5-sodium salt 2.0 g 2.0 g Sodium sulfite 7.0 g 7.0 g Trisodium phosphate dodecahydrate 36 g 36 g Potassium bromide 1.0 g-Potassium iodide 90 mg-Sodium hydroxide 3.0 g 3.0 g Citrazine acid 1.5 g 1.5 g N-ethyl-N- (β-methanesulfonamidoethyl) -3-methyl-4- Aminoaniline / 3/2 sulfuric acid monohydrate 11 g 11 g 3,6-dithiaoctane-1,8-diol 1.0 g 1.0 g Water is added to 1000 ml 1000 ml pH 11.80 12.00 pH is adjusted with sulfuric acid or potassium hydroxide. did.

[Pre-bleaching] [Tank liquid] [Replenishing liquid] Ethylenediaminetetraacetic acid / sodium salt / dihydrate 8.0 g 8.0 g Sodium sulfite 6.0 g 8.0 g 1-Thioglycerol 0.4 g 0.4 g Formaldehyde sodium bisulfite adduct 30 g 35 g Water was added to 1000 ml 1000 ml pH 6.30 6.10 The pH was adjusted with acetic acid or sodium hydroxide.

[Bleaching solution] [Tank solution] [Replenisher] Ethylenediaminetetraacetic acid / sodium salt / dihydrate 2.0 g 4.0 g Ethylenediaminetetraacetic acid / Fe (III) / ammonium / dihydrate 120 g 240 g Bromide Potassium 100 g 200 g Ammonium nitrate 10 g 20 g Water was added to 1000 ml 1000 ml pH 5.70 5.50 pH was adjusted with acetic acid or sodium hydroxide.

[Fixing solution] [Tank solution] [Replenisher] Ammonium thiosulfate 80 g The same sodium sulfite 5.0 g 〃 sodium bisulfite 5.0 g 〃 water is added to 1000 ml 〃 pH 6.60 pH is acetic acid or aqueous ammonia. It was adjusted.

[Stabilizing liquid] [Tank liquid] [Replenishing liquid] 1,2-benzisothiazolin-3-one 0.02g 0.03g polyoxyethylene-p-monononylphenyl ether (average degree of polymerization 10) 0.3g 0.3g polymalein Acid (average molecular weight 2,000) 0.1g 0.15g Add water 1000 ml 1000 ml pH 7.0 7.0

The results of (1) and (2) above are shown in Tables 1 and 2.

[0126]

[Table 1]

[0127]

[Table 2]

From Tables 1 and 2, the general formula (AI) of the present invention is shown.
The sample in which the compound represented by (A-III) and the coupler represented by the general formula (m) of the present invention are used in combination has no or almost no reduction in color density even when the long sample is stored at high temperature. It can be seen that the pressure fog also suppresses the increase and there is almost no increase in fog when compared with the comparative sample. The pressure fog had a higher density on the winding core side of the spool than on the outer side, and had a density gradient. The so-called 4-equivalent coupler (comparative coupler) in which the coupling active position is not substituted originally has a low production amount of a coloring dye due to the formation of a by-product during color development. There was a clear difference in the color density between and. The general formula (A-
The difference in color density due to the addition of the compounds represented by formulas (I) to (A-III) is as follows. It is assumed that the compound of the present invention reacts with the ═N—OH group to inactivate. Investigation of the cause is an issue for the future. However, this decrease in Dmax is significantly improved by using the compounds represented by the general formulas (AI) to (A-III) of the present invention in the coupler represented by the general formula (m) of the present invention. That is amazing.

Example 2 Sample 1 described in the example of JP-A-6-138574
The same sample as 01 was prepared according to the same description. This is designated as Sample 201. Further, the magenta coupler C-4 used in the ninth to eleventh layers of the green-sensitive layer is the coupler (m- of the present invention).
Sample 202 was prepared by replacing C-7 with (m-1), C-8 with (m-2), and C-12 with (m-19) in equimolar amounts. did. Sample 203 is a compound of the present invention (A-
18) at 5 mg / m ² , the 10th layer also has 3 mg / m ² , and the 11th layer
Samples were also prepared by adding 4 mg / m ² to the layer. The sample 204 was manufactured by adding the same amount of (A-18) to the ninth to eleventh layers of the sample 202 as in the case of the sample 203.

The prepared sample was 35 mm as in Example 1.
The width and length of 160 cm were cut and processed, wound on a spool and stored in a 135 cartridge. Each of these cartridges was stored according to the method described in (1) and (2) of Example 1, and then color-developed. The exposure in (1) was performed by attaching a G filter to the front surface of the wedge for sensitometry, and the processing time of the first development of the color development processing was 6 minutes. The developed samples were similarly measured for G density, and examined for changes in color density and pressure fog in the same manner. Table 3 shows the results.

[0131]

[Table 3]

From Table 3, in the sample 204 of the present invention, the difference in color density due to the temperature change and the increase in pressure fog (ΔD).
Is clearly improved.

Example 3 1) Support The support used in this example was prepared by the following method. Polyethylene-2,6-naphthalate polymer 100
After drying 2 parts by weight and 2 parts by weight of Tinuvin P.326 (manufactured by Ciba-Geigy Co.) as an ultraviolet absorber, 300 ° C.
After being melted at, it was extruded from a T-die, stretched 3.3 times at 140 ° C, then stretched 3.3 times at 130 ° C, and heat-fixed at 250 ° C for 6 seconds to form a 90 μm thick PEN.
I got a film. The PEN film has a blue dye, a magenta dye, and a yellow dye (public technical report: I-1, I-4, I-6, I-24, I-26, I-26 described in the official gazette number 94-6023). 27, II-5)
Was added in an appropriate amount. Further, the support was wound around a stainless steel core having a diameter of 20 cm to give a heat history of 110 ° C. and 48 hours, thereby providing a support that was not easily curled.

2) Coating of undercoat layer The above-mentioned support was subjected to corona discharge treatment, UV discharge treatment and glow discharge treatment on both surfaces thereof, and then gelatin 0.1 g / m ² and sodium α-sulfodione were formed on each surface. -2-ethylhexyl succinate 0.01 g / m ² , salicylic acid 0.04 g / m ² , p
-Chlorophenol 0.2 g / m ² , (CH ₂ = CHSO ₂ CH ₂ CH ₂ NHCO) ₂
CH ^₂ 0.012g / m _2, polyamide - epichlorohydrin polycondensate was coated an undercoat solution ^{0.02g / m 2 (10cc / m} 2, a bar coater used), provided with a subbing layer hotter side at the time of stretching. Dry 1
The test was carried out at 15 ° C for 6 minutes (all rollers and transport devices in the drying zone were at 115 ° C). 3) Coating of Back Layer An antistatic layer, a magnetic recording layer and a sliding layer having the following composition were coated as a back layer on one surface of the support after the undercoat.

3-1) Coating of antistatic layer A tin oxide-antimony oxide composite having an average particle size of 0.005 μm has a specific resistance of 5 Ω · cm and is a dispersion of fine particle powder (secondary agglomerated particle size of about 0.08 μm). 0.2 g / m ^2, gelatin 0.05g / m ^2, (C
H ₂ = CHSO ₂ CH ₂ CH ₂ NHCO) ₂ CH ₂ 0.02 g / m ² , poly (degree of polymerization 1
0) Oxyethylene-p-nonylphenol 0.005 g / m ²
And 100 mg / m ^{2 of} resorcin. 3-2) Coating of magnetic recording layer 3-poly (degree of polymerization: 15) Cobalt-γ-iron oxide coated with oxyethylene-propyloxytrimethoxysilane (15% by weight) (specific surface area: 43 m ² / g; Long axis 0.14μm, single axis 0.03μm, saturation magnetization 89emu / g, Fe ^{+ 2} / Fe ⁺³ = 6/94, the surface is treated with silicon oxide aluminum oxide with 2% by weight of iron oxide) 0.06g / m ² diacetyl cellulose 1.2 g / m ² (dispersion of the iron oxide was carried out using an open kneader and a sand _{mill), C 2 H 5 C (} CH 2 OCONH-C 6 H 3 (CH 3) NCO) as a curing agent ₃
0.3 g / m ² was applied with a bar coater using acetone, methyl ethyl ketone, cyclohexanone, and dibutyl phthalate as solvents to obtain a 1.2 μm-thick magnetic recording layer. C ₆ H ₁₃ CH (OH) C ₁₀ H ₂₀ COOC ₄₀ H ₈₁ 50 g / m as a slip agent
^2. Aluminum oxide (0.20 μm and 1.0 μm) as an abrasive coated with silica particles (1.0 μm) as matting agent and 3-poly (polymerization degree 15) oxyethylene-propyloxytrimethoxysilane (15 wt%) 50 mg / m ² and
It was added to 10 mg / m ² . Drying was carried out at 115 ° C for 6 minutes.
° C). X- write saturation magnetization moment of the magnetic recording layer of the D color density increment of about 0.1 of ^B, also the magnetic recording layer is 4.2 emu / g, coercive force 7.3 × 10 ⁴ A / m, the squareness ratio in (blue filter) Was 65%.

3-3) Preparation of sliding layer Diacetyl cellulose (25 mg / m ² ), C ₆ H ₁₃ CH (OH) C ₁₀ H ₂₀ C
OOC ₄₀ H ₈₁ (6mg / m ² ), poly (dimethylsiloxane) (B
-3) (1.5 mg / m ² ) was applied. In addition, this mixture is
In xylene / propylene monomethyl ether (1/1) 1
It was melted at 05 ° C., poured into and dispersed in propylene monomethyl ether (10 times amount) at room temperature to prepare a dispersion (acetone having an average particle diameter of 0.01 μm), and then added. Dry 1
The test was carried out at 15 ° C for 6 minutes (115 ° C for all the rollers and conveying devices in the drying zone). The sliding layer had excellent characteristics such as a dynamic friction coefficient of 0.10 (5 mmφ stainless steel ball, load 100 g, speed of 6 cm / min), static friction coefficient of 0.08 (clip method), and a dynamic friction coefficient of 0.15 between the emulsion surface and the sliding layer described later. .

4) Coating of Photosensitive Layer Next, each layer having the following composition was multilayer-coated on the side opposite to the back layer obtained above to prepare a color negative film.
This is designated as Sample 301.

(Photosensitive Layer Composition) The main materials used for each layer are classified as follows: ExC: Cyan coupler UV: UV absorber ExM: Magenta coupler HBS: High boiling organic solvent ExY: Yellow coupler H: Gelatin hardening agent ExS: Sensitizing dye The numeral corresponding to each component indicates the coating amount expressed in g / m ² unit, and for silver halide, the coating amount in terms of silver. However, for the sensitizing dye, the coating amount is shown in mol units with respect to 1 mol of silver halide in the same layer.

First Layer (Antihalation Layer) Black Colloidal Silver Silver 0.09 Gelatin 1.60 ExM-1 0.12 ExF-1 2.0 × 10 ^-3 Solid Disperse Dye ExF-2 0.030 Solid Disperse Dye ExF-3 0.040 HBS-1 0.15 HBS- 2 0.02

Second layer (intermediate layer) Silver iodobromide emulsion M Silver 0.065 ExC-2 0.04 Polyethyl acrylate latex 0.20 Gelatin 1.04

Third Layer (Low Sensitivity Red Sensitive Emulsion Layer) Silver iodobromide Emulsion A Silver 0.25 Silver iodobromide Emulsion B Silver 0.25 ExS-1 6.9 × 10 ^-5 ExS-2 1.8 × 10 ^-5 ExS-3 3.1 × 10 ^-4 ExC-1 0.17 ExC-3 0.030 ExC-4 0.10 ExC-5 0.020 ExC-6 0.010 Cpd-2 0.025 HBS-1 0.10 Gelatin 0.87

Fourth Layer (Medium Sensitivity Red Sensitive Emulsion Layer) Silver Iodobromide Emulsion C Silver 0.70 ExS-1 3.5 × 10 ^-4 ExS-2 1.6 × 10 ^-5 ExS-3 5.1 × 10 ^-4 ExC-1 0.13 ExC-2 0.060 ExC-3 0.0070 ExC-4 0.090 ExC-5 0.015 ExC-6 0.0070 Cpd-2 0.023 HBS-1 0.10 Gelatin 0.75

Fifth layer (high-sensitivity red-sensitive emulsion layer) Silver iodobromide emulsion D Silver 1.40 ExS-1 2.4 × 10 ^-4 ExS-2 1.0 × 10 ^-4 ExS-3 3.4 × 10 ^-4 ExC-1 0.10 ExC-3 0.045 ExC-6 0.020 ExC-7 0.010 Cpd-2 0.050 HBS-1 0.22 HBS-2 0.050 Gelatin 1.10

Sixth layer (intermediate layer) Cpd-1 0.090 Solid disperse dye ExF-4 0.030 HBS-1 0.050 Polyethyl acrylate latex 0.15 Gelatin 1.10

Seventh layer (low-sensitivity green-sensitive emulsion layer) Silver iodobromide emulsion E Silver 0.23 Silver iodobromide emulsion F Silver 0.15 Silver iodobromide emulsion G Silver 0.15 ExS-4 3.0 × 10 ^-5 ExS-5 2.1 × 10 ^-4 ExS-6 8.0 × 10 ^-4 ExM-2 0.30 ExM-3 0.086 ExY-1 0.015 HBS-1 0.30 HBS-3 0.010 Gelatin 0.73

Eighth Layer (Medium-Sensitivity Green Sensitive Emulsion Layer) Silver Iodobromide Emulsion H Silver 0.80 ExS-4 3.2 × 10 ^-5 ExS-5 2.2 × 10 ^-4 ExS-6 8.4 × 10 ^-4 ExC-8 0.010 ExM-2 0.10 ExM-3 0.025 ExY-1 0.018 ExY-4 0.010 ExY-5 0.040 HBS-1 0.13 HBS-3 4.0 × 10 ^-3 Gelatin 0.80

Ninth layer (high-sensitivity green-sensitive emulsion layer) Silver iodobromide emulsion I Silver 1.25 ExS-4 3.7 × 10 ^-5 ExS-5 8.1 × 10 ^-5 ExS-6 3.2 × 10 ^-4 ExC-1 0.010 ExM-1 0.020 ExM-4 0.025 ExM-5 0.040 Cpd-3 0.040 HBS-1 0.25 Polyethyl acrylate latex 0.15 Gelatin 1.33

10th layer (yellow filter layer) Yellow colloidal silver Silver 0.015 Cpd-1 0.16 Solid disperse dye ExF-5 0.060 Solid disperse dye ExF-6 0.060 Oil-soluble dye ExF-7 0.010 HBS-1 0.60 Gelatin 0.60

11th layer (low-sensitivity blue emulsion layer) Silver iodobromide emulsion J Silver 0.09 Silver iodobromide emulsion K Silver 0.09 ExS-7 8.6 × 10 ^-4 ExC-8 7.0 × 10 ^-3 ExY-1 0.050 ExY-2 0.22 ExY-3 0.50 ExY-4 0.020 Cpd-2 0.10 Cpd-3 4.0 × 10 ^-3 HBS-1 0.28 Gelatin 1.20

12th layer (high-sensitivity blue-sensitive emulsion layer) Silver iodobromide emulsion L Silver 1.00 ExS-7 4.0 × 10 ^-4 ExY-2 0.10 ExY-3 0.10 ExY-4 0.010 Cpd-2 0.10 Cpd-3 1.0 × 10 ^-3 HBS-1 0.070 Gelatin 0.70

13th layer (first protective layer) UV-1 0.19 UV-2 0.075 UV-3 0.065 HBS-1 5.0 × 10 ^-2 HBS-4 5.0 × 10 ^-2 gelatin 1.8

Fourteenth layer (second protective layer) Silver iodobromide emulsion M Silver 0.10 H-1 0.40 B-1 (diameter 1.7 μm) 5.0 × 10 ^-2 B-2 (diameter 1.7 μm) 0.15 B-3 0.13 S-1 0.20 Gelatin 0.70

Further, in order to improve the storability, processability, pressure resistance, antifungal / antibacterial property, antistatic property and coating property of each layer, W-1 to W-3, B-4 to B- may be used. 6, F
-1 to F-17, and iron salts, lead salts, gold salts, platinum salts,
It contains a palladium salt, an iridium salt, and a rhodium salt.

[0154]

[Table 4]

In Table 4, (1) Emulsions G to L were reduction-sensitized at the time of grain preparation using thiourea dioxide and thiosulfonic acid in accordance with the examples of JP-A-2-91938. (2) Emulsions A to L were subjected to gold sensitization, sulfur sensitization and selenium sensitization in the presence of the spectral sensitizing dye described in each photosensitive layer and sodium thiocyanate according to the examples of JP-A-3-237450. ing. (3) For the preparation of tabular grains, low molecular weight gelatin is used according to the example of JP-A 1-158426. (4) Dislocation lines as described in JP-A-3-237450 are observed in the tabular grains using a high voltage electron microscope.

Preparation of Dispersion of Organic Solid Disperse Dye ExF-3 shown below was dispersed by the following method. That is, 1430 g of a wet cake of a dye containing 30% of methanol was mixed with water and Pluronic F88 (ethylene oxide
200 g of propylene oxide block copolymer) was added and stirred to obtain a slurry having a dye concentration of 6%. Next, Ultra Visco Mill (UVM-2) manufactured by IMEX Co., Ltd.
1700 ml of zirconia beads having an average particle diameter of 0.5 mm was filled in the slurry, and the peripheral speed was about 10 m / sec and the discharge rate was 0.
It was pulverized at 5 l / min for 8 hours. The beads are filtered off, water is added to dilute to a dye concentration of 3%, and then 9
Heat at 0 ° C. for 10 hours. The obtained dye fine particles had an average particle size of 0.60 μm, and the breadth of the particle size distribution (particle size standard deviation × 100 / average particle size) was 18%.

Similarly, ExF-4, ExF-5, E
A solid dispersion of xF-6 was obtained. The average particle size of the fine dye particles is 0.45 μm, 0.54 μm, and 0.52 μm, respectively.
Met. ExF-2 was dispersed by the fine precipitation dispersion method by pH shift described in the Example of JP-A-3-182743. The average particle size of the dye fine particles was 0.05 μm.

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[0173]

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[0174] Next, Sample 302 is a compound (A-18) to ^{6mg / m 2, 10mg / m} 2 of coating amount of the present invention in the seventh layer and the eighth layer of the green-sensitive layer in the sample 301 A sample was prepared in the same manner with the above additions. Samples 303 and 304 are magenta couplers ExM used for the seventh and eighth layers of the green-sensitive layer in Samples 301 and 302, respectively.
-2 was replaced with the coupler (m-20) of the present invention in an equimolar amount to prepare samples in the same manner. After sample 305, the magenta coupler and the compound of the present invention were replaced as shown in Table 5, and samples were prepared in the same manner as sample 301. Regarding the couplers, the polymer couplers were replaced by equimolar amounts by converting the weight ratio of the pyrazolone mother nucleus of the constituent units.

[0175]

[Table 5]

The light-sensitive material produced as described above is used for 24 mm
The photosensitive material is cut to a width of 160 cm, and two perforations of 2 mm square are provided at a distance of 5.8 mm 0.7 mm from one side in the length direction of the photosensitive material. A set in which these two sets were provided at intervals of 32 mm was prepared and stored in the plastic film cartridge shown in FIG. The diameter of the core is 7
In mm, the number of turns is 32. This sample had a head gap of 5 μm from the coated side of the magnetic recording layer and a turn number of 2,000.
An FM signal was recorded at a feed rate of 1,000 / s during the above-mentioned perforation of the light-sensitive material using a head capable of inputting and outputting.

The following performances were examined using the light-sensitive materials housed in these cartridges. (1) Change in color density One set of each photographic material was stored at 50 ° C and 70% relative humidity, and the other set was stored at 5 ° C and 35% relative humidity for 7 days. The outermost part of the part which was rolled up in the cartridge and taken out was taken out, a G filter was attached to the front surface of the sensitometric wedge to expose it, and the color development process shown below was carried out. For the developed photosensitive material, G density is measured, and the minimum density +
From the point of exposure giving a density of 0.2
The density (D _2.0 ) obtained by subtracting the minimum density value from the density value was read for the light-sensitive material, and the change in color density was examined according to the method of Example 1. .
In addition, as a reference, the concentration value of sample 301 stored at 5 ° C. was taken as 100.

(2) Pressure Fogging (ΔD) After each sensitive material was stored at 45 ° C. and a relative humidity of 75% for 15 days, the sample was taken out from the cartridge and subjected to the following color development processing without exposure. The G concentration of the developed sample was measured from the tip to the end. From this measurement, the difference between the maximum and minimum G concentration (ΔD)
I asked. This difference in G concentration value was such that when stored in a cartridge, the G concentration was higher inside the winding core and lower on the outside. The smaller the value, the smaller the pressure fog. The results are summarized in Table 5 above.

The color development processing steps and processing solution compositions used are shown below. Fujicolor Negative Super G Ace 4
00 (manufactured by Fuji Photo Film Co., Ltd.) photographed by a camera was subjected to the following treatment for 1 m ² per day for 15 days (running treatment). Each processing was carried out as follows using an automatic processor FP-360B manufactured by Fuji Photo Film Co., Ltd. The remodeling was performed so that the overflow solution of the bleaching bath was not discharged to the post-bath but was entirely discharged to the waste liquid tank. This FP-360B is equipped with the evaporation correction means described in JIII Journal of Technical Disclosure No. 94-4992. The treatment process and the treatment liquid composition are shown below.

(Treatment process) Process Treatment time Treatment temperature Replenishment amount * Tank capacity Color development 3 minutes 5 seconds 38.0 ° C 20 ml 17 liters Bleach 50 seconds 38.0 ° C 5 ml 5 liters Fixed (1) 50 seconds 38.0 ° C -5 Liter settling (2) 50 seconds 38.0 ℃ 8 ml 5 liter water wash 30 s 38.0 ℃ 17 ml 3.5 liter stability (1) 20 s 38.0 ℃ −3 liter stability (2) 20 s 38.0 ℃ 15 ml 3 liter dry Drying 1 min 30 sec 60 ° C * Replenishment amount per 35 mm width of photosensitive material 1.1 m (equivalent to 24Ex. 1) Stabilizer is countercurrent method from (2) to (1), and overflow liquid of washing water is all Introduced in fixing (2). The fixing solution is also connected from (2) to (1) by a countercurrent pipe. The amount of developing solution brought into the bleaching process, the amount of bleaching solution brought into the fixing process, and the amount of fixing solution brought into the washing process were 2.5 ml, 2.0 ml, and 2 ml, respectively, of the photosensitive material of 35 mm width and 1.1 m. It was 0.0 ml. The crossover time is 6 seconds in all cases, and this time is included in the processing time of the previous step. Open area 100 cm ² in the color developing solution in the processing machine, 120 cm ² in the bleaching solution, the other processing solutions was about 100 cm ^2.

The composition of the processing liquid is shown below. (Color developing solution) Tank solution (g) Replenisher (g) Diethylenetriaminepentaacetic acid 2.0 2.0 1-hydroxyethylidene-1,1-diphosphonic acid 2.0 2.0 Sodium sulfite 3.9 5.3 Potassium carbonate 37.5 39.0 Potassium bromide 1.4 0.4 Potassium iodide 1.3 mg-disodium-N, N-bis (sulfonatoethyl) hydroxylamine 2.0 2.0 hydroxylamine sulfate 2.4 3.3 2-Methyl-4- [N-ethyl-N- (β-hydroxyethyl) amino] aniline sulfate 4.5 6.4 Add water 1.0 liter 1.0 liter pH (adjusted with potassium hydroxide and sulfuric acid) 10.05 10.18

(Bleaching Solution) Tank Solution (g) Replenishing Solution (g) 1,3-Diaminopropanetetraacetic Acid Ammonium Ferric Acid Monohydrate 118 180 Ammonium Bromide 80 115 Ammonium Nitrate 14 21 Succinic Acid 40 60 Maleic Acid 33 50 1.0 liter by adding water 1.0 liter pH (adjusted with ammonia water) 4.4 4.0

(Fixer) Tank solution (g) Replenisher (g) Ammonium methanesulfinate 10 30 Ammonium methanethiosulfonate 4 12 Ammonium thiosulfate aqueous solution (700 g / l) 280 ml 840 ml Imidazole 7 20 Ethylenediaminetetraacetic acid 15 45 1.0 liter by adding water 1.0 liter pH (adjusted with aqueous ammonia and acetic acid) 7.4 7.45

(Washing Water) Tap water was used as an H-type strongly acidic cation exchange resin (Amberlite IR-produced by Rohm and Haas).
120B) and an OH-type strongly basic anion exchange resin (Amberlite IR-400) are passed through a mixed bed column to adjust the concentration of calcium and magnesium ions to 3 mg /
Treat to less than 1 liter, followed by 20 mg sodium isocyanurate dichloride / liter and 150 mg sodium sulfate
/ Liter was added. The pH of this solution is 6.5 to 7.5.
Was in the range.

(Stabilizing Solution) Tank Solution and Replenishing Solution Common (Unit g) Sodium p-toluenesulfinate 0.03 Polyoxyethylene-p-monononylphenyl ether 0.2 (Average degree of polymerization 10) Disodium salt of ethylenediaminetetraacetic acid 0.05 1, 2,4-triazole 1.3 1,4-bis (1,2,4-triazol-1-ylmethyl) piperazine 0.75 1,2-benzisothiazolin-3-one 0.10 Water added 1.0 liter pH 8.5

From Table 5, the light-sensitive materials 304 to 312 of the present invention are shown.
Shows that the color density does not decrease or is very small even if the color density decreases, and shows good colorability even when the long length of rolled photosensitive material is stored at high temperature. Also, in the pressure fog, the photosensitive material of the present invention shows almost no increase in fog, and it is clear that even when the photosensitive material is rolled up for a long time and stored at high temperature, excellent results are obtained.

Example 4 The sample produced in Example 3 was cut into a width of 36 mm and a length of 160 cm, provided with a perforation similar to that of the current 135 type, and wound on a spool having a diameter of 11 mm in the same manner as in Example 1 to make a cartridge. Stored in. The number of turns at this time is 31 turns. Let these samples be 401-412. Sample 401 corresponds to 301, sample 402 corresponds to 302, and so on. The performance evaluation was carried out in the same manner according to the method described in Example 3 using the light-sensitive materials housed in these cartridges. The results are shown in Table 6 below.

[0188]

[Table 6]

From the results of Table 6, the light-sensitive materials 404 to 4 of the present invention.
Similar to the results of Samples 304 to 312 of Example 3, No. 12 has no decrease in the color density or is very small even if the decrease occurs, and it is good to store the long-length rolled photosensitive material at high temperature. Exhibits excellent color developability. Also, with respect to pressure fog, the photosensitive material of the present invention shows almost no increase in fog, and similarly, the photosensitive material gives excellent results even when the photosensitive material is rolled up for a long time and stored at high temperature. When comparing the results of this embodiment with the results of the third embodiment, in this embodiment, the same photosensitive material was wound 31 times around a spool having a diameter of 11 mm and stored in a current cartridge, but compared with the third embodiment. Therefore, the pressure near the core seems to be rather low, and the difference in pressure fog from the comparative sample appears to be somewhat small. As described above, it can be seen from the comparison with Example 3 that the pressure fog is large when a long core is wound around a core having a small diameter.

Example 5 The same test as in Example 3 was conducted except that the back layer of the support used in Example 3 was changed as follows, and the same result was obtained. 3-1) Antistatic Layer The resorcin added was removed. 3-2) Magnetic recording layer Silica particles added as a matting agent were removed, and an abrasive having alumina of 0.20 μm was added in an amount of 50 mg / m ² to 15 mg.
mg / m ^2, those of 1.0μm 10mg / m ² from 5mg / m ²
Respectively changed to. Furthermore, the drying conditions are 115 ° C / 6 minutes (115 ° C for all rollers and conveyors in the drying zone)
To 95 ° C./6 minutes (95 ° C. for all rollers and conveyance devices in the drying zone). 3-3) Sliding layer Diacetyl cellulose (25 mg / m ² ) was converted to hydroxypropyl cellulose (2 mg / m ² ) with C ₆ H ₁₃ CH (OH) C ₁₀ H ₂₀ CO ₂
C ₄₀ H ₈₁ was changed from 6 mg / m ² to 9 mg / m ² . as a result,
The coefficient of kinetic friction was reduced from 0.10 to 0.08, showing more favorable characteristics.

[0191]

According to the present invention, a silver halide color which prevents a decrease in color density which occurs when a light-sensitive material is long-wound and stored under conditions of high temperature and which suppresses an increase in pressure fog. A photographic light-sensitive material and a light-sensitive material package can be provided.

[Brief description of the drawings]

FIG. 1 is an exploded perspective view of a photographic light-sensitive material package (photographic film cartridge) according to one embodiment of the present invention.

FIG. 2 is a diagram of the photographic light-sensitive material package as viewed from a radial direction.

FIG. 3 is a view of the photographic light-sensitive material package viewed from a radial direction at a position different from that in FIG.

FIG. 4 is a view of the photographic light-sensitive material package as viewed from one side in the axial direction thereof.

FIG. 5 is a view of the photographic light-sensitive material package as seen from the other axial direction.

FIG. 6 is a sectional view of the photographic light-sensitive material package cut along the axial direction.

FIG. 7 is a diagram showing an adhesive label stock sheet with release paper.

[Explanation of symbols]

 100 Photo Film Patrone 101 Patrone Main Body 102 Photo Film 103 Spool 104 Patrone Label 105 Upper Case 106 Lower Case 107 Film Feed Out Port 108 Lid Member 109 Separation Claw 110 Key Groove 111 Key Groove 112 Spool Shaft 113 Flange 114 Flange 115 Data Disc 116 Bar Code Label 117 Flange engaging portion 118 Flange engaging portion 119 Slit 120 Use display member support portion 121 Key groove 122 Key groove 123 Use display member 124 Bearing portion 125 Ratchet pawl 126 Gear 127 Display plate 128 Spool lock 129 Round hole 130 Round hole 131 Opening edge 132 Opening edge 133 Hole 134 Large-diameter fan-shaped portion 135 Notch 136 Opening 137 Opening 138 Displaying opening 139 Table Display opening 140 Display opening 141 Display opening 142 Film roll 143 Film tip 144 Rock paw 145 Sensitivity detection notch 146 Opening 147 Developed display tab 150 Gate 151 ID number printing space 152 Variety printing space 153 Bar code printing space

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁶ Identification code Internal reference number FI Technical display location G03C 7/384 G03C 7/384 G11B 5/633 G11B 5/633

Claims (3)

[Claims] 1. A silver halide color photographic light-sensitive material having at least one light-sensitive silver halide emulsion layer and at least one light-insensitive layer on one side of a support. -I), general formula (A-II)
Alternatively, a silver halide color photographic light-sensitive material containing at least one compound selected from the general formula (A-III) and a coupler represented by the following general formula (m). Embedded image In the general formula (AI), _Ra1 represents an alkyl group, an alkenyl group, an aryl group, an acyl group, an alkyl or arylsulfonyl group, an alkyl or arylsulfinyl group,
A carbamoyl group, a sulfamoyl group, an alkoxycarbonyl group or an aryloxycarbonyl group;
_a2 represents a hydrogen atom or a group represented by R _a1 . However,
When R _a1 is an alkyl group, an alkenyl group or an aryl group, R _a2 is an acyl group, an alkyl or arylsulfonyl group, an alkyl or arylsulfinyl group, a carbamoyl group, a sulfamoyl group, an alkoxycarbonyl group or an aryloxycarbonyl group. R _a1 and R _a2 may combine with each other to form a 5- to 7-membered ring, provided that S
-Does not form a triazine ring. General formula (A-I
In I), X represents a heterocyclic group excluding the S-triazine ring, and R _b1 represents an alkyl group, an alkenyl group or an aryl group. X and R _b1 may combine with each other to form a 5- to 7-membered ring, provided that they do not form an S-triazine ring. In the general formula (A-III), Y is -N =
Represents a group of nonmetallic atoms necessary for forming a 5-membered ring together with C-. Y further represents a nonmetallic atom group necessary for forming a 6-membered ring together with the -N = C- group, and -N = C
The terminal of Y bonded to the carbon atom of the group is -N (R _c1 )-, -C
(R _c2 ) (R _c3 )-, —C (R _c4 ) =, —O—, a group selected from —S— (bonded to the carbon atom of —N═C— on the left side of each group) Represents However, it does not form an S-triazine ring. R _{c1 to} R _c4 each represent a hydrogen atom or a substituent. Embedded image In formula (m), R ₁ represents an alkyl group, an aryl group, an acyl group, or a carbamoyl group. Ar represents a phenyl group or a phenyl group substituted with one or more halogen atoms, an alkyl group, a cyano group, an alkoxy group, an alkoxycarbonyl group, an acylamino group, a sulfonamide group, a sulfonyl group or a sulfamoyl group. Z ₁ represents a group capable of splitting off upon reaction with an oxidized product of an aromatic primary amine color developing agent. 2. The silver halide color photographic light-sensitive material according to claim 1, further comprising a magnetic recording layer containing magnetic grains on the side opposite to the side having the emulsion layer and the support. 3. A cartridge main body 101 is internally rotatably accommodated in a spool 103 around which a photographic light-sensitive material 102 having an emulsion layer provided on a support is wound, and the tip of the photographic light-sensitive material is freely rotated by the rotation of the spool. The cartridge main body has a photographic light-sensitive material feed-out passage having a light-shielding mechanism for feeding out the photographic light-sensitive material, and a pair of flanges 113 with lips are respectively provided inside both ends of the spool shaft 112 of the spool. , 11
4. A photographic light-sensitive material package 100 in which 4 is attached for holding a photographic light-sensitive material, wherein the photographic light-sensitive material is the silver halide color photographic light-sensitive material according to claim 1 or 2. Photosensitive material package.