JPH0943763A - Silver halide color photographic sensitive material and package containing same - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide occurrence of pressure fog when stored at high temperature by incorporating a specified compound and a specified coupler in at least one of photosensitive layers. SOLUTION: At least one of the photosensitive layers contains a compound selected from formula I and the like, and the acyl-acetoamide type coupler selected from formula II and/or a coupler selected from formula III and the like, and in formulae I-III, Ra1 is an alkyl, alkenyl, aryl, or acyl group or the like; Ra2 is an H atom or a group same as Ra1 ; R1 is a substituent; Q is a nonmetallic atomic group necessary to form a 3-∼5-membered hydrocarbon ring or a 3-∼6-membered ring having hetero atoms, such as N or O, together with the C atom; each of X1 and X2 is an alkyl or aryl or heterocyclic group: Y is an aryl or a heterocyclic group; and Z is a group to be released by reaction of the coupler of formula III with the oxidation product of a developing agent.

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a silver halide color photographic light-sensitive material and a package thereof. In particular, the present invention relates to a silver halide color photographic light-sensitive material and a package thereof, which promotes color development, imparts high sensitivity and gradation, and prevents pressure fog when the light-sensitive material is rolled up for a long time and stored at high temperature.

[0002]

2. Description of the Related Art A silver halide color photographic light-sensitive material, especially a color light-sensitive material for photographing, is left in various environments for a long time from the manufacture of the light-sensitive material to photographing and development. There is a strong demand for a stable light-sensitive material in which photographic performance does not fluctuate and the finished quality of development is always constant. Therefore, it is known to use a hydroxylamine derivative in a photographic photosensitive layer. For example, U.S. Pat. Nos. 4,339,515 and 4,3.
It is described in No. 30,606. However, all of these patents improve the storability of the color image produced by the coupling reaction between the coupler and the oxidized form of the developing agent,
It has not been possible to solve the problem of being left in various environments for a long period of time between the production of the light-sensitive material, the photographing and the development. In addition, it is known to use a compound having an S-triazine ring as a material for improving the storage stability of the above light-sensitive material. For example, JP-A-59-162546 discloses that the storability of a latent image is improved by using it in combination with a compound having an active vinyl group. JP-A-59-97134 discloses that a tabular silver halide grain is used. It is disclosed that the fog is reduced by the combined use with the emulsion.
However, even with the above technique using a compound having an S-triazine (1,3,5-triazine) ring, fog during storage of the light-sensitive material and latent image sensitization that occurs when the light-sensitive material is photographed over time, Further, it has been impossible to prevent the pressure fog which occurs when the photosensitive material is wound long.

Further, for example, European Published Patent No. 447969.
U.S. Pat. Nos. 5,194,369 and 5,21
The color images obtained from the couplers disclosed in No. 3,958 and No. 5,306,609 are similar in color image fastness to those obtained from the widely used pivaloylacetanilide type couplers. In addition, the molecular extinction coefficient of the formed dye is higher than that of the dye obtained from the pivaloylacetanilide type coupler, and higher than that of the benzoylacetanilide type which is also widely used, and the spectral absorption characteristics of the dye solution. Has favorable characteristics such as small absorption in the green region on the long wavelength side and excellent color reproducibility. However, the couplers disclosed in the above specification do not have sufficiently high coupling activity,
There is also a problem of pressure fog that occurs when the photosensitive material is rolled up in a long length and stored at high temperature.

[0004]

SUMMARY OF THE INVENTION The present invention therefore generally provides at least one photosensitive layer comprising at least one photosensitive silver halide emulsion layer and at least one light-insensitive layer on one side of a support. An acylacetamide-type coupler containing a compound selected from the formulas (AI) to (A-III) and having an acyl group represented by the general formula (YI) and / or the general formula (1) or the general formula (1) A silver halide color photographic light-sensitive material containing a coupler represented by 2), which promotes color development and provides high color developability, and prevents pressure fog that occurs when the light-sensitive material is rolled up for a long time and stored at high temperature. An object is to provide a silver halide color photographic light-sensitive material and a package containing the light-sensitive material.

[0005]

The inventors of the present invention have found that the above-mentioned problems are generally solved in at least one of the light-sensitive layers constituting the light-sensitive material by improving the color-forming property and the storage stability by promoting color formation of the light-sensitive material. An acylacetamide type coupler having a specific hydroxylamine compound selected from the formulas (A-I) to (A-III) and an acyl group represented by the general formula (YI) and / or the general formula (1) or the general formula ( 2)
The inventors have found that what can be achieved by a silver halide color photographic light-sensitive material containing a specific coupler represented by and also can be achieved by a package in which the light-sensitive material is housed in a specific cartridge, and have completed the present invention. . That is, the present invention provides (1) a silver halide color photographic light-sensitive material having, on one side of a support, a light-sensitive layer comprising at least one light-sensitive silver halide emulsion layer and at least one light-insensitive layer, General formula (A-I) in at least one layer of the photosensitive layer,
An acylacetamide type coupler containing a compound selected from formula (A-II) or formula (A-III) and having an acyl group represented by formula (YI) and / or
Alternatively, a silver halide color photographic light-sensitive material containing a coupler represented by the general formula (1) or the general formula (2).

[0006]

Embedded image

In the general formula (AI), R _a1 is an alkyl group, an alkenyl group, an aryl group, an acyl group, an alkyl or aryl sulfonyl group, an alkyl or aryl sulfinyl group, a carbamoyl group, a sulfamoyl group, an alkoxycarbonyl group or aryl. It represents an oxycarbonyl group, and R _a2 represents a hydrogen atom or a group represented by R _a1 . However, when R _a1 is an alkyl group, an alkenyl group or an aryl group, R _a2 is an acyl group, an alkyl or arylsulfonyl group, an alkyl or arylsulfinyl group,
A carbamoyl group, a sulfamoyl group, an alkoxycarbonyl group or an aryloxycarbonyl group. R _a1
And R _a2 may combine with each other to form a 5- to 7-membered ring, provided that they do not form an S-triazine ring. In formula (A-II), X represents a heterocyclic group excluding the S-triazine ring, and R _b1 represents an alkyl group, an alkenyl group or an aryl group. X and R _b1 may combine with each other to form a 5- to 7-membered ring, provided that they do not form an S-triazine ring. In the general formula (A-III), Y represents a nonmetallic atom group necessary for forming a 5-membered ring together with -N = C-. Y further represents a group of non-metal atoms necessary for forming a 6-membered ring together with the -N = C- group, and the terminal of Y bonded to the carbon atom of the -N = C- group
-N (R _c1 )-, -C (R _c2 ) (R _c3 )-, -C (R _c4 ) =, -O-, -S-
Represents a group selected from among the groups (bonded to the carbon atom of -N = C- on the left side of each group). However, it does not form an S-triazine ring. R _{c1 to} R _c4 represent a hydrogen atom or a substituent. General formula (YI)

[0008]

[Chemical 6]

In the formula, R ₁ represents a substituent, Q is a 3- to 5-membered hydrocarbon ring together with C, or 3 to 5 having at least one hetero atom selected from N, O, S and P in the ring.
It represents a group of non-metal atoms necessary for forming a 6-membered heterocycle. General formula (1)

[0010]

[Chemical 7]

General formula (2)

[0012]

Embedded image

In the formula, X ₁ and X ₂ each represent an alkyl group, an aryl group or a heterocyclic group, X ₃ represents an organic residue forming a nitrogen-containing heterocyclic group together with> N-, and Y represents an aryl group. Alternatively, Z represents a heterocyclic group, and Z represents a group which is released when the coupler represented by the general formula reacts with an oxidized product of a developing agent.

(2) The silver halide color as described in (1), which has a magnetic recording layer containing magnetic particles in a back layer opposite to the side having the photosensitive layer and the support. Photographic material.

(3) Inside the cartridge body 101,
A spool 103 around which a photographic light-sensitive material 102 having an emulsion layer on a support is wound is rotatably accommodated, and the tip of the photographic light-sensitive material can be freely sent out of the cartridge by the rotation of the spool. In order to feed the photographic light-sensitive material, it has a photographic light-sensitive material feed-out passage having a light-shielding mechanism, and inside the spool shaft 112 of the spool, inside the both ends of the spool shaft 112, a pair of flanges 113 with lips, respectively.
In the photographic light-sensitive material package 100 in which 114 is attached for holding the photographic light-sensitive material, the photographic light-sensitive material is the silver halide photographic light-sensitive material described in (1) or (2). Material packaging.

The embodiment (1) above is directed to a silver halide color photographic light-sensitive material comprising a photosensitive layer having at least one photosensitive silver halide emulsion layer and at least one non-photosensitive layer on one side of a support. A compound selected from the general formulas (AI) to (A-III) and an acylacetamide type coupler having an acyl group represented by the general formula (YI) and / or the general formula (1) in at least one layer of the photosensitive layer. Alternatively, it is a color light-sensitive material containing a coupler represented by the general formula (2). Thus, using the specific compounds represented by the general formulas (AI) to (A-III), the acylacetamide type coupler having the acyl group represented by the general formula (YI) and / or the general formula (1) Alternatively, when used in combination with these specific yellow couplers represented by the general formula (2), the color-promoting effect can be obtained without impairing the excellent color image fastness, high molecular extinction coefficient and color reproduction of these yellow couplers. The object of the present invention is to provide high sensitivity and gradation, and to prevent pressure fog that occurs when the photosensitive material is rolled up for a long time and stored at high temperature.

A preferred mode (2) is a color light-sensitive material having a magnetic recording layer containing magnetic particles in a back layer opposite to the above-mentioned photosensitive layer with a support interposed therebetween, and having a magnetic recording layer. Shows a tendency to further deteriorate the pressure fog when the photosensitive material is longly rolled up, but it is also effective for solving this problem, and also has an effect of promoting color development, and achieves the object of the present invention. .

A preferred mode (3) is a package in which the photosensitive material is housed in a specific cartridge. However, the pressure fog generated in such a package can be solved in the same manner as described above, and the effect of promoting color development is also exhibited. Therefore, the object of the present invention is also achieved.

[0019]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below. The compounds represented by formulas (AI) to (A-III) will be described in more detail. The alkyl group referred to in the present invention is a linear, branched, or cyclic alkyl group, and may have a substituent. In the general formula (AI), R _a1
Is an alkyl group (preferably an alkyl group having 1 to 36 carbon atoms such as methyl, ethyl, i-propyl, cyclopropyl, butyl, isobutyl, cyclohexyl, t-octyl, decyl, dodecyl, hexadecyl, benzyl), an alkenyl group (preferably Is an alkenyl group having 2 to 36 carbon atoms, for example, allyl, 2-butenyl, isopropenyl, oleyl, vinyl), an aryl group (preferably having 6 to 6 carbon atoms).
40 aryl groups such as phenyl and naphthyl, acyl groups (preferably acyl groups having 2 to 36 carbon atoms such as acetyl, benzoyl, pivaloyl, α- (2,4-di-).
tert-amylphenoxy) butyryl, (3-cyclohexen-1-yl) -carbonyl, myristoyl, stearoyl, naphthoyl, m-pentadecylbenzoyl,
(5-norbornen-2-yl) carbonyl, isonicotinoyl), an alkyl or arylsulfonyl group (preferably an alkyl or arylsulfonyl group having 1 to 36 carbon atoms, such as methanesulfonyl, octanesulfonyl,
Benzenesulfonyl, toluenesulfonyl), alkyl or arylsulfinyl group (preferably having 1 to 4 carbon atoms).
An alkyl or arylsulfinyl group of 0 such as methanesulfinyl and benzenesulfinyl), a carbamoyl group (including an N-substituted carbamoyl group, preferably a carbamoyl group having 1 to 40 carbon atoms such as N-ethylcarbamoyl, N-phenylcarbamoyl, N, N-dimethylcarbamoyl, N-butyl-N-phenylcarbamoyl), a sulfamoyl group (including an N-substituted sulfamoyl group, preferably a sulfamoyl group having 1 to 40 carbon atoms such as N-methylsulfamoyl, N, N-diethylsulfamoyl, N-phenylsulfamoyl, N-cyclohexyl-N-phenylsulfamoyl, N-ethyl-N-dodecylsulfamoyl), alkoxycarbonyl group (preferably alkoxy having 2 to 36 carbon atoms) For example, a carbonyl group Alkoxycarbonyl, cyclohexyloxycarbonyl, benzyloxycarbonyl, isoamyl oxycarbonyl, hexadecyl oxycarbonyl)
Alternatively, it represents an aryloxycarbonyl group (preferably an aryloxycarbonyl group having 7 to 40 carbon atoms, such as phenoxycarbonyl or naphthoxycarbonyl).
R _a2 represents a hydrogen atom or the group represented by R _a1 above.

In the general formula (A-II), the heterocyclic group of X is a 5- to 7-membered S-triazine ring (having at least one of nitrogen atom, sulfur atom, oxygen atom or phosphorus atom as a ring-constituting atom) 1,3,5-triazine ring) to form a hetero ring, and the bonding position of the hetero ring (position of monovalent group) is preferably a carbon atom, for example, 1,2,4-triazine-3. -Yl, pyridin-2-yl, pyrazinyl, pyrimidinyl, purinyl, quinolyl,
Imidazolyl, 1,2,4-triazol-3-yl,
Represents benzimidazol-2-yl, thienyl, furyl, imidazolidinyl, pyrrolinyl, tetrahydrofuryl, morpholinyl, phosphinolin-2-yl. R
_b1 is an alkyl group for R _a1 in the above general formula (AI),
It has the same meaning as an alkenyl group or an aryl group.

In the general formula (A-III), Y is -N = C.
-A non-metallic atom group necessary to form a 5-membered ring together with (for example, the ring group formed is imidazolyl, benzimidazolyl, 1,3-thiazol-2-yl, 2-imidazolin-2-yl, purinyl, 3H -Indol-2-yl). Y is a group of nonmetallic atoms necessary for forming a 6-membered ring together with the -N = C- group, and -N
The end of Y bonded to the carbon atom of the ═C-group is -N (R _C1 )-, -C
(R _C2 ) (R _C3 )-, —C (R _C4 ) =, —O—, a group selected from —S— (bonded to the carbon atom of —N═C— on the left side of each group) Represents However, it does not form an S-triazine (1,3,5-triazine) ring. R _{c1 to} R _c4 may be the same or different and each represents a hydrogen atom or a substituent (for example, an alkyl group, an alkenyl group, an aryl group, an alkoxy group,
Aryloxy group, alkylthio group, arylthio group,
Alkylamino group, arylamino group, halogen atom)
Represents Here, the alkyl group, the alkenyl group, and the aryl group have the same meanings as the alkyl group, the alkenyl group, and the aryl group in R _a1 of the general formula (A-1), and the alkoxy group, the alkylthio group, the alkyl group of the alkylamino group, The aryl group of aryloxy group, arylthio group and arylamino group also has the same meaning as described for R _a1 in formula (A-1). The halogen atom represents, for example, chlorine, bromine or fluorine atom. Examples of the 6-membered ring group formed by Y include quinolyl, isoquinolyl, phthalazinyl, quinoxalinyl, 6H-1,2,
5-thiadiazin-6-yl is mentioned.

In the general formula (AI) or (A-II), R _a1 and R _a2 , and X and R _b1 may combine with each other to form a 5- to 7-membered ring, for example, a succinimide ring or a phthalimide ring. , Triazole ring, urazole ring, hydantoin ring, and 2-oxo-4-oxazolidinone ring. However, the S-triazine ring is excluded. General formula (AI)
Each group of the compounds represented by to (A-III) may be further substituted with a substituent. Examples of these substituents include an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a hydroxy group, an alkoxy group, an aryloxy group,
Alkylthio group, arylthio group, amino group, acylamino group, sulfonamide group, alkylamino group, arylamino group, carbamoyl group, sulfamoyl group, sulfo group, carboxyl group, halogen atom, cyano group, nitro group, sulfonyl group, acyl group , An alkoxycarbonyl group, an aryloxycarbonyl group, an acyloxy group, a hydroxyamino group and the like.

In the general formula (AI), R _a2 is a hydrogen atom, an alkyl group, an alkenyl group or an aryl group, and R _a1 is an acyl group, an alkyl or aryl sulfonyl group, an alkyl or aryl sulfinyl group or a carbamoyl group. , Sulfamoyl group, alkoxycarbonyl group,
It is preferably an aryloxycarbonyl group, more preferably R _a2 is an alkyl group or an alkenyl group, and R _a1 is an acyl group, an alkyl or arylsulfonyl group, a carbamoyl group, a sulfamoyl group, an alkoxycarbonyl group, or aryloxy. A compound that is a carbonyl group. Most preferably, R _a2 is an alkyl group and R _a1 is an acyl group.

In the general formula (A-II), R _b1 is preferably an alkyl group or an alkenyl group, more preferably an alkyl group. On the other hand, the general formula (A-II) is preferably represented by the following general formula (A-II-1).

[0025]

Embedded image

[0026] In the general formula (A-II-1), R b1 represents R _b1 in formula (A-II), X ₁ is -C = N-with necessary to form a 5- or 6-membered ring Represents a non-metallic atomic group. Among the compounds represented by formula (A-II-1), it is more preferable that X ₁ forms a 5- or 6-membered heteroaromatic ring. However, it does not form an S-triazine ring.

Of the compounds represented by formula (A-III), Y is preferably a group of non-metal atoms necessary for forming a 5-membered ring, and is bonded to a carbon atom of -N = C- group. It is more preferable that the terminal atom of Y is a nitrogen atom. However, it does not form an S-triazine ring. Most preferably, Y forms an imidazoline ring. This imidazoline ring may be condensed with a benzene ring.

Of the compounds represented by the general formulas (A-I) to (A-III), those having a total carbon number of 15 or less are represented by the general formulas (A-I) to (A-III). It is preferable in that it acts on layers other than the compound-added layer represented by, and conversely, compounds having a total carbon number of 16 or more are preferred for the purpose of acting only on the above-mentioned added layer. General formula (AI)-
Among the compounds represented by (A-III), the compound represented by the general formula (A-
Those represented by I) and (A-II) are preferable, and those represented by the general formula (AI) are more preferable. Specific examples of the compounds represented by formulas (AI) to (A-III) of the present invention are shown below, but the present invention is not limited thereto.

[0029]

Embedded image

[0030]

Embedded image

[0031]

[Chemical 12]

[0032]

Embedded image

[0033]

Embedded image

These compounds and the above-mentioned general formula (AI)
The correspondence with (A-III) is as follows. General formula (AI): A-1 to A-9, A-11 to A-1
8, A-33 to A-55. General formula (A-II): A-10, A-20, A-30. General formula (A-III): A-19, A-21 to A-29, A
-31, A-32. These compounds of the present invention are described in J. Org. Chem., 27, 405.
4 ('62), J. Amer. Chem. Soc., 73,2981 ('51), Japanese Patent Publication No. 4
It can be easily synthesized by the method described in 9-10692 or the like or a method similar thereto. In the present invention, the compounds represented by the general formulas (AI) to (A-III) are emulsified even if dissolved in water, a water-soluble solvent such as methanol or ethanol, or a mixed solvent thereof. It may be added by dispersion. Further, they may be added in advance during the preparation of the emulsion. When it dissolves in water, the higher or lower the pH, the higher the solubility, the pH
It may be added by dissolving it by raising or lowering.
In the present invention, two or more kinds of the compounds represented by the general formulas (AI) to (A-III) may be used in combination. For example, using both water-soluble and oil-soluble
It is advantageous in photographic performance. Compounds (A-I) to (A-III)
The coating amount of 0.01 to 0.01
100 mg / m ² is preferred. 0.1 to 50 mg / m ² is more preferable, and 1 to 20 mg / m ² is even more preferable. These compounds are used in at least one layer of the silver halide photosensitive layer, but the same compound may be used in a plurality of layers.
Different compounds may be used in each photosensitive layer.
Further, at the same time as the photosensitive layer, a non-photosensitive layer, for example, an intermediate layer,
It can also be used in a colloidal silver-containing yellow filter layer, an AH layer and a protective layer.

In the present invention, general formulas (AI) to
The compound represented by (A-III) is preferably an oil-soluble compound. It is particularly preferable to use the oil-soluble compound in the same layer as the layer containing the coupler described below. Furthermore, water-soluble compounds may be used.

General formulas (AI) to (A-III) of the present invention
Although the reason for using the compound represented by the following with the coupler is not clear, it accelerates the color development of the coupler,
It provides high sensitivity and gradation, and its action and effect are greater than those of other benzoylacetanilide type couplers. Further, when the photosensitive material is wound long, it exhibits an effect of preventing pressure fog generated in an inner portion (winding core) of the wound outer portion, particularly pressure fog when stored at high temperature. Here, long-length involvement means
It means that the winding is 20 or more. Especially, it means to involve more than 30 laps. In addition, the high temperature when the photosensitive material is rolled up and stored at high temperature means a temperature range higher than the normal indoor temperature, and specifically, the inside of the car when the car is left in the hot sun in summer. Say the approximate temperature. Therefore, the high temperature is 35 ° C. or higher, and the upper limit is a temperature range up to 90 ° C.

Next, the acylacetamide type yellow coupler having an acyl group represented by formula (YI) used in the present invention will be described in more detail.

The acylacetamide type yellow coupler used in the present invention is preferably represented by the following general formula (YII).
Is represented by General formula (YII)

[0039]

Embedded image

In the general formula (YII), R ₁ is a substituent except a hydrogen atom, Q is a hydrocarbon ring of 3 to 5 members together with C or at least one of N, S, O, P, Se and Te. R ₂ is a hydrogen atom, a halogen atom (F, Cl, Br, I), an alkoxy group, or a non-metal atom group necessary for forming a 3- to 6-membered heterocycle containing a selected heteroatom in the ring. An aryloxy group, an alkyl group or an amino group, R ₃ is a group capable of substituting on the benzene ring, and X is a group capable of splitting off by a coupling reaction with a hydrogen atom or an oxidized product of an aromatic primary amine developer. (Hereinafter referred to as a leaving group) and k represents an integer of 0 to 4, respectively. However, when k is plural, plural R ₃ may be the same or different. R ₁ is preferably an organic residue containing no metal atom, and more preferably a hydrocarbon group which may have a substituent. In the following, the acylacetamide-type yellow dye according to the present invention
In the description of the coupler, the halogen atom is F, Cl, B.
means r or I.

Here, as an example of R ₃ , a halogen atom,
Alkyl group, aryl group, alkoxy group, aryloxy group, alkoxycarbonyl group, aryloxycarbonyl group, carbonamido group, sulfonamide group, carbamoyl group, sulfamoyl group, alkylsulfonyl group,
Ureido group, sulfamoylamino group, alkoxycarbonylamino group, alkoxysulfonyl group, aryloxysulfonyl group, acyloxy group, nitro group, heterocyclic group, cyano group, acyl group, acyloxy group, alkylsulfonyloxy group, arylsulfonyloxy Examples of the leaving group include a heterocyclic group bonded to the coupling active position at a nitrogen atom, an aryloxy group, an arylthio group, an acyloxy group, an alkylsulfonyloxy group, an arylsulfonyloxy group, a heterocyclic oxy group, and a heterocyclic group. There are ring thio groups and halogen atoms.

In the general formula (YII), when the substituent is an alkyl group or contains an alkyl group, the alkyl group is linear, branched or cyclic, unless otherwise specified. Or an alkyl group which may contain an unsaturated bond (for example, methyl, isopropyl, t-butyl, cyclopentyl, t-pentyl, cyclohexyl,
2-ethylhexyl, 1,1,3,3-tetramethylbutyl, dodecyl, hexadecyl, allyl, 3-cyclohexenyl, oleyl, benzyl, trifluoromethyl,
Hydroxymethylmethoxyethyl, ethoxycarbonylmethyl, phenoxyethyl).

In the general formula (YII), when the substituent is an aryl group or contains an aryl group, the aryl group may be a monocyclic or composite ring aryl group (which may be substituted) unless otherwise specified. For example, phenyl, 1-naphthyl, p-tolyl, o-tolyl, p-chlorophenyl,
4-methoxyphenyl, 8-quinolyl, 4-hexadecyloxyphenyl, pentafluorophenyl, p-hydroxyphenyl, p-cyanophenyl, 3-pentadecylphenyl, 2,4-di-t-pentylphenyl, p-
Methanesulfonamidophenyl, 3,4-dichlorophenyl).

In the general formula (YII), when the substituent is a heterocyclic group or contains a heterocyclic ring, the heterocyclic group is selected from O, N, S, P, Se and Te unless otherwise specified. A 3- to 8-membered optionally substituted monocyclic or condensed-ring heterocyclic group containing at least one hetero atom in the ring (for example, 2-furyl, 2-pyridyl, 4-pyridyl,
1-pyrazolyl, 1-imidazolyl, 1-benzotriazolyl, 2-benzotriazolyl, succinimide, phthalimide, 1-benzyl-2,4-imidazolidindione-3-yl) is meant.

The substituents preferably used in formula (YII) will be described below.

In the general formula (YII), R ₁ is preferably a halogen atom, a cyano group, or a monovalent group having 1 to 30 total carbon atoms (hereinafter abbreviated as C number) which may be substituted (for example, C number). , An alkyl group, an alkoxy group, an alkylthio group) or a monovalent group having a C number of 6 to 30 (for example, an aryl group, an aryloxy group, an arylthio group), and the substituent thereof is, for example, a halogen atom, There are alkyl groups, alkoxy groups, nitro groups, amino groups, carbonamide groups, sulfonamide groups, and acyl groups. R ₁ may be a so-called ballast group. R ₁ may combine with Q to form a bicyclo ring.

In the general formula (YII), Q is preferably C together with C, which may be substituted with any of 3 to 5 members.
A hydrocarbon ring of the number 3 to 30 or at least one N, S,
C number 2-3 containing a hetero atom selected from O and P in the ring
Represents a group of nonmetallic atoms necessary for forming a heterocyclic ring of 0. The ring formed by Q together with C may contain an unsaturated bond in the ring, and may be substituted or unsubstituted. Examples of the ring formed by Q together with C include cyclopropane ring, cyclobutane ring, cyclopentane ring, cyclopropene ring, cyclobutene ring, cyclopentene ring, oxetane ring, oxolane ring, oxane ring, 1,3-dioxolane ring, dioxane ( 1,3- or 1,4-) ring, thietane ring, thiolane ring, thiane ring, 1,3-dithiolane ring, dithiane (1,3- or 1,4-) ring, 1,4-
There are oxathian ring and pyrrolidine ring. Examples of the substituent are the same as those described for R ₃ , but they may be further substituted with an oxo group (═O), or the substituents may be bonded to each other to form a ring.

In the general formula (YII), R ₂ is preferably a halogen atom, an optionally substituted alkoxy group having 1 to 30 C atoms, an aryloxy group having 6 to 30 C atoms, or 1 to C atoms. It represents an alkyl group of 30 or an amino group having a C number of 0 to 30, and the substituent thereof is, for example, a halogen atom, an alkyl group, an alkoxy group or an aryloxy group.

In the general formula (YII), R ₃ is preferably a halogen atom, which may have a C number of 1-3.
0 alkyl group, 6-30 C aryl group, 1-C number
30, an alkoxycarbonyl group having 2 to 30 carbon atoms, an aryloxycarbonyl group having 7 to 30 carbon atoms,
A C 1-30 carbonamide group, a C 1-30 sulfonamide group, a C 1-30 carbamoyl group, a C number 0
To 30 sulfamoyl groups, alkylsulfonyl groups having 1 to 30 carbon atoms, arylsulfonyl groups having 6 to 30 carbon atoms, C
A ureido group having 1 to 30 carbon atoms, a sulfamoylamino group having 0 to 30 carbon atoms, an alkoxycarbonylamino group having 2 to 30 carbon atoms, a heterocyclic group having 1 to 30 carbon atoms, an acyl group having 1 to 30 carbon atoms, Represents an alkylsulfonyloxy group having 1 to 30 carbon atoms or an arylsulfonyloxy group having 6 to 30 carbon atoms, and examples of the substituent include a halogen atom, an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, and an aryloxy group. , Heterocyclic oxy, alkylthio, arylthio, heterocyclic thio, alkylsulfonyl, arylsulfonyl, acyl, carbonamido, sulfonamido, carbamoyl, sulfamoyl, alkoxycarbonylamino, sulfamoyl Amino group, ureido group, cyano group, nitro group, acyloxy group, alkoxycarbonyl group, Lumpur aryloxycarbonyl group, an alkylsulfonyloxy group, an arylsulfonyloxy group.

In the general formula (YII), k preferably represents an integer of 1 or 2, and the substitution position of R ₃ is preferably meta or para to the acylacetamide group.

In the general formula (YII), X preferably represents a heterocyclic group or an aryloxy group bonded to the coupling active position with a nitrogen atom.

When X represents a heterocyclic group, X is preferably an optionally substituted 5- to 7-membered monocyclic or condensed-ring heterocyclic group, for example, succinimide,
Maleimide, phthalimide, diglycolimide,
Pyrrole, pyrazole, imidazole, 1,2,4-triazole, tetrazole, indole, indazole, benzimidazole, benzotriazole, imidazolidine-2,4-dione, oxazolidine-2,4-
Dione, thiazolidine-2,4-dione, imidazolidin-2-one, oxazolidin-2-one, thiazolidin-2-one, benzimidazolin-2-one, benzoxazolin-2-one, benzothiazolin-2-one, 2-pyrrolin-5-one, 2-imidazolin-5
On, indoline-2,3-dione, 2,6-dioxypurine, parabanic acid, 1,2,4-triazolidine-
3,5-dione, 2-pyridone, 4-pyridone, 2-pyrimidone, 6-pyridazone, 2-pyrazone, 2-amino-1,3,4-thiazolidine, 2-imino-1,3,4
-Thiazolidin-4-one, these heterocycles being optionally substituted.

Examples of the substituents on these heterocycles include halogen atom, hydroxyl group, nitro group, cyano group, carboxyl group, sulfo group, alkyl group, aryl group, alkoxy group, aryloxy group, alkylthio group and arylthio group. Group, alkylsulfonyl group, arylsulfonyl group, alkoxycarbonyl group, aryloxycarbonyl group, acyl group, acyloxy group, amino group, carbonamido group, sulfonamide group, carbamoyl group, sulfamoyl group, ureido group, alkoxycarbonylamino group, There is a sulfamoylamino group.

When X represents an aryloxy group, X preferably represents an aryloxy group having a C number of 6 to 30,
It may be substituted with a group selected from the substituent group mentioned when X is a heterocycle. The substituent of the aryloxy group, a halogen atom, a cyano group, a nitro group, a carboxyl group, a trifluoromethyl group, an alkoxycarbonyl group, a carbonamido group, a sulfonamide group, a carbamoyl group, a sulfamoyl group, an alkylsulfonyl group,
An arylsulfonyl group or a cyano group is preferable.

Next, the substituents particularly preferably used in formula (YII) will be described.

R ₁ is particularly preferably an alkyl group having a C number of 1 to 30 (eg methyl, ethyl, n-propyl, n-).
Butyl, isobutyl, n-octyl, n-dodecyl, phenoxymethyl, phenylthiomethyl, p-toluenesulfonylmethyl, benzyl, cyclohexylmethyl, methoxyethyl), most preferably an alkyl group having 1 to 4 carbon atoms. .

Q is particularly preferably a group of non-metal atoms whose ring formed with C forms a hydrocarbon ring of 3 to 5 members,
For example, it is an ethylene group, a trimethylene group, or a tetramethylene group, all of which may be substituted. Here, as the substituent, for example, an alkyl group, an alkoxy group,
There are aryl groups and halogen atoms.

Q is most preferably a substituted or unsubstituted ethylene group.

R ₂ is particularly preferably a chlorine atom, a fluorine atom, an alkyl group having a C number of 1 to 6 (eg methyl, trifluoromethyl, ethyl, isopropyl, t-butyl), an alkoxy group having a C number of 1 to 30. (For example, methoxy, ethoxy, methoxyethoxy, butoxy, hexadecyloxy), or an aryloxy group having a C number of 6 to 24 (for example, phenoxy group, p-tolyloxy, p-methoxyphenoxy), most preferably a chlorine atom. , A methoxy group or a trifluoromethyl group.

R ₃ is particularly preferably a halogen atom,
Cyano group, trifluoromethyl group, alkoxy group, alkoxycarbonyl group, aryloxycarbonyl group, carbonamido group, sulfonamide group, carbamoyl group or sulfamoyl group, most preferably chlorine atom, alkoxy group, alkoxycarbonyl group, sulfamoyl A group, a carbonamido group, or a sulfonamide group.

X is particularly preferably the following formula (Y-
It is a group represented by 1), (Y-2) or (Y-3).

[0062]

Embedded image

[0063]

Embedded image

[0064]

Embedded image

In the formula (Y-1), Z is -O-CR.
_{4 (R 5) -, -} S-CR 4 (R 5) -, - NR 6 -CR 4 (R 5)
_{-, - NR 6 -NR 7 -} , - NR 6 -C (= O) -, -
_{CR 4 (R 5) -CR 8} (R 9) - or -CR ₁₀ = CR ₁₁ - represent.

Here, R ₄ , R ₅ , R ₈ and R ₉ are a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, an alkylsulfonyl group, an arylsulfonyl group or an amino group. the stands, R ₆ and R ₇ are a hydrogen atom, an alkyl group,
It represents an aryl group, an alkylsulfonyl group, an arylsulfonyl group or an alkoxycarbonyl group, and R ₁₀ and R ₁₁ represent a hydrogen atom, an alkyl group or an aryl group. R ₁₀ and R ₁₁ may combine with each other to form a benzene ring. R ₄ and R ₅ , R ₅ and R ₆ , R ₆ and R ₇ or R
₄ and R ₈ may combine with each other to form a ring (for example, cyclobutane, cyclohexane, cycloheptane, cyclohexene, pyrrolidine, piperidine).

Among the heterocyclic groups represented by the formula (Y-1), particularly preferable one is Z in the formula (Y-1).
O-CR ₄ (R ₅ )-, -NR ₆ -CR ₄ (R ₅ )-or -N
A heterocyclic group which is R ₆ —NR ₇ —. The heterocyclic group represented by formula (Y-1) has a C number of 2 to 30, preferably 4 to.
20 and more preferably 5 to 16.

In the formula (Y-2), at least one of R ₁₂ and R ₁₃ is a halogen atom, a cyano group, a nitro group,
A group selected from a trifluoromethyl group, a carboxyl group, an alkoxycarbonyl group, a carbonamido group, a sulfonamide group, a carbamoyl group, a sulfamoyl group, an alkylsulfonyl group, an arylsulfonyl group or an acyl group, and the other is a hydrogen atom or an alkyl group. It may be a group or an alkoxy group. R ₁₄ represents a group having the same meaning as R ₁₂ or R _13, and m represents an integer of 0-2. The C number of the aryloxy group represented by the formula (Y-2) is 6 to.
30, preferably 6 to 24, more preferably 6 to 15
It is.

In the formula (Y-3), W represents a nonmetallic atom group necessary for forming a pyrrole ring, a pyrazole ring, an imidazole ring or a triazole ring together with N.
Here, the ring represented by formula (Y-3) may have a substituent, and preferred examples of the substituent include a halogen atom, a nitro group, a cyano group, an alkoxycarbonyl group, an alkyl group and an aryl group. , An amino group, an alkoxy group, an aryloxy group or a carbamoyl group. The C number of the heterocyclic group represented by the formula (Y-3) is 2 to 30, preferably 2 to 24, more preferably 2 to 16.

X is most preferably a group represented by the formula (Y-1).

The coupler represented by the general formula (YII) is
The substituents R ₁ , R ₂ , R ₃ , Q or X may form a dimer or a multimer which is bonded to each other through a bond or a divalent or higher valent group. in this case,
It may be out of the range of the number of carbon atoms shown in each of the above substituents.

Specific examples of the yellow coupler represented by formula (YII) are shown below.

[0073]

Embedded image

[0074]

Embedded image

[0075]

[Chemical 21]

[0076]

Embedded image

[0077]

Embedded image

[0078]

Embedded image

[0079]

Embedded image

[0080]

[Chemical formula 26]

[0081]

Embedded image

[0082]

Embedded image

[0083]

[Chemical 29]

[0084]

Embedded image

[0085]

[Chemical 31]

[0086]

Embedded image

The yellow coupler represented by the general formula (YII) can be synthesized by a conventionally known synthesis method, for example, a European patent application (E
P) 447969A, US Pat. No. 5,118,59
It can be synthesized by the method described in No. 9.

The coupler represented by formula (YII) can be used in any layer in the light-sensitive material. That is, any of a photosensitive layer (a blue-sensitive emulsion layer, a green-sensitive emulsion layer, and a red-sensitive emulsion layer) and a non-photosensitive layer (for example, a protective layer, a yellow filter layer, an intermediate layer, and an antihalation layer) can be used. In particular, it is preferably used for a blue-sensitive emulsion layer or a non-light-sensitive layer adjacent thereto.

The preferred amount of the coupler represented by formula (YII) is 0.001 to 5.0 mmol / m ² ,
More preferably, it is in the range of 0.01 to 2.0 mmol / m ² .

When the coupler represented by the general formula (YII) is used in the photosensitive layer, the preferable molar ratio of the coupler to the silver halide is in the range of 1: 0.1 to 1: 200, more preferably. It is 1: 2-1: 150. Also,
When used in non-photosensitive layer, 0.001-1.0mm
ol / m ² , preferably 0.005-0.5 mmol / m ²
Range.

The coupler represented by the general formula (YII) is
Of course, they may be used alone or in the general formula (1) described later.
Alternatively, it is preferably used in combination with the coupler represented by the general formula (2). Further, it may be used in combination with other known yellow couplers (for example, benzoylacetanilide type yellow couplers and pivaloylacetanilide type yellow couplers).

In the present invention, the coupler represented by the general formula (YII) exhibits high color developability and excellent color image fastness, but has excellent spectral absorption characteristics, in particular, small spectral absorption on the long wavelength side (green light region). Shows that excellent color reproducibility is provided and further sharpness is improved. In particular, the light-sensitive material produced by using the polyester support of the present invention further improves the color image fastness and improves the storage stability of the light-sensitive material over time.

In the present invention, the coupler represented by the general formula (YII) is prepared by applying an oil-in-water dispersion method to prepare a fine emulsified dispersion using a high-boiling point organic solvent, which will be described later, and introducing it into a light-sensitive material. At this time, even if the amount of the high boiling point organic solvent with respect to the coupler is reduced, it has excellent performance of exhibiting high color development. Therefore, this coupler is preferably on the side farther from the support of the color photosensitive material for photographing (the side closer to the incident light).
Is used for the blue-sensitive layer, which contributes to the reduction of the film thickness and advantageously acts on the sharpness of the photosensitive layer on the side closer to the support.

In the present invention, the coupler represented by the general formula (YII) is excellent in that it exhibits high color image fastness and exhibits excellent spectral absorption characteristics with small spectral absorption on the long wavelength side (green light region). Gives good color reproducibility. This general formula (YI
The coupler represented by the formula (I) is prepared by using the above general formula (A-I) to
When used in the same layer as the compound represented by (A-III), color development is promoted and good photographic performance such as high sensitivity, gradation and color density is provided. This color-promoting effect is greater than that for other benzoylcetoanilide type couplers. In addition, it also has the effect of preventing pressure fog on the winding core side that occurs when the photosensitive material is wound long and stored at high temperature.

Next, the couplers represented by the above general formulas (1) and (2) of the present invention will be described in detail.

When X ₁ and X ₂ represent an alkyl group,
C1-C30, preferably C1-C20, linear, branched,
It is a cyclic, saturated, unsaturated, substituted or unsubstituted alkyl group. Examples of alkyl groups include methyl, ethyl, propyl, butyl, cyclopropyl, allyl, t-octyl,
i-butyl, dodecyl, 2-hexyldecyl.

When X ₁ and X ₂ represent a heterocyclic group, the heterocyclic group has 1 to 20 carbon atoms, preferably 1 to 10 carbon atoms.
And 3 to 12, preferably 5 or 6-membered, saturated or unsaturated, substituted or unsubstituted, and monocyclic or condensed ring containing at least one nitrogen atom, oxygen atom or sulfur atom as a hetero atom. Is a heterocyclic group. Examples of the heterocyclic group include 3-pyrrolidinyl,
1,2,4-triazol-3-yl, 2-pyridyl,
4-pyrimidinyl, 3-pyrazolyl, 2-pyrrolyl,
2,4-dioxo-1,3-imidazolidin-5-yl or pyranyl can be mentioned.

When X ₁ and X ₂ represent an aryl group,
It represents a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, preferably 6 to 10 carbon atoms. Representative examples of the aryl group include phenyl and naphthyl.

When X ₃ represents a nitrogen-containing heterocyclic group formed with> N-, this heterocyclic group has 1 to 20 carbon atoms,
It is preferably 1 to 15, and may be, for example, an oxygen atom or a sulfur atom in addition to a nitrogen atom as a hetero atom, and is a substituted or unsubstituted, saturated or unsaturated 3- to 12-membered ring, preferably 5- or 6-membered ring. It is a saturated or monocyclic or condensed-ring heterocyclic group. Examples of this heterocyclic group are pyrrolidino, piperidino, morpholino, 1-piperazinyl, 1-indolinyl, 1,2,3,4-tetrahydroquinolin-1-yl, 1-imidazolidinyl, 1
-Pyrazolyl, 1-pyrrolinyl, 1-pyrazolidinyl,
2,3-dihydro-1-indazoline, 2-isoindolinyl, 1-indolyl, 1-pyrrolyl, 4-thiazin-S, S-dioxo-4-yl or benzoxazin-4-yl are mentioned.

When X ₁ and X ₂ represent an alkyl, aryl or heterocyclic group having a substituent, and when the nitrogen-containing heterocyclic group formed with X ₃ with> N- has a substituent, The following are mentioned as an example of those substituents. Halogen atom (for example, fluorine, chlorine), alkoxycarbonyl group (having 2 to 30 carbon atoms, preferably 2 to 20. For example, methoxycarbonyl, hexadecyloxycarbonyl), acylamino group (having 2 to 2 carbon atoms).
30, preferably 2-20. For example, acetamide, tetradecanamide, 2- (2,4-di-t-amylphenoxy) butanamide, benzamide), sulfonamide group (having 1 to 30 carbon atoms, preferably 1 to 20. For example, methanesulfonamide, hexadecylsulfonamide) , Benzenesulfonamide), carbamoyl group (having 1 to 3 carbon atoms)
0, preferably 1-20. For example, N-butylcarbamoyl, N, N-diethylcarbamoyl), N-sulfonylcarbamoyl group (having 1 to 30 carbon atoms, preferably 1 to 2 carbon atoms).
0. For example, N-mesylcarbamoyl, N-dodecylsulfonylcarbamoyl), sulfamoyl group (having 0 to 10 carbon atoms)
30, preferably 1-20. For example, N-butylsulfamoyl, N-hexadecylsulfamoyl, N-3-
(2,4-di-t-amylphenoxy) butylsulfamoyl, N, N-diethylsulfamoyl), alkoxy group (1 to 30, preferably 1 to 20 carbon atoms, for example, methoxy, hexadecyloxy, iso Propoxy), an aryloxy group (6-20 carbon atoms, preferably 6-10 carbon atoms).
For example, phenoxy, 4-methoxyphenoxy, 3-t-
Butyl-4-hydroxyphenoxy, naphthoxy), an aryloxycarbonyl group (7-21 carbon atoms, preferably 7-11, for example phenoxycarbonyl), an N-acylsulfamoyl group (2-30 carbon atoms, preferably 2-
20. For example, N-propanoylsulfamoyl, N-tetradecanoylsulfamoyl), sulfonyl group (having 1 to 30 carbon atoms, preferably 1 to 20. For example, methanesulfonyl, 4-hydroxyphenylsulfonyl, dodecanesulfonyl), alkoxycarbonyl. Amino group (2 carbon atoms
-30, preferably 2-20. For example, ethoxycarbonylamino), cyano group, nitro group, carboxyl group, hydroxyl group, sulfo group, alkylthio group (having 1 to 1 carbon atoms).
30, preferably 1-20. For example, methylthio, dodecylthio, dodecylcarbamoylmethylthio), and ureido group (having 1 to 30 carbon atoms, preferably 1 to 20 carbon atoms. For example, N-
Phenyl ureido, N-hexadecyl ureido), aryl group (C6-20, preferably 6-10. For example, phenyl, naphthyl, 4-methoxyphenyl), heterocyclic group (C1-20, preferably 1-). 10. As a hetero atom, for example, at least one or more of nitrogen, oxygen, or sulfur is contained and has 3 to 12, preferably 5 or 6 membered ring,
Single ring or fused ring. For example, 2-pyridyl, 3-pyrazolyl, 1-pyrrolyl, 2,4-dioxo-1,3-imidazolidin-1-yl, 2-benzoxazolyl, morpholino, indolyl), alkyl group (having 1 to 30 carbon atoms) ,
Preferably 1 to 20 straight chain, branched or cyclic, and saturated or unsaturated alkyl, such as methyl, isopropyl, cyclopropyl, t-octyl, cyclopentyl, s-butyl, 2-hexyldecyl), acyl group (number of carbon atoms) 2 to 30, preferably 2 to 20. For example, acetyl, benzoyl), an acyloxy group (having 2 to 30 carbon atoms, preferably 2 to 20. For example, propanoyloxy, tetradecanoyloxy), an arylthio group (having 6 to 20 carbon atoms, Preferably 6 to 10. For example, phenylthio, naphthylthio, a sulfamoylamino group (having 0 to 30 carbon atoms, preferably 0 to 20. For example, N-butylsulfamoylamino, N-dodecylsulfamoylamino, N-phenyl. Sulfamoylamino) or N-sulfonylsulfamoyl group (having 1 carbon atom 30, preferably from 1 to 20. For example N- mesyl sulfamoyl, N- ethane acylsulfamoyl, N- dodecane acylsulfamoyl, N- hexadecane sulfonylsulfamoyl) is Ageraru. The above substituents may further have a substituent.
Examples of the substituent include the substituents mentioned here.

Preferred substituents in the above are alkoxy group, halogen atom, alkoxycarbonyl group, acyloxy group, acylamino group, sulfonyl group, carbamoyl group, sulfamoyl group, sulfonamide group, nitro group, alkyl group or aryl group. Is mentioned.

In formulas (1) and (2), when Y represents an aryl group, Y has 6 to 20 carbon atoms, preferably 6 carbon atoms.
10 to 10 substituted or unsubstituted aryl groups. For example, a phenyl group and a naphthyl group are typical examples.

When Y represents a heterocyclic group in the general formulas (1) and (2), Y has the same meaning as described above when X ₁ or X ₂ represents a heterocyclic group.

When Y represents a substituted aryl group or a substituted heterocyclic group, examples of the substituent include, for example, the above X ₁
Examples of the substituent when has a substituent include the substituents listed above. Preferred examples of the substituent for Y include:
One of the substituents is a halogen atom, an alkoxycarbonyl group, a sulfamoyl group, a carbamoyl group, a sulfonyl group, an N-sulfonylsulfamoyl group, an N-acylsulfamoyl group, an alkoxy group, an acylamino group, N-
This is when it is a sulfonylcarbamoyl group, a sulfonamide group or an alkyl group.

A particularly preferred example of Y is a phenyl group having at least one substituent in the ortho position.

The group represented by Z in the general formulas (1) and (2) may be any conventionally known coupling-off group. Preferred Z is a nitrogen-containing heterocyclic group, an aryloxy group, an arylthio group, a heterocyclic oxy group, a heterocyclic thio group, an acyloxy group, a carbamoyloxy group, an alkylthio group, or a halogen atom bonded to the coupling position with a nitrogen atom. No. These leaving groups are non-photographic useful groups or photographically useful groups or precursors thereof (eg, development inhibitors, development accelerators, desilvering accelerators, fogging agents, dyes, hardeners, couplers, developing agent oxidation agents). Body scavenger, fluorescent dye, developing agent or electron transfer agent).

When Z is a photographically useful group, those conventionally known are useful. For example, U.S. Pat.
8,962, 4,409,323, 4,43
8,193, 4,421,845, 4,61
8,571, 4,652,516, 4,86
1,701, 4,782,012, 4,85
7,440, 4,847,185, 4,47
7,563, 4,438,193, 4,62
Nos. 8,024, 4,618,571, 4,74
1,994, EP-A-193389A
No. 348139A or No. 272573A, or a leaving group (for example, a timing group) for releasing the photographically useful group.

When Z represents a nitrogen-containing heterocyclic group bonded to the coupling position at a nitrogen atom, the nitrogen-containing heterocyclic group has 5 or 6 members and has 1 to 15, preferably 1 to 10 carbon atoms. It is preferably a cyclic, substituted or unsubstituted, saturated or unsaturated, and monocyclic or condensed heterocyclic group. The hetero atom may contain an oxygen atom or a sulfur atom in addition to the nitrogen atom. Preferred specific examples of the heterocyclic group include 1-pyrazolyl, 1-imidazolyl, pyrrino, 1,2,4-triazol-2-yl,
1,2,3-triazol-1-yl, benzotriazolyl, benzimidazolyl, imidazolidine-2,4-
Dione-3-yl, oxazolidin-2,4-dione-
3-yl, 1,2,4-triazolidine-3,5-dione-4-yl, imidazolidin-2,4,5-trion-3-yl, 2-imidazolinone-1-yl, 3,5-
Examples include dioxomorpholino or 1-yldazoline. When these heterocyclic groups have a substituent, examples of the substituent include the substituents listed as the substituents which the group represented by X ₁ may have. Preferred substituents include one alkyl group, an alkoxy group, a halogen atom, an alkoxycarbonyl group,
Aryloxycarbonyl group, alkylthio group, acylamino group, sulfonamide group, aryl group, nitro group,
This is when it is a carbamoyl group, a cyano group or a sulfonyl group.

When Z represents an aryloxy group, it is preferably a substituted or unsubstituted aryloxy group having 6 to 10 carbon atoms. Particularly preferred is a substituted or unsubstituted phenoxy group. When it has a substituent, examples of the substituent include the substituents listed as the substituent which the group represented by X ₁ may have. Among them, a preferable substituent is a case where at least one substituent is an electron-withdrawing group, and examples thereof include a sulfonyl group, an alkoxycarbonyl group, a sulfamoyl group,
Examples thereof include a halogen atom, a carbamoyl group, a nitro group, a cyano group and an acyl group.

When Z represents an arylthio group, it is preferably a substituted or unsubstituted arylthio group having 6 to 10 carbon atoms. Particularly preferred is a substituted or unsubstituted phenylthio group. When it has a substituent, examples of the substituent include the substituents listed as the substituent which the group represented by X ₁ may have. Among them, preferred substituents are when at least one substituent is an alkyl group, an alkoxy group, a sulfonyl group, an alkoxycarbonyl group, a sulfamoyl group, a halogen atom, a carbamoyl group, or a nitro group.

When Z represents a heterocyclic oxy group, the heterocyclic group moiety has 1 to 20 carbon atoms, preferably 1 to 10 carbon atoms, and has at least one nitrogen atom, oxygen atom or sulfur atom as a hetero atom. It is a substituted or unsubstituted, saturated or unsaturated, and monocyclic or condensed-ring heterocyclic group containing 3 to 12 or more, preferably 5 or 6-membered rings. Examples of the heterocyclic oxy group include a pyridyloxy group, a pyrazolyloxy group, and a furyloxy group. When it has a substituent, examples of the substituent include the substituents listed as the substituent which the group represented by X ₁ may have. Among them, preferable substituents include one alkyl group, aryl group, carboxyl group, alkoxy group, halogen atom, alkoxycarbonyl group, aryloxycarbonyl group,
Alkylthio group, acylamino group, sulfonamide group,
When it is a nitro group, a carbamoyl group, or a sulfonyl group.

When Z represents a heterocyclic thio group,
The portion has 1 to 20 carbon atoms, preferably 1 to 10 carbon atoms.
A hetero atom such as a nitrogen atom, an oxygen atom or
3 to 12, containing at least one sulfur atom, preferably
5 or 6-membered ring, substituted or unsubstituted, saturated
Or unsaturated, and monocyclic or condensed ring heterocyclic groups
is there. Examples of heterocyclic thio groups include tetrazolylthio
Group, 1,3,4-thiadiazolylthio group, 1,3,4-
Oxadiazolylthio group, 1,3,4-triazolylthio group
O group, benzimidazolylthio group, benzothiazolyl group
And a 2-pyridylthio group. Substituent
When the compound has ₁Indicated by
The substituents listed as the substituents which the group may have are
As an example. Among them, preferred substituents
At least one of the substituents is an alkyl group or aryl
Group, carboxyl group, alkoxy group, halogen atom,
Lucoxycarbonyl group, aryloxycarbonyl group,
Alkylthio group, acylamino group, sulfonamide group,
Nitro group, carbamoyl group, heterocyclic group or sulfoni group
When it is a radical.

When Z represents an acyloxy group, the acyloxy group preferably has 6 to 10 carbon atoms and is a monocyclic ring or a condensed ring. It is a substituted or unsubstituted arylacyloxy group or a substituted or unsubstituted alkylacyloxy group having 2 to 30, preferably 2 to 20 carbon atoms. When these have a substituent, examples of the substituent include the substituents listed as the substituent which the group represented by X ₁ may have.

When Z represents a carbamoyloxy group, the carbamoyloxy group is an alkyl, aryl, heterocycle, substituted or unsubstituted carbamoyloxy group having 1 to 30 carbon atoms, preferably 1 to 20 carbon atoms. For example N,
Mention may be made of N-diethylcarbamoyloxy, N-phenylcarbamoyloxy, 1-imidazolylcarbonyloxy or 1-pyrrolocarbonyloxy. When these have a substituent, examples of the substituent include the substituents listed as the substituent which the group represented by X ₁ may have.

When Z represents an alkylthio group, the alkylthio group has 1 to 30 carbon atoms, preferably 1 to 20 carbon atoms.
Which are linear, branched or cyclic, saturated or unsaturated, and substituted or unsubstituted alkylthio groups. When it has a substituent, examples of the substituent include the aforementioned X
_The substituents listed as the substituents that the group represented by ₁ may have are mentioned as examples.

Next, a particularly preferred range of the couplers represented by the general formulas (1) and (2) will be described below.

The group represented by X ₁ in the general formula (1) is preferably an alkyl group. Particularly preferred is an alkyl group having 1 to 10 carbon atoms.

The group represented by Y in the general formulas (1) and (2) is preferably an aryl group. Particularly preferred is a phenyl group having at least one substituent at the ortho position. As the explanation of the substituent, those enumerated as the substituents which may be possessed when Y is an aryl group can be mentioned.
The example of a preferable substituent is also the same.

The group represented by Z in the general formulas (1) and (2) is preferably a 5- or 6-membered nitrogen-containing heterocyclic group bonded to the coupling position at a nitrogen atom, an aryloxy group,
Examples thereof include a 5- to 6-membered heterocyclic oxy group and a 5- to 6-membered heterocyclic thio group.

Among the couplers represented by the general formula (1) or (2), preferred couplers are the couplers represented by the general formula (3), (4) or (5) shown in the following chemical formulas 33 to 35.

[0121]

[Chemical 33]

[0122]

Embedded image

[0123]

Embedded image

In the formula, Z has the same meaning as described in formula (1), X ₄ represents an alkyl group, X ₅ represents an alkyl group or an aryl group, and Ar represents at least one substituent at the ortho position. Represents a phenyl group having, X ₆ is-
Represents an organic residue forming a nitrogen-containing heterocyclic group (monocyclic or condensed ring) together with C (R ₁ R ₂ ) -N <, and X ₇ represents —C (R
₃ ) = C (R ₄ ) —N <, and represents an organic residue forming a nitrogen-containing heterocyclic group (monocycle or condensed ring), R ₁ , R ₂ and R
₃ and R ₄ represent a hydrogen atom or a substituent.

X _{4 to} X ₇ in the general formulas (3) to (5)
Regarding the detailed description and the preferable range of the group represented by Z and Z, they have the same meanings as the description of the corresponding group in the descriptions of the general formulas (1) and (2). R ₁ ~ R
_{When 4} represents a substituent, those enumerated as the substituent that X ₁ may have are mentioned as examples.

Particularly preferred couplers in the above general formula are the couplers represented by the general formula (4) or (5).

The couplers represented by the general formulas (1) to (5) are represented by X _{1 to} X ₇ , Y, Ar, R _{1 to} R ₄ and Z, and are bis or divalent or higher groups. Dimers or higher multimers (eg telomers or polymers) may be formed which are linked together via
In this case, the number of carbon atoms may be out of the specified range for each substituent.

The couplers represented by the general formulas (1) to (5) are preferably non-diffusion type couplers. The diffusion-resistant coupler is a coupler having a group (diffusion-resistant group) in the molecule that increases the molecular weight sufficiently in order to immobilize the molecule in the added layer. As the diffusion resistant group, an alkyl group having a total carbon number of 8 to 30, preferably 10 to 20 or an aryl group having a substituent having a total carbon number of 4 to 20 is usually used. These diffusion resistant groups may be substituted in any of the molecules, or may have a hetero group.

General formulas (1) to (5) shown below in Chemical formulas 36 to 46
Specific examples of the coupler and the yellow coupler represented by are shown below, but the present invention is not limited thereto.

[0130]

Embedded image

[0131]

Embedded image

[0132]

Embedded image

[0133]

Embedded image

[0134]

Embedded image

[0135]

Embedded image

[0136]

Embedded image

[0137]

Embedded image

[0138]

Embedded image

[0139]

Embedded image

[0140]

Embedded image

In addition, YB-24 in Chemical formula 43 and Chemical formula 44
YB-25 in Chemical formula 45, YB-29 and YB-30 in Chemical formula 45 and YB-31, YB-3 in Chemical formula 46
In 2 and YB-33, “}” indicates that the substituent is substituted at the 5- or 6-position of the benzotriazolyl group.

The yellow couplers represented by the general formulas (1) to (5) used in the present invention are described in European Patent 447,
It can be synthesized according to the method described in No. 920A and No. 482,552A.

In the present invention, the amount of the yellow couplers represented by the general formulas (1) to (5) is 1 m ² of the light-sensitive material.
It is 0.001 to 5.0 mmol, preferably 0.1.
It is in the range of 01 to 2.0 mmol. Even when it is used in combination with the coupler represented by the general formula (YI), it does not exceed the range of the amount used. The same applies when used in combination with other known yellow couplers.

In the present invention, when the yellow couplers represented by the general formulas (1) to (5) are used as the main coupler, it is preferably added to the blue-sensitive silver halide emulsion layer or the adjacent non-photosensitive layer. When the coupler releases a photographically useful group, it is added to the silver halide photosensitive layer or the non-photosensitive layer according to the purpose.

In the present invention, the yellow couplers represented by formulas (1) to (5) may be used alone or in combination of two or more kinds. It is preferably used in combination with the coupler represented by the general formula (YI). Further, other known couplers such as benzoylacetanilide type couplers and pivaloylacetanilide type couplers can be used in combination. The present invention is characterized by a photographic material having at least one layer containing a coupler represented by the general formula (YI) and / or the general formula (1) or the general formula (2).

In the present invention, the couplers represented by the general formulas (1) to (5) can be prepared by various known dispersion methods.
It can be incorporated into a color light-sensitive material.

In the oil-in-water dispersion method, which is one of the known dispersion methods, a low-boiling organic solvent (eg, ethyl acetate, butyl acetate, methyl ethyl ketone, isopropanol) is used to apply a fine dispersion and dry it. A method in which the low boiling point organic solvent does not substantially remain in the film can be used. When a high-boiling organic solvent is used, any of those having a boiling point of 175 ° C. or higher under normal pressure may be used, and one kind or two or more kinds may be arbitrarily mixed and used. The ratio of the couplers represented by the general formulas (1) to (5) to these high boiling point organic solvents can be in a wide range, but 1 g of the coupler can be used.
The range is 5.0 or less per weight ratio. Preferably 0
To 2.0, and more preferably 0.01 to 1.0.

The latex dispersion method described below can also be applied.

Further, various couplers and compounds described later can be mixed or used together.

The couplers represented by the general formulas (1) to (5) of the present invention exhibit excellent color image fastness and have excellent spectral absorption characteristics with small spectral absorption on the long wavelength side (green light region). Excellent color reproducibility. Further, when it is a coupler which releases a photographically useful group, especially a development inhibitor or its precursor, it exhibits excellent effects in improving image quality such as sharpness and color reproducibility.

In the present invention, while maintaining the above-mentioned excellent characteristics, the above-mentioned color-promoting effect is exhibited, high sensitivity and gradation are imparted to improve the color-developing property, and the light-sensitive material is rolled up for a long time. Prevents pressure fog that occurs when stored at high temperatures. In particular, the couplers represented by the general formulas (1) and (2) of the present invention exhibit a large color-promoting effect. This is because the coupling reaction was delayed and the activity was low due to the originally high acid dissociation constant (pKa) of the coupler, which is represented by the general formulas (AI) to (A-III) of the present invention. It is considered that the use of the compound promoted dissociation and improved the color developability. The couplers represented by the general formulas (1) to (5) of the present invention have the same general formulas (AI) to (A) as described above.
It is particularly preferable to use the compound represented by the formula (III) together in the same layer. As a result, the effects of promoting color development and preventing pressure fog are more prominent.

Next, the magnetic layer used in the present invention (hereinafter,
The magnetic recording layer will also be described). The magnetic recording layer used in the present invention is obtained by coating a support with an aqueous or organic solvent-based coating solution in which magnetic particles are dispersed in a binder. The magnetic particles used in the present invention are γ
Ferromagnetic iron oxides such as Fe ₂ O ₃ , Co-deposited γFe ₂ O ₃ , Co-deposited magnetite, Co-containing magnetite, ferromagnetic chromium dioxide, ferromagnetic metals, ferromagnetic alloys, hexagonal Ba ferrite, Sr Ferrite, Pb ferrite, Ca ferrite, etc. can be used. Co-deposited ferromagnetic iron oxides such as Co-deposited γFe ₂ O ₃ are preferred. The shape may be needle-like, rice grain-like, spherical, cubic, plate-like or the like. 20 m ^{2 in} S _BET for specific surface area
/ g or more is preferable, and 30 m ² / g or more is particularly preferable. The saturation magnetization (σs) of the ferromagnetic material is preferably 3.0 × 10 ⁴ to 3.0 ×
10 ⁵ A / m, particularly preferably 4.0 × 10 ^{4 to} 2.5 × 10 ⁵ A
/ m. The ferromagnetic particles may be subjected to a surface treatment with silica and / or alumina or an organic material. Further, the surface of the magnetic particles may be treated with a silane coupling agent or a titanium coupling agent as described in JP-A-6-161032. Further, magnetic particles having a surface coated with an inorganic or organic material described in JP-A-4-259911 and 5-81652 can also be used.

The binder used for the magnetic particles is a thermoplastic resin, a thermosetting resin, a radiation curable resin, a reactive resin, an acid, an alkali or a biodegradable polymer described in JP-A-4-219569, a natural product Coalescence (cellulose derivatives, sugar derivatives, etc.) and mixtures thereof can be used. The above resin has a Tg of -40 ° C to 300 ° C and a weight average molecular weight of 2,000 to 1,000,000. Examples thereof include vinyl copolymers, cellulose diacetate, cellulose triacetate, cellulose derivatives such as cellulose acetate propionate, cellulose acetate butyrate, and cellulose tripropionate, acrylic resins and polyvinyl acetal resins, and gelatin is also preferable. Particularly, cellulose di (tri) acetate is preferable. The binder can be cured by adding an epoxy-based, aziridine-based, or isocyanate-based crosslinking agent. Examples of the isocyanate-based crosslinking agent include isocyanates such as tolylene diisocyanate, 4,4'-diphenylmethane diisocyanate, hexamethylene diisocyanate, and xylylene diisocyanate, and reaction products of these isocyanates with polyalcohol (for example, 3mol of isocyanate and 1m of trimethylolpropane
ol reaction product), and polyisocyanates formed by condensation of these isocyanates.
For example, it is described in JP-A-6-59357.

As a method for dispersing the above-mentioned magnetic material in the binder, a kneader, a pin type mill, an annular type mill, etc. are preferable and a combination thereof is also preferable, as in the method described in JP-A-6-35092. Dispersants described in JP-A-5-088283 and other known dispersants can be used. The thickness of the magnetic recording layer is 0.1 μm to 10 μm, preferably 0.2 μm to 5 μm.
m, more preferably 0.3 μm to 3 μm. The weight ratio between the magnetic particles and the binder is preferably 0.5: 100 to 60: 100.
And more preferably from 1: 100 to 30: 100. The coating amount of the magnetic particles 0.005~ 3g / m ^2, preferably from 0.01 to 2
g / m ² , more preferably 0.02 to 0.5 g / m ² . The transmission yellow density of the magnetic recording layer is preferably 0.01 to 0.50,
03 to 0.20 is more preferable, and 0.04 to 0.15 is particularly preferable.
The magnetic recording layer can be provided on the entire back surface of the photographic support by coating or printing, or in a stripe shape. As a method of applying the magnetic recording layer, an air doctor, a blade, an air knife, a squeeze, an impregnation, a reverse roll,
Transfer rolls, gravure, kisses, casts, sprays, dips, bars, extrusions and the like can be used, and the coating solutions described in JP-A-5-341436 are preferred.

In the magnetic recording layer, improvement of lubricity, curl adjustment,
It may have functions such as antistatic, anti-adhesion and head polishing, or may be provided with another functional layer to impart these functions, and at least one kind of particles has a Mohs hardness of 5 or more. The above-mentioned non-spherical inorganic particle abrasives are preferable. As the composition of the non-spherical inorganic particles, oxides such as aluminum oxide, chromium oxide, silicon dioxide, titanium dioxide and silicon carbide, carbides such as silicon carbide and titanium carbide, and fine powders such as diamond are preferable. These abrasives may have their surfaces treated with a silane coupling agent or a titanium coupling agent. These particles may be added to the magnetic recording layer, or may be overcoated (for example, a protective layer, a lubricant layer, etc.) on the magnetic recording layer. As the binder used at this time, the above-mentioned binders can be used, and the same binder as the binder for the magnetic recording layer is preferable. For photosensitive materials having a magnetic recording layer, see US Pat.
5,229,259, 5,215,874 and EP 466,130.

The light-sensitive material having the magnetic recording layer described above causes pressure fog on the core side when it is rolled up for a long time and stored at a high temperature, and is more deteriorated than a light-sensitive material having no magnetic recording layer. Is large, the general formula (A-
I) to (A-III) and the general formula (YI)
An acylacetamide type coupler having an acyl group represented by and / or general formula (1) or general formula (2)
In a light-sensitive material using a coupler represented by the above formula, this pressure fog is reduced, and a color-promoting effect is also exhibited, so that the object of the present invention can be achieved.

The structure of the photographic light-sensitive material package of the present invention (hereinafter, also referred to as "photographic film cartridge") 100 of the present invention will be described below with reference to the drawings. 1 is an exploded perspective view of the photographic film cartridge, FIG. 2 is a view of the photographic film cartridge viewed from the radial direction, and FIG. 3 is a view of the photographic film cartridge viewed from the radial direction at a position different from FIG. The photographic film cartridge 100 includes a cartridge body 101 in which a spool 103 around which a photographic photosensitive material (photo film) 102 is wound is rotatably housed.
A cartridge label 104 is adhered to the outer periphery of 1.
The cartridge body (patrone body) 101 is composed of upper and lower cases 105 and 106 which are two molded parts.

An upper case 105 having a gate 150,
Photo film 1 on the front side joint with the lower case 106
A film delivery port 107 (passage) for delivering 02 is formed. A lid member 108 for preventing light from entering there is behind the film delivery port 107.
And a separation claw 109 which is arranged at the back of the separation film and separates the tip of the photographic film 102. The lid member 108 has key grooves 110,
111 is formed, and the keyway 11 is formed when loaded in the camera.
The opening / closing drive shaft on the camera side that engages with 0 and 111 is rotated between a closed position that closes the film feed opening 107 and an open position that allows entry and exit of the photographic film. FIG. 5 shows a state in which the lock pawl 144 and the lid member 108 are engaged with each other and the lid member is locked at the closed position.

The spool 103 comprises a pair of lip flanges 113, 1 on the inner sides of both ends of the spool shaft 112.
14 is attached, and a data disk is provided on the outside of one flange 113. The other flange 1
A use display member 123 is attached to the outer side of 14. A data label is attached to the data disk 115. A pair of flange engaging portions 1 with which the spool shaft 112, the data disk 115, and the respective flanges 113 and 114 are engaged.
17, 118, slit 11 for locking the rear end of the photographic film
9 and the use display member supporting portion 120 are formed integrally with each other, and when the spool 10 is mounted on the camera,
The drive shaft on the camera side is engaged with the key grooves 121 and 122 on the key holes provided at both ends of the drive shaft 3, and is rotated by the rotation of the drive shaft.

The use display member 123 includes a bearing portion 12
The four ratchet pawls 125, the gear 126, and the use display plate 127 are integrally formed, and these rotate integrally with the spool shaft 112.

The inside of the photographic film cartridge 100 is
A spool lock 128 is housed so as to mesh with the gear 126. This spool lock 128 is a lid member 1.
When 08 is in the closed position, the gear 126 is engaged to lock the rotation of the spool shaft 112, prevent careless feeding of the photographic film 102, and cover member 108.
When is in the open position, it disengages from the gear 126.

The pair of flanges 113 and 114 are made of a plastic material and have a thin cup-shaped cross section. The cup-shaped bottom has a flange engaging portion 117,
Round holes 129 and 130 are rotatably engaged with 118, respectively. Also, the cup-shaped opening edge 13
1, 132 are arranged to face each other when attached to the spool shaft 112, and wrap around the outermost ends of the photographic film 102 wound between them (see FIG. 6). The opening edge portions 131 and 132 allow the rotation of the spool 103 to be transmitted to the outermost periphery of the photographic film 102 and prevent the film roll 142 from being loosened.

Four holes 133 are formed in the flange 114 at a predetermined pitch so as to surround the round holes 130. These holes 133 are provided with a display member 123 for use when the spool shaft 112 rotates in the photo film feeding direction.
Ratchet claw 125 of is engaged. Ratchet claw 125
Transmits the rotation of the spool shaft 112 to the flange 114 when engaged with the hole 133, and when the spool shaft 112 rotates in the photo film winding direction, the ratchet claw 125 of the use indicating member 123 causes the hole 133 to rotate. Therefore, the rotation of the spool shaft 112 is not transmitted to the flange 114.

When the photographic film 102 is fed, the spool 103 is rotated in the film feeding direction. When the spool 103 is rotated in the film feeding direction, the tip of the photographic film 102 is separated by the separation claw 10.
9 and is separated from the part wound inside the leading edge of the photographic film. When the spool 103 is subsequently rotated, since the pair of thin flanges 113 and 114 has elasticity, the pair of flanges 113 and 114 are pushed outward by the separated film tips. The leading edge of the photographic film (143 in FIG. 3) released from the wrapping is delivered to the outside of the photographic film cartridge 100 through the film delivery port. Further, when the spool shaft 112 rotates in the photo film winding direction (the direction opposite to the photo film feeding direction), the flanges 113 and 114 do not rotate integrally with the spool shaft 112. Therefore, the photographic film 102
Since the flanges 113 and 114 do not rotate when the film is wound, a slip occurs between the opening edge portions 131 and 132 and the photographic film 102, and the photographic film 102.
Slides under the opening edges 131, 132 of the flanges to wrap the photographic film.

The data disk 115 has a large-diameter fan-shaped portion 1
34 and a notch portion 135. The barcode label 116 has a shape similar to that of the data disc 115 and is attached to the data disc.

A bar code is printed on the bar code label 116 and represents various kinds of information such as the type of the photo film 102 to be stored. This information is obtained when the spool 103 is rotated in the film feeding direction.
As shown in FIG. 5, it is read by a reading sensor provided on the camera side through an opening 136 formed on one side surface of the upper case 105 to calculate an exposure value and count the number of exposures of stored photo films. Used.

In this photo film cartridge 100,
Since even the leading edge of the photographic film 102 is stored, it is indistinguishable from the external appearance whether the unexposed photographic film or the exposed photographic film is stored. Therefore, in order to prevent the photographic film cartridge 100 containing the exposed photographic film from being reloaded into the camera and taking pictures, a post-loading prevention opening 137 is formed on one side surface of the lower case 106. There is. This one side surface is a side that is inserted toward the cartridge chamber of the camera, and a lever that enters the opening 137 is provided in the cartridge chamber.

The photographic film cartridge 100 stores the unexposed photographic film such that the large-diameter fan-shaped portion 134 is exposed in the opening 137 when the exposed photographic film is stored. If so, the stop position of the spool 103 is controlled by the drive shaft on the camera side so that the large-diameter fan-shaped portion 134 is not exposed in the opening 137. Therefore, by detecting the amount of movement of the lever, the camera side can discriminate between the exposed and unexposed photographic film.

Further, in order to allow the user to grasp from the appearance, in this photo film patrone 100,
As shown in FIG. 4, on the other side surface (the side surface opposite to the side surface on which the openings 136 and 137 are provided), an opening 138 for displaying the usage state when the unexposed photo film is stored, a part thereof is photographed. When the photographic film is stored, the usage status display opening 139, when the exposed photo film that has been photographed on all is stored, the usage status display opening 140, and when the developed photographic film is stored Of the four use status display openings 138 to 141 are formed by exposing the use display plate 127 located in the back by controlling the stop position of the spool 103. The usage status of the film is displayed.

Further, the present cartridge 100 is provided with a sensitivity detecting notch 145 used for detecting the sensitivity of the stored photographic film 102. This is a notch for detecting sensitivity with an inexpensive camera that does not have a bar code reader that reads the bar code written on the bar code label. When the sensitivity detecting notch 145 is provided as shown in FIG. 5, the stored photographic film 102 is IS.
The O sensitivity is 400 or more, and the ISO sensitivity is 400 or less when there is no notch.

Further, the present cartridge 100 is provided with a developed display tab showing whether the stored photographic film 102 has been developed or not. As shown in FIG.
The tab 147 is provided in an opening 146 provided on one side surface of the cartridge 100, and when the tab 147 is broken off, it means that the stored photographic film 102 has been developed.

Next, a typical example of the manufacturing method of the cartridge 100 of the present invention will be specifically described. Upper case / lower case 1
05, 106, the spool 103, and the lid member 108,
High-impact polystyrene resin (Denkastyrol HI-R-Q manufactured by Denki Kagaku Kogyo) is added with 1.0% by weight of carbon black (Mitsubishi Carbon Black # 950 manufactured by Mitsubishi Chemical) for imparting light-shielding properties, and lubricity. Silicone oil for use (Shin-Etsu Chemical Co., Ltd. Shin-Etsu Silicone KF96H-viscosity 30,000 cs) is molded by injection molding using a resin kneaded with 1.5% by weight. The use indication member 123 is made by injection molding using a resin obtained by kneading the above-mentioned high impact polystyrene resin with 0.01% by weight of the above carbon black and 3.5% by weight of titanium oxide (CR60-2 manufactured by Ishihara Sangyo). Mold.

The flanges 113 and 114 are formed by a vacuum / pressure method using a film having a thickness of 150 μm made from a polymer alloy of polystyrene resin and polyphenylene ether resin (Zylon X9101 manufactured by Asahi Kasei).

The Patrone label 104 has a thickness of 50.
A coating for imparting printability is provided on one side of a polystyrene film containing a white pigment having a thickness of μm, an adhesive is attached to the back side thereof, and a release paper is attached to the release label to prepare an adhesive label stock. As shown in FIG. 7, on the surface of the original fabric,
Patrone ID number printing space written in numbers 15
1. A manufacturer name, a product name, a film type / sensitivity / the number of exposures, a cautionary note, and a print space 152 for a product type for printing a memo field to be filled by the user, and a bar code print space 153. First, a printing space such as a product type is printed, then half-cut processing is performed, and thereafter, a barcode and a Patrone ID number are printed to create. The bar code contains the manufacturer's name, production lot, production date, type of photo film stored, sensitivity, number of exposures,
Also, the Patrone ID number and the like are encoded and printed. The cartridge ID number is a unique number attached to each cartridge.

The bar code label 116 has a thickness of 50 μm.
A transparent vapor deposition polystyrene film with a thickness of about 400 Å is provided on one side of the transparent vapor deposition film, and an adhesive label is attached on top of it to create an adhesive label with release paper, and a bar on the opposite side of the aluminum vapor deposition layer. After printing the code, half cut the outer peripheral part, and then punch out the center to create.

The present invention is one in which the photographic light-sensitive material is housed in a package having the structure and manufacturing method exemplified above. The above-mentioned object of the present invention can be achieved by the photographic light-sensitive material housed in such a package.

The light-sensitive material of the present invention may have at least one light-sensitive layer provided on a support. A typical example is a silver halide photographic light-sensitive material having at least one light-sensitive layer comprising a plurality of silver halide emulsion layers having substantially the same color sensitivity but different sensitivities on a support. It is. The photosensitive layer is a unit photosensitive layer having color sensitivity to any of blue light, green light, and red light, and in a multilayer silver halide color photographic material, the arrangement of the unit photosensitive layers is generally A red-sensitive layer, a green-sensitive layer, and a blue-sensitive layer are provided in this order from the support side. However, the order of installation may be reversed depending on the purpose, or the order of installation may be such that different photosensitive layers are sandwiched between the same color-sensitive layers. A non-light-sensitive layer may be provided between the silver halide light-sensitive layers and as the uppermost layer and the lowermost layer. These may contain a coupler, a DIR compound, a color mixing inhibitor, etc. described later. A plurality of silver halide emulsion layers constituting each unit light-sensitive layer are formed by sequentially exposing two layers, a high-speed emulsion layer and a low-speed emulsion layer, to a support as described in DE 1,121,470 or GB 923,045. It is preferable to arrange them so that the degree is low. In addition, JP-A-57-112751, 62-200350, 62-2
As described in 06541 and 62-206543, a low-sensitivity emulsion layer may be provided on the side farther from the support and a high-sensitivity emulsion layer may be provided on the side closer to the support. As specific examples, from the farthest side from the support, a low-sensitivity blue-sensitive layer (BL) / a high-sensitivity blue-sensitive layer (BH) / a high-sensitivity green-sensitive layer (GH) / a low-sensitivity green-sensitive layer (GL) / High-sensitivity red-sensitive layer (RH) / low-sensitivity red-sensitive layer (RL), or BH / BL / GL / GH / RH / RL, or BH / BL / GH / GL / RL / RH And so on. Also, as described in JP-B-55-34932, the blue-sensitive layer / GH / RH / GL starts from the side farthest from the support.
/ RL can be arranged in this order. JP-A-56-2573
8, as described in JP-A-62-63936, the layers may be arranged in the order of blue-sensitive layer / GL / RL / GH / RH from the side farthest from the support. Further, as described in JP-B-49-15495, the upper layer is the silver halide emulsion layer having the highest sensitivity, the middle layer is the silver halide emulsion layer having a lower sensitivity, and the lower layer is a silver halide emulsion layer having a higher sensitivity than the middle layer. An example is an arrangement in which low silver halide emulsion layers are arranged and three layers having different sensitivities are sequentially lowered toward the support. Even when it is composed of such three layers having different sensitivities, as described in JP-A-59-202464, in the same color-sensitive layer, the medium-sensitivity emulsion layer / high-sensitivity layer is separated from the side distant from the support. You may arrange in order of a speed emulsion layer / a low speed emulsion layer. In addition, the layers may be arranged in the order of high-speed emulsion layer / low-speed emulsion layer / medium-speed emulsion layer, or low-speed emulsion layer / medium-speed emulsion layer / high-speed emulsion layer. Also, in case of 4 layers or more,
The arrangement may be changed as described above. In order to improve color reproducibility, BL, GL, described in US 4,663,271, 4,705,744, 4,707,436, JP-A-62-160448 and 63-89850, are described.
It is preferable that a donor layer (CL) having a multilayer effect having a spectral sensitivity distribution different from that of the main photosensitive layer such as RL is disposed adjacent to or close to the main photosensitive layer.

The preferred silver halide used in the present invention is silver iodobromide, silver iodochloride, or silver iodochlorobromide, which contains about 30 mol% or less of silver iodide. Particularly preferred is silver iodobromide or silver iodochlorobromide containing from about 2 mol% to about 10 mol% silver iodide. Silver halide grains in photographic emulsions have regular crystals such as cubes, octahedra and tetradecahedrons, grains having irregular crystal forms such as spheres and plates, twin planes, etc. It may have a crystal defect of, or a composite form thereof. The grain size of silver halide is about 0.2 μm or less
It may be large-sized grains up to 10 μm, and may be a polydisperse emulsion or a monodisperse emulsion. The silver halide photographic emulsion which can be used in the present invention is, for example, Research Disclosure (hereinafter abbreviated as RD) No. 17643 (December 1978), 22-2.
Page 3, "I. Emulsion preparation and type
s) ”and ibid. No. 18716 (November 1979), p. 648, ibid.
No.307105 (November 1989), pages 863-865, and Graphide, "Physics and Chemistry of Photography", published by Paul Montel (P.
Glafkides, Chemie et PhisiquePhotographique, Paul
Montel, 1967), "Photographic Emulsion Chemistry" by Duffin, published by Focal Press (GF Duffin, Photographic Emulsion
Chemistry, Focal Press, 1966), "Production and Coating of Photographic Emulsion" by Zelikmann et al., Published by Focal Press (VL Z
elikman, et al., Making and Coating Photographic E
mulsion, Focal Press, 1964) and the like.

US 3,574,628, US 3,655,394 and GB 1,4
Monodisperse emulsions described in 13,748 are also preferred. Further, tabular grains having an aspect ratio of about 3 or more can be used in the present invention. Tabular grains are described in Gutof, Photographic Science and Engineering (Gutof
f, Photographic Science and Engineering), Volume 14
248-257 (1970); US 4,434,226, US 4,414,310,
It can be easily prepared by the methods described in 4,433,048, 4,439,520 and GB 2,112,157. The crystal structure may be uniform, the inside and the outside may be composed of different halogen compositions, or may have a layered structure. Silver halides having different compositions may be joined by epitaxial joining, or may be joined to a compound other than silver halide, such as, for example, silver rhodanate or lead oxide. Also, a mixture of particles of various crystal forms may be used. The above emulsion is a surface latent image type that forms a latent image mainly on the surface,
Either an internal latent image type formed inside the grain or a type having a latent image both on the surface and inside may be used, but it is necessary that the emulsion is a negative type. Of the internal latent image types, JP-A-6
The core / shell type internal latent image type emulsion described in 3-264740 may be used, and its preparation method is described in JP-A-59-133542. The thickness of the shell of this emulsion varies depending on the development process, but is preferably 3 to 40 nm, particularly preferably 5 to 20 nm.

The silver halide emulsion is usually one which has been physically ripened, chemically ripened and spectrally sensitized. The additives used in such a process are RD No. 17643, RD No. 1
8716 and No. 307105, and the relevant parts are summarized in the table below. In the light-sensitive material of the present invention, two or more types of emulsions having at least one characteristic different from each other in the grain size, grain size distribution, halogen composition, grain shape and sensitivity of the photosensitive silver halide emulsion are mixed in the same layer. Can be used. US Pat. No. 4,082,553, the surface of which is covered with silver halide grains, US Pat.
It is preferred to apply the internally fogged silver halide grains and colloidal silver described in 214852 to the photosensitive silver halide emulsion layer and / or the substantially non-photosensitive hydrophilic colloid layer. The fogged silver halide grain inside or on the surface means a silver halide grain which enables uniform (non-imagewise) development regardless of the unexposed area and exposed area of the light-sensitive material. , Its preparation method is described in US 4,626,498 and JP-A-59-214852. The silver halide forming the internal nucleus of the core / shell type silver halide grain having the inside of the grain fogged may have a different halogen composition. As the silver halide having the inside or surface of the grain fogged, any of silver chloride, silver chlorobromide, silver iodobromide and silver chloroiodobromide can be used. The average grain size of these fogged silver halide grains is 0.01 to 0.75 μm
, Particularly preferably 0.05 to 0.6 μm. The grains may be regular grains or polydisperse emulsions, but may be monodisperse (at least the weight or the number of silver halide grains).
95% have a particle size within ± 40% of the average particle size)
It is preferred that

In the present invention, it is preferable to use a non-photosensitive fine grain silver halide. Non-photosensitive fine grain silver halide is silver halide fine grains that are not exposed during imagewise exposure to obtain a dye image and are not substantially developed in the developing process, and are preferably not fogged in advance. . The fine grain silver halide has a silver bromide content of 0 to 100 mol%, and may contain silver chloride and / or silver iodide, if necessary. Preferably, it contains 0.5 to 10 mol% of silver iodide. Fine grain silver halide has an average grain size (average value of circle equivalent diameter of projected area)
Is preferably 0.01 to 0.5 μm, more preferably 0.02 to 0.2 μm. Fine grain silver halide can be prepared by the same method as that for ordinary photosensitive silver halide. The surface of the silver halide grains does not need to be optically sensitized, and no spectral sensitization is required. However, prior to adding this to the coating solution, it is preferable to add a known stabilizer such as a triazole-based, azaindene-based, benzothiazolium-based, or mercapto-based compound or a zinc compound in advance. Colloidal silver can be contained in the layer containing fine silver halide grains. Coated silver amount of the light-sensitive material of the present invention is preferably 6.0 g / m ² or less, 4.5 g / m ² or less is most preferred.

The photographic additives that can be used in the present invention are also described in RD, and the relevant portions are shown in the table below. Type of additive RD17643 RD18716 RD307105 Chemical sensitizer page 23, page 648, right column, page 866 2. Sensitivity enhancer, page 648, right column 3. Spectral sensitizer, pages 23 to 24, page 648, right column 866 to 868, supersensitizer, page 649, right column 4. Whitening agent, page 24, page 647, right column, page 868, 5 Light absorber, pages 25 to 26, page 649, right column, page 873, filter, page 650, left column, dye, ultraviolet absorber 6. Binder, page 26, page 651, left column 873 to 874, page 7. Plasticizer, page 27, page 650, right Column 876 Lubricants 8. Coating aids, 26-27 Pages 650 Right column 875-876 Pages Surfactant 9. Static 27 pages 650 Page right columns 876-877 Inhibitors 10. Matting agents 878-879

Various dye-forming couplers can be used in the light-sensitive material of the present invention, and the following couplers are particularly preferable. Magenta coupler; JP-A-3-39737 (L-57 (page 11, lower right), L-
68 (lower right of page 12), L-77 (lower right of page 13); [A-4] -6 of EP 456,257
3 (p. 134), [A-4] -73, -75 (p. 139); M-4, -6 in EP 486,965
(Page 26), M-7 (page 27); EP-571,959A M-45 (page 19);
5-204106 (M-1) (page 6); JP-A-4-362631, paragraph 0237 M-
twenty two. Cyan coupler: CX-1,3,4,5,11,12,1 of JP-A-4-204843
4,15 (pages 14 to 16); C-7,10 (page 35) of JP-A-4-43345, 3
4,35 (page 37), (I-1), (I-17) (pages 42 to 43); JP-A-6-67385
A coupler represented by the general formula (Ia) or (Ib) according to claim 1. Polymer coupler: P-1, P-5 (p. 11) of JP-A-2-44345.

As couplers in which the color forming dye has a suitable diffusibility, US 4,366,237, GB 2,125,570, EP 96,873B,
Those described in DE 3,234,533 are preferred. Couplers for correcting unnecessary absorption of color-forming dyes are yellow colored cyan couplers represented by the formulas (CI), (CII), (CIII), and (CIV) described on page 5 of EP 456,257A1 (especially on page 84). YC-86), the EP
Yellow colored magenta coupler ExM-7 (202
), EX-1 (page 249), EX-7 (page 251), US 4,833,069
Magenta colored cyan coupler CC-9 (column
8), CC-13 (column 10), (2) of US 4,837,136 (column 8),
Colorless masking couplers of formula (A) in claim 1 of WO 92/11575 (especially the exemplified compounds on pages 36 to 45) are preferred. Examples of the compound (including a coupler) which releases a photographically useful compound residue by reacting with an oxidized developing agent include the following. Development inhibitor releasing compound: EP 37
Compounds represented by the formulas (I), (II), (III) and (IV) described on page 11 of 8,236A1 (especially T-101 (page 30), T-104 (page 31), T-113 ( 36
T-131 (p. 45), T-144 (p. 51), T-158 (p. 58)), EP436, 93
Compounds of formula (I) described on page 7 of 8A2 (particularly D-4
9 (page 51)), the compound of formula (1) of EP 568,037A (especially (23) (page 11)), and the compounds of formulas (I), (II), Compounds represented by (III) (especially I-
(1)); Bleaching accelerator releasing compounds: compounds represented by formulas (I) and (I ′) on page 5 of EP 310,125A2 (especially (60) and (6) on page 61)
1)) and the compound represented by formula (I) of claim 1 of JP-A-6-59411 (particularly (7) (page 7)); Ligand releasing compound: US
Compound represented by LIG-X described in claim 1 of 4,555,478 (especially compound on lines 21 to 41 of column 12); Leuco dye-releasing compound: compound 1 of columns 3 to 8 of US 4,749,641
~ 6; Fluorescent dye-releasing compound: C in claim 1 of US 4,774,181
Compounds represented by OUP-DYE (particularly compounds 1 to 11 in columns 7 to 10); development accelerator or fogging agent releasing compound: US
4,656,123, the compounds of formulas (1), (2) and (3) in column 3 (especially (I-22) in column 25) and EP 450,637A2
ExZK-2, p. 75, lines 36-38; Compound which releases a group which becomes a dye only when it is cleaved: Formula (I) of claim 1 of US 4,857,447
(Especially Y-1 to Y-19 in columns 25 to 36)
.

As the additives other than the coupler, the following are preferable. Dispersion medium of oil-soluble organic compound: P-3,5, JP-A-62-215272
16,19,25,30,42,49,54,55,66,81,85,86,93 (140-144
Page); Latex for impregnation of oil-soluble organic compounds: US 4,199,
Latex described in 363; Oxidized developer scavenger: a compound represented by the formula (I) in column 2, lines 54 to 62 of US Pat. ) (Column 4-
5), US Pat. No. 4,923,787, columns 5 to 10 of formula (particularly compound 1 (column 3); stain inhibitor: EP 298321A 4
Formulas (I) to (III) on page 30-33, especially I-47, 72, III-1, 27 (24
-48 pages); Anti-fading agent: A-6, 7, 20, 21, 23, 2 of EP 298321A
4,25,26,30,37,40,42,48,63,90,92,94,164 (69-118
P.), US 5,122,444, columns 25-38 II-1 to III-23, especially
III-10, EP 471347A I-1 to III-4 on pages 8 to 12, especially II-
2, US 5,139,931 columns 32-40 A-1 to 48, especially A-39,
42; Material that reduces the amount of color enhancer or color mixture inhibitor used: I-1 to II-15 on pages 5 to 24 of EP 411324A, especially I-4
6; Formalin scavenger: EP 477932A, pages 24 to 29 SCV-1 to 28, especially SCV-8; Hardener: JP-A 1-214845
Formulas in columns 13-23 of H-1,4,6,8,14, US 4,618,573 on page 17
Compounds (H-1 to 54) represented by (VII) to (XII),
214852, page 8, lower right, compound represented by formula (6) (H-1 to 7
6), especially the compound described in claim 1 of H-14, US 3,325,287; Development inhibitor precursor: P-2 of JP-A-62-168139
4,37,39 (pages 6-7); compounds as claimed in claim 1 of US 5,019,492, in particular column 7, 28,29; preservatives, fungicides: US
4,923,790 columns 3 to 15 I-1 to III-43, especially II-1,
9,10,18, III-25; Stabilizer, antifoggant: US 4,923,79
I-1 to (14) in columns 6 to 16 of 3, especially I-1,60, (2), (13), U
S 4,952,483 columns 25-32 compounds 1-65, especially 36:
Chemical sensitizer: triphenylphosphine selenide, compound 50 of JP-A-5-40324; dye: 15-18 of JP-A-3-156450
A-1 to b-20, especially a-1,12,18,27,35,36, b-5,27 to 29
Pages V-1 to 23, especially V-1, EP 445627A pages 33 to 55 FI-
1 to F-II-43, especially FI-11, F-II-8, EP 457153A 17 to 28
Pages III-1 to 36, especially III-1,3, WO 88/04794 8-26
Microcrystalline dispersion of Dye-1 to 124, compounds 1 to 22 of EP 319999A, pages 6 to 11, especially compound 1, compounds D-1 to 87 (3) represented by formulas (1) to (3) of EP 519306A. ~ Page 28), US 4,26
8,622 compounds represented by the formula (I) (columns 3 to 1)
0), compounds (1) to (4) of US Pat.
(31) (Columns 2 to 9); UV absorber: Formula of JP-A-46-3335
Compounds (18b) to (18r), 101 to 427 (6 to
9), and the compounds (3) to (6) represented by the formula (I) in EP 520938A.
6) (Pages 10 to 44) and compound HBT-1 represented by formula (III)
~ 10 (page 14), a compound represented by formula (1) in EP 521823A
(1) to (31) (columns 2 to 9).

The present invention can be applied to various color light-sensitive materials such as color negative films for general use or movies, color reversal films for slides or televisions, color papers, color positive films and color reversal papers. In addition, Japanese Patent Publication No.
Suitable for the lens-fitted film unit described in 3-39784. Suitable supports that can be used in the present invention are
For example, the RD. No. 17643, page 28, same No. 18716
Page 647, right column to page 648, left column, and 879 of the same No. 307105
Page. In the light-sensitive material of the present invention, the total thickness of all hydrophilic colloid layers on the emulsion layer side is preferably 28 μm or less, more preferably 23 μm or less,
It is more preferably not more than μm, particularly preferably not more than 16 μm.
Further, the film swelling speed T _1/2 is preferably 30 seconds or less, more preferably 20 seconds or less. T _1/2 is a color developer at 30 ° C for 3 minutes 15
When 90% of the maximum swollen film thickness reached at the time of second treatment is taken as the saturated film thickness, it is defined as the time until the film thickness reaches 1/2. The film thickness means the film thickness measured under a humidity condition of 25 ° C. and 55% relative humidity (2 days), and T _1/2 is A Green (A.
Green) et al. Photographic Science and
Engineering (Photogr.Sci.Eng.), 19 squares, 2,124
It can be measured by using a swellometer of the type described on page 129. T _1/2 can be adjusted by adding a hardening agent to gelatin as a binder or changing the aging condition after coating.
The swelling rate is preferably 150 to 400%. What is swelling rate?
It can be calculated from the maximum swollen film thickness under the conditions described above by the formula: (maximum swollen film thickness-film thickness) / film thickness. In the light-sensitive material of the present invention, a hydrophilic colloid layer (referred to as a back layer) having a total dry film thickness of 2 μm to 20 μm is preferably provided on the side opposite to the side having the emulsion layer. The back layer preferably contains the above-mentioned light absorber, filter dye, ultraviolet absorber, antistatic agent, hardener, binder, plasticizer, lubricant, coating aid, and surfactant. The swelling ratio of the back layer is preferably from 150 to 500%.

The light-sensitive material of the present invention is the same as RD. No. 17
Development can be carried out by a usual method described on pages 28 to 29 of 643, 651 left column to right column of No. 18716, and pages 880 to 881 of No. 307105. Next, the processing solution for the color negative film used in the present invention will be described. The color developing solution used in the present invention is described in JP-A-4-2171.
The compounds described on page 9, upper right column, line 1 to page 11 lower left column, line 4 can be used. As a color developing agent for particularly rapid processing, 2-methyl-4- [N-ethyl-N- (2-hydroxyethyl) amino] aniline,
2-Methyl-4- [N-ethyl-N- (3-hydroxypropyl) amino] aniline, 2-methyl-4- [N-
Ethyl-N- (4-hydroxybutyl) amino] aniline is preferred. These color developing agents are preferably used in the range of 0.01 to 0.08 mol per liter of the color developing solution, particularly preferably in the range of 0.015 to 0.06 mol, more preferably 0.02 to 0.05 mol. The replenisher for the color developing solution preferably contains 1.1 to 3 times the concentration of the color developing agent, and particularly preferably 1.3 to 2.5 times the concentration.

Hydroxylamine can be widely used as a preservative for the color developing solution, but when higher preservability is required, substitution of an alkyl group, a hydroxyalkyl group, a sulfoalkyl group, a carboxyalkyl group or the like is required. A hydroxylamine derivative having a group is preferable, and specifically, N, N-di (sulfoethyl) hydroxylamine, monomethylhydroxylamine, dimethylhydroxylamine, monoethylhydroxylamine, diethylhydroxylamine, N, N-di (carboxyethyl). Hydroxylamine is preferred. Among the above, N, N-di (sulfoethyl) hydroxylamine is particularly preferred. These may be used in combination with hydroxylamine, but it is preferable to use one or more of them instead of hydroxylamine. The preservative is preferably used in the range of 0.02 to 0.2 mol per liter, particularly preferably 0.03 to 0.15 mol, and further preferably 0.04 to 0.1 mol. As in the case of the color developing agent, the replenisher preferably contains a preservative at a concentration of 1.1 to 3 times the concentration of the mother liquor (processing tank solution). The color developer contains
Sulfite is used as an anti-talling agent for oxides of color developing agents. The sulfite is preferably used in an amount of 0.01 to 0.05 mol, and particularly preferably 0.02 to 0.04 mol, per liter. In the replenisher, these 1.1 ~
It is preferable to use it at a concentration of 3 times. Further, the pH of the color developing solution is preferably in the range of 9.8 to 11.0, but particularly 10.0
˜10.5 is preferable, and in the replenisher, it is preferable to set a high value in the range of 0.1 to 1.0 from these values. In order to stably maintain such a pH, a known buffer such as carbonate, phosphate, sulfosalicylate, and borate is used.

The replenishing amount of the color developing solution is preferably 80 to 1300 ml per m ² of the light-sensitive material, but is preferably smaller from the viewpoint of reducing the environmental pollution load, specifically 80 to 6
It is preferably 00 ml, more preferably 80 to 400 ml. The bromide ion concentration in the color developing solution is usually 0.01 to 1 liter / liter.
Although it is 0.06 mol, it is preferably set to 0.015 to 0.03 mol per liter for the purpose of suppressing the fog while maintaining the sensitivity, improving the discrimination, and improving the graininess. When the bromide ion concentration is set in such a range, the replenisher may contain bromide ions calculated by the following formula. However, when C becomes negative, it is preferred that the replenisher does not contain bromide ions. C = A-W / V C: Bromide ion concentration in the color developing replenisher (mol / liter) A: Target bromide ion concentration in the color developing solution (mol / liter) W: 1m ² of light-sensitive material is colored Amount of bromide ion eluted from the light-sensitive material to the color-developing solution when developed (mol) V: Replenishment amount of color-development replenisher for a light-sensitive material of 1 m ² (liter). When the bromide ion concentration is set, 1-phenyl-3-pyrazolidone or 1-phenyl-2-methyl-2 can be used as a method for increasing the sensitivity.
It is also preferable to use a development accelerator such as pyrazolidones represented by -hydroxymethyl-3-pyrazolidone and thioether compounds represented by 3,6-dithia-1,8-octanediol.

The compounds and processing conditions described in JP-A-4-125558, page 4, lower left column, line 16 to page 7, lower left column, line 6 can be applied to the processing solution having bleaching ability in the present invention. . The bleaching agent preferably has an oxidation-reduction potential of 150 mV or more, and specific examples thereof include JP-A-5-72694 and JP-A-5-7333.
The compounds described in No. 12 are preferred, and 1,3-diaminopropanetetraacetic acid, particularly, a ferric complex salt of the compound of Specific Example 1 on page 7 of JP-A-5-73312 is preferred. In addition, in order to improve the biodegradability of the bleaching agent, JP-A-4-218845, 4-268552, EP588,
289, 591,934, and the compound ferric complex salts described in JP-A-6-208213 are preferably used as a bleaching agent. The concentration of these bleaching agents is 0.05 per liter of bleaching solution.
The amount is preferably from 0.3 to 0.3 mol, and particularly from the viewpoint of reducing the amount discharged to the environment, it is preferably designed from 0.1 to 0.15 mol. Further, when the bleaching solution is a bleaching solution, it is preferable to contain 0.2 mol to 1 mol of bromide per liter, particularly 0.3 to 0.8 mol. The replenisher for the bleaching solution basically contains the concentrations of the respective components calculated by the following formula. This allows
The concentration in the mother liquor can be kept constant. C _R = C _T × (V ₁ + V ₂ ) / V ₁ + C _P C _R : Concentration of component in replenisher C _T : Concentration of component in mother liquor (treatment tank liquid) C _P : Consumed during treatment Concentration of components V ₁ : Replenishing amount of replenisher having bleaching ability for 1 m ² of light-sensitive material (mL) V ₂ : Bring-in amount of 1 m ² of light-sensitive material from the previous bath (mL) It is preferable to contain an agent, and it is particularly preferable to contain a dicarboxylic acid having a low odor such as succinic acid, maleic acid, malonic acid, glutaric acid, and adipic acid. Also, JP-A-53-95630, RDN
It is also preferable to use known bleaching accelerators described in O. 17129, US 3,893,858. The bleaching solution is preferably replenished with 50 to 1000 ml of the bleach replenishing solution per 1 m ² of the light-sensitive material, particularly 80 to 500 ml, more preferably 100 to 300 ml. Further, it is preferable to perform aeration on the bleaching solution.

The processing liquid having fixing ability is described in JP-A
The compounds and processing conditions described on page 7, lower left column, line 10 to page 8, lower right column, line 19 of 4-125558 can be applied. In particular, in order to improve the fixing speed and the homeostasis, the compounds represented by the general formulas (I) and (II) of JP-A-6-301169 are contained alone or in combination in a processing solution having fixing ability. It is preferable. In addition to the p-toluenesulfinic acid salt, the sulfinic acid described in JP-A 1-224762 can also be used.
It is preferable from the viewpoint of improving the homeostasis. It is preferable to use ammonium as a cation in a solution having a bleaching ability and a solution having a fixing ability from the viewpoint of improving desilvering ability, but from the viewpoint of reducing environmental pollution, it is preferable to reduce or eliminate ammonium. . In the bleaching, bleach-fixing and fixing steps, jet stirring described in JP-A-1-309059 is particularly preferable. The replenishing amount of the replenisher in the bleach-fixing or fixing step is 100 to 1000 ml, preferably 150 to 700 ml, and particularly preferably 200, per 1 m ² of the light-sensitive material.
~ 600 ml. In the bleach-fixing and fixing steps, it is preferable to install various silver recovery devices in-line or off-line to recover silver. By installing in-line, the processing can be carried out with a reduced silver concentration in the solution, so that the replenishment amount can be reduced. It is also preferable to recover silver off-line and reuse the remaining liquid as a replenisher. The bleach-fixing step and the fixing step can be composed of a plurality of processing tanks, and it is preferable that each tank is cascade-piped to form a multistage countercurrent system. Generally, the two-tank cascade configuration is efficient because of the balance with the size of the developing machine.
The ratio of the processing time in the front tank and the rear tank is
The range of 0.5: 1 to 1: 0.5 is preferable, and the range of 0.8: 1 to 1: 0.8 is particularly preferable. In the bleach-fixing solution or the fixing solution, it is preferable to allow a free chelating agent which is not a metal complex to be present from the viewpoint of improving the preservative property. It is preferred to use chelating agents.

Regarding the washing and stabilizing steps, the above JP-A-4-125558, page 12, lower right column, line 6 to page 13, lower right column, line 16
The contents described in the line can be preferably applied. In particular, EP 504,60 replaces formaldehyde in stabilizers.
9. Use of the azolylmethylamines described in 519,190 and N-methylolazoles described in JP-A-4-362943, and the use of an interface free of image stabilizers such as formaldehyde by dimerizing a magenta coupler. It is preferable to use a liquid of the activator from the viewpoint of preserving the working environment. Further, in order to reduce the adhesion of dust to the magnetic recording layer coated on the light-sensitive material, the stabilizing solution described in JP-A-6-289559 can be preferably used. The amount of washing and replenishment of the stabilizing solution is preferably 80 to 1000 ml / m ² of the light-sensitive material, and particularly 100 to 5 ml.
00 ml, and more preferably 150 to 300 ml, are preferable ranges from the viewpoint of ensuring the washing or stabilizing function and reducing waste liquid for environmental protection. In the treatment performed with such a supplement amount, thiabendazole, 1,2-benzisothiazolin-3one,
Known antifungal agents such as 5-chloro-2-methylisothiazolin-3-one and antibiotics such as gentamicin,
It is preferable to use water deionized with an ion exchange resin or the like. It is more effective to use deionized water in combination with antibacterial agents and antibiotics. Also, the liquid in the washing or stabilizing liquid tank is disclosed in JP-A-3-46652, JP-A-3-53246 and JP-A-3-53246.
It is also preferable to perform the reverse osmosis membrane treatment described in 55542, 3-121448, and 3-126030 to reduce the replenishment amount. In this case, the reverse osmosis membrane is preferably a low-pressure reverse osmosis membrane.

In the processing of the present invention, it is particularly preferable to carry out the evaporation correction of the processing liquid as disclosed in JIII Journal of Technical Disclosure, Japanese Patent No. 94-4992. In particular, a method of making a correction using the temperature and humidity information of the environment where the developing machine is installed is preferable based on (Equation-1) on page 2. The water used for evaporation correction is preferably collected from a replenishment tank for washing,
In that case, it is preferable to use deionized water as the replenishing water for washing.

As the treating agent used in the present invention, those described on page 3, right column, line 15 to page 4, left column, line 32 of the above-mentioned Kokai Giho are preferable. In addition, as a developing machine used for this,
The film processor described on page 3, right column, lines 22 to 28 is preferred. Specific examples of preferred processing agents, automatic processors, and evaporation correction methods for carrying out the present invention are described on page 5, right column, line 11 to page 7, right column, last line. .

The supply form of the treating agent used in the present invention is as follows:
It may be in any form, such as a liquid preparation in the form of a liquid used or a concentrated form, or granules, powders, tablets, pastes, and emulsions. As an example of such a treating agent, JP-A-63-1
7453 discloses a liquid agent contained in a container having low oxygen permeability,
19655, 4-230748, vacuum-packed powders or granules, 4-221951, granules containing a water-soluble polymer,
JP-A-51-61837 and JP-A-6-102628 have tablets and special tables
Discloses a paste-like treating agent, which can be preferably used, but from the viewpoint of simplicity at the time of use,
It is preferable to use a liquid which has been prepared in advance in a concentration at the state of use. Polyethylene, polypropylene, polyvinyl chloride, polyethylene terephthalate, nylon and the like are used alone or as a composite material in a container for containing these treatment agents. These are selected according to the required level of oxygen permeability. For an easily oxidizable liquid such as a color developing solution, a material having low oxygen permeability is preferable, and specifically, a polyethylene terephthalate or a composite material of polyethylene and nylon is preferable. These materials are used in containers having a thickness of 500 to 1500 μm, and preferably have an oxygen permeability of 20 ml / m ² · 24 hrs · atm or less.

Next, the processing solution for the color reversal film used in the present invention will be described. Regarding the processing for the color reversal film, known technology No. 6 (April 1, 1991), page 1, line 5 to page 10, line 5, and page 15, line 8 to page 24, 2 of Aztec Co., Ltd. It is described in detail in the line, and any of its contents can be preferably applied. In color reversal film processing, image stabilizers are included in either the conditioning bath or the final bath. Examples of such an image stabilizer include formalin, formaldehyde sodium bisulfite, and N-methylolazoles.
From the viewpoint of the working environment, sodium formaldehyde bisulfite or N-methylolazoles are preferable, and as N-methylolazoles, N-methyloltriazole is particularly preferable. The contents relating to the color developing solution, the bleaching solution, the fixing solution, the washing water, etc. described in the processing of the color negative film can be preferably applied to the processing of the color reversal film. A preferred color reversal film treating agent containing the above is E-manufactured by Eastman Kodak Company.
6 processing agents and CR-56 processing agents of Fuji Photo Film Co., Ltd. can be mentioned.

Next, the polyester support used in the present invention will be described. For details including sensitive materials, treatments, cartridges and examples other than the above, open technical report, official technique number 94-6023 (Invention Society; 1994.3.15.). The polyester used in the present invention is formed by using diol and aromatic dicarboxylic acid as essential components. As aromatic dicarboxylic acids, 2,6-, 1,5-, 1,4- and 2,7-naphthalenedicarboxylic acid, terephthalic acid Examples of the acid, isophthalic acid, phthalic acid, and diol include diethylene glycol, triethylene glycol, cyclohexanedimethanol, bisphenol A, and bisphenol. Examples of the polymerized polymer include homopolymers such as polyethylene terephthalate, polyethylene naphthalate, and polycyclohexanedimethanol terephthalate. Particularly preferred is a polyester containing 50 to 100 mol% of 2,6-naphthalenedicarboxylic acid. Among them, polyethylene-2,6 is particularly preferable.
-Naphthalate. The average molecular weight ranges from about 5,000 to 200,000. Tg of the polyester of the present invention is 50 ° C.
And more preferably 90 ° C. or higher.

Next, the polyester support is subjected to a heat treatment at a heat treatment temperature of 40 ° C. or higher and lower than Tg, more preferably Tg−20 ° C. or higher and lower than Tg in order to prevent the curling tendency. The heat treatment may be performed at a constant temperature within this temperature range, or may be performed while cooling. The heat treatment time is 0.1 to 1500 hours, more preferably 0.5 to 200 hours. The heat treatment of the support may be performed in the form of a roll, or may be performed while transporting the support in the form of a web.
Surface irregularities may be imparted (for example, conductive inorganic fine particles such as SnO ₂ or Sb ₂ O ₅ may be applied) to improve the surface state. It is also desirable to take measures such as applying knurls to the ends and raising the ends only slightly to prevent cut-out of the core. These heat treatments are performed after forming the support, after surface treatment,
It may be carried out at any stage after application of the back layer (antistatic agent, slip agent, etc.) and after application of the undercoat. Preferably after application of the antistatic agent. An ultraviolet absorber may be incorporated into this polyester. Also, to prevent light piping,
The purpose can be achieved by kneading dyes or pigments commercially available for polyesters such as Diaresin manufactured by Mitsubishi Kasei and Kayaset manufactured by Nippon Kayaku.

Next, in the present invention, it is preferable to carry out a surface treatment in order to bond the support and the light-sensitive material constituting layer. Chemical treatment, mechanical treatment, corona discharge treatment, flame treatment, ultraviolet treatment, high frequency treatment, glow discharge treatment, active plasma treatment,
Surface activation treatments such as laser treatment, mixed acid treatment, ozone oxidation treatment and the like can be mentioned. Among the surface treatments, ultraviolet irradiation treatment, flame treatment, corona treatment, and glow treatment are preferable. Next, the undercoating method will be described. It may be a single layer or two or more layers. As the binder for the undercoat layer, vinyl chloride, vinylidene chloride, butadiene, methacrylic acid,
Examples include a copolymer using a monomer selected from acrylic acid, itaconic acid, maleic anhydride and the like as a starting material, polyethylene imine, epoxy resin, grafted gelatin, nitrocellulose, and gelatin. Compounds that swell the support include resorcin and p-chlorophenol. As a gelatin hardening agent for the undercoat layer, chromium salts (chrome alum, etc.), aldehydes (formaldehyde, glutaraldehyde, etc.), isocyanates, active halogen compounds (2,4-dichloro-6-) are used.
Hydroxy-S-triazine, etc.), epichlorohydrin resin, active vinyl sulfone compound and the like. SiO ₂ , TiO ₂ , inorganic fine particles or polymethylmethacrylate copolymer fine particles (0.01 to 10 μm) may be contained as a matting agent.

In the present invention, an antistatic agent is preferably used. Examples of these antistatic agents include carboxylic acids and carboxylates, polymers containing sulfonates, cationic polymers, and ionic surfactant compounds. The most preferred antistatic agent is Z
_{nO, TiO 2, SnO 2,} Al 2 O 3, In 2 O 3, SiO 2, MgO, BaO,
MoO ₃ , at least one selected from V ₂ O ₅ has a volume resistivity of 10 ⁷ Ω · cm or less, more preferably 10 ⁵ Ω · cm or less. Fine particles of oxides or composite oxides thereof (Sb, P, B, In, S, Si, C, etc.), and sol-like metal oxides or fine particles of these composite oxides. The content in the photosensitive material should be between 5 and
500 mg / m ² are preferred and particularly preferably 10 to 350 mg / m ^2. The ratio of the amount of the conductive crystalline oxide or its composite oxide to the binder is preferably from 1/300 to 100/1, more preferably from 1/100 to 100/5.

The light-sensitive material of the present invention preferably has a slip property. The slip agent-containing layer is preferably used on both the photosensitive layer surface and the back surface. A preferable slip property is a dynamic friction coefficient of 0.
It is 25 or less and 0.01 or more. The measurement at this time represents the value when the stainless steel ball with a diameter of 5 mm is transported at 60 cm / min (25
℃, 60% RH). In this evaluation, even if the surface of the photosensitive layer is replaced as the partner material, the values are almost the same level. Examples of the slip agent usable in the present invention include polyorganosiloxanes, higher fatty acid amides, higher fatty acid metal salts, esters of higher fatty acids and higher alcohols, and polyorganosiloxanes such as polydimethyl siloxane, polydiethyl siloxane, poly Styrylmethylsiloxane, polymethylphenylsiloxane, or the like can be used. The additional layer is preferably the outermost layer of the emulsion layer or the back layer. Particularly, polydimethylsiloxane or an ester having a long-chain alkyl group is preferable.

The light-sensitive material of the present invention preferably contains a matting agent. The matting agent may be on either the emulsion side or the back side, but is particularly preferably added to the outermost layer on the emulsion side.
The matting agent may be soluble in the processing solution or insoluble in the processing solution, and preferably both are used in combination. For example, polymethylmethacrylate, poly (methylmethacrylate / methacrylic acid = 9/1 or 5/5 (molar ratio)), polystyrene particles and the like are preferable. The particle size is preferably 0.8 to 10 μm, and the particle size distribution is preferably narrow, and the average particle size is 0.9 to 1.
It is preferable that 90% or more of the total number of particles be contained in one time. It is also preferable to simultaneously add fine particles of 0.8 μm or less in order to enhance the matting property. Particles (0.25μm), colloidal silica (0.03μm)
Is mentioned.

Next, the film cartridge used in the present invention will be described. The main material of the patrone used in the present invention may be metal or synthetic plastic. Preferred plastic materials are polystyrene, polyethylene, polypropylene, polyphenyl ether and the like. Further, the patrone of the present invention may contain various antistatic agents, and carbon black, metal oxide particles, nonionic, anionic, cationic and betaine surfactants or polymers can be preferably used. These antistatic patrones are described in JP-A 1-312537 and JP-A 1-312538. Particularly, the resistance at 25 ° C. and 25% RH is preferably 10 ¹² Ω or less. Usually, a plastic patrone is manufactured using a plastic into which carbon black, a pigment, or the like is kneaded in order to impart light shielding properties. The size of the patrone may be 135 size at present, and for miniaturization of the camera,
It is also effective to reduce the diameter of the current 135 size 25 mm cartridge to 22 mm or less. The volume of the patrone case is preferably 30 cm ³ or less, more preferably 25 cm ³ or less. The weight of the plastic used for the patrone and the patrone case is preferably 5 g to 15 g.

Further, the cartridge used in the present invention may be a cartridge that rotates the spool to feed the film. Further, a structure may be employed in which the leading end of the film is housed in the cartridge body, and the leading end of the film is sent out from the port of the cartridge by rotating the spool shaft in the film sending direction. These are disclosed in US Pat. Nos. 4,834,306 and 5,226,613. The photographic film used in the present invention may be a so-called raw film before development, or may be a photographic film subjected to development processing. Also, raw film and developed photographic film may be stored in the same new patrone,
Different patrones may be used.

[0205]

EXAMPLES The present invention will be described in more detail with reference to the following Examples, which should not be construed as limiting the scope of the present invention.

Example 1 Using a comparative coupler (1), dibutyl phthalate, ethyl acetate and sodium dodecylbenzenesulfonate were added to this coupler and dissolved, and the coupler dispersion finely emulsified in an aqueous gelatin solution was iodobrominated. In addition to silver emulsion (AgI content 4 mol%, average particle size 0.5 μm, cubic, multi-structured particles), poly (vinylbenzene sulfonate) as a thickener and 2,4-dichloro-6-oxy- as a hardener. An emulsion coating solution was prepared by adding 1,3,5-triazine sodium salt and a tetrazaindene compound as a stabilizer. This coating solution was uniformly coated on an undercoated cellulose triacetate film support, and a coating solution consisting mainly of an aqueous gelatin solution was applied thereon to provide a protective layer to prepare a sample. This is designated as Sample 101. The main composition of each of the above layers is shown below. (Emulsion layer) Silver iodobromide emulsion (in terms of silver) 1.04 g / m ² Coupler (Comparative Coupler (1)) 0.985 g / m ² dibutyl phthalate 0.33 g / m ² Gelatin 3.00 g / m ² (Protective layer) Gelatin 2.50 g / m ²

Sample 102 was prepared by adding Comparative Compound (A) to Sample 101. The comparative compound (A) was emulsified and dispersed in addition to the coupler. The coating amount of the comparative compound (A) is 12.84 mg / m ² . Sample 103 is the compound (A-1) of the present invention, which is the comparative compound (A) used in Sample 102.
5) was prepared by substituting equimolar amounts. Samples 104-10
Sample No. 6 was prepared in the same manner as Samples 101 to 103 except that Comparative Coupler (1) used in Samples 101 to 103 was replaced with Comparative Coupler (2) in an equimolar amount. Sample 1
Nos. 07 to 109 were produced in the same manner as in Samples 101 to 103 except that the comparative coupler (1) used in Samples 101 to 103 was replaced with the coupler (Y-29) of the present invention in an equimolar amount.

Samples 110 to 120 were prepared by substituting the compound (A-15) of the present invention used in Sample 109 with another compound of the present invention shown in Table 1 in an equimolar amount. Sample 121
-123 were produced in the same manner as in Samples 101 to 103 except that the comparative coupler (1) used in Samples 101 to 103 was replaced with the coupler (YB-7) of the present invention in an equimolar amount. Samples 124 to 130 were prepared by substituting the compound (A-15) of the present invention used in Sample 123 with another compound of the present invention shown in Table 1 in an equimolar amount. Sample 131-
Up to 154, the coupler (Y-29) of the present invention used in Sample 109 was replaced with another coupler of the present invention as shown in Table 2 in an equimolar amount. The comparative couplers (1) and (2) and comparative compound (A) used were
Shown in

[0209]

Embedded image

These produced samples 101 to 154 are
It was cut and processed into a width of 35 mm and a length of 160 cm, and the following performances were evaluated. (1) Color development White light exposure is given through a wedge for sensitometry,
Color development processing shown below was carried out. The B density of the developed sample was measured, and the logarithmic value of the reciprocal of the exposure amount giving the density of (A) fog + 0.5 was found from the characteristic curve of each sample and used as the sensitivity. No. 103 to Sample 101, Samples 104 to 106 to Sample 104, Sample 1
The samples 107 to 120, 131 to 141, 153 and 154 are based on the sample 107, and the samples 121 to 130, 142 to 152 are based on the sample 121, and the difference (ΔS) is calculated. The larger the value, the higher the sensitivity. (B) Connect the points that give a density of 0.5 and a density of 1.5 with a straight line,
The gradient of the horizontal axis (exposure dose axis) vs. the vertical line (density axis) is obtained, and this is taken as the gradient (γ ₀ ).
The ratio based on 1 (γ = γ _{102 or 103} / γ ₁₀₁ )
In the following, the ratio was calculated for each of the same groups as in (A) above. The larger the value, the higher the gradation.

(2) Pressure Fogging The samples cut and processed into the width of 35 mm and the length of 160 cm were wound on the existing spools and stored in a 135 cartridge. The diameter of the winding core is 11 mm, and the number of windings is 31 rounds. 5 at 60 ° C and 70% relative humidity
After storing for a day, the samples were taken out from the cartridge, and all the samples were subjected to the following color development process without being exposed to light, and then the B concentration was measured from the tip to the end of each sample. The difference (ΔD) from the B concentration value was obtained for each sample. The samples having a difference in density were high on the inside (winding core part) wound on the spool and low on the outside. The smaller the ΔD is, the smaller the pressure fog is, which is preferable. The color development processing used in the above (1) and (2) is shown below. Processing was performed using Fuji Photo Film's automatic processor FP-360B and Fuji Color Negative Super G Ace 400 (manufactured by Fuji Photo Film Co., Ltd.) taken with a camera.
The following treatment was carried out for each m ² for 15 days (running treatment). The overflow solution of the bleaching bath was modified so that it was entirely discharged into the waste liquid tank without flowing into the post bath. This FP-360B is equipped with the evaporation correction means described in JIII Journal of Technical Disclosure No. 944992.
The processing steps and the composition of the processing solution are shown below.

(Processing process) Process processing time Processing temperature Replenishment amount ^* Tank capacity Color development 3 minutes 5 seconds 38.0 ° C 20 ml 17 liter Bleach 50 seconds 38.0 ° C 5 ml 5 liter Fixing (1) 50 seconds 38.0 ° C- 5 liters Fixing (2) 50 seconds 38.0 ° C 8 ml 5 liters Water washing 30 seconds 38.0 ° C 17 ml 3.5 liters Stable (1) 20 seconds 38.0 ° C-3 liters Stable (2) 20 seconds 38.0 ° C 15 ml 3 liters Dry 1 Minute 30 seconds 60 ℃ ^* Replenishment amount per 1m of 35mm width of photosensitive material (equivalent to 24Ex. 1) Stabilizer is countercurrent from (2) to (1), and all overflow liquid of washing water is fixed Introduced into the bath. The fixing solution is also connected from (2) to (1) by a countercurrent pipe. still,
The amount of developing solution brought into the bleaching process, the amount of bleaching solution brought into the bleach-fixing process, the amount of bleach-fixing solution brought into the fixing process and the amount of fixing solution brought into the washing process were 35 mm
The width was 2.5 ml, 2.0 ml, and 2.0 ml per 1.1 m in width, respectively. The crossover time is 6 seconds in all cases, and this time is included in the processing time of the previous step. 100 cm ² opening area of the processing groups are color developer, 120 cm ² in the bleaching solution, the other processing solutions was about 100 cm ^2.

The composition of the processing liquid is shown below. (Color developer) Tank liquid (g) Replenisher (g) Diethylenetriaminepentaacetic acid 2.0 2.0 1-Hydroxyethylidene-1,1-diphosphonic acid 2.0 2.0 Sodium sulfite 3.9 5.3 Potassium carbonate 37.5 39.0 Potassium bromide 1.4 0.4 Potassium iodide 1.3 mg-Disodium-N, N-bis (sulfonate ethyl) hydroxylamine 2.0 2.0 Hydroxylamine sulfate 2.4 3.3 2-Methyl-4- [N-ethyl-N- (β-hydroxyethyl) amino] aniline sulfate 4.5 6.4 Add water 1.0 liter 1.0 liter pH (adjust with potassium hydroxide and sulfuric acid) 10.05 10.18

(Bleaching Solution) Tank Solution (g) Replenishing Solution (g) 1,3-Diaminopropaneferric Acid Ferric Acid Ammonium Monohydrate 118 180 Ammonium Bromide 80 115 Ammonium Nitrate 14 21 Succinic Acid 40 60 Maleic Acid 33 50 1.0 liter with addition of water 1.0 liter pH (prepared with ammonia water) 4.4 4.0

(Fixing liquid) Tank liquid (g) Replenishing liquid (g) Ammonium methanesulfonate 10 30 Ammonium methanethiosulfonate 4 12 Ammonium thiosulfate aqueous solution (700 g / l) 280 millitottle 840 millitottle imidazole 7 20 Ethylenediaminetetraacetic acid 15 45 1.0 liter by adding water 1.0 liter pH [Prepared with ammonia water and acetic acid] 7.4 7.45

(Rinsing water) Tap water was used as an H-type strongly acidic cation exchange resin (Amberlite IR- manufactured by Rohm and Haas).
120B) and OH-type strongly basic anion exchange resin (Amberlite IR-400) were passed through a mixed bed column to adjust the concentration of calcium and magnesium ions to 3 mg.
/ Liter or less, followed by 20 mg / liter sodium dichloroisocyanate and 150 sodium sulfate
mg / l was added. The pH of this solution is 6.5 to 7.
It was in the range of 5.

(Fixing Solution) Tank Solution and Replenishing Solution Common (Unit: g) Sodium p-toluenesulfinate 0.03 Polyoxyethylene-p-monononylphenyl ether (Average degree of polymerization: 10) 0.2 Ethylenediaminetetraacetic acid disodium salt 0.05 1, 2,4-triazole 1.3 1,4-bis (1,2,4-triazol-1-ylmethyl) piperazine 0.75 1,2-benzisothiazol-3-one 0.10 Water was added to 1.0 liter pH 8.5 (1) and The results of (2) are summarized in Tables 1 and 2.

[0218]

[Table 1]

[0219]

[Table 2]

From the table, general formulas (AI) to (A) of the present invention can be obtained.
-III) and an acylacetamide type coupler having an acyl group represented by the general formula (YI) of the present invention and / or a coupler represented by the general formula (1) or (2) Samples 109 to 12 of the present invention
Nos. 0 and 123 to 154 exhibited higher sensitivity and gradation than the comparative sample and showed excellent color development, and were capable of preventing pressure fog that occurs when the photosensitive material was rolled up and stored in a 135 cartridge and stored at high temperature. it is obvious. Further, as compared with the acylacetamide type coupler having an acyl group represented by the general formula (YI), the couplers represented by the general formulas (1) and (2) are represented by the general formulas (AI) to
It can also be seen that the use of the compound represented by (A-III) provides higher sensitivity and gradation, and has a large effect of promoting color development and excellent color developability. This is because the couplers represented by the general formulas (1) and (2) have a higher acid dissociation constant (pKa) than the acylacetamide type having an acyl group represented by the general formula (YI). What was originally somewhat low in activity is the general formula (AI) of the present invention.
It is considered that the use of the compounds represented by (A-III) promoted dissociation and increased the color development.

Example 2 1) Support The support used in this example was prepared by the following method. Polyethylene-2,6-naphthalate polymer 100
After drying 2 parts by weight and 2 parts by weight of Tinuvin P.326 (manufactured by Ciba-Geigy Co.) as an ultraviolet absorber, 300 ° C.
After being melted at, it was extruded from a T-die, stretched 3.3 times at 140 ° C, then stretched 3.3 times at 130 ° C, and heat-fixed at 250 ° C for 6 seconds to form a 90 μm thick PEN.
I got a film. The PEN film has a blue dye, a magenta dye, and a yellow dye (public technical report: I-1, I-4, I-6, I-24, I-26, I-26 described in the official gazette number 94-6023). 27, II-5)
Was added in an appropriate amount. Further, the support was wound around a stainless steel core having a diameter of 20 cm to give a heat history of 110 ° C. and 48 hours, thereby providing a support that was not easily curled.

2) Coating of undercoat layer The above-mentioned support was subjected to corona discharge treatment, UV discharge treatment, and glow discharge treatment on both sides thereof, and then gelatin 0.1 g / m ² and sodium α-sulfodione on each side. -2-ethylhexyl succinate 0.01 g / m ² , salicylic acid 0.04 g / m ² , p
-Chlorophenol 0.2 g / m ² , (CH ₂ = CHSO ₂ CH ₂ CH ₂ NHCO) ₂
CH ^₂ 0.012g / m _2, polyamide - epichlorohydrin polycondensate was coated an undercoat solution ^{0.02g / m 2 (10cc / m} 2, a bar coater used), provided with a subbing layer hotter side at the time of stretching. Dry 1
The test was carried out at 15 ° C for 6 minutes (all rollers and transport devices in the drying zone were at 115 ° C). 3) Coating of Back Layer An antistatic layer, a magnetic recording layer and a sliding layer having the following composition were coated as a back layer on one surface of the support after the undercoat.

3-1) Coating of antistatic layer A tin oxide-antimony oxide composite having an average particle size of 0.005 μm has a specific resistance of 5 Ω · cm and is a dispersion of fine particle powder (secondary agglomerated particle size of about 0.08 μm). 0.2 g / m ^2, gelatin 0.05g / m ^2, (C
H ₂ = CHSO ₂ CH ₂ CH ₂ NHCO) ₂ CH ₂ 0.02 g / m ² , poly (degree of polymerization 1
0) Oxyethylene-p-nonylphenol 0.005 g / m ²
And resorcinol. 3-2) Coating of magnetic recording layer 3-poly (degree of polymerization: 15) Cobalt-γ-iron oxide coated with oxyethylene-propyloxytrimethoxysilane (15% by weight) (specific surface area: 43 m ² / g; Long axis 0.14μm, single axis 0.03μm, saturation magnetization 89emu / g, Fe ^{+ 2} / Fe ⁺³ = 6/94, the surface is treated with silicon oxide aluminum oxide with 2% by weight of iron oxide) 0.06g / m ² diacetyl cellulose 1.2 g / m ² (dispersion of the iron oxide was carried out using an open kneader and a sand _{mill), C 2 H 5 C (} CH 2 OCONH-C 6 H 3 (CH 3) NCO) as a curing agent ₃
0.3 g / m ² was applied with a bar coater using acetone, methyl ethyl ketone, cyclohexanone, and dibutyl phthalate as solvents to obtain a 1.2 μm-thick magnetic recording layer. C ₆ H ₁₃ CH (OH) C ₁₀ H ₂₀ COO as a slip agent
C ₄₀ H ₈₁ 50 mg / m ² , silica particles as matting agent
(1.0 μm) and 3-poly (polymerization degree 15) oxyethylene-propyloxytrimethoxysilane (15 wt%) treated and coated with abrasive aluminum oxide (0.20 μm and 1.0 μm) at 50 mg / m ² and It was added at 10 mg / m ² . Drying was carried out at 115 ° C for 6 minutes (all rollers and transporting devices in the drying zone were at 115 ° C). X- light (blue filter) saturation magnetization moment of the magnetic recording layer of the D color density increment of about 0.1 of ^B, also the magnetic recording layer in the 4.2 emu / g, coercive force
The square ratio was 7.3 × 10 ⁴ A / m and the ratio was 65%.

3-3) Preparation of sliding layer Diacetyl cellulose (25 mg / m ² ), C ₆ H ₁₃ CH (OH) C ₁₀ H ₂₀ C
OOC ₄₀ H ₈₁ (6mg / m ² ), poly (dimethylsiloxane) (B
-3) (1.5 mg / m ² ) was applied. In addition, this mixture is
In xylene / propylene monomethyl ether (1/1) 1
It was melted at 05 ° C., poured into and dispersed in propylene monomethyl ether (10 times amount) at room temperature to prepare a dispersion (acetone having an average particle diameter of 0.01 μm), and then added. Dry 1
The test was carried out at 15 ° C for 6 minutes (115 ° C for all the rollers and conveying devices in the drying zone). The sliding layer had excellent characteristics such as a dynamic friction coefficient of 0.10 (5 mmφ stainless steel ball, load 100 g, speed of 6 cm / min), static friction coefficient of 0.08 (clip method), and a dynamic friction coefficient of 0.15 between the emulsion surface and the sliding layer described later. .

4) Coating of Photosensitive Layer Next, on the opposite side of the back layer obtained above, each layer having the following composition was multilayer coated to prepare a color negative film.
This is designated as Sample 201.

(Photosensitive layer composition) The main materials used for each layer are classified as follows: ExC: Cyan coupler UV: UV absorber ExM: Magenta coupler HBS: High boiling organic solvent ExY: Yellow coupler H: Gelatin hardening agent ExS: Sensitizing dye The numeral corresponding to each component indicates the coating amount expressed in g / m ² unit, and for silver halide, the coating amount in terms of silver. However, for the sensitizing dye, the coating amount is shown in mol units with respect to 1 mol of silver halide in the same layer.

First Layer (Antihalation Layer) Black Colloidal Silver Silver 0.09 Gelatin 1.60 ExM-1 0.12 ExF-1 2.0 × 10 ^-3 Solid Disperse Dye ExF-2 0.030 Solid Disperse Dye ExF-3 0.040 HBS-1 0.15 HBS- 2 0.02

Second layer (intermediate layer) Silver iodobromide emulsion M Silver 0.065 ExC-2 0.04 Polyethyl acrylate latex 0.20 Gelatin 1.04

Third Layer (Low Sensitivity Red Sensitive Emulsion Layer) Silver iodobromide Emulsion A Silver 0.25 Silver iodobromide Emulsion B Silver 0.25 ExS-1 6.9 × 10 ^-5 ExS-2 1.8 × 10 ^-5 ExS-3 3.1 × 10 ^-4 ExC-1 0.17 ExC-3 0.030 ExC-4 0.10 ExC-5 0.020 ExC-6 0.010 Cpd-2 0.025 HBS-1 0.10 Gelatin 0.87

Fourth Layer (Medium Sensitivity Red Sensitive Emulsion Layer) Silver Iodobromide Emulsion C Silver 0.70 ExS-1 3.5 × 10 ^-4 ExS-2 1.6 × 10 ^-5 ExS-3 5.1 × 10 ^-4 ExC-1 0.13 ExC-2 0.060 ExC-3 0.0070 ExC-4 0.090 ExC-5 0.015 ExC-6 0.0070 Cpd-2 0.023 HBS-1 0.10 Gelatin 0.75

Fifth Layer (High Sensitivity Red Sensitive Emulsion Layer) Silver iodobromide emulsion D Silver 1.40 ExS-1 2.4 × 10 ^-4 ExS-2 1.0 × 10 ^-4 ExS-3 3.4 × 10 ^-4 ExC-1 0.10 ExC-3 0.045 ExC-6 0.020 ExC-7 0.010 Cpd-2 0.050 HBS-1 0.22 HBS-2 0.050 Gelatin 1.10

Sixth layer (intermediate layer) Cpd-1 0.090 Solid disperse dye ExF-4 0.030 HBS-1 0.050 Polyethyl acrylate latex 0.15 Gelatin 1.10

Seventh Layer (Low Sensitivity Green Sensitive Emulsion Layer) Silver iodobromide Emulsion E 0.15 Silver iodobromide Emulsion F Silver 0.10 Silver iodobromide Emulsion G Silver 0.10 ExS-4 3.0 × 10 ^-5 ExS-5 2.1 × 10 ^-4 ExS-6 8.0 × 10 ^-4 ExM-2 0.33 ExM-3 0.086 ExY-1 0.015 HBS-1 0.30 HBS-3 0.010 Gelatin 0.73

Eighth Layer (Medium Sensitivity Green Sensitive Emulsion Layer) Silver Iodobromide Emulsion H Silver 0.80 ExS-4 3.2 × 10 ^-5 ExS-5 2.2 × 10 ^-4 ExS-6 8.4 × 10 ^-4 ExC-8 0.010 ExM-2 0.10 ExM-3 0.025 ExY-1 0.018 ExY-4 0.010 ExY-5 0.040 HBS-1 0.13 HBS-3 4.0 × 10 ^-3 Gelatin 0.80

Ninth layer (high-sensitivity green sensitive emulsion layer) Silver iodobromide emulsion I Silver 1.25 ExS-4 3.7 × 10 ^-5 ExS-5 8.1 × 10 ^-5 ExS-6 3.2 × 10 ^-4 ExC-1 0.010 ExM-1 0.020 ExM-4 0.025 ExM-5 0.040 Cpd-3 0.040 HBS-1 0.25 Polyethyl acrylate latex 0.15 Gelatin 1.33

10th layer (yellow filter layer) Yellow colloidal silver Silver 0.015 Cpd-1 0.16 Solid disperse dye ExF-5 0.060 Solid disperse dye ExF-6 0.060 Oil soluble dye ExF-7 0.010 HBS-1 0.60 Gelatin 0.60

11th layer (low-sensitivity blue-sensitive emulsion layer) Silver iodobromide emulsion J Silver 0.09 Silver iodobromide emulsion K Silver 0.09 ExS-7 8.6 × 10 ^-4 ExC-8 7.0 × 10 ^-3 ExY-1 0.050 ExY-2 0.32 ExY-3 0.40 ExY-4 0.016 Cpd-2 0.10 Cpd-3 4.0 × 10 ^-3 HBS-1 0.28 Gelatin 1.20

12th layer (high-sensitivity blue-sensitive emulsion layer) Silver iodobromide emulsion L Silver 1.00 ExS-7 4.0 × 10 ^-4 ExY-2 0.10 ExY-3 0.10 ExY-4 0.008 Cpd-2 0.10 Cpd-3 1.0 × 10 ^-3 HBS-1 0.070 Gelatin 0.70

13th layer (first protective layer) UV-1 0.19 UV-2 0.075 UV-3 0.065 F-18 0.020 F-19 0.012 F-20 0.003 F-21 0.003 HBS-1 5.0 × 10 ^-2 HBS- 4 5.0 × 10 ^-2 Gelatin 1.8

14th layer (second protective layer) Silver iodobromide emulsion M Silver 0.10 H-1 0.40 B-1 (diameter 1.7 μm) 5.0 × 10 ^-2 B-2 (diameter 1.7 μm) 0.15 B-3 0.13 S-1 0.20 Gelatin 0.70

Further, in order to improve storage stability, processability, pressure resistance, antifungal / antibacterial property, antistatic property and coating property, each layer may be provided with W-1 to W-3, B-4 to B-. 6, F
-1 to F-21 and iron salt, lead salt, gold salt, platinum salt,
It contains a palladium salt, an iridium salt, and a rhodium salt.

[0242]

[Table 3]

In Table 3, (1) Emulsions G to L were reduction-sensitized at the time of grain preparation using thiourea dioxide and thiosulfonic acid according to the examples of JP-A-2-91938. (2) Emulsions A to L were subjected to gold sensitization, sulfur sensitization and selenium sensitization in the presence of the spectral sensitizing dye described in each photosensitive layer and sodium thiocyanate according to the examples of JP-A-3-237450. ing. (3) For the preparation of tabular grains, low molecular weight gelatin is used according to the example of JP-A 1-158426. (4) Dislocation lines as described in JP-A-3-237450 are observed in the tabular grains using a high voltage electron microscope.

Preparation of Dispersion of Organic Solid Disperse Dye ExF-3 shown below was dispersed by the following method. That is, water and 200 g of Pluronic F88 (ethylene oxide-propylene oxide block copolymer) manufactured by BASF were added to 1430 g of a wet cake of a dye containing 30% of methanol, followed by stirring to obtain a slurry having a dye concentration of 6%. Next, 1700 ml of zirconia beads having an average particle diameter of 0.5 mm was added to Ultra Visco Mill (UVM-2) manufactured by IMEX Co., Ltd.
It was filled and pulverized through the slurry at a peripheral speed of about 10 m / sec and a discharge rate of 0.51 / min for 8 hours. The beads were removed by filtration, diluted with water to a dye concentration of 3% by adding water, and then heated at 90 ° C. for 10 hours for stabilization. The average particle size of the obtained dye fine particles was 0.60 μm, and the breadth of the particle size distribution (particle size standard deviation × 100 / average particle size) was 18%.

Similarly, ExF-4, ExF-5, E
A solid dispersion of xF-6 was obtained. The average particle size of the fine dye particles is 0.45 μm, 0.54 μm, and 0.52 μm, respectively.
Met. ExF-2 was dispersed by the fine precipitation dispersion method by pH shift described in the Example of JP-A-3-182743. The average particle size of the dye fine particles was 0.05 μm. The compounds used above are shown below.

[0246]

Embedded image

[0247]

Embedded image

[0248]

Embedded image

[0249]

[Chemical 51]

[0250]

Embedded image

[0251]

Embedded image

[0252]

Embedded image

[0253]

Embedded image

[0254]

Embedded image

[0255]

Embedded image

[0256]

Embedded image

[0257]

Embedded image

[0258]

Embedded image

[0259]

[Chemical formula 61]

[0260]

Embedded image

[0261]

Embedded image

[0262]

Embedded image

Next, Sample 202 is the eleventh blue-sensitive emulsion layer.
Comparative compound (A) was used in the 11th and 11th layers.
0.7 mg / m ^2, the twelfth layer to prepare a sample was added to a coating amount of 3.1 mg / m ^2. Sample 203 is sample 2
The comparative compound (A) used in No. 02 was used as the compound of the present invention (A
-15) was replaced by an equimolar amount. Sample 204 ~
Reference numeral 206 denotes the coupler ExY-3 used in the eleventh and twelfth layers of Samples 201 to 203 and the coupler Y-29 of the present invention.
Were replaced by equimolar amounts. Sample 207-
209 is the coupler ExY-4 used for the eleventh and twelfth layers of Samples 201 to 203 and the coupler YB-3 of the present invention.
3 was produced by substituting 3 in equimolar amounts. Sample 210
-212 were prepared by replacing the coupler ExY-4 used in the 11th and 12th layers of Samples 204-206 with the equimolar amount of YB-33 used in Samples 207-209, respectively. However, the sample 208 was prepared by replacing the comparative compound (A) with the comparative compound (B). The comparative compound (B) is the same compound as F-11 described in Chemical Formula 63 and is a compound corresponding to the compound (1) in the above-cited Japanese Patent Application Laid-Open No. 59-162546. After Sample 213, as shown in Table 5, the couplers of the 11th and 12th layers and the compound of the present invention were changed, and all were replaced by equimolar amounts to prepare Samples 220 to 220. Samples 219 and 2
No. 20 was prepared by adding Compound A-15 of the present invention to the 10th layer (yellow filter layer) so that the coating amount was 5.0 mg / m ² .

The photosensitive material produced as described above is used for 24 mm
The photosensitive material is cut to a width of 160 cm, and two perforations of 2 mm square are provided at a distance of 5.8 mm 0.7 mm from one side in the length direction of the photosensitive material. A set in which these two sets were provided at intervals of 32 mm was prepared and housed in the plastic film cartridge shown in FIG. The diameter of the winding core is 7 mm, and the number of windings is 32 rounds. A head gap of 5 μ was applied to this sample from the coated surface side of the magnetic recording layer.
An FM signal was recorded at a feed rate of 1,000 / s during the above-mentioned perforation of the light-sensitive material using a head capable of inputting and outputting of m and 2,000 turns.

The following performance evaluations were carried out on these light-sensitive materials. (1) Coloring property After storing each light-sensitive material at 40 ° C. and 70% relative humidity for 7 days,
When the film sample was taken out from the cartridge and wound into the cartridge, the portion located outside was cut out, and these film samples were exposed to white light (color temperature of light source: 4800 ° K) through a wedge for sensitometry, and described in Example 1. Color development processing was performed. The developed sample is subjected to B density measurement, and from the characteristic curve thereof, (a) as a sensitivity, a logarithmic value of the reciprocal of the exposure amount giving the density of the minimum density + 0.5 is obtained. For samples 204 to 206, sample 2
04, Samples 207 to 209 are Samples 207,
The difference (ΔS) between the sensitivity values within the group was calculated with reference to the sample 210 for the samples 210 to 212 and the sample 210 for the samples 213 to 220. The larger the value, the higher the altitude and the greater the effect of color development. (b) Connect two points giving the minimum density +0.5 and the minimum density +1.5 with a straight line, obtain the gradient, and set it as the gradation, and in the same way as above, calculate the ratio (γ) of the gradation within the group. It was calculated.

(2) Pressure fog A cartridge containing a sample was placed at 70 ° C. and a relative humidity of 65.
%, The film sample was taken out from the cartridge, and the color development process described in Example 1 was performed without exposing each sample. For each of the developed film samples, the B concentration was measured from the tip to the end of each sample, the maximum density value and the minimum density value in each sample were obtained, and the difference (ΔD) between the density values was calculated. In each case, the inside (winding core) wound in the cartridge had a higher density value than the outside. The results obtained in these (1) and (2) are summarized in Tables 4 and 5.

[0267]

[Table 4]

[0268]

[Table 5]

From the table, the acylacetamide type coupler having an acyl group represented by the general formula (YI) of the present invention and / or the coupler represented by the general formula (1) or (2) and the general formula (AI) are shown. ) To (A-III) in combination with Samples 206, 209, 212 and 213 to 220 give higher sensitivity and gradation than other comparative samples, exhibit excellent color developability, and are sensitive to light. It can be seen that the effect of remarkably preventing the pressure fog that occurs when the material is rolled long and stored at high temperature is shown.

[0270]

According to the present invention, at least one layer of a silver halide color photographic light-sensitive material comprising at least one light-sensitive silver halide emulsion layer and at least one light-insensitive layer is used as a light-sensitive material of the general formula (AI). By incorporating a compound selected from (A-III) and an acylacetamide type coupler having an acyl group represented by the general formula (YI) and / or a coupler represented by the general formula (1) or (2), Provided are a silver halide color photographic light-sensitive material and a package for the light-sensitive material, which have improved color forming property, provide high sensitivity and gradation, and prevent pressure fog when the light-sensitive material is rolled up for a long time and stored at high temperature. can do.

[Brief description of drawings]

FIG. 1 is an exploded perspective view of a photographic light-sensitive material package (photographic film cartridge) according to one embodiment of the present invention.

FIG. 2 is a diagram of the photographic light-sensitive material package as viewed from a radial direction.

FIG. 3 is a view of the photographic light-sensitive material package viewed from a radial direction at a position different from that in FIG.

FIG. 4 is a view of the photographic light-sensitive material package as viewed from one side in the axial direction thereof.

FIG. 5 is a view of the photographic light-sensitive material package as seen from the other axial direction.

FIG. 6 is a sectional view of the photographic light-sensitive material package cut along the axial direction.

FIG. 7 is a diagram showing an adhesive label stock sheet with release paper.

[Explanation of symbols]

 100 Photo Film Patrone 101 Patrone Main Body 102 Photo Film 103 Spool 104 Patrone Label 105 Upper Case 106 Lower Case 107 Film Feed Out Port 108 Lid Member 109 Separation Claw 110 Key Groove 111 Key Groove 112 Spool Shaft 113 Flange 114 Flange 115 Data Disc 116 Bar Code Label 117 Flange engaging portion 118 Flange engaging portion 119 Slit 120 Use display member support portion 121 Key groove 122 Key groove 123 Use display member 124 Bearing portion 125 Ratchet pawl 126 Gear 127 Display plate 128 Spool lock 129 Round hole 130 Round hole 131 Opening edge 132 Opening edge 133 Hole 134 Large-diameter fan-shaped portion 135 Notch 136 Opening 137 Opening 138 Displaying opening 139 Table Display opening 140 Display opening 141 Display opening 142 Film roll 143 Film tip 144 Rock paw 145 Sensitivity detection notch 146 Opening 147 Developed display tab 150 Gate 151 ID number printing space 152 Variety printing space 153 Bar code printing space

Claims (3)

[Claims] 1. A silver halide color photographic light-sensitive material having a photosensitive layer comprising at least one photosensitive silver halide emulsion layer and at least one non-photosensitive layer on one side of a support. Of at least one layer of the general formula (A
-I), an acylacetamide type coupler containing a compound selected from the general formula (A-II) or the general formula (A-III) and having an acyl group represented by the general formula (YI) and / or the general formula A silver halide color photographic light-sensitive material comprising a coupler represented by (1) or the general formula (2). Embedded image In the general formula (AI), _Ra1 represents an alkyl group, an alkenyl group, an aryl group, an acyl group, an alkyl or arylsulfonyl group, an alkyl or arylsulfinyl group,
A carbamoyl group, a sulfamoyl group, an alkoxycarbonyl group or an aryloxycarbonyl group;
_a2 represents a hydrogen atom or a group represented by R _a1 . However,
When R _a1 is an alkyl group, an alkenyl group or an aryl group, R _a2 is an acyl group, an alkyl or arylsulfonyl group, an alkyl or arylsulfinyl group, a carbamoyl group, a sulfamoyl group, an alkoxycarbonyl group or an aryloxycarbonyl group. R _a1 and R _a2 may combine with each other to form a 5- to 7-membered ring, provided that S-
It does not form a triazine ring. General formula (A-II)
In, X represents a heterocyclic group excluding the S-triazine ring, and R _b1 represents an alkyl group, an alkenyl group or an aryl group. X and R _b1 may combine with each other to form a 5- to 7-membered ring, but they do not form an S-triazine ring. In the general formula (A-III), Y represents a nonmetallic atom group necessary for forming a 5-membered ring together with -N = C-. Y represents a group of non-metal atoms necessary for forming a 6-membered ring together with a -N = C- group, and the terminal of Y bonded to the carbon atom of the -N = C- group is -N (R _c1 ). -, -C (R _c2 ) (R _c3 )
_Represents a group selected _from- , -C (R _c4 ) =, -O-, and -S- (bonds to the carbon atom of -N = C- on the left side of each group). However, it does not form an S-triazine ring.
R _{c1 to} R _c4 represent a hydrogen atom or a substituent. General formula (YI) In the formula, R ₁ represents a substituent, Q together with C is a 3- to 5-membered hydrocarbon ring or a 3- to 6-membered hydrocarbon ring having at least one hetero atom selected from N, O, S, and P in the ring. Represents a group of non-metal atoms necessary to form a heterocycle. General formula (1) General formula (2) In the formula, X ₁ and X ₂ each represent an alkyl group, an aryl group or a heterocyclic group, X ₃ represents an organic residue forming a nitrogen-containing heterocyclic group with> N-, and Y represents an aryl group or a heterocyclic group. Represents a group, and Z represents a group which leaves when the coupler represented by the general formula reacts with an oxidized product of a developing agent. 2. A silver halide color photograph according to claim 1, further comprising a magnetic recording layer containing magnetic particles in a back layer opposite to the side having the photosensitive layer and the support. Photosensitive material. 3. A cartridge main body 101 is internally rotatably accommodated in a spool 103 around which a photographic light-sensitive material 102 having an emulsion layer provided on a support is wound, and the tip of the photographic light-sensitive material is freely rotated by the rotation of the spool. The cartridge main body has a photographic light-sensitive material feed-out passage having a light-shielding mechanism for feeding out the photographic light-sensitive material, and a pair of flanges 113 with lips are respectively provided inside both ends of the spool shaft 112 of the spool. , 11
4. A photographic light-sensitive material package 100 in which 4 is attached for holding a photographic light-sensitive material, wherein the photographic light-sensitive material is the silver halide photographic light-sensitive material according to claim 1 or 2. Material packaging.