JPH07503993A - コーキングの少ない熱分解方法 - Google Patents
コーキングの少ない熱分解方法Info
- Publication number
- JPH07503993A JPH07503993A JP6515179A JP51517994A JPH07503993A JP H07503993 A JPH07503993 A JP H07503993A JP 6515179 A JP6515179 A JP 6515179A JP 51517994 A JP51517994 A JP 51517994A JP H07503993 A JPH07503993 A JP H07503993A
- Authority
- JP
- Japan
- Prior art keywords
- furnace
- tube
- pyrolysis
- phosphorus
- olefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 64
- 238000000197 pyrolysis Methods 0.000 title claims description 60
- 238000004939 coking Methods 0.000 title description 11
- 150000001336 alkenes Chemical class 0.000 claims description 86
- 239000000571 coke Substances 0.000 claims description 75
- 239000003795 chemical substances by application Substances 0.000 claims description 58
- 229910052751 metal Inorganic materials 0.000 claims description 55
- 239000002184 metal Substances 0.000 claims description 55
- 229930195733 hydrocarbon Natural products 0.000 claims description 51
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 51
- 150000002430 hydrocarbons Chemical class 0.000 claims description 50
- 239000004215 Carbon black (E152) Substances 0.000 claims description 48
- 238000004519 manufacturing process Methods 0.000 claims description 45
- 229910052698 phosphorus Inorganic materials 0.000 claims description 40
- 239000011574 phosphorus Substances 0.000 claims description 40
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 37
- 230000003197 catalytic effect Effects 0.000 claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 23
- 238000005336 cracking Methods 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000003054 catalyst Substances 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- DQNJHGSFNUDORY-UHFFFAOYSA-N bis(2-ethylhexoxy)-sulfanyl-sulfanylidene-$l^{5}-phosphane Chemical group CCCCC(CC)COP(S)(=S)OCC(CC)CCCC DQNJHGSFNUDORY-UHFFFAOYSA-N 0.000 claims description 7
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 2
- 150000002894 organic compounds Chemical class 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 21
- 230000008569 process Effects 0.000 description 21
- 238000005262 decarbonization Methods 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 17
- 238000005235 decoking Methods 0.000 description 16
- 241000196324 Embryophyta Species 0.000 description 15
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 15
- 239000005977 Ethylene Substances 0.000 description 15
- 239000002519 antifouling agent Substances 0.000 description 14
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 10
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 10
- 238000005755 formation reaction Methods 0.000 description 10
- 239000003112 inhibitor Substances 0.000 description 10
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- -1 crack down hydrocarbon Chemical class 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 238000012546 transfer Methods 0.000 description 8
- 229910019142 PO4 Inorganic materials 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 5
- XQNIYBBHBZAQEC-UHFFFAOYSA-N diphosphorus trisulphide Chemical compound S=PSP=S XQNIYBBHBZAQEC-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 238000005984 hydrogenation reaction Methods 0.000 description 4
- 238000002386 leaching Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000002161 passivation Methods 0.000 description 4
- 235000011007 phosphoric acid Nutrition 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 150000005690 diesters Chemical class 0.000 description 3
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical class OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- 238000012935 Averaging Methods 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VKCLPVFDVVKEKU-UHFFFAOYSA-N S=[P] Chemical compound S=[P] VKCLPVFDVVKEKU-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229910001026 inconel Inorganic materials 0.000 description 2
- 229910001055 inconels 600 Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 159000000003 magnesium salts Chemical class 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 230000003446 memory effect Effects 0.000 description 2
- 238000005272 metallurgy Methods 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- KPSSIOMAKSHJJG-UHFFFAOYSA-N neopentyl alcohol Chemical compound CC(C)(C)CO KPSSIOMAKSHJJG-UHFFFAOYSA-N 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 150000003003 phosphines Chemical class 0.000 description 2
- 150000003018 phosphorus compounds Chemical class 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- SMQUZDBALVYZAC-UHFFFAOYSA-N salicylaldehyde Chemical class OC1=CC=CC=C1C=O SMQUZDBALVYZAC-UHFFFAOYSA-N 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000004227 thermal cracking Methods 0.000 description 2
- YWWDBCBWQNCYNR-UHFFFAOYSA-N trimethylphosphine Chemical compound CP(C)C YWWDBCBWQNCYNR-UHFFFAOYSA-N 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical group CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 1
- WCVOGSZTONGSQY-UHFFFAOYSA-N 2,4,6-trichloroanisole Chemical compound COC1=C(Cl)C=C(Cl)C=C1Cl WCVOGSZTONGSQY-UHFFFAOYSA-N 0.000 description 1
- YGMLOGWOEDZXIJ-UHFFFAOYSA-N 2-ethylhexylsulfanyl-dihydroxy-sulfanylidene-$l^{5}-phosphane Chemical compound CCCCC(CC)CSP(O)(O)=S YGMLOGWOEDZXIJ-UHFFFAOYSA-N 0.000 description 1
- MEEKGULDSDXFCN-UHFFFAOYSA-N 2-pentylphenol Chemical compound CCCCCC1=CC=CC=C1O MEEKGULDSDXFCN-UHFFFAOYSA-N 0.000 description 1
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 241000609816 Pantholops hodgsonii Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- GMSOIBLTSDGVEX-UHFFFAOYSA-N dimethyl propyl phosphate Chemical compound CCCOP(=O)(OC)OC GMSOIBLTSDGVEX-UHFFFAOYSA-N 0.000 description 1
- YOTZYFSGUCFUKA-UHFFFAOYSA-N dimethylphosphine Chemical compound CPC YOTZYFSGUCFUKA-UHFFFAOYSA-N 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- SAWKFRBJGLMMES-UHFFFAOYSA-N methylphosphine Chemical compound PC SAWKFRBJGLMMES-UHFFFAOYSA-N 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 230000001483 mobilizing effect Effects 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- RPGWZZNNEUHDAQ-UHFFFAOYSA-N phenylphosphine Chemical compound PC1=CC=CC=C1 RPGWZZNNEUHDAQ-UHFFFAOYSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 150000003017 phosphorus Chemical class 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- OKQKDCXVLPGWPO-UHFFFAOYSA-N sulfanylidenephosphane Chemical compound S=P OKQKDCXVLPGWPO-UHFFFAOYSA-N 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- VYNGFCUGSYEOOZ-UHFFFAOYSA-N triphenylphosphine sulfide Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=S)C1=CC=CC=C1 VYNGFCUGSYEOOZ-UHFFFAOYSA-N 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- 235000011178 triphosphate Nutrition 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G9/14—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils in pipes or coils with or without auxiliary means, e.g. digesters, soaking drums, expansion means
- C10G9/16—Preventing or removing incrustation
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US99271992A | 1992-12-18 | 1992-12-18 | |
| US992,719 | 1992-12-18 | ||
| PCT/US1993/011730 WO1994014923A1 (en) | 1992-12-18 | 1993-12-09 | Thermal cracking process with reduced coking |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH07503993A true JPH07503993A (ja) | 1995-04-27 |
Family
ID=25538658
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6515179A Pending JPH07503993A (ja) | 1992-12-18 | 1993-12-09 | コーキングの少ない熱分解方法 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US5446229A (enExample) |
| EP (1) | EP0626990A1 (enExample) |
| JP (1) | JPH07503993A (enExample) |
| KR (1) | KR950700381A (enExample) |
| CN (1) | CN1096285A (enExample) |
| AU (1) | AU5684994A (enExample) |
| BG (1) | BG98987A (enExample) |
| BR (1) | BR9305912A (enExample) |
| CA (1) | CA2117493A1 (enExample) |
| CZ (1) | CZ199494A3 (enExample) |
| HU (1) | HUT67948A (enExample) |
| PL (1) | PL304810A1 (enExample) |
| RU (1) | RU94042400A (enExample) |
| SK (1) | SK98794A3 (enExample) |
| TW (1) | TW250478B (enExample) |
| WO (1) | WO1994014923A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013508506A (ja) * | 2009-10-21 | 2013-03-07 | ナルコ カンパニー | ファウリングを抑制するための表面不動態化法 |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4332473C2 (de) * | 1993-09-24 | 1995-09-14 | Krupp Vdm Gmbh | Katalysator für die Hydroraffination von Kohlenwasserstoffgemischen und seine Verwendung |
| US5500107A (en) * | 1994-03-15 | 1996-03-19 | Betz Laboratories, Inc. | High temperature corrosion inhibitor |
| US5656150A (en) * | 1994-08-25 | 1997-08-12 | Phillips Petroleum Company | Method for treating the radiant tubes of a fired heater in a thermal cracking process |
| US5863416A (en) * | 1996-10-18 | 1999-01-26 | Nalco/Exxon Energy Chemicals, L.P. | Method to vapor-phase deliver heater antifoulants |
| WO1998055563A2 (en) * | 1997-06-05 | 1998-12-10 | Atf Resources, Inc. | Method and apparatus for removing and suppressing coke formation during pyrolysis |
| US5954943A (en) * | 1997-09-17 | 1999-09-21 | Nalco/Exxon Energy Chemicals, L.P. | Method of inhibiting coke deposition in pyrolysis furnaces |
| BR9812738A (pt) | 1997-10-08 | 2000-08-29 | Shell Int Research | Aquecedor de processo, e, processo para proporcionar calor a uma reação de processo |
| US5944981A (en) * | 1997-10-28 | 1999-08-31 | The M. W. Kellogg Company | Pyrolysis furnace tubes |
| US6852213B1 (en) * | 1999-09-15 | 2005-02-08 | Nalco Energy Services | Phosphorus-sulfur based antifoulants |
| US6830676B2 (en) * | 2001-06-11 | 2004-12-14 | Chrysalis Technologies Incorporated | Coking and carburization resistant iron aluminides for hydrocarbon cracking |
| US6648988B2 (en) * | 2001-08-17 | 2003-11-18 | Exxonmobil Research And Engineering Company | Furnace run length extension by fouling control |
| KR100645660B1 (ko) * | 2001-11-09 | 2006-11-13 | 에스케이 주식회사 | 탄화수소 유분으로부터 노말파라핀을 분리하는 공정 및분리된 유분의 활용 |
| US20030234171A1 (en) * | 2002-06-19 | 2003-12-25 | Owen Steven A. | Cracking furnace antifoulant injection system |
| US7125483B2 (en) * | 2003-04-10 | 2006-10-24 | Equistar Chemicals, Lp | Corrosion control in olefin production plants |
| MX2007010987A (es) * | 2005-03-10 | 2007-09-25 | Shell Int Research | Metodo para iniciar un sistema de calentamiento directo para la combustion sin flama de combustible, y el calentamiento directo de un fluido de proceso. |
| BRPI0608336B1 (pt) * | 2005-03-10 | 2018-09-11 | Shell Int Research | sistema de processamento, sistema de aquecimento direto de quatro tubos para queima de um combustível e aquecimento direto de um fluido de processamento e método |
| CN101163918A (zh) * | 2005-03-10 | 2008-04-16 | 国际壳牌研究有限公司 | 一种用于燃料燃烧和加热工艺流体的传热系统以及使用该系统的工艺 |
| KR100746583B1 (ko) | 2006-09-05 | 2007-08-06 | 엘지석유화학 주식회사 | 코크 저감용 탄화수소 열분해 반응장치 및 코크의 저감방법 |
| CN101679879B (zh) * | 2007-05-07 | 2013-03-13 | 鲁姆斯科技公司 | 乙烯炉辐射段炉管除焦方法 |
| JP2010534311A (ja) * | 2007-07-20 | 2010-11-04 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 無炎燃焼加熱器 |
| WO2009014979A2 (en) * | 2007-07-20 | 2009-01-29 | Shell Oil Company | A flameless combustion heater |
| US20090022635A1 (en) * | 2007-07-20 | 2009-01-22 | Selas Fluid Processing Corporation | High-performance cracker |
| JP5336595B2 (ja) | 2008-08-08 | 2013-11-06 | ケーシーアイ ライセンシング インコーポレイテッド | リザーバ制御付減圧治療システム |
| US8002951B2 (en) * | 2008-09-05 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Furnace and process for incinerating a decoke effluent in a twin-tube-plane furnace |
| US8684384B2 (en) | 2009-01-05 | 2014-04-01 | Exxonmobil Chemical Patents Inc. | Process for cracking a heavy hydrocarbon feedstream |
| US20110014372A1 (en) * | 2009-07-15 | 2011-01-20 | Webber Kenneth M | Passivation of thermal cracking furnace conduit |
| US8906822B2 (en) * | 2012-06-01 | 2014-12-09 | BASF Qtech, Inc. | Catalytic surfaces and coatings for the manufacture of petrochemicals |
| US20160231219A1 (en) * | 2013-09-20 | 2016-08-11 | Shell Oil Company | Method of detecting flow status in an olefin heater tube |
| US10219814B2 (en) | 2013-12-13 | 2019-03-05 | Rex Medical, L.P. | Aspiration system for thrombectomy procedures |
| WO2015181638A1 (en) * | 2014-05-28 | 2015-12-03 | Sabic Global Technologies B.V. | Ethylene furnace process and system |
| US9845437B2 (en) | 2015-02-12 | 2017-12-19 | Ecolab Usa Inc. | Surface passivation method for fouling reduction |
| CN109562360A (zh) | 2016-07-29 | 2019-04-02 | 巴斯夫库德克有限公司 | 催化涂层、其制备方法及其用途 |
| CA2962667C (en) * | 2017-03-30 | 2024-03-19 | Nova Chemicals Corporation | Decoking process |
| CN111712558B (zh) * | 2017-12-29 | 2022-06-14 | 埃克森美孚化学专利公司 | 烃热解中的焦炭减轻 |
| CA3033604C (en) * | 2019-02-12 | 2022-12-13 | Michael KOSELEK | Decoking process |
| EP3976736A4 (en) * | 2019-05-24 | 2023-04-12 | Eastman Chemical Company | THERMAL PYROLYTIC OIL TO A GAS-FED CRACKER FURNACE |
| US11365357B2 (en) | 2019-05-24 | 2022-06-21 | Eastman Chemical Company | Cracking C8+ fraction of pyoil |
| CN114846119A (zh) | 2019-10-31 | 2022-08-02 | 伊士曼化工公司 | 用于形成再循环物烃组合物的方法和系统 |
| CN120484846A (zh) | 2019-10-31 | 2025-08-15 | 伊士曼化工公司 | 用于形成回收成分烃组合物的方法和系统 |
| EP4051760A4 (en) * | 2019-10-31 | 2024-03-20 | Eastman Chemical Company | METHODS AND SYSTEMS FOR THE FORMATION OF HYDROCARBON COMPOSITIONS WITH RECYCLED CONTENT |
| CN117264654A (zh) * | 2023-10-16 | 2023-12-22 | 金浦新材料股份有限公司 | 一种新型乙烯裂解抑焦剂及其制备方法和应用 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2092626A1 (en) * | 1970-06-02 | 1972-01-28 | Exxon Research Engineering Co | Cracking petroleum-steam mixture - with addn of phosphorus or bismuth cpd to suppress coking and carbon monoxide formation |
| US4321128A (en) * | 1980-05-19 | 1982-03-23 | Atlantic Richfield Company | Phosphorus passivation process |
| US4542253A (en) * | 1983-08-11 | 1985-09-17 | Nalco Chemical Company | Use of phosphate and thiophosphate esters neutralized with water soluble amines as ethylene furnace anti-coking antifoulants |
| US4551227A (en) * | 1984-04-16 | 1985-11-05 | Phillips Petroleum Company | Antifoulants for thermal cracking processes |
| US4599480A (en) * | 1985-07-12 | 1986-07-08 | Shell Oil Company | Sequential cracking of hydrocarbons |
| US5000836A (en) * | 1989-09-26 | 1991-03-19 | Betz Laboratories, Inc. | Method and composition for retarding coke formation during pyrolytic hydrocarbon processing |
| US5171921A (en) * | 1991-04-26 | 1992-12-15 | Arco Chemical Technology, L.P. | Production of olefins |
| US5284994A (en) * | 1993-01-13 | 1994-02-08 | Phillips Petroleum Company | Injection of antifoulants into thermal cracking reactors |
-
1993
- 1993-12-09 EP EP94902493A patent/EP0626990A1/en not_active Ceased
- 1993-12-09 CA CA002117493A patent/CA2117493A1/en not_active Abandoned
- 1993-12-09 US US08/162,025 patent/US5446229A/en not_active Expired - Fee Related
- 1993-12-09 RU RU94042400/26A patent/RU94042400A/ru unknown
- 1993-12-09 KR KR1019940702888A patent/KR950700381A/ko not_active Withdrawn
- 1993-12-09 PL PL93304810A patent/PL304810A1/xx unknown
- 1993-12-09 JP JP6515179A patent/JPH07503993A/ja active Pending
- 1993-12-09 HU HU9402385A patent/HUT67948A/hu unknown
- 1993-12-09 CZ CZ941994A patent/CZ199494A3/cs unknown
- 1993-12-09 WO PCT/US1993/011730 patent/WO1994014923A1/en not_active Ceased
- 1993-12-09 AU AU56849/94A patent/AU5684994A/en not_active Abandoned
- 1993-12-09 BR BR9305912A patent/BR9305912A/pt not_active Application Discontinuation
- 1993-12-09 SK SK987-94A patent/SK98794A3/sk unknown
- 1993-12-18 CN CN93120761A patent/CN1096285A/zh active Pending
- 1993-12-18 TW TW082110763A patent/TW250478B/zh active
-
1994
- 1994-08-18 BG BG98987A patent/BG98987A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013508506A (ja) * | 2009-10-21 | 2013-03-07 | ナルコ カンパニー | ファウリングを抑制するための表面不動態化法 |
Also Published As
| Publication number | Publication date |
|---|---|
| BG98987A (en) | 1995-06-30 |
| BR9305912A (pt) | 1997-08-19 |
| SK98794A3 (en) | 1995-06-07 |
| US5446229A (en) | 1995-08-29 |
| CN1096285A (zh) | 1994-12-14 |
| WO1994014923A1 (en) | 1994-07-07 |
| KR950700381A (ko) | 1995-01-16 |
| HUT67948A (en) | 1995-05-29 |
| HU9402385D0 (en) | 1994-11-28 |
| RU94042400A (ru) | 1996-07-27 |
| CA2117493A1 (en) | 1994-07-07 |
| EP0626990A1 (en) | 1994-12-07 |
| AU5684994A (en) | 1994-07-19 |
| TW250478B (enExample) | 1995-07-01 |
| CZ199494A3 (en) | 1995-03-15 |
| PL304810A1 (en) | 1995-01-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH07503993A (ja) | コーキングの少ない熱分解方法 | |
| US4024049A (en) | Mono and di organophosphite esters as crude oil antifoulants | |
| US4024050A (en) | Phosphorous ester antifoulants in crude oil refining | |
| EP0158968B1 (en) | Antifoulants for thermal cracking processes | |
| US5552085A (en) | Phosphorus thioacid ester inhibitor for naphthenic acid corrosion | |
| EP0086461A1 (en) | A process for reducing the formation of coke in a thermal cracking process and antifoulant composition | |
| EP0473170A1 (en) | Antifoulants comprising titanium for thermal cracking processes | |
| EP0241845B1 (en) | Antifoulants for thermal cracking processes | |
| EP0698652A1 (en) | Method for treating the radiant tubes of a fired heater in a thermal cracking process | |
| AU660867B2 (en) | Phosphorothioate coking inhibitors | |
| US5954943A (en) | Method of inhibiting coke deposition in pyrolysis furnaces | |
| EP0242693B1 (en) | Antifoulants for thermal cracking processes | |
| US6852213B1 (en) | Phosphorus-sulfur based antifoulants | |
| JPH06228018A (ja) | 水蒸気分解炉の汚れ及びコークス生成を減らす方法 | |
| PL180515B1 (pl) | Sposób zmniejszenia zanieczyszczenia nagarem powierzchni wymiany ciepla PL | |
| US5779881A (en) | Phosphonate/thiophosphonate coking inhibitors | |
| EP0714969A2 (en) | Inhibition of fouling or coke formation in hydrocarbon processing equipment | |
| JPS61166882A (ja) | 炭化水素処理プロセスのコ−キング防止方法 | |
| EP0837119A2 (en) | Method to vapor-phase deliver heater antifoulants | |
| EP0601609A1 (en) | Phosphoric triamide coking inhibitors | |
| JPH0527678B2 (enExample) | ||
| CA2155044A1 (en) | Method for promoting the spalling of coke produced during the thermal cracking of hydrocarbons |