JPH06166645A - ２，４−ジアルキル−６−第二−アルキルフェノール - Google Patents

Info

Publication number

JPH06166645A

JPH06166645A JP5197892A JP19789293A JPH06166645A JP H06166645 A JPH06166645 A JP H06166645A JP 5197892 A JP5197892 A JP 5197892A JP 19789293 A JP19789293 A JP 19789293A JP H06166645 A JPH06166645 A JP H06166645A

Authority

JP

Japan

Prior art keywords

group

formula

butyl

compound

tert

Prior art date

1992-07-15

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Pending

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• -1 α-methylbenzyl Chemical group 0.000 claims abstract description 75
• 150000001875 compounds Chemical class 0.000 claims abstract description 65
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 29
• 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 24
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 19
• 238000007254 oxidation reaction Methods 0.000 claims abstract description 17
• 230000003647 oxidation Effects 0.000 claims abstract description 15
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 14
• 239000004793 Polystyrene Substances 0.000 claims abstract description 14
• 229920002223 polystyrene Polymers 0.000 claims abstract description 13
• 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 11
• 229920006324 polyoxymethylene Polymers 0.000 claims abstract description 10
• 239000004417 polycarbonate Substances 0.000 claims abstract description 9
• 229920006380 polyphenylene oxide Polymers 0.000 claims abstract description 9
• 239000004711 α-olefin Substances 0.000 claims abstract description 9
• 239000004814 polyurethane Substances 0.000 claims abstract description 8
• 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims abstract description 8
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims abstract description 6
• 239000011368 organic material Substances 0.000 claims abstract description 6
• 229920000098 polyolefin Polymers 0.000 claims abstract description 6
• 229920002635 polyurethane Polymers 0.000 claims abstract description 6
• 229920000515 polycarbonate Polymers 0.000 claims abstract description 5
• 230000000087 stabilizing effect Effects 0.000 claims abstract description 5
• 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims abstract description 3
• 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims abstract description 3
• 229930182556 Polyacetal Natural products 0.000 claims abstract 2
• 239000010775 animal oil Substances 0.000 claims abstract 2
• 239000002480 mineral oil Substances 0.000 claims abstract 2
• 239000008158 vegetable oil Substances 0.000 claims abstract 2
• 239000000203 mixture Substances 0.000 claims description 57
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 40
• 229920001577 copolymer Polymers 0.000 claims description 38
• 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 18
• 125000000217 alkyl group Chemical group 0.000 claims description 17
• 239000000126 substance Substances 0.000 claims description 17
• 238000000034 method Methods 0.000 claims description 14
• XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 13
• 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 13
• 238000000354 decomposition reaction Methods 0.000 claims description 10
• 230000006641 stabilisation Effects 0.000 claims description 9
• 238000011105 stabilization Methods 0.000 claims description 9
• 230000005855 radiation Effects 0.000 claims description 8
• 239000004952 Polyamide Substances 0.000 claims description 7
• 229920002647 polyamide Polymers 0.000 claims description 7
• 229920000728 polyester Polymers 0.000 claims description 7
• 229920001897 terpolymer Polymers 0.000 claims description 7
• MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 4
• 229920000578 graft copolymer Polymers 0.000 claims description 3
• 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 claims description 3
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 3
• BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
• 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
• VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 1
• 229940125773 compound 10 Drugs 0.000 claims 1
• 229920005669 high impact polystyrene Polymers 0.000 claims 1
• 239000004797 high-impact polystyrene Substances 0.000 claims 1
• ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical compound C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 claims 1
• 238000002156 mixing Methods 0.000 claims 1
• 235000014593 oils and fats Nutrition 0.000 claims 1
• 150000003440 styrenes Chemical class 0.000 claims 1
• 235000013311 vegetables Nutrition 0.000 claims 1
• 239000003381 stabilizer Substances 0.000 abstract description 16
• 238000005804 alkylation reaction Methods 0.000 abstract description 3
• 230000015556 catabolic process Effects 0.000 abstract 1
• 229920006018 co-polyamide Polymers 0.000 abstract 1
• 238000006731 degradation reaction Methods 0.000 abstract 1
• 239000003925 fat Substances 0.000 abstract 1
• 235000010446 mineral oil Nutrition 0.000 abstract 1
• 235000015112 vegetable and seed oil Nutrition 0.000 abstract 1
• 229920000642 polymer Polymers 0.000 description 22
• 238000012360 testing method Methods 0.000 description 17
• LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 16
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
• 239000004743 Polypropylene Substances 0.000 description 14
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
• VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 12
• 239000003054 catalyst Substances 0.000 description 12
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 12
• 229910052757 nitrogen Inorganic materials 0.000 description 12
• 229920001155 polypropylene Polymers 0.000 description 11
• 229920001684 low density polyethylene Polymers 0.000 description 9
• 239000004702 low-density polyethylene Substances 0.000 description 9
• 229910052751 metal Inorganic materials 0.000 description 9
• 239000002184 metal Substances 0.000 description 9
• 239000003921 oil Substances 0.000 description 9
• 239000005977 Ethylene Substances 0.000 description 8
• 239000004698 Polyethylene Substances 0.000 description 8
• 239000000654 additive Substances 0.000 description 8
• GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
• 239000000243 solution Substances 0.000 description 8
• 229920005989 resin Polymers 0.000 description 7
• 239000011347 resin Substances 0.000 description 7
• WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
• 150000002148 esters Chemical class 0.000 description 6
• 229920001903 high density polyethylene Polymers 0.000 description 6
• 239000004700 high-density polyethylene Substances 0.000 description 6
• 150000002989 phenols Chemical class 0.000 description 6
• 229920000573 polyethylene Polymers 0.000 description 6
• 239000000047 product Substances 0.000 description 6
• NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 5
• 239000005062 Polybutadiene Substances 0.000 description 5
• 150000001412 amines Chemical class 0.000 description 5
• 238000006243 chemical reaction Methods 0.000 description 5
• 150000001993 dienes Chemical class 0.000 description 5
• RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
• 229920000126 latex Polymers 0.000 description 5
• 239000004816 latex Substances 0.000 description 5
• 229920002857 polybutadiene Polymers 0.000 description 5
• 239000004800 polyvinyl chloride Substances 0.000 description 5
• 229920000915 polyvinyl chloride Polymers 0.000 description 5
• 150000005846 sugar alcohols Polymers 0.000 description 5
• DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 4
• BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 4
• ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
• HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 4
• ZPIRWAHWDCHWLM-UHFFFAOYSA-N 2-dodecylsulfanylethanol Chemical compound CCCCCCCCCCCCSCCO ZPIRWAHWDCHWLM-UHFFFAOYSA-N 0.000 description 4
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
• NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
• GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 4
• 229920000877 Melamine resin Polymers 0.000 description 4
• PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
• 229920002292 Nylon 6 Polymers 0.000 description 4
• ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 4
• BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 4
• FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 4
• CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 4
• 239000008116 calcium stearate Substances 0.000 description 4
• 235000013539 calcium stearate Nutrition 0.000 description 4
• XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
• 230000000694 effects Effects 0.000 description 4
• XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 4
• DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
• SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 4
• WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 4
• 229920005862 polyol Polymers 0.000 description 4
• 150000003077 polyols Chemical class 0.000 description 4
• 235000013772 propylene glycol Nutrition 0.000 description 4
• YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 4
• ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 4
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
• 229920002554 vinyl polymer Polymers 0.000 description 4
• ZEBMSMUPGIOANU-UHFFFAOYSA-N (3,5-ditert-butyl-4-hydroxyphenyl)methylphosphonic acid Chemical compound CC(C)(C)C1=CC(CP(O)(O)=O)=CC(C(C)(C)C)=C1O ZEBMSMUPGIOANU-UHFFFAOYSA-N 0.000 description 3
• KXPXKNBDCUOENF-UHFFFAOYSA-N 2-(Octylthio)ethanol Chemical compound CCCCCCCCSCCO KXPXKNBDCUOENF-UHFFFAOYSA-N 0.000 description 3
• PCONHAXLMNWOQO-UHFFFAOYSA-N 2-dodecan-2-ylphenol Chemical compound CCCCCCCCCCC(C)C1=CC=CC=C1O PCONHAXLMNWOQO-UHFFFAOYSA-N 0.000 description 3
• LPJRTZISLDYSFG-UHFFFAOYSA-N 2-hexadecan-2-ylphenol Chemical compound CCCCCCCCCCCCCCC(C)C1=CC=CC=C1O LPJRTZISLDYSFG-UHFFFAOYSA-N 0.000 description 3
• GEXGYOKUETVDBV-UHFFFAOYSA-N 2-octadecan-2-ylphenol Chemical compound CCCCCCCCCCCCCCCCC(C)C1=CC=CC=C1O GEXGYOKUETVDBV-UHFFFAOYSA-N 0.000 description 3
• NOMBEMBZPZEHFG-UHFFFAOYSA-N 2-tetradecan-2-ylphenol Chemical compound CCCCCCCCCCCCC(C)C1=CC=CC=C1O NOMBEMBZPZEHFG-UHFFFAOYSA-N 0.000 description 3
• CKPKHTKLLYPGFM-UHFFFAOYSA-N 6,6-dimethylheptane-1,1-diol Chemical compound CC(CCCCC(O)O)(C)C CKPKHTKLLYPGFM-UHFFFAOYSA-N 0.000 description 3
• YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical compound NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 description 3
• 229920002396 Polyurea Polymers 0.000 description 3
• 239000002253 acid Substances 0.000 description 3
• PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
• 235000010354 butylated hydroxytoluene Nutrition 0.000 description 3
• 229910052799 carbon Inorganic materials 0.000 description 3
• HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 3
• 229920006226 ethylene-acrylic acid Polymers 0.000 description 3
• 229910052736 halogen Inorganic materials 0.000 description 3
• 150000002367 halogens Chemical class 0.000 description 3
• 229910052739 hydrogen Inorganic materials 0.000 description 3
• 239000003446 ligand Substances 0.000 description 3
• 229920000092 linear low density polyethylene Polymers 0.000 description 3
• 239000004707 linear low-density polyethylene Substances 0.000 description 3
• 239000000178 monomer Substances 0.000 description 3
• FPQJEXTVQZHURJ-UHFFFAOYSA-N n,n'-bis(2-hydroxyethyl)oxamide Chemical compound OCCNC(=O)C(=O)NCCO FPQJEXTVQZHURJ-UHFFFAOYSA-N 0.000 description 3
• VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
• 150000002815 nickel Chemical class 0.000 description 3
• TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
• 229920000647 polyepoxide Polymers 0.000 description 3
• 229920000570 polyether Polymers 0.000 description 3
• 239000005056 polyisocyanate Substances 0.000 description 3
• 229920001228 polyisocyanate Polymers 0.000 description 3
• 238000006116 polymerization reaction Methods 0.000 description 3
• QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
• 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
• 150000003839 salts Chemical class 0.000 description 3
• 238000003756 stirring Methods 0.000 description 3
• 238000004383 yellowing Methods 0.000 description 3
• HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 2
• 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 2
• HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
• KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 2
• BVUXDWXKPROUDO-UHFFFAOYSA-N 2,6-di-tert-butyl-4-ethylphenol Chemical compound CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 BVUXDWXKPROUDO-UHFFFAOYSA-N 0.000 description 2
• SLUKQUGVTITNSY-UHFFFAOYSA-N 2,6-di-tert-butyl-4-methoxyphenol Chemical compound COC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SLUKQUGVTITNSY-UHFFFAOYSA-N 0.000 description 2
• OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
• YTHQTKBAVNQRFN-UHFFFAOYSA-N 2-cyano-3-(4-methoxyphenyl)but-2-enoic acid Chemical compound COC1=CC=C(C(C)=C(C#N)C(O)=O)C=C1 YTHQTKBAVNQRFN-UHFFFAOYSA-N 0.000 description 2
• RXFCIXRFAJRBSG-UHFFFAOYSA-N 3,2,3-tetramine Chemical compound NCCCNCCNCCCN RXFCIXRFAJRBSG-UHFFFAOYSA-N 0.000 description 2
• LALMYSXJJWCRDR-UHFFFAOYSA-N 4-tert-butyl-2-hexadecan-2-yl-6-methylphenol Chemical compound CCCCCCCCCCCCCCC(C)C1=CC(C(C)(C)C)=CC(C)=C1O LALMYSXJJWCRDR-UHFFFAOYSA-N 0.000 description 2
• 239000004925 Acrylic resin Substances 0.000 description 2
• VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
• 229920002943 EPDM rubber Polymers 0.000 description 2
• KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
• BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
• 229930040373 Paraformaldehyde Natural products 0.000 description 2
• 229920002367 Polyisobutene Polymers 0.000 description 2
• KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
• QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
• 239000007983 Tris buffer Substances 0.000 description 2
• 230000002378 acidificating effect Effects 0.000 description 2
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
• 229920000800 acrylic rubber Polymers 0.000 description 2
• 239000012190 activator Substances 0.000 description 2
• WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
• 230000032683 aging Effects 0.000 description 2
• 229920000180 alkyd Polymers 0.000 description 2
• 230000029936 alkylation Effects 0.000 description 2
• XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
• 239000003963 antioxidant agent Substances 0.000 description 2
• 125000003118 aryl group Chemical group 0.000 description 2
• TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
• 230000015572 biosynthetic process Effects 0.000 description 2
• 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
• 235000013877 carbamide Nutrition 0.000 description 2
• 150000001721 carbon Chemical group 0.000 description 2
• 230000003197 catalytic effect Effects 0.000 description 2
• 239000007859 condensation product Substances 0.000 description 2
• LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
• 150000001991 dicarboxylic acids Chemical class 0.000 description 2
• POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
• 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
• 239000003822 epoxy resin Substances 0.000 description 2
• SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 2
• 125000004494 ethyl ester group Chemical group 0.000 description 2
• 238000011156 evaluation Methods 0.000 description 2
• 239000003063 flame retardant Substances 0.000 description 2
• 238000004128 high performance liquid chromatography Methods 0.000 description 2
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
• 239000007788 liquid Substances 0.000 description 2
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