JPH0570602B2 - - Google Patents
Info
- Publication number
- JPH0570602B2 JPH0570602B2 JP59176974A JP17697484A JPH0570602B2 JP H0570602 B2 JPH0570602 B2 JP H0570602B2 JP 59176974 A JP59176974 A JP 59176974A JP 17697484 A JP17697484 A JP 17697484A JP H0570602 B2 JPH0570602 B2 JP H0570602B2
- Authority
- JP
- Japan
- Prior art keywords
- insect repellent
- plasticizer
- paper
- pine
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000077 insect repellent Substances 0.000 claims description 31
- 239000004014 plasticizer Substances 0.000 claims description 19
- -1 unsaturated fatty acid ester Chemical class 0.000 claims description 12
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 9
- 235000011613 Pinus brutia Nutrition 0.000 claims description 9
- 241000018646 Pinus brutia Species 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 6
- 239000004033 plastic Substances 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 4
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 claims description 3
- 230000008034 disappearance Effects 0.000 claims description 3
- XLOPRKKSAJMMEW-SFYZADRCSA-M (R,R)-chrysanthemate Chemical compound CC(C)=C[C@@H]1[C@@H](C([O-])=O)C1(C)C XLOPRKKSAJMMEW-SFYZADRCSA-M 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 150000004671 saturated fatty acids Chemical group 0.000 claims description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims description 2
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical group FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 10
- 238000011161 development Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 241000283690 Bos taurus Species 0.000 description 3
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 3
- FLIACVVOZYBSBS-UHFFFAOYSA-N Methyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC FLIACVVOZYBSBS-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- VTIMKVIDORQQFA-UHFFFAOYSA-N 2-Ethylhexyl-4-hydroxybenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=C(O)C=C1 VTIMKVIDORQQFA-UHFFFAOYSA-N 0.000 description 2
- 241000238876 Acari Species 0.000 description 2
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 2
- NDKYEUQMPZIGFN-UHFFFAOYSA-N Butyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCC NDKYEUQMPZIGFN-UHFFFAOYSA-N 0.000 description 2
- GOJCZVPJCKEBQV-UHFFFAOYSA-N Butyl phthalyl butylglycolate Chemical compound CCCCOC(=O)COC(=O)C1=CC=CC=C1C(=O)OCCCC GOJCZVPJCKEBQV-UHFFFAOYSA-N 0.000 description 2
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 description 2
- 241000255925 Diptera Species 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 241001674048 Phthiraptera Species 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 241000258242 Siphonaptera Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- ZDWGXBPVPXVXMQ-UHFFFAOYSA-N bis(2-ethylhexyl) nonanedioate Chemical compound CCCCC(CC)COC(=O)CCCCCCCC(=O)OCC(CC)CCCC ZDWGXBPVPXVXMQ-UHFFFAOYSA-N 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- ULBTUVJTXULMLP-UHFFFAOYSA-N butyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCC ULBTUVJTXULMLP-UHFFFAOYSA-N 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 2
- JBSLOWBPDRZSMB-BQYQJAHWSA-N dibutyl (e)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C\C(=O)OCCCC JBSLOWBPDRZSMB-BQYQJAHWSA-N 0.000 description 2
- YKDMBTQVKVEMSA-UHFFFAOYSA-N diethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOCCOC(=O)CCCCCCCCCCCCCCCCC YKDMBTQVKVEMSA-UHFFFAOYSA-N 0.000 description 2
- TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical compound CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 description 2
- YCZJVRCZIPDYHH-UHFFFAOYSA-N ditridecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCC YCZJVRCZIPDYHH-UHFFFAOYSA-N 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 2
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- BPJZKLBPJBMLQG-KWRJMZDGSA-N propanoyl (z,12r)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(=O)OC(=O)CC BPJZKLBPJBMLQG-KWRJMZDGSA-N 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- PACBIGNRUWABMA-UHFFFAOYSA-N 2-(2,3-dihydro-1,3-benzothiazol-2-yl)-6-dodecyl-4-methylphenol Chemical compound CCCCCCCCCCCCC1=CC(C)=CC(C2SC3=CC=CC=C3N2)=C1O PACBIGNRUWABMA-UHFFFAOYSA-N 0.000 description 1
- 241000254032 Acrididae Species 0.000 description 1
- 241000189524 Baccharis halimifolia Species 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 241000218691 Cupressaceae Species 0.000 description 1
- 241000252233 Cyprinus carpio Species 0.000 description 1
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
- YUGWDVYLFSETPE-JLHYYAGUSA-N Empenthrin Chemical compound CC\C=C(/C)C(C#C)OC(=O)C1C(C=C(C)C)C1(C)C YUGWDVYLFSETPE-JLHYYAGUSA-N 0.000 description 1
- 241000256259 Noctuidae Species 0.000 description 1
- BDJRBEYXGGNYIS-UHFFFAOYSA-N Nonanedioid acid Natural products OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000256856 Vespidae Species 0.000 description 1
- ARCGXLSVLAOJQL-UHFFFAOYSA-N anhydrous trimellitic acid Natural products OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- ROPXFXOUUANXRR-YPKPFQOOSA-N bis(2-ethylhexyl) (z)-but-2-enedioate Chemical compound CCCCC(CC)COC(=O)\C=C/C(=O)OCC(CC)CCCC ROPXFXOUUANXRR-YPKPFQOOSA-N 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 231100000517 death Toxicity 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940111071 diethylene glycol distearate Drugs 0.000 description 1
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- RZRNAYUHWVFMIP-HXUWFJFHSA-N glycerol monolinoleate Natural products CCCCCCCCC=CCCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-HXUWFJFHSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229940073769 methyl oleate Drugs 0.000 description 1
- 229940074096 monoolein Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-N n-Decanedioic acid Natural products OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Description
本発明は、４−メチル−４−ヘプテン−１−イ
ン−３−イン ｄ−シス、トランス−クリサンテ
マート《以降、ベーパスリンと称す》もしくはこ
れに可塑剤を配合してなる組成物を、パルプある
いはリンター基紙層、着色層と油透過性地色層か
ら成る発色紙で、かつインジケーターとして機能
する防虫マツトに含浸させ、届折率の変化により
着色層の色相を発色せしめたのち、使用のエンド
ポイントを発色の消失により容易に確認しうるよ
うにした該防虫マツトを、プラスチツクケースあ
るいはラミネート加工した紙または不織布の内装
紙に包納した衣料用防虫剤に関する。
従来、衣料用防虫剤としては、パラジクロール
ベンゼン、ナフタリンおよびシヨウノウが固形状
として一般に使用されてきた。これら３種類の衣
料用防虫剤については、完全に満足しえるもので
なく、例えば臭いの問題、使用量の多いこと、３
〜４ケ月ごとに新しいものを入れ替えなければな
らないこと、殺虫効力がなく防虫効果も弱いこと
等、種々の欠点があつた。本発明者らは、上記衣
料防虫剤の欠点と、更に近年発生の増大している
ノミ、シラミ、ダニ、シバンムシ、アリガタバ
チ、更にハエ、蚊、ゴキブリ等の害虫対策にも使
用できる薬剤の研究を行なつた結果、揮散性薬剤
としてベーパスリンを使用した衣料用防虫剤が、
市販のパラジクロールベンゼン、ナフタリンやシ
ヨウノウ製剤のと異なり、衣料害虫に対する防虫
効果のみならず殺虫力をも兼備していること、
又、パラジクロールベンゼン、ナフタリンやシヨ
ウノウ製剤のような防虫剤特有の強い臭いや刺激
をもたないことから目的に適合することを見い出
した。
更に、ベーパスリンの揮散量を調節し、長期間
防虫効果を発揮させるためや、薬剤成分の衣料へ
のしみ出しを抑えるために、ベーパスリン含有の
防虫マツトをプラスチツクケースあるいはラミネ
ート加工した紙又は不織布の内装紙に包納する方
法が極めて有効であることを発見し、特許願昭和
59年15940号として出願した。しかしながら、ベ
ーパスリンは液体であり、これを含浸させた防虫
マツトにおいては、パラジクロールベンゼンやナ
フタリンの結晶が消失する如くに、使用のエンド
ポイントを見きわめることがむずかしいという欠
点があつた。
そこで本発明者らは、水筆用紙の原理を応用
し、鋭意研究を続けた結果、従来のパルプ製マツ
トに替えて、発色紙を用い、ベーパスリンもしく
はこれに可塑剤を配合してなる組成物を含浸させ
て発色せしめ、防虫マツトとして使用した時、一
定期間経過後発色の消失により使用のエンドポイ
ントが容易に確認されうることを発見して本発明
を完成した。
本発明で使用される発色紙は、パルプあるいは
リンター製基紙層、該基紙層と表面に設けられた
任意の色相の着色層ならびに該着色層の上に設け
られた低屈折率顔料を含み、適当な耐油性及び油
透過性を有し着色層とは色相を異にする地色層か
ら成つており、ベーパスリンもしくはこれに可塑
剤を配合してなる組成物を塗布すると、屈折率の
変化により着色層の色相が発色する。薬剤の揮散
によつて発色紙中、とくに地色層の濃度が減少す
るに伴ない、発色は徐々に退色し、やがては地色
層の色相に復元する性質を有している。
本発明で用いる可塑剤としては、通常使用され
るエステル系可塑剤が使用でき、例えば脂肪酸エ
ステル、フタール酸エステル、アジピン酸エステ
ル、アゼライン酸エステル、セバシン酸エステ
ル、クエン酸エステル、トリメリツト酸エステ
ル、グリコール酸エステル、リン酸エステル、多
価アルコールエステル等があるが、炭素数14〜24
の飽和あるいは不飽和脂肪酸エステルが好まし
い。
上記可塑剤のうち代表的なものをあげるとつぎ
のとおりであるが、これらのみに限定されるもの
でないことはもちろんである。
(1) ステアリン酸ｎ−ブチル
(2) ミリスチン酸イソプロピル
(3) オレイン酸メチル
(4) オレイン酸ｎ−ブチル
(5) ラウリン酸ｎ−ブチル
(6) パルミチン酸メチル
(7) マレイン酸ジｎ−ブチル
(8) アジピン酸ジｎ−ブチル
(9) フタル酸ジトリデシル
(10) フタル酸ｎ−ブチルベンジル
(11) フタル酸ジ２−エチルヘキシル
(12) アゼライン酸ジ２−エチルヘキシル
(13) セバシン酸ジベンジル
(14) クエン酸アセチルトリブチル
(15) トリメリツト酸トリオクチル
(16) ｐ−ヒドロキシ安息香酸２−エチルヘキシル
(17) グリコール酸ブチルフタリルブチル
(18) ジステアリン酸ジエチレングリコール
(19) アセチルリシノール酸メチル
(20) モノオレイン酸グリセリル
(21) リン酸トリ２−エチルヘキシル
(22) フマール酸ジオクチル
(23) フマール酸ジブチル
(24) マレイン酸ジ２−エチルヘキシル
本発明の実施にあたつては、防虫マツトの使用
条件、効力持続条件にあわせて、使用する可塑剤
の種類、塗布量あるいは、ベーパスリンと可塑剤
の配合比率を適宜決定することが好ましい。この
場合、可塑剤の屈折率による発色度、揮散性等が
考慮され、例えば、揮散性の低い可塑剤を発色最
低必要量塗布し、これにベーパスリンをオンする
方法も有用である。従つて本発明は、ベーパスリ
ンに比べて非常に安価な可塑剤を使用し、防虫剤
使用のエンドポイントをより確実に指示する方法
を提供する点で極めて有用かつ実用的な発明であ
る。なお、ベーパスリン含有防虫マツトとは別
に、小片の発色紙に薬液を含浸させたインデイケ
ーターを備える方法もあるが、本発明衣料用防虫
剤は、全体が発色する点でわかりやすく、また、
防虫マツトと発色紙間の揮散性の差を考慮する必
要がない長所がある。
本発明の防虫マツトに含浸されるベーパスリン
は蒸気圧の高いピレスロイド化合物で人畜に対す
る毒性が極めて低く、又、パラジクロールベンゼ
ン、ナフタリンやシヨウノウ製剤のような臭いや
刺激がないことから家庭において安全に使用する
ことができる。なお薬剤の安定化を計るため、こ
れらにBHT，DBH，BHA等の酸化防止剤を添
加したり、芳香性を加味するために香料を添加す
ることも有用である。
また、防虫マツトを包納するプラスチツクケー
スや、内装紙に適用されるラミネート加工、ある
いはベーパスリンもしくはこれに可塑剤を加えた
組成物の発色紙への印刷、塗布方法は、従来公知
の樹脂加工、ラミネート加工、薬剤処理方法に基
づくもので、何等新しい設備を必要とせず、従来
の設備が多目的に使用できる点で有益である。
次に本発明を実施例で詳細に説明する。
実施例 １
面積48cm2（６×８cm）の発色紙に種々の薬剤を
含浸させて防虫マツトを得、これをプラスチツク
ケース中に包納してタンスの中につるした。８ケ
月後に防虫マツト中のベーパスリン残存量とイン
デイケーターの発色度を調べたところ以下の如く
であつた。
The present invention uses 4-methyl-4-hepten-1-yn-3-yne d-cis, trans-chrysanthemate (hereinafter referred to as vaporthrin) or a composition prepared by blending the same with a plasticizer into pulp. Alternatively, a colored paper consisting of a linter base paper layer, a colored layer, and an oil-permeable ground color layer is impregnated with insect repellent pine that functions as an indicator, and the hue of the colored layer is developed by changing the folding rate, and then used. The present invention relates to an insect repellent for clothing, in which the insect repellent mat whose end point can be easily confirmed by the disappearance of color development is enclosed in a plastic case or an interior paper made of laminated paper or nonwoven fabric. Conventionally, paradichlorobenzene, naphthalene, and cypress have generally been used in solid form as insect repellents for clothing. These three types of insect repellents for clothing are not completely satisfactory, such as problems with odor, large amounts of use,
It had various drawbacks, such as having to replace it with a new one every four months, and having no insecticidal effect and weak insect repellent effect. The present inventors investigated the drawbacks of the above-mentioned clothing insect repellents, and also researched agents that can be used to control pests such as fleas, lice, ticks, grasshoppers, wasps, flies, mosquitoes, and cockroaches, which have been increasingly occurring in recent years. As a result of these efforts, an insect repellent for clothing that uses vapor rind as a volatile agent has been developed.
Unlike commercially available paradichlorbenzene, naphthalene, and other preparations, it not only has an insect repellent effect on clothing pests, but also has insecticidal power.
In addition, it has been found that it is suitable for the purpose because it does not have the strong odor or irritation characteristic of insect repellents such as paradichlorobenzene, naphthalene and camphor preparations. In addition, in order to control the amount of volatilization of vapor thin and to maintain its insect repellent effect for a long period of time, and to prevent chemical components from seeping into clothing, insect repellent mats containing vapor thin are placed in plastic cases or laminated paper or non-woven fabric interiors. He discovered that the method of packaging in paper was extremely effective and applied for a patent in the Showa era.
Filed as No. 15940 in 1959. However, vapor rind is a liquid, and insect repellent mats impregnated with it have the disadvantage that it is difficult to determine the end point of use, such as when crystals of paradichlorobenzene or naphthalene disappear. Therefore, the present inventors applied the principle of water brush paper and, as a result of intensive research, developed a composition that uses colored paper instead of the conventional pulp mat and blends vapor rinse or a plasticizer with it. The present invention was completed based on the discovery that when impregnated to develop color and used as an insect repellent pine, the end point of use can be easily confirmed by the disappearance of color after a certain period of time. The colored paper used in the present invention includes a base paper layer made of pulp or linter, a colored layer of any hue provided on the base paper layer and the surface, and a low refractive index pigment provided on the colored layer. It consists of a ground color layer that has appropriate oil resistance and oil permeability and has a different hue from the colored layer, and when vapor rind or a composition made by blending it with a plasticizer is applied, the refractive index changes. As a result, the hue of the colored layer develops. As the density of the colored paper, especially the ground color layer, decreases due to volatilization of the chemicals, the color gradually fades and eventually returns to the hue of the ground color layer. As the plasticizer used in the present invention, commonly used ester plasticizers can be used, such as fatty acid ester, phthalate ester, adipate ester, azelaic acid ester, sebacic acid ester, citric acid ester, trimellitic acid ester, glycol There are acid esters, phosphate esters, polyhydric alcohol esters, etc., but they have 14 to 24 carbon atoms.
saturated or unsaturated fatty acid esters are preferred. Representative examples of the above plasticizers are listed below, but it goes without saying that the plasticizers are not limited to these. (1) n-butyl stearate (2) isopropyl myristate (3) methyl oleate (4) n-butyl oleate (5) n-butyl laurate (6) methyl palmitate (7) di-n-maleate Butyl (8) Di-n-butyl adipate (9) Ditridecyl phthalate (10) n-Butylbenzyl phthalate (11) Di-2-ethylhexyl phthalate (12) Di-2-ethylhexyl azelate (13) Dibenzyl sebacate ( 14) Acetyl tributyl citrate (15) Trioctyl trimellistate (16) 2-ethylhexyl p-hydroxybenzoate (17) Butylphthalyl butyl glycolate (18) Diethylene glycol distearate (19) Methyl acetyl ricinoleate (20) Monoolein Glyceryl acid (21) Tri-2-ethylhexyl phosphate (22) Dioctyl fumarate (23) Dibutyl fumarate (24) Di-2-ethylhexyl maleate In carrying out the present invention, the conditions for use of the insect repellent pine, the duration of its effectiveness, etc. It is preferable to appropriately determine the type of plasticizer to be used, the amount of application, or the blending ratio of vapor rinse and plasticizer in accordance with the conditions. In this case, the degree of color development, volatility, etc. depending on the refractive index of the plasticizer are taken into consideration. For example, it is also useful to apply a minimum amount of a plasticizer with low volatility required for color development, and then turn on vapor rins. Therefore, the present invention is an extremely useful and practical invention in that it provides a method for more reliably indicating the end point of insect repellent use, using a plasticizer that is much cheaper than vapor thrine. In addition to vapor thin-containing insect repellent mats, there is also a method of equipping a small piece of colored paper with an indicator impregnated with a chemical solution, but the insect repellent for clothing of the present invention is easy to understand because the entire part is colored, and
It has the advantage that there is no need to consider the difference in volatility between insect repellent pine and colored paper. The vapor rin impregnated into the insect repellent pine of the present invention is a pyrethroid compound with a high vapor pressure and has extremely low toxicity to humans and livestock, and it is safe to use at home because it does not have the odor or irritation of paradichlorobenzene, naphthalene or other chemicals. can do. It is also useful to add antioxidants such as BHT, DBH, BHA, etc. to these drugs in order to stabilize them, and to add fragrances to add aromatic properties. In addition, the plastic case that houses the insect repellent mat, the laminating process applied to the interior paper, and the printing and coating method of vapor rinse or a composition with a plasticizer added to colored paper are conventionally known resin processing, It is based on lamination processing and chemical processing methods, and is advantageous in that it does not require any new equipment and conventional equipment can be used for multiple purposes. Next, the present invention will be explained in detail with reference to Examples. Example 1 A colored paper with an area of 48 cm 2 (6 x 8 cm) was impregnated with various chemicals to obtain insect repellent mats, which were enclosed in a plastic case and hung in a dresser. After 8 months, the residual amount of vapor rin in the insect-proof pine and the degree of color development of the indicator were investigated and the results were as follows.
【表】
本試験においてはインデイケーター発色の量低
必要量は薬剤５mg／cm2程度であつた。ベーパスリ
ン単独の場合（試験１）、８ケ月後既に退色して
おり、より高濃度のベーパスリンが必要と考えら
れたが、発色紙の薬剤保持性に限度があることか
ら、薬剤の濃度アツプは必ずしも好ましくない。
一方、ベーパスリンより揮散性の低い可塑剤を併
用した場合（試験２〜６）、トータル的な揮散量
が抑えられ８ケ月後に発色が消失する程度にコン
トロールされた。本発明で使用される可塑剤がベ
ーパスリンに比べて極めて安価なことから、ベー
パスリンと可塑剤の併用がより有利であることが
認められた。
実施例 ２
面積11cm2（2.2×5.0cm）、厚さ0.3mmのパルプリ
ンター製発色紙に下表の薬剤及びDBH3mg、香料
１mgを含浸させて防虫マツトを得、これをポリプ
ロピレン20μのラミネート加工をほどこした内装
紙に包納した。約50の引き出しいつぱいに５枚
のモスリン布を重ねて収納し、その間に本発明衣
料防虫剤５個をそれぞれ置いた。試験開始直後及
び８ケ月経過後、インデイケーターの発色度を調
べるとともに、底から３枚目及び５枚目のモスリ
ン布の上にイガ幼虫60匹を放虫し、経時的に致死
数を観察した。致死率は３枚目と５枚目の平均で
示す。[Table] In this test, the minimum required amount for indicator color development was approximately 5 mg/cm 2 of the drug. In the case of vapor rin alone (Test 1), the color had already faded after 8 months, and it was thought that a higher concentration of vapor rin would be necessary. Undesirable.
On the other hand, when a plasticizer with lower volatility than vapor rin was used in combination (Tests 2 to 6), the total amount of volatilization was suppressed and the color development was controlled to the extent that it disappeared after 8 months. Since the plasticizer used in the present invention is much cheaper than vapor thrine, it has been found that the combination of vapor thrine and a plasticizer is more advantageous. Example 2 A colored paper made by Palprinter with an area of 11 cm 2 (2.2 x 5.0 cm) and a thickness of 0.3 mm was impregnated with the chemicals shown in the table below, 3 mg of DBH, and 1 mg of fragrance to obtain an insect repellent mat, which was then laminated with 20 μm of polypropylene. It was packaged in the inner paper. Approximately 50 drawers were filled with 5 sheets of muslin cloth, and 5 pieces of the insect repellent for clothing of the present invention were placed between each layer. Immediately after the start of the test and after 8 months, the degree of color development of the indicator was examined, and 60 burr larvae were released onto the third and fifth muslin cloths from the bottom, and the number of deaths was observed over time. . The mortality rate is shown as the average of the 3rd and 5th images.
【表】
試験の結果、本発明衣料用防虫剤は８ケ月経過
後においても効果は十分で、インデイケーターの
発色がコントロールされていた。なお、セミネー
ト加工のフイルムの材質は問わず15〜60μの例え
ばポリエチレン、ポリプロピレンの片面、両面加
工で同様の結果が得られた。また、タンス、衣装
箱、更に台所の調味料等収納庫等においても、イ
ガ、コイガ、ヒメカツオブシムシ等の衣料害虫、
あるいはノミ、シラミ、ダニ等の衛生害虫等の防
除に効果的であつた。[Table] As a result of the test, the effect of the insect repellent for clothing of the present invention was sufficient even after 8 months, and the color development of the indicator was controlled. Regardless of the material of the semi-finished film, similar results were obtained when polyethylene or polypropylene of 15 to 60 μm was processed on one side or both sides. In addition, clothing pests such as burrs, carp moths, and cutworms, etc.
It was also effective in controlling sanitary pests such as fleas, lice, and mites.
Claims (1)
イル ｄ−シス、トランス−クリサンテマートも
しくはこれに可塑剤を配合してなる組成物を、パ
ルプあるいはリンター基紙層、着色層と油透過性
地色層から成る発色紙で、かつインジケーターと
して機能する防虫マツトに含浸させ、届折率の変
化により着色層の色相を発色せしめたのち、使用
のエンドポイントを発色の消失により容易に確認
しうるようにした該防虫マツトを、プラスチツク
ケースあるいはラミネート加工した紙または不織
布の内装紙に包納したことを特徴とする衣料用防
虫剤。 ２ 可塑剤が炭素数14〜24の飽和あるいは不飽和
脂肪酸エステルである特許請求の範囲第１項記載
の衣料用防虫剤。 ３ 可塑剤がステアリン酸ブチルあるいはミリス
チン酸イソプロピルである特許請求の範囲第１項
または第２項記載の衣料用防虫剤。[Claims] 1 4-Methyl-4-hepten-1-yn-3-
A colored paper consisting of a pulp or linter base paper layer, a colored layer and an oil-permeable ground color layer, and which functions as an indicator, is made of il d-cis, trans-chrysanthemate, or a composition prepared by blending these with a plasticizer. The insect repellent pine is impregnated with the insect repellent pine, and the colored layer develops the hue depending on the change in the rate of return.The insect repellent pine is then placed in a plastic case or laminated so that the end point of use can be easily confirmed by the disappearance of the color. An insect repellent for clothing, characterized in that it is enclosed in a paper or non-woven interior paper. 2. The insect repellent for clothing according to claim 1, wherein the plasticizer is a saturated or unsaturated fatty acid ester having 14 to 24 carbon atoms. 3. The insect repellent for clothing according to claim 1 or 2, wherein the plasticizer is butyl stearate or isopropyl myristate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59176974A JPS6156109A (en) | 1984-08-25 | 1984-08-25 | Insecticide for cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59176974A JPS6156109A (en) | 1984-08-25 | 1984-08-25 | Insecticide for cloth |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6156109A JPS6156109A (en) | 1986-03-20 |
| JPH0570602B2 true JPH0570602B2 (en) | 1993-10-05 |
Family
ID=16022963
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59176974A Granted JPS6156109A (en) | 1984-08-25 | 1984-08-25 | Insecticide for cloth |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6156109A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63101301A (en) * | 1986-10-16 | 1988-05-06 | Fumakiraa Kk | Packaged drug |
| US4931955A (en) * | 1987-04-28 | 1990-06-05 | Juki Corporation | Ink jet printing apparatus with preprinting jet purging mechanism |
| JPH082768B2 (en) * | 1987-12-28 | 1996-01-17 | 小林製薬株式会社 | Liquid insect repellent |
| DE69311397T2 (en) * | 1992-03-02 | 1997-10-30 | Seiko Epson Corp | Color jet printer, electronic device equipped therewith and operating method therefor |
| DE19514948C2 (en) * | 1995-04-24 | 1998-01-22 | Bayer Ag | Moth control pillow |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50116638A (en) * | 1974-02-25 | 1975-09-12 | ||
| JPS5250237U (en) * | 1975-10-04 | 1977-04-09 | ||
| JPS5690004A (en) * | 1979-12-21 | 1981-07-21 | Earth Chem Corp Ltd | Insecticide for cloth |
| JPS57158682A (en) * | 1981-03-25 | 1982-09-30 | Kuroisutaa Chemicals Kk | Period indicator |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5464186U (en) * | 1977-10-17 | 1979-05-07 |
-
1984
- 1984-08-25 JP JP59176974A patent/JPS6156109A/en active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50116638A (en) * | 1974-02-25 | 1975-09-12 | ||
| JPS5250237U (en) * | 1975-10-04 | 1977-04-09 | ||
| JPS5690004A (en) * | 1979-12-21 | 1981-07-21 | Earth Chem Corp Ltd | Insecticide for cloth |
| JPS57158682A (en) * | 1981-03-25 | 1982-09-30 | Kuroisutaa Chemicals Kk | Period indicator |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6156109A (en) | 1986-03-20 |
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