JPH0567568B2 - - Google Patents
Info
- Publication number
- JPH0567568B2 JPH0567568B2 JP1271363A JP27136389A JPH0567568B2 JP H0567568 B2 JPH0567568 B2 JP H0567568B2 JP 1271363 A JP1271363 A JP 1271363A JP 27136389 A JP27136389 A JP 27136389A JP H0567568 B2 JPH0567568 B2 JP H0567568B2
- Authority
- JP
- Japan
- Prior art keywords
- zeolite
- aluminosilicate
- ion exchange
- ultrafine
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 39
- 239000010457 zeolite Substances 0.000 claims description 28
- 229910021536 Zeolite Inorganic materials 0.000 claims description 27
- 238000005342 ion exchange Methods 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 13
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 229920003169 water-soluble polymer Polymers 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052751 metal Chemical class 0.000 claims description 6
- 239000002184 metal Chemical class 0.000 claims description 6
- 239000002243 precursor Substances 0.000 claims description 5
- 239000008119 colloidal silica Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 230000002194 synthesizing effect Effects 0.000 claims description 4
- 150000004645 aluminates Chemical class 0.000 claims description 3
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 3
- 150000004692 metal hydroxides Chemical class 0.000 claims description 3
- 239000003125 aqueous solvent Substances 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000002245 particle Substances 0.000 description 10
- 108010010803 Gelatin Proteins 0.000 description 8
- 229920000159 gelatin Polymers 0.000 description 8
- 239000008273 gelatin Substances 0.000 description 8
- 235000019322 gelatine Nutrition 0.000 description 8
- 235000011852 gelatine desserts Nutrition 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000013078 crystal Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000011882 ultra-fine particle Substances 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- CRHLEZORXKQUEI-UHFFFAOYSA-N dialuminum;cobalt(2+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Co+2].[Co+2] CRHLEZORXKQUEI-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- KVOIJEARBNBHHP-UHFFFAOYSA-N potassium;oxido(oxo)alumane Chemical compound [K+].[O-][Al]=O KVOIJEARBNBHHP-UHFFFAOYSA-N 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 229910001631 strontium chloride Inorganic materials 0.000 description 1
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 1
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 1
- 229910001866 strontium hydroxide Inorganic materials 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2815—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of type A (UNION CARBIDE trade name; corresponds to GRACE's types Z-12 or Z-12L)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2838—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively)
- C01B33/2853—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively) of type Y
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1271363A JPH03131514A (ja) | 1989-10-18 | 1989-10-18 | イオン交換能等の機能を有した超微粒子アルミノ珪酸塩 |
| DE69112377T DE69112377T2 (de) | 1989-10-18 | 1991-04-16 | Mikroteilige Aluminosilikaten und Verfahren zu ihrer Herstellung. |
| EP91303358A EP0509164B1 (en) | 1989-10-18 | 1991-04-16 | Micro-particulate aluminosilicate and process for producing the same |
| US07/686,517 US5183650A (en) | 1989-10-18 | 1991-04-17 | Micro-particulate aluminosilicate and process for producing the same |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1271363A JPH03131514A (ja) | 1989-10-18 | 1989-10-18 | イオン交換能等の機能を有した超微粒子アルミノ珪酸塩 |
| EP91303358A EP0509164B1 (en) | 1989-10-18 | 1991-04-16 | Micro-particulate aluminosilicate and process for producing the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03131514A JPH03131514A (ja) | 1991-06-05 |
| JPH0567568B2 true JPH0567568B2 (OSRAM) | 1993-09-27 |
Family
ID=40227707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1271363A Granted JPH03131514A (ja) | 1989-10-18 | 1989-10-18 | イオン交換能等の機能を有した超微粒子アルミノ珪酸塩 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US5183650A (OSRAM) |
| EP (1) | EP0509164B1 (OSRAM) |
| JP (1) | JPH03131514A (OSRAM) |
| DE (1) | DE69112377T2 (OSRAM) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6306363B1 (en) * | 1998-05-29 | 2001-10-23 | Tosoh Corporation | Fine low silica faujasite type zeolite and process for its production |
| US6894019B2 (en) * | 2000-12-18 | 2005-05-17 | Kao Corporation | Base particles and detergent particles |
| US8177867B2 (en) * | 2008-06-30 | 2012-05-15 | Nano Dispersions Technology Inc. | Nano-dispersions of coal in water as the basis of fuel related technologies and methods of making same |
| US20130074396A1 (en) | 2008-06-30 | 2013-03-28 | Gustavo A. Núñez | Nano-dispersions of carbonaceous material in water as the basis of fuel related technologies and methods of making same |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4416805A (en) * | 1978-12-20 | 1983-11-22 | J. M. Huber Corporation | Synthesis of zeolites of small and uniform size having a high magnesium exchange capacity |
| GB2040900B (en) * | 1978-12-20 | 1983-05-11 | Huber Corp J M | Zeolites of small particle size |
| IT1165442B (it) * | 1979-01-26 | 1987-04-22 | Montedison Spa | Zeoliti di tipo a,ad elevato grado di cristallinita' e a granulometria fine e processo per la loro produzione |
| DE2941636A1 (de) * | 1979-10-13 | 1981-05-07 | Degussa Ag, 6000 Frankfurt | Verfahren zur kontinuierlichen herstellung feinstteiliger zeolithischer natriumaluminiumsilikate |
| US4372931A (en) * | 1980-05-30 | 1983-02-08 | Air Products And Chemicals, Inc. | Microcrystalline synthetic faujasite |
| JPS5711819A (en) * | 1980-06-24 | 1982-01-21 | Mitsubishi Heavy Ind Ltd | Preparation of crystalline zeolite |
| JPS58208127A (ja) * | 1982-05-27 | 1983-12-03 | Nippon Chem Ind Co Ltd:The | 懸濁安定性のよいゼオライトスラリ− |
| DE3363827D1 (en) * | 1983-01-11 | 1986-07-03 | Coal Industry Patents Ltd | Improvements in catalyst production |
| JPS6071518A (ja) * | 1983-09-27 | 1985-04-23 | Chiyoda Chem Eng & Constr Co Ltd | 結晶性アルミノシリケ−トの製造方法 |
| JPS60251121A (ja) * | 1984-05-24 | 1985-12-11 | Agency Of Ind Science & Technol | 微結晶ｚｓｍ−５型ゼオライトの製造方法 |
| JPS638212A (ja) * | 1986-06-27 | 1988-01-14 | Lion Corp | アルミノ珪酸塩含有スラリ−の製造方法 |
| JPS63162520A (ja) * | 1986-12-26 | 1988-07-06 | Tosoh Corp | 合成マザイトの製造方法 |
| DE3869642D1 (de) * | 1987-02-25 | 1992-05-07 | Exxon Chemical Patents Inc | Herstellung von zeolith-l. |
-
1989
- 1989-10-18 JP JP1271363A patent/JPH03131514A/ja active Granted
-
1991
- 1991-04-16 EP EP91303358A patent/EP0509164B1/en not_active Expired - Lifetime
- 1991-04-16 DE DE69112377T patent/DE69112377T2/de not_active Expired - Fee Related
- 1991-04-17 US US07/686,517 patent/US5183650A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0509164A1 (en) | 1992-10-21 |
| US5183650A (en) | 1993-02-02 |
| JPH03131514A (ja) | 1991-06-05 |
| DE69112377T2 (de) | 1996-03-07 |
| EP0509164B1 (en) | 1995-08-23 |
| DE69112377D1 (de) | 1995-09-28 |
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