JPH0547577B2 - - Google Patents
Info
- Publication number
- JPH0547577B2 JPH0547577B2 JP1204089A JP1204089A JPH0547577B2 JP H0547577 B2 JPH0547577 B2 JP H0547577B2 JP 1204089 A JP1204089 A JP 1204089A JP 1204089 A JP1204089 A JP 1204089A JP H0547577 B2 JPH0547577 B2 JP H0547577B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- styrene
- foam
- flame
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 73
- 229920005989 resin Polymers 0.000 claims description 44
- 239000011347 resin Substances 0.000 claims description 44
- 239000003063 flame retardant Substances 0.000 claims description 29
- 239000006260 foam Substances 0.000 claims description 27
- 239000004604 Blowing Agent Substances 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 23
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 21
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 18
- 229920001577 copolymer Polymers 0.000 claims description 13
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 11
- OZHJEQVYCBTHJT-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-methylbenzene Chemical compound CC1=C(Br)C(Br)=C(Br)C(Br)=C1Br OZHJEQVYCBTHJT-UHFFFAOYSA-N 0.000 claims description 10
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 claims description 10
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 description 11
- 238000001125 extrusion Methods 0.000 description 10
- 229920001890 Novodur Polymers 0.000 description 9
- 238000009413 insulation Methods 0.000 description 8
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- -1 3,5-dibromophenyl Chemical group 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 229940050176 methyl chloride Drugs 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- BHNZEZWIUMJCGF-UHFFFAOYSA-N 1-chloro-1,1-difluoroethane Chemical compound CC(F)(F)Cl BHNZEZWIUMJCGF-UHFFFAOYSA-N 0.000 description 2
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 2
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 2
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 2
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 2
- 229960003750 ethyl chloride Drugs 0.000 description 2
- 150000002484 inorganic compounds Chemical class 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229940073584 methylene chloride Drugs 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 1
- RZLLIOPGUFOWOD-UHFFFAOYSA-N 1,3,5-tribromo-2-prop-2-enoxybenzene Chemical compound BrC1=CC(Br)=C(OCC=C)C(Br)=C1 RZLLIOPGUFOWOD-UHFFFAOYSA-N 0.000 description 1
- GGSRTHRSSCWGGK-UHFFFAOYSA-L 2,2-dibutyl-5-hydroxy-1,3,2-dioxastannepane-4,7-dione Chemical compound CCCC[Sn]1(CCCC)OC(=O)CC(O)C(=O)O1 GGSRTHRSSCWGGK-UHFFFAOYSA-L 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000779 depleting effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical compound FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 description 1
- 229940099364 dichlorofluoromethane Drugs 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- VCAFTIGPOYBOIC-UHFFFAOYSA-N phenyl dihydrogen phosphite Chemical compound OP(O)OC1=CC=CC=C1 VCAFTIGPOYBOIC-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical group OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006327 polystyrene foam Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000005437 stratosphere Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1204089A JPH02194038A (ja) | 1989-01-23 | 1989-01-23 | 難燃性スチレン系樹脂板状発泡体の製造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1204089A JPH02194038A (ja) | 1989-01-23 | 1989-01-23 | 難燃性スチレン系樹脂板状発泡体の製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH02194038A JPH02194038A (ja) | 1990-07-31 |
JPH0547577B2 true JPH0547577B2 (bg) | 1993-07-19 |
Family
ID=11794488
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1204089A Granted JPH02194038A (ja) | 1989-01-23 | 1989-01-23 | 難燃性スチレン系樹脂板状発泡体の製造方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH02194038A (bg) |
-
1989
- 1989-01-23 JP JP1204089A patent/JPH02194038A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPH02194038A (ja) | 1990-07-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0932641B1 (en) | Heat stabilized, flame retardant styrenic polymer foam compostions | |
JP6469973B2 (ja) | 熱可塑性樹脂押出発泡断熱板の製造方法 | |
US5416129A (en) | Closed cell, low density ethylenic polymer foam produced with inorganic halogen-free blowing agents | |
JP4111437B2 (ja) | ポリスチレン系樹脂押出発泡板の製造方法及びポリスチレン系樹脂押出発泡板 | |
US20160340517A1 (en) | Flame retardant compositions and processes for preparation thereof | |
US4486550A (en) | Styrenic foam and process therefor | |
US4086192A (en) | Olefin polymer composition having reduced flame propagation characteristics | |
WO1998016579A1 (en) | Heat stabilized, flame retardant thermoplastic polymer compositions | |
JPH08504689A (ja) | 耐火性の熱可塑性複合構造物 | |
JPH0547577B2 (bg) | ||
JP7449827B2 (ja) | ポリスチレン系樹脂押出発泡板の製造方法、及びポリスチレン系樹脂押出発泡板 | |
ES2211347B1 (es) | Espuma polimerica estirenica retardante a la llama. | |
JPH0515735B2 (bg) | ||
US6087408A (en) | Process for the production of polyolefin resin foams | |
JPH02123143A (ja) | 難燃性スチレン系樹脂板状発泡体の製造方法 | |
JPH0277435A (ja) | 難燃性スチレン系樹脂板状発泡体の製造方法 | |
JPH07507592A (ja) | アルケニル芳香族ポリマーフォームおよび該フォームの製造法 | |
JPS6029743B2 (ja) | 難燃性ポリスチレン系樹脂発泡体の製造方法 | |
JPH02284934A (ja) | スチレン系樹脂板状発泡体の製造方法 | |
JPH01247434A (ja) | 難燃性スチレン系樹脂発泡体の製造方法 | |
JP5909903B2 (ja) | 難燃性発泡性スチレン系樹脂粒子の製造方法 | |
JPS63215740A (ja) | 難燃性スチレン系樹脂発泡体の製造方法 | |
JPH0547574B2 (bg) | ||
JP3963617B2 (ja) | スチレン系樹脂押出発泡板体の製造方法 | |
JP6135791B2 (ja) | 難燃性発泡性スチレン系樹脂粒子の製造方法 |