JPH0533101B2 - - Google Patents
Info
- Publication number
- JPH0533101B2 JPH0533101B2 JP60138056A JP13805685A JPH0533101B2 JP H0533101 B2 JPH0533101 B2 JP H0533101B2 JP 60138056 A JP60138056 A JP 60138056A JP 13805685 A JP13805685 A JP 13805685A JP H0533101 B2 JPH0533101 B2 JP H0533101B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- paste
- hydrogen fluoride
- fluorination
- chromium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 claims description 58
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 22
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 238000003682 fluorination reaction Methods 0.000 claims description 14
- 239000000395 magnesium oxide Substances 0.000 claims description 13
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 13
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 7
- BSKAIKMQTLKUOW-UHFFFAOYSA-N chromium;fluoro hypofluorite Chemical group [Cr].FOF BSKAIKMQTLKUOW-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 230000001172 regenerating effect Effects 0.000 claims description 4
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 3
- 239000000347 magnesium hydroxide Substances 0.000 claims description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 2
- 230000008020 evaporation Effects 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 description 12
- QCMJBECJXQJLIL-UHFFFAOYSA-L chromium(6+);oxygen(2-);difluoride Chemical compound [O-2].[O-2].[F-].[F-].[Cr+6] QCMJBECJXQJLIL-UHFFFAOYSA-L 0.000 description 12
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- HXELGNKCCDGMMN-UHFFFAOYSA-N [F].[Cl] Chemical group [F].[Cl] HXELGNKCCDGMMN-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 235000011837 pasties Nutrition 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000009849 deactivation Effects 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 229910019440 Mg(OH) Inorganic materials 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000010327 methods by industry Methods 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- 229910021564 Chromium(III) fluoride Inorganic materials 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- OGDYVWQEAVKKDI-UHFFFAOYSA-N chromium(3+);oxygen(2-);hydrate Chemical class O.[O-2].[O-2].[O-2].[Cr+3].[Cr+3] OGDYVWQEAVKKDI-UHFFFAOYSA-N 0.000 description 1
- VQWFNAGFNGABOH-UHFFFAOYSA-K chromium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Cr+3] VQWFNAGFNGABOH-UHFFFAOYSA-K 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- UJRBOEBOIXOEQK-UHFFFAOYSA-N oxo(oxochromiooxy)chromium hydrate Chemical compound O.O=[Cr]O[Cr]=O UJRBOEBOIXOEQK-UHFFFAOYSA-N 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000007420 reactivation Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- FTBATIJJKIIOTP-UHFFFAOYSA-K trifluorochromium Chemical compound F[Cr](F)F FTBATIJJKIIOTP-UHFFFAOYSA-K 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3423625.2 | 1984-06-27 | ||
| DE19843423625 DE3423625A1 (de) | 1984-06-27 | 1984-06-27 | Verfahren zur wiederaufbereitung von fluorierungskatalysatoren |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6115738A JPS6115738A (ja) | 1986-01-23 |
| JPH0533101B2 true JPH0533101B2 (en, 2012) | 1993-05-18 |
Family
ID=6239238
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60138056A Granted JPS6115738A (ja) | 1984-06-27 | 1985-06-26 | 弗素化触媒の再生方法 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4578369A (en, 2012) |
| EP (1) | EP0166336B1 (en, 2012) |
| JP (1) | JPS6115738A (en, 2012) |
| AR (1) | AR242129A1 (en, 2012) |
| AU (1) | AU567274B2 (en, 2012) |
| BR (1) | BR8503063A (en, 2012) |
| CA (1) | CA1242691A (en, 2012) |
| DE (2) | DE3423625A1 (en, 2012) |
| ES (1) | ES8604036A1 (en, 2012) |
| GR (1) | GR851545B (en, 2012) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0788326B2 (ja) * | 1987-11-26 | 1995-09-27 | 旭硝子株式会社 | １，１−ジクロロ−１，２，２，２−テトラフルオロエタンの製造方法 |
| US5227350A (en) * | 1990-09-14 | 1993-07-13 | Imperial Chemical Industries Plc | Fluorination catalyst regeneration |
| GB9020084D0 (en) * | 1990-09-14 | 1990-10-24 | Ici Plc | Chemical process |
| GB9105166D0 (en) * | 1991-03-12 | 1991-04-24 | Ici Plc | Chemical process |
| GB9219720D0 (en) * | 1992-09-17 | 1992-10-28 | Ici Plc | Catalyst production |
| ES2216736T1 (es) | 2001-06-28 | 2004-11-01 | Honeywell International Inc. | Proceso para preparar un catalizador en la fluoracion. |
| JP4327012B2 (ja) * | 2003-05-06 | 2009-09-09 | 株式会社日本触媒 | クロム系触媒の回収方法 |
| FR2998815B1 (fr) * | 2012-12-03 | 2017-01-27 | Arkema France | Catalyseur prepare par broyage reactif |
| CN108579726A (zh) * | 2018-04-10 | 2018-09-28 | 湖北省宏源药业科技股份有限公司 | 一种利用废弃铬酸洗液制备铬基氟化催化剂的方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2745886A (en) * | 1955-01-31 | 1956-05-15 | Dow Chemical Co | Process for fluorinating aliphatic halohydrocarbons with a chromium fluoride catalyst and process for preparing the catalyst |
| DE1194826B (de) * | 1963-06-29 | 1965-06-16 | Hoechst Ag | Verfahren zur Stabilisierung und/oder Aktivierung von Fluorierungskatalysatoren der Chromoxyfluoridgruppe |
| DE1767200B1 (de) * | 1968-04-11 | 1971-12-30 | Hoechst Ag | Verfahren zur Regenerierung von Fluorierungskatalysatoren der Chromoxyfluoridgruppe |
| DE2702360A1 (de) * | 1977-01-21 | 1978-08-03 | Hoechst Ag | Verfahren zur reaktivierung von fluorierungskatalysatoren |
| JPS5617146A (en) * | 1979-07-20 | 1981-02-18 | Japan Steel Works Ltd:The | Production of long sized hollow material by outer circumferential restraining |
-
1984
- 1984-06-27 DE DE19843423625 patent/DE3423625A1/de not_active Withdrawn
-
1985
- 1985-06-15 DE DE8585107422T patent/DE3572314D1/de not_active Expired
- 1985-06-15 EP EP85107422A patent/EP0166336B1/de not_active Expired
- 1985-06-24 GR GR851545A patent/GR851545B/el unknown
- 1985-06-25 AR AR85300799A patent/AR242129A1/es active
- 1985-06-25 US US06/748,546 patent/US4578369A/en not_active Expired - Lifetime
- 1985-06-25 ES ES544541A patent/ES8604036A1/es not_active Expired
- 1985-06-26 CA CA000485281A patent/CA1242691A/en not_active Expired
- 1985-06-26 BR BR8503063A patent/BR8503063A/pt not_active IP Right Cessation
- 1985-06-26 AU AU44204/85A patent/AU567274B2/en not_active Ceased
- 1985-06-26 JP JP60138056A patent/JPS6115738A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| AR242129A1 (es) | 1993-03-31 |
| CA1242691A (en) | 1988-10-04 |
| BR8503063A (pt) | 1986-03-11 |
| EP0166336A2 (de) | 1986-01-02 |
| DE3572314D1 (en) | 1989-09-21 |
| US4578369A (en) | 1986-03-25 |
| JPS6115738A (ja) | 1986-01-23 |
| AU4420485A (en) | 1986-01-02 |
| AU567274B2 (en) | 1987-11-12 |
| EP0166336A3 (en) | 1987-10-28 |
| EP0166336B1 (de) | 1989-08-16 |
| GR851545B (en, 2012) | 1985-11-25 |
| ES8604036A1 (es) | 1986-02-01 |
| ES544541A0 (es) | 1986-02-01 |
| DE3423625A1 (de) | 1986-01-02 |
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