JPH0463915B2 - - Google Patents
Info
- Publication number
- JPH0463915B2 JPH0463915B2 JP57082053A JP8205382A JPH0463915B2 JP H0463915 B2 JPH0463915 B2 JP H0463915B2 JP 57082053 A JP57082053 A JP 57082053A JP 8205382 A JP8205382 A JP 8205382A JP H0463915 B2 JPH0463915 B2 JP H0463915B2
- Authority
- JP
- Japan
- Prior art keywords
- molasses
- fuel
- crude
- points
- waste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000013379 molasses Nutrition 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- 239000000446 fuel Substances 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 239000003924 oil dispersant Substances 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- 125000003158 alcohol group Chemical group 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000002699 waste material Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000005416 organic matter Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 3
- 235000019750 Crude protein Nutrition 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 235000019784 crude fat Nutrition 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- -1 that is Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
【発明の詳細な説明】
この発明は、アルコール残液の燃料化方法に関
するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for converting alcohol residual liquid into fuel.
従来、アルコール残液を、アルコール関係の工
場より廃液として大量に排出しており、一部家畜
飼料の添加剤、又は粘結剤として使用してはいる
ものの処分方法がなく、同残液は産業廃棄物とし
て指定されている。 Traditionally, large amounts of alcohol residual liquid have been discharged as waste liquid from alcohol-related factories, and although it has been used as an additive or binder in some livestock feed, there is no way to dispose of it, and the residual liquid is not used industrially. It is designated as waste.
この発明では濃縮排糖蜜に、引火点と発火点と
が異なる油を数種混合し、それに界面活性剤又は
乳化剤等の油分散剤を添加してなるアルコール残
液の燃料化方法を提供せんとするものである。 This invention aims to provide a method for converting alcohol residue into fuel by mixing several types of oils with different flash points and ignition points with concentrated molasses, and adding an oil dispersant such as a surfactant or an emulsifier to the mixture. It is something.
排糖蜜を常圧乾燥法により濃縮した後、分析試
験を行うと第１表のような結果となり、同結果よ
り排糖蜜は水分と同水分以外の成分、すなわち固
形分から成り、水分と固形分の比は約６：４の成
分比になつていることがわかる。 After concentrating waste molasses by normal pressure drying method, an analytical test was performed and the results were shown in Table 1.The results showed that waste molasses consists of water and components other than water, that is, solids. It can be seen that the ratio of components is about 6:4.
また、固形分中燃焼物となるのは粗蛋白・粗脂
肪・粗灰分、そして粗繊維の有機物であり、同有
機物を燃焼せしめた際には、1735kcal／Kgの高熱
量を発生するものであり、同高発熱量を発生せし
めて利用に供するためには、同排糖蜜を400℃〜
470℃の発火温度に高めなければならないことが
わかつている。 In addition, the combustible substances in the solid content are organic matter such as crude protein, crude fat, crude ash, and crude fiber, and when the organic matter is combusted, it generates a high amount of heat of 1735 kcal/Kg. In order to generate the same high calorific value and use it, the molasses must be heated to 400°C or more.
It has been found that the ignition temperature must be increased to 470°C.
そして、排糖蜜の発火温度を400℃〜470℃に高
めている原因は、固形分の分子に水分子が強固に
囲繞結合して、固形分子相互の結合を水分子が隔
絶した状態で微細に混合しているためであり、固
形分と水分の分離化は非常に困難なものとなつて
いる。 The reason why the ignition temperature of waste molasses is raised to 400°C to 470°C is that water molecules tightly surround and bond to the solid molecules, and the bonds between the solid molecules are broken down into fine particles while the water molecules are isolated. This is because they are mixed, making it extremely difficult to separate the solid content and water.
そこで、同有機物を燃焼させて高熱量を発生せ
しめる為の前段階の方法として、以下の方法を提
供する。 Therefore, the following method is provided as a preliminary method for burning the organic matter to generate a high amount of heat.
濃縮排糖蜜に、引火点と発火点とが異なる可燃
性物質としての油を数種混合すると共に、界面活
性剤又は乳化剤等の油分散剤を添加して濃縮排糖
蜜を燃料化するものである。 The concentrated waste molasses is converted into fuel by mixing several kinds of oils as combustible substances with different flash points and ignition points, and adding an oil dispersant such as a surfactant or an emulsifier.
前記のような方法を用いれば、濃縮排糖蜜中の
有機物を、直後400℃〜470℃という高発火温度ま
で高めずして、間接的、かつ合理的に有機物中の
燃焼物を燃焼せしめることができ、この際発生す
る高熱量を産業上有効に利用することができるも
のである。 By using the method described above, it is possible to indirectly and rationally combust the combustible materials in the organic matter in the concentrated waste molasses without immediately raising the ignition temperature to a high ignition temperature of 400°C to 470°C. The high amount of heat generated at this time can be used effectively in industry.
この発明によれば、排液として処分していた大
量のアルコール残液を、再度有効に燃料化するこ
とができるという効果を有する。 According to this invention, a large amount of residual alcohol liquid that has been disposed of as waste liquid can be effectively converted into fuel again.
第１表 分析試験結果 水分 57.9％ 粗蛋白 16.0％ 粗脂肪 2.7％ 粗灰分 4.2％ 粗繊維 0.4％ 可溶性無窒素物 18.8％ カルシウム 60.8mg％ リン 77.0mg％ 第２表 可燃性物質 引火点 燈 油 35〜50℃ 軽 油 50〜60℃ 重 油 60℃以上 機械油 130℃〜300℃ Table 1 Analysis test results Moisture 57.9% Crude protein 16.0% Crude fat 2.7% Crude ash 4.2% Crude fiber 0.4% Soluble nitrogen-free 18.8% Calcium 60.8mg% Phosphorus 77.0mg% Table 2 Flammable substances flash point Light oil 35-50℃ Light oil 50-60℃ Heavy oil 60℃ or higher Machine oil 130℃～300℃
Claims (1)
を数種混合し、それに界面活性剤又は乳化剤等の
油分散剤を添加してなるアルコール残液の燃料化
方法。1. A method for converting alcohol residue into fuel by mixing several types of oils with different flash points and ignition points with concentrated molasses, and adding an oil dispersant such as a surfactant or emulsifier to the mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8205382A JPS58198590A (en) | 1982-05-14 | 1982-05-14 | Convention of alcohol bottom into fuel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8205382A JPS58198590A (en) | 1982-05-14 | 1982-05-14 | Convention of alcohol bottom into fuel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58198590A JPS58198590A (en) | 1983-11-18 |
| JPH0463915B2 true JPH0463915B2 (en) | 1992-10-13 |
Family
ID=13763765
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8205382A Granted JPS58198590A (en) | 1982-05-14 | 1982-05-14 | Convention of alcohol bottom into fuel |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58198590A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8328128D0 (en) * | 1983-10-20 | 1983-11-23 | Sial N M | Fuels |
| IT1268891B1 (en) * | 1994-12-15 | 1997-03-13 | Alpha Trading Spa | LOW ENVIRONMENTAL IMPACT FUELS. |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56159289A (en) * | 1980-05-14 | 1981-12-08 | Yanmar Diesel Engine Co Ltd | Fuel for diesel engine |
-
1982
- 1982-05-14 JP JP8205382A patent/JPS58198590A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56159289A (en) * | 1980-05-14 | 1981-12-08 | Yanmar Diesel Engine Co Ltd | Fuel for diesel engine |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58198590A (en) | 1983-11-18 |
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