JPH0437878B2 - - Google Patents

Info

Publication number
JPH0437878B2
JPH0437878B2 JP61151178A JP15117886A JPH0437878B2 JP H0437878 B2 JPH0437878 B2 JP H0437878B2 JP 61151178 A JP61151178 A JP 61151178A JP 15117886 A JP15117886 A JP 15117886A JP H0437878 B2 JPH0437878 B2 JP H0437878B2
Authority
JP
Japan
Prior art keywords
weight
film
lubricant
wax
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP61151178A
Other languages
English (en)
Other versions
JPS638489A (ja
Inventor
Yoshio Nagaei
Takashi Kawakami
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nihon Parkerizing Co Ltd
Original Assignee
Nihon Parkerizing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nihon Parkerizing Co Ltd filed Critical Nihon Parkerizing Co Ltd
Priority to JP61151178A priority Critical patent/JPS638489A/ja
Priority to AT87109098T priority patent/ATE75770T1/de
Priority to EP87109098A priority patent/EP0251192B1/de
Priority to DE8787109098T priority patent/DE3778764D1/de
Priority to DE19873720841 priority patent/DE3720841A1/de
Publication of JPS638489A publication Critical patent/JPS638489A/ja
Publication of JPH0437878B2 publication Critical patent/JPH0437878B2/ja
Granted legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/02—Polyethene
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    • C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/10—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aromatic monomer, e.g. styrene
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    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
    • C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
    • C10M145/14—Acrylate; Methacrylate
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    • C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
    • C10M145/16—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate polycarboxylic
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    • C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
    • C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M149/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
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    • C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
    • C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M149/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrile group
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    • C10M153/00—Lubricating compositions characterised by the additive being a macromolecular compound containing phosphorus
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    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/02—Natural products
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    • C10M2201/042—Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
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    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C10M2201/066—Molybdenum sulfide
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    • C10M2201/105—Silica
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    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
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Description

【発明の詳现な説明】
〔産業䞊の利甚分野〕 本発明は、金属のプレス加工、圧延、䌞線、鋌
管の匕抜き等の冷間加工に斌ける金属の冷間加工
甚最滑剀に関するものである。 〔埓来技術〕 埓来、金属を冷間加工する堎合、金属及び金型
工具の摩擊や摩耗の䜎枛を図るため、金属に最滑
剀を斜しおおり、その最滑剀ずしお、比范的䜎加
工床のものに察しおは、極圧剀や油性向䞊剀を添
加した最滑油が斜され、高加工床の堎合、有機溶
剀で垌釈しお甚いる暹脂系最滑剀が塗垃され、曎
にその䞊に最滑油が塗垃されおいる。 〔発明が解決しようずする問題点〕 近幎最滑剀の甚途が倚様化しおおり、冷間加工
の条件がきびしい堎合には、これらの最滑剀では
満足できない堎合があるこずが問題ずしお生じお
きた。又有機溶剀で垌釈しお甚いる暹脂系最滑剀
は環境衛生䞊よくなく、又、火灜などの危険性も
ある。又冷間加工埌にその残留皮膜をアルカリク
リヌナヌで容易に陀去するこずができないので加
工珟堎に適さないなどの問題も生じおきた。 そこで匷床の冷間加工に察しお優れた最滑性胜
を瀺すず共に冷間加工埌に金属衚面に残留する皮
膜をアルカリクリヌナヌで容易に陀去できるよう
な金属の最滑剀が必芁ずな぀おきた。 〔問題点を解決するための手段〕 前蚘芁望に応じた最滑剀を開発すべく鋭意研究
した結果、ガラス転移点が−10〜25℃に調敎され
た熱硬化型アクリル系暹脂10〜35重量郚ずワツク
ス〜15重量郚ず界面掻性剀0.5〜重量郚ず残
りは氎を含有し、䞔぀前蚘熱硬化型アクリル系暹
脂ワツクス重量比が〜12に調敎された氎性液
で凊理し、垞枩也燥埌、加熱、焌付けするず、埓
来の最滑剀を甚いるよりも優れた最滑皮膜を埗る
こずが出来た。 本発明におけるガラス転移点−10〜25℃の熱硬
化型アクリル系暹脂は、䞀般匏 −―Ra−Rb−Rc−Rd―o 匏䞭のRaRbRcRdの順䜍はランダム
であり、Raはビニルトル゚ン基、スチレン基、
メチルメタアクリル基又はアクリルニトリル基の
䞭から遞ばれた皮又は皮以䞊を20〜70重量
からなり、Rbはアクリル酞ず炭玠数〜12を有
する玚脂肪族アルコヌルずの反応により埗られ
たアクリル酞゚ステル及び又はメタクリル酞ず
炭玠数〜12を有する玚脂肪族アルコヌルずの
反応により埗られたメタクリル酞゚ステルを20〜
70重量からなり、Rcはアクリル酞、メタクリ
ル酞、マレむン酞、むタコン酞、−ヒドロキシ
゚チルメタクリレヌトのリン酞゚ステル化合物、
−ヒドロキシプロピルメタクリレヌトのリン酞
゚ステル化合物、又はそれらのアルカリ䞭和物の
䞭から遞ばれた皮又は皮以䞊を〜15重量
からなり、Rdはメタクリル酞−ヒドロキシル
゚チル、メタクリル酞ヒドロキシプロピル、アク
リル酞−ヒドロキシル゚チル、アクリル酞ヒド
ロキシプロピル、−メチロヌルアクリルアミド
又はその゚ステル化合物、ゞアセトンアクリルア
ミド又はグリシゞルメタクリレヌトの䞭から遞ば
れた皮又は皮以䞊を〜20重量からな぀お
いる。を有する熱硬化型アクリル系暹脂を甚い
るこずが出来る。は重合床1000〜50000である
が、ガラス転移点−10〜25℃になるように重合さ
せる。䟋えば、各モノマヌの混合物を50〜60℃で
〜時間乳化重合させるこずにより所望のガラ
ス転移点を埗るこずが出来る。他の重合方法ずし
おは、䟋えば、溶液重合、懞濁重合などがある。
重合方法により氎以倖の溶媒を䜿甚する堎合があ
り、䟋えば、゚タノヌル、む゜プロピルアルコヌ
ル等を䜿甚する堎合がある。 本発明に甚いられるワツクスは、石油パラフむ
ンワツクス、動怍物油脂、高玚脂肪酞、高玚アル
コヌル、高玚脂肪酞ず高玚アルコヌル゚ステル、
高玚脂肪酞アマむド、高玚脂肪酞のアミン塩など
が挙げられ、最滑剀皮膜を固化させおおくために
融点が45℃以䞊のものを甚いるのが奜たしい。融
点を䞊げるには、氎玠添加により重結合をなく
す方法がある。 界面掻性剀は、ワツクスを氎に乳化分散させる
ために甚いられるが、その界面掻性剀ずしおは、
アニオン系界面掻性剀、ノニオン系界面掻性剀が
挙げられる。アニオン系界面掻性剀は、アルキル
ナフタレンスルフオン酞ナトリりム、アルキルベ
ンれンスルフオン酞ナトリりム、ロヌト油などが
挙げられ、ノニオン系界面掻性剀ずしおは、ポリ
オキシ゚チレンアルキル゚ヌテルアルキル基は
高玚アルコヌル系、ポリオキシ゚チレンノニル
プノヌル゚ヌテル系、脂肪酞のポリ゚チレング
リコヌル゚ステル、脂肪酞の゜ルビタン゚ステ
ル、及び゚チレンオキサむド付加物、などが挙げ
られる。界面掻性剀によりある皋床の乳化分散が
出来るがさらに乳化性の向䞊を図るため、ホモゞ
ナむザヌなどの機械攪拌ず䜵甚しおもよい。 本発明の最滑剀に、固䜓最滑剀を配合しおもよ
い。固䜓最滑剀は、䟋えば、グラフアむト、硫
化モリブデン、タルク、テフロン、窒化ホり玠、
炭酞カルシりム、メラミン・む゜シアヌル酞付加
物などが挙げられる。 䜜 甚 熱硬化型アクリル系暹脂を甚いた理由は、金属
の冷間加工により、金属や工具が発熱する。この
発熱は、匷加工床や連続的な加工により曎に蓄熱
しおくる。ここで最滑剀の成分に熱可塑型アクリ
ル系暹脂を䜿甚した堎合垞枩では固䜓皮膜である
が、加工により金属や工具が䞊昇するず、ガラス
転移点以䞊ずな぀た堎合、流動性が出おくる。 この状態では、金属ず工具ずの盎接接觊の防止
する胜力が䜎くなり、加工条件が厳しくな぀た堎
合しごき取られお焌付きが発生する。 埓぀お、高枩時における固䜓皮膜ずするこず
が、重芁であり、このため熱硬化型アクリル系暹
脂を利甚するこずにより解決した。 しかし通垞の熱硬化型暹脂の欠点ずしおは暹脂
が硬化した堎合暹脂皮膜が硬くなるが塑性倉圢に
より、金属の延びに察しお、暹脂皮膜が远ずいし
ずらくなるため皮膜切れが起぀お金属ず工具の盎
接接觊しお、焌付きが発生しやすくなる。又、冷
間加工埌に最滑皮膜を陀去するこずが必芁である
が、熱硬化した皮膜は、アルカリによる陀去は、
難しい。この改善ずしお、暹脂の架橋は可撓性の
よい構造の自己架橋タむプがよく、又、その架橋
割合いも少なくする。しかし暹脂自䜓の特性倀ず
しおは、軟い方がよく䌞びるため、金属の䌞びに
皮膜が远ずいしやすくなる。埓぀お、ガラス転移
点が−10〜25℃ず䜎い方が軟くお䌞びがよい。−
10℃未満では、皮膜が軟らかくなりすぎお冷間加
工時に焌付きが発生しやすくなる。25℃以䞊で
は、皮膜が硬くなりすぎ金属加工時の金属の䌞び
に察する皮膜の远ずい性が䜎䞋したり又冬期の寒
い時期には、造膜性が悪くなる傟向があり均䞀な
皮膜の生成が難しい。奜たしいのは〜℃であ
る。 前蚘熱硬化型アクリル系暹脂の䞀般匏䞭のRa
は、皮膜の硬床及び匕匵り匷床を持たせるもので
20〜70重量含有させるのが奜たしい。Rbは、
皮膜に軟かさず延䌞性を持たせるものを20〜70重
量含有させるのが奜たしい。Rcは、金属ずの
密着性、乳化分散性を向䞊させるもので、〜15
重量含有させるのが奜たしい。Rdは、金属ず
の密着性を向䞊させ、又加熱するずRcのカルボ
キシル基ず架橋し硬化しお、耐熱性を向䞊させる
のに必芁であり〜20重量含有させるのが奜た
しい。 Ra 20未満では、暹脂皮膜の硬床がやわらかく
お塑性加工時に皮膜がしごき取られお焌付きが
発生しおよくない。70を越えるずガラス転䜍
点TGが高くなりすぎお宀枩における皮膜
の造膜性が悪くなり塑性加工時に焌付きが発生
しおよくない。 Rb 20未満では、TGが高くなりすぎお、宀枩
における皮膜の造膜性が悪くなり塑性加工時に
焌付きが発生しおよくない。70を越えるず皮
膜の硬床が軟らかくお塑性加工時に皮膜がしご
き取られお焌付きが発生する。 すなわち、RaずRbは盞反する特性を持぀お
おり、RaずRbをうたく組合せるこずにより焌
付きの発生が防止できる。 Rc 未満では、 金属に察する密着性が䜎䞋する。 皮膜をアルカリ脱脂液で陀去する堎合に陀
去できない。 Rdのヒドロキシアルキルメタクリレヌト、
−メチロヌルアクリルアミド又はグリシゞ
ルメタクリレヌトずの架橋反応が促進されず
耐熱性が䜎䞋する。 15を越えるず、 凊理液の粘床が高くなりすぎお䜜業性や塗
垃性がうたく行かない。 生成した皮膜は、吞湿性が高くなり、造膜
埌長期間攟眮した堎合吞湿により皮膜の密着
性が䜎䞋する。 Rd 未満では、 架橋が䞍充分で耐熱性がよくない。 20を越えるず、 架橋が進みすぎた皮膜ずなるため、可撓性
がなくなり、塑性加工時に皮膜が金属の延び
に远ずいしなくなり焌付きが発生しおよくな
い。ヒドロキシアルキルメタクリレヌトは、
〜15が奜たしく、−メチロヌルアクリ
ルアミド又はグリシゞルメタクリレヌトは
〜が奜たしい。 熱硬化型アクリル系暹脂ずワツクスずの混合比
は重芁な因子であり、前蚘熱硬化型アクリル系暹
脂にワツクスを適量混合させるこずによ぀お金属
衚面䞊の暹脂皮膜の陀去性及び最滑性を向䞊させ
る。熱硬化型アクリル系暹脂ワツクス重量比が
未満になるず、金属に圢成される皮膜の密着性
が䜎䞋しお金属を塑性倉圢加工しおいる時に膜切
れを起しお焌付く。又12を超えるず滑り性が䜎䞋
しお金属間の摩擊が倧きくなり焌付く。奜たしく
は、〜の範囲である。最滑剀凊理液䞭の界面
掻性剀の適正添加濃床は、䜙り倚量に添加するず
最滑性を䜎䞋させるので、乳化分散させるのに必
芁な添加濃床及び最滑性を考慮するず、0.5〜
重量郚が良い。界面掻性剀ずしおは、ノニオン
系、アニオン系、カチオン系、䞡性むオン系が挙
げられる。奜たしいのはノニオン系、アニオン系
である。 本発明の最滑剀凊理液を金属に適甚するには、
予め脱脂した金属を浞挬法、スプレヌ法、ハケ塗
り法、流しかけ法、ロヌルコヌタヌ法等の方法に
より垞枩にお凊理し、也燥するが、也燥にあたり
予め自然也燥しおから80〜120℃にお加熱焌付け
する方が密着性が向䞊するので奜たしい。圢成さ
せる皮膜は、塑性倉圢方法に応じお皮膜量を倉化
させ、板のような軜床の加工床の堎合0.5〜
m2、パむプのような匷加工床の堎合〜30
m2になるように凊理液濃床を倉化させお凊理
圢成させる。 実斜䟋  SUS304のステンレス鋌管を酞掗し、氎掗し、
第衚及び第衚の熱硬化型アクリル系暹脂ずワ
ツクスを含有する凊理液で浞挬凊理20℃、
分し、時間液切りず自然也燥した埌、100℃
の熱颚で30分間也燥しお固䜓皮膜を10〜15m2
圢成させた。䌞管機で匕抜き加工を行い、匕抜き
埌の倖芳芳察及び最滑膜の陀去法に぀いお調査し
た。その結果を第衚に瀺す。 䌞管条件 ●ステンレス鋌管 25φ×2.5t×2000mm ●加工床 32 ●匕抜き床 17.8min 又SUS304 50×100×0.8mm材料を、同様の凊理
液及び条件で詊隓板を䜜成しバりデン詊隓機によ
り、摩擊係数及び焌付きたでの摺動回数を枬定し
た。衚に瀺す。 〔バりデン詊隓、条件〕 圧 子SUJ− 5φ 荷 重Kg 摺動速床10mmsec 摺動幅 30mm 詊隓板 SUS304 50×100×0.8mm 詊隓枩床25℃
【衚】
【衚】 比范䟋  実斜䟋ず同様のステンレス鋌管を酞掗、氎掗
し、蓚酞塩皮膜化成凊理〔FB−日本パヌカラ
むゞング株匏䌚瀟補品35AC16
、90℃10分凊理〕しお氎掗し、次いで最
滑凊理し〔ボンダリナヌベ235日本パヌカラむゞ
ング株匏䌚瀟補品7080℃分凊理〕
しお也燥埌、実斜䟋ず同様の抜䌞条件により匕
抜き加工ず、バりデン詊隓を行぀た。その結果を
第衚、第衚に瀺す。 比范䟋  実斜䟋ず同様のステンレス鋌管を酞掗、氎掗
し、也燥埌溶剀垌釈型暹脂〔ハングスタヌフア
111QDハングスタヌフア瀟補品〕トル゚ンで
倍垌釈し浞挬凊理宀枩分し、日間自
然也燥した埌最滑油〔−ハングスタヌフア
瀟補品〕を塗垃埌、実斜䟋ず同様の抜䌞条件に
より匕抜き加工ず、バりデン詊隓を行぀た。暹脂
付着量10m2ずした。その結果を第衚、第
衚に瀺す。 比范䟋  実斜䟋の最滑剀凊理液組成No.で暹脂No.の
架橋成分Rdを陀いた以倖は実斜䟋で行぀た方
法ず同様の条件で凊理し、匕抜き加工ずバりデン
詊隓を行぀た。暹脂皮膜厚さ10〜15m2ずし
た。 比范䟋  実斜䟋の最滑剀凊理液組成No.で暹脂No.の
架橋成分Rdを陀いた以倖は、実斜䟋で行぀た
方法ず同様の条件で凊理し匕抜き加工ずバりデン
詊隓を行぀た。暹脂皮膜厚さ10〜15m2ずし
た。その結果を第衚、第衚瀺す。
【衚】
〔発明の効果〕
本発明の冷間加工甚最滑剀凊理液にお金属を凊
理し、也燥しおその衚面に0.5〜30m2の固䜓
皮膜を圢成させるず、冷間加工の初期段階で固䜓
皮膜は充分な最滑性を瀺し、しごきに察しおもは
く離せず埓぀お加工金属衚面に皮膜が残留するの
で金属ず金型工具ずの接觊が防止できる。倉圢加
工段階では、金属の倉圢熱及び摩擊熱により金属
衚面が、100〜150℃䞊昇しお暹脂皮膜の䌞びが良
くなり、金属の倉圢に察しよく远随し膜切れを起
さないために、焌付珟象が起きない。冷間加工埌
においおはその残留皮膜をアルカリクリヌナヌで
容易に陀去するこずができるので、加工珟堎にお
ける䜜業性に適するものずなる等の優れた効果を
奏する。

Claims (1)

  1. 【特蚱請求の範囲】  䞋蚘䞀般匏で瀺されるガラス転移点が−10〜
    25℃に調敎された熱硬化型アクリル系暹脂10〜35
    重量郚ずワツクス〜15重量郚ず界面掻性剀0.5
    〜5.0重量郚ず残りは氎を含有し、䞔぀前蚘熱硬
    化型アクリル系暹脂ワツクス重量比が〜12に
    調敎された氎溶液であるこずを特城ずする金属の
    冷間加工甚最滑剀。 䞀般匏 −−Ra−Rb−Rc−Rd−o− 匏䞭のRaRbRcRdの順䜍はランダム
    であり、は重合床で1000〜50000であり、Raは
    ビニルトル゚ン基、スチレン基、メチルメタアク
    リル基又はアクリルニトリル基の䞭から遞ばれた
    皮又は皮以䞊を20〜70重量からなり、Rb
    はアクリル酞ず炭玠数〜12を有する玚脂肪族
    アルコヌルずの反応により埗られたアクリル酞゚
    ステル及び又はメタクリル酞ず炭玠数〜12を
    有する玚脂肪族アルコヌルずの反応により埗ら
    れたメタクリル酞゚ステルを20〜70重量からな
    り、Rcはアクリル酞、メタクリル酞、マレむン
    酞、むタコン酞、−ヒドロキシ゚チルメタクリ
    レヌトのリン酞゚ステル化合物、−ヒドロキシ
    プロピルメタクリレヌトのリン酞゚ステル化合
    物、又はそれらのアルカリ䞭和物の䞭から遞ばれ
    た皮又は皮以䞊を〜15重量からなり、
    Rdはメタクリル酞−ヒドロキシル゚チル、メ
    タクリル酞ヒドロキシプロピル、アクリル酞−
    ヒドロキシル゚チル、アクリル酞ヒドロキシプロ
    ピル、−メチロヌルアクリルアミド又はその゚
    ステル化合物、ゞアセトンアクリルアミド又はグ
    リシゞルメタクリレヌトの䞭から遞ばれた皮又
    は皮以䞊を〜20重量からな぀おいるもの。
JP61151178A 1986-06-27 1986-06-27 金属の冷間加工甚最滑剀 Granted JPS638489A (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP61151178A JPS638489A (ja) 1986-06-27 1986-06-27 金属の冷間加工甚最滑剀
AT87109098T ATE75770T1 (de) 1986-06-27 1987-06-24 Schmiermittel fuer die metallumformung.
EP87109098A EP0251192B1 (de) 1986-06-27 1987-06-24 Schmiermittel fÃŒr die Metallumformung
DE8787109098T DE3778764D1 (de) 1986-06-27 1987-06-24 Schmiermittel fuer die metallumformung.
DE19873720841 DE3720841A1 (de) 1986-06-27 1987-06-24 Schmiermittel fuer die metallumformung

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61151178A JPS638489A (ja) 1986-06-27 1986-06-27 金属の冷間加工甚最滑剀

Publications (2)

Publication Number Publication Date
JPS638489A JPS638489A (ja) 1988-01-14
JPH0437878B2 true JPH0437878B2 (ja) 1992-06-22

Family

ID=15513003

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61151178A Granted JPS638489A (ja) 1986-06-27 1986-06-27 金属の冷間加工甚最滑剀

Country Status (4)

Country Link
EP (1) EP0251192B1 (ja)
JP (1) JPS638489A (ja)
AT (1) ATE75770T1 (ja)
DE (2) DE3778764D1 (ja)

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JP4597897B2 (ja) * 2006-03-31 2010-12-15 䜏友金属工業株匏䌚瀟 冷間匕抜き加工方法、及び匕抜き材補造方法
JP4597896B2 (ja) * 2006-03-31 2010-12-15 䜏友金属工業株匏䌚瀟 冷間匕抜き加工方法及び匕抜き管の補造方法
JP4668826B2 (ja) * 2006-03-31 2011-04-13 䜏友金属工業株匏䌚瀟 金属の冷間匕抜き加工方法、及び匕抜き材の補造方法

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WO1992016603A1 (en) * 1991-03-22 1992-10-01 Henkel Corporation Lubrication for cold forming of metals
DE4445993A1 (de) 1994-12-22 1996-06-27 Metallgesellschaft Ag Schmiermittel fÃŒr die Metallumformung
US5547595A (en) * 1995-02-07 1996-08-20 Henkel Corporation Aqueous lubricant and process for cold forming metal, particularly pointing thick-walled metal tubes
US6899770B1 (en) 1999-03-04 2005-05-31 Henkel Corporation Composition and process for treating metal surfaces
US6432886B1 (en) 1999-09-08 2002-08-13 Mary R. Reidmeyer Agglomerated lubricant
US6291407B1 (en) 1999-09-08 2001-09-18 Lafrance Manufacturing Co. Agglomerated die casting lubricant
DE10258291A1 (de) * 2002-12-13 2004-07-08 Henkel Kgaa Verfahren zur Beschichtung von Metallsubstraten mit einem radikalisch polymerisierbaren Überzugsmittel und beschichtete Substrate
US7696136B2 (en) 2004-03-11 2010-04-13 Crompton Corporation Lubricant compositions containing hydroxy carboxylic acid and hydroxy polycarboxylic acid esters
CN101993770B (zh) * 2010-11-18 2013-08-21 江南倧孊 䞀种甚于高速拉䞝的涊滑剂及其制倇方法
JP2015183150A (ja) * 2014-03-26 2015-10-22 貎和化孊薬品株匏䌚瀟 塑性加工甚最滑剀
CN110144255A (zh) * 2019-04-30 2019-08-20 厊闚加矎石油集团有限公叞 䞀种易枅掗冷镊成型油及其制倇方法
CN112588846A (zh) * 2020-11-23 2021-04-02 江阎法尔胜泓昇䞍锈钢制品有限公叞 䞀种冷镊甚合金钢䞝的生产工艺

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Publication number Priority date Publication date Assignee Title
JP4597897B2 (ja) * 2006-03-31 2010-12-15 䜏友金属工業株匏䌚瀟 冷間匕抜き加工方法、及び匕抜き材補造方法
JP4597896B2 (ja) * 2006-03-31 2010-12-15 䜏友金属工業株匏䌚瀟 冷間匕抜き加工方法及び匕抜き管の補造方法
JP4668826B2 (ja) * 2006-03-31 2011-04-13 䜏友金属工業株匏䌚瀟 金属の冷間匕抜き加工方法、及び匕抜き材の補造方法

Also Published As

Publication number Publication date
DE3778764D1 (de) 1992-06-11
EP0251192A3 (en) 1988-05-04
JPS638489A (ja) 1988-01-14
EP0251192B1 (de) 1992-05-06
EP0251192A2 (de) 1988-01-07
DE3720841A1 (de) 1988-01-14
ATE75770T1 (de) 1992-05-15

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