JPH04338613A - Magnetic shielding resin - Google Patents

Magnetic shielding resin

Info

Publication number
JPH04338613A
JPH04338613A JP3140895A JP14089591A JPH04338613A JP H04338613 A JPH04338613 A JP H04338613A JP 3140895 A JP3140895 A JP 3140895A JP 14089591 A JP14089591 A JP 14089591A JP H04338613 A JPH04338613 A JP H04338613A
Authority
JP
Japan
Prior art keywords
resin
sealing resin
magnetic sealing
powder
core
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3140895A
Other languages
Japanese (ja)
Inventor
Yoshinori Saito
斉  藤   芳  則
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Murata Manufacturing Co Ltd
Original Assignee
Murata Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Murata Manufacturing Co Ltd filed Critical Murata Manufacturing Co Ltd
Priority to JP3140895A priority Critical patent/JPH04338613A/en
Publication of JPH04338613A publication Critical patent/JPH04338613A/en
Pending legal-status Critical Current

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  • Insulating Of Coils (AREA)

Abstract

PURPOSE:To obtain magnetic shielding resin having small stress to be generated at curing time by adding silicon resin powder. CONSTITUTION:Magnetic shielding resin 26 is molded around a core and a coil 20. This magnetic shielding resin 26 contains thermosetting type resin, for instance, such as epoxy resin, phenol resin or a copolymer resin thereof, and this thermosetting type resin contains ferrite powder as magnetic powder for heightening its magnetic permeability, further powder of silicon resin is added thereto in order to lower its elastic modules. In this way, as compared with magnetic shielding resin not containing silicon resin powder, the elastic modulus of magnetic shielding resin 26 reduced so as to reduce stress imposed on the core 12 at the time of curing magnetic shielding resin.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】この発明は磁性封止樹脂に関し、
特にたとえば、チップ型コイル素子のコアおよびコイル
の周囲にモールドされる、磁性封止樹脂に関する。
[Industrial Application Field] This invention relates to magnetic sealing resin.
In particular, the present invention relates to a magnetic sealing resin that is molded around the core and coil of a chip-type coil element.

【0002】0002

【従来の技術】この種の従来の磁性封止樹脂には、エポ
キシ樹脂に透磁率を上げるためにフェライト粉末を充填
したものがあった。この磁性封止樹脂は、フェライト粉
末を含有しない通常のエポキシ樹脂からなる封止樹脂よ
りも弾性率が高い。
2. Description of the Related Art Conventional magnetic sealing resins of this type include epoxy resins filled with ferrite powder to increase magnetic permeability. This magnetic sealing resin has a higher elastic modulus than a sealing resin made of a normal epoxy resin that does not contain ferrite powder.

【0003】0003

【発明が解決しようとする課題】このような磁性封止樹
脂でチップ型コイル素子の周囲をモールドする場合、磁
性封止樹脂の硬化時において、磁性封止樹脂からコアに
対して応力がかかる。また、この磁性封止樹脂でモール
ドされるコアのつばの部分は、その厚みがたとえば0.
5mm程度に形成され、その強度が最も弱い。そのため
、磁性封止樹脂からコアにかかる応力によって、特に、
コアのつばの部分にクラックが発生することがあった。
When the periphery of a chip-type coil element is molded with such a magnetic sealing resin, stress is applied from the magnetic sealing resin to the core when the magnetic sealing resin hardens. Further, the thickness of the brim portion of the core molded with this magnetic sealing resin is, for example, 0.
It is formed with a thickness of about 5 mm, and its strength is the weakest. Therefore, due to the stress applied to the core from the magnetic sealing resin,
Cracks sometimes occurred at the brim of the core.

【0004】そこで、コアにかかる磁性封止樹脂からの
応力を低減させてクラックの発生を防止するために、フ
ェライト粉末などの無機充填材料を高充填化することに
よってコアと磁性封止樹脂との熱膨張係数の差を低下さ
せる方法やシリコンオイルなどを添加して樹脂のマトリ
ックス中に応力を低下させる他の材料を島状に分散させ
ることによって磁性封止樹脂の弾性率を低下させる方法
などが用いられているが、成形性や材料の信頼性の影響
からこれらの方法による磁性封止樹脂の低応力化に限界
がある。たとえば、シリコンオイルは、反応に寄与しな
いため、硬化した樹脂中に液状で存在する。そのため、
シリコンオイルの添加量には限界がある。さらに、シリ
コンオイルは樹脂の硬化後もその表面に浮き出てくる場
合があり、その場合は製品の信頼性に欠ける。
[0004] Therefore, in order to reduce the stress from the magnetic sealing resin applied to the core and prevent the occurrence of cracks, the bond between the core and the magnetic sealing resin is increased by increasing the amount of inorganic filler material such as ferrite powder. There are methods to reduce the elastic modulus of magnetic sealing resin by reducing the difference in thermal expansion coefficients, and by adding silicone oil and other materials that reduce stress in the resin matrix by dispersing them in island shapes. However, there are limits to the reduction of stress in magnetic sealing resins by these methods due to the influence of moldability and reliability of the material. For example, silicone oil exists in a liquid state in the cured resin because it does not contribute to the reaction. Therefore,
There is a limit to the amount of silicone oil that can be added. Furthermore, silicone oil may float on the surface of the resin even after it has hardened, and in this case, the reliability of the product is compromised.

【0005】それゆえに、この発明の主たる目的は、硬
化時に生じる応力の小さい磁性封止樹脂を提供すること
である。
[0005] Therefore, the main object of the present invention is to provide a magnetic sealing resin that generates less stress during curing.

【0006】[0006]

【課題を解決するための手段】この発明は、シリコン樹
脂の粉末が添加された、磁性封止樹脂である。
[Means for Solving the Problems] The present invention is a magnetic sealing resin to which silicone resin powder is added.

【0007】[0007]

【作用】シリコン樹脂の粉末を含有した磁性封止樹脂は
、弾性率が低くなる。そのため、硬化時に生じる応力が
低下する。
[Operation] Magnetic sealing resin containing silicone resin powder has a low elastic modulus. Therefore, the stress generated during curing is reduced.

【0008】[0008]

【発明の効果】この発明によれば、硬化時に生じる応力
の小さい磁性封止樹脂が得られる。そのため、この磁性
封止樹脂でたとえばチップ型コイル素子のコアおよびコ
イルをモールドすれば、磁性封止樹脂からコアにかかる
応力によってコアにクラック等が発生しにくくなる。
According to the present invention, a magnetic sealing resin with low stress generated during curing can be obtained. Therefore, if the core and coil of a chip-type coil element, for example, are molded with this magnetic sealing resin, cracks and the like are less likely to occur in the core due to stress applied to the core from the magnetic sealing resin.

【0009】この発明の上述の目的,その他の目的,特
徴および利点は、図面を参照して行う以下の実施例の詳
細な説明から一層明らかとなろう。
The above objects, other objects, features and advantages of the present invention will become more apparent from the following detailed description of embodiments with reference to the drawings.

【0010】0010

【実施例】図1はこの発明の背景となり、かつ、この発
明が適用されるチップ型コイル素子の一例を示す断面図
である。このチップ型コイル素子10はコア12を含む
。コア12は、たとえば円柱状の軸14を含み、軸14
の両端には、たとえば4角板状のつば16および18が
それぞれ形成されている。このコア12の軸14の周囲
には、コイル20が巻かれる。また、コア12の一方の
つば16の表面には、端子22および24が固着される
。これらの端子22および24には、コイル20が電気
的に接続される。
DESCRIPTION OF THE PREFERRED EMBODIMENTS FIG. 1 is a cross-sectional view showing an example of a chip-type coil element which forms the background of the present invention and to which the present invention is applied. This chip-type coil element 10 includes a core 12 . The core 12 includes a cylindrical shaft 14, for example, and the shaft 14
For example, rectangular plate-shaped collars 16 and 18 are formed at both ends, respectively. A coil 20 is wound around the axis 14 of this core 12. Furthermore, terminals 22 and 24 are fixed to the surface of one collar 16 of the core 12. A coil 20 is electrically connected to these terminals 22 and 24.

【0011】一方、コア12およびコイル20の周囲に
は、磁性封止樹脂26がモールドされる。この磁性封止
樹脂26は、たとえばエポキシ樹脂,フェノール樹脂あ
るいはこれらの共重合体樹脂などの熱硬化型樹脂を含み
、この熱硬化型樹脂には、透磁率を上げるために、磁性
粉末としてのフェライト粉末が含有され、さらに、弾性
率を低下させるために、シリコン樹脂の粉末が添加され
ている。
On the other hand, a magnetic sealing resin 26 is molded around the core 12 and coil 20. The magnetic sealing resin 26 includes a thermosetting resin such as an epoxy resin, a phenol resin, or a copolymer resin thereof, and the thermosetting resin contains ferrite as a magnetic powder to increase magnetic permeability. Powder is included, and silicone resin powder is also added to reduce the elastic modulus.

【0012】この磁性封止樹脂26中の熱硬化型樹脂と
しては、耐熱性に優れ、かつ、低溶融粘度のものを用い
ることが好ましい。また、熱硬化型樹脂としては、溶融
粘度が150℃で5000cps以下のものを用いるこ
とが好ましい。これは、溶融粘度が低いほどモールドが
容易だからである。また、磁性封止樹脂26中の磁性粉
末については、その粒径が数10μm径程度のものを用
いることができるが、成形性を考慮した場合、10μm
〜30μmの磁性粉末を用いることが好ましい。さらに
、シリコン樹脂の粉末としては、その粒径がたとえば1
0μm以下のものが好ましい。このようにシリコン樹脂
の粉末の粒径を小さくそろえれば、磁性封止樹脂26に
おいて応力低下の効果が大きい。
It is preferable to use a thermosetting resin in the magnetic sealing resin 26 that has excellent heat resistance and low melt viscosity. Further, as the thermosetting resin, it is preferable to use one having a melt viscosity of 5000 cps or less at 150°C. This is because the lower the melt viscosity, the easier it is to mold. Further, as for the magnetic powder in the magnetic sealing resin 26, particles having a particle size of about several tens of micrometers can be used, but when moldability is taken into account, it is 10 micrometers.
It is preferable to use magnetic powder of ~30 μm. Furthermore, the particle size of the silicone resin powder is, for example, 1
Preferably, the thickness is 0 μm or less. If the particle size of the silicone resin powder is made small in this way, the effect of reducing stress in the magnetic sealing resin 26 is large.

【0013】なお、端子22および24は、コア12の
下方で磁性封止樹脂26の表面に沿って折り曲げられて
いる。
Note that the terminals 22 and 24 are bent below the core 12 along the surface of the magnetic sealing resin 26.

【0014】このチップ型コイル素子10では、その磁
性封止樹脂26中にシリコン樹脂の粉末が添加されてい
るので、シリコン樹脂の粉末を含まない磁性封止樹脂に
比べて、磁性封止樹脂26の弾性率が小さくなり、磁性
封止樹脂26を硬化するときにコア12にかかる応力が
小さくなる。そのため、コア12の最も強度の弱いつば
16および18にクラックが生じにくくなる。
In this chip-type coil element 10, since silicone resin powder is added to the magnetic sealing resin 26, the magnetic sealing resin 26 is lower than that of a magnetic sealing resin that does not contain silicone resin powder. The elastic modulus of the core 12 becomes smaller, and the stress applied to the core 12 when the magnetic sealing resin 26 is cured becomes smaller. Therefore, cracks are less likely to occur in the flanges 16 and 18 of the core 12, which have the weakest strength.

【0015】次に、このチップ型コイル素子10の製造
方法の一例について説明する。まず、コイル20を巻い
たコア12を、図2に示すように、金属製の端子材30
上に固定する。この場合、コア12のつば16を、端子
材30の間隔を隔てて対向する2つの片32および34
上に固定する。なお、端子材30の2つの片32および
34は、図2の1点鎖線Aで示すそれらの根元部分で切
断されて、端子16および18として構成されるもので
ある。そして、端子材30上に固定されたコア12を、
図3に示す金型40のキャビティ42内に配置する。そ
の後、トランスファポット44から溶融状態の磁性封止
樹脂26を注入し、トランスファ・モールドを行い、コ
ア12およびコイル20の周囲を磁性封止樹脂26で被
覆する。そして、図2の1点鎖線Aに沿って端子材30
を切断することによって2つの端子22および24を形
成し、それらの端子22および24をコア12の下方で
折り曲げて、図1に示すチップ型コイル素子10を得る
Next, an example of a method for manufacturing the chip-type coil element 10 will be explained. First, as shown in FIG.
Fix it on top. In this case, the collar 16 of the core 12 is separated from the two pieces 32 and 34 facing each other with the terminal material 30 spaced apart.
Fix it on top. The two pieces 32 and 34 of the terminal material 30 are cut at their root portions indicated by the dashed line A in FIG. 2 to form the terminals 16 and 18. Then, the core 12 fixed on the terminal material 30 is
It is placed in a cavity 42 of a mold 40 shown in FIG. Thereafter, molten magnetic sealing resin 26 is injected from transfer pot 44 and transfer molding is performed to cover the core 12 and coil 20 with magnetic sealing resin 26 . Then, the terminal material 30 is
are cut to form two terminals 22 and 24, and these terminals 22 and 24 are bent below the core 12 to obtain the chip-type coil element 10 shown in FIG.

【0016】上述の製造方法に従って、表1に示す各種
合成樹脂材を用いてトランスファ・モールドを行って、
実施例1〜3および比較例1〜3のチップ型コイル素子
を得た。なお、実施例1〜3と比べて、比較例1および
2ではシリコン粉末に代えてシリコンオイルを添加し、
比較例3ではシリコン樹脂の粉末もシリコンオイルも添
加していない。
According to the above manufacturing method, transfer molding was performed using various synthetic resin materials shown in Table 1.
Chip-type coil elements of Examples 1 to 3 and Comparative Examples 1 to 3 were obtained. In addition, compared to Examples 1 to 3, in Comparative Examples 1 and 2, silicon oil was added instead of silicon powder,
In Comparative Example 3, neither silicone resin powder nor silicone oil was added.

【0017】[0017]

【表1】[Table 1]

【0018】このようにして得られた実施例1〜3およ
び比較例1〜3のチップ型コイル素子について、それぞ
れ、曲げ強度および曲げ弾性率を測定し、それらの測定
結果を表1に示した。
The bending strength and bending elastic modulus of the chip-type coil elements of Examples 1 to 3 and Comparative Examples 1 to 3 thus obtained were measured, and the measurement results are shown in Table 1. .

【0019】表1から明らかなように、実施例1〜3で
は、磁性封止樹脂にシリコン樹脂の粉末が添加されてい
るので、磁性封止樹脂の曲げ弾性率が小さい。そのため
、磁性封止樹脂からコアにかかる応力が小さい。また、
比較例1〜2では、磁性封止樹脂にシリコンオイルが添
加されているので、磁性封止樹脂の曲げ弾性率が小さく
、磁性封止樹脂からコアにかかる応力が小さい。一方、
比較例3では、磁性封止樹脂にシリコン樹脂の粉末ある
いはシリコンオイルが添加されていないので、磁性封止
樹脂の曲げ弾性率が大きく、磁性封止樹脂からコアにか
かる応力も大きい。
As is clear from Table 1, in Examples 1 to 3, since silicone resin powder is added to the magnetic sealing resin, the bending elastic modulus of the magnetic sealing resin is small. Therefore, the stress applied to the core from the magnetic sealing resin is small. Also,
In Comparative Examples 1 and 2, since silicone oil is added to the magnetic sealing resin, the bending elastic modulus of the magnetic sealing resin is small, and the stress applied from the magnetic sealing resin to the core is small. on the other hand,
In Comparative Example 3, since no silicone resin powder or silicone oil is added to the magnetic sealing resin, the bending elastic modulus of the magnetic sealing resin is high, and the stress applied from the magnetic sealing resin to the core is also large.

【0020】また、実施例1〜2および比較例1〜2か
ら明らかなように、シリコン樹脂の粉末あるいはシリコ
ンオイルの添加量が同じであれば、それらの曲げ弾性率
の違いは小さいが、曲げ強度は、シリコン樹脂の粉末を
添加した実施例1〜2の方が大きい。これは、磁性封止
樹脂の強度が同じであるならば、シリコン樹脂の粉末を
添加した実施例の方がシリコンオイルを添加した比較例
より小さい弾性率が得られることを示している。言い換
えると、シリコン樹脂の粉末が添加された磁性封止樹脂
は、シリコンオイルを添加した磁性封止樹脂に比べて、
同一強度の場合は、より弾性率が低くなることがわかる
。すなわち、磁性封止樹脂の強度を同じにすれば、シリ
コン樹脂の粉末を添加した磁性封止樹脂を用いたチップ
型コイル素子は、シリコンオイルを添加した磁性封止樹
脂を用いたチップ型コイル素子と比べて、そのコアにか
かる応力が小さく、コアの特につばにクラックが生じに
くい。
Furthermore, as is clear from Examples 1 and 2 and Comparative Examples 1 and 2, if the amount of silicone resin powder or silicone oil added is the same, the difference in their flexural modulus is small; The strength is higher in Examples 1 and 2 in which silicone resin powder is added. This indicates that, if the strength of the magnetic sealing resin is the same, the example in which silicone resin powder is added has a smaller elastic modulus than the comparative example in which silicone oil is added. In other words, the magnetic sealing resin to which silicone resin powder is added is more effective than the magnetic sealing resin to which silicone oil is added.
It can be seen that for the same strength, the elastic modulus becomes lower. In other words, if the strength of the magnetic sealing resin is the same, a chip-type coil element using a magnetic sealing resin containing silicone resin powder will be different from a chip-type coil element using a magnetic sealing resin containing silicone oil. Compared to other materials, the stress applied to the core is small, and cracks are less likely to occur in the core, especially at the brim.

【0021】また、実施例1〜3のように磁性封止樹脂
にシリコンオイルを添加しなければ、その表面にシリコ
ンオイルが浮き出ることもない。そのため、製品の信頼
性も低下しない。さらに、シリコン樹脂の粉末は、シリ
コンオイルのように浮き出ることがないので、磁性封止
樹脂中に多く添加することができる。また、シリコン樹
脂の粉末に表面処理を施せば、シリコン樹脂の粉末が磁
性封止樹脂中の熱硬化型樹脂と反応するため、磁性封止
樹脂中のシリコン樹脂の粉末の添加量を多くしても、磁
性封止樹脂の強度があまり低下しない。
Furthermore, unless silicone oil is added to the magnetic sealing resin as in Examples 1 to 3, no silicone oil will come out on the surface of the magnetic sealing resin. Therefore, the reliability of the product does not deteriorate. Furthermore, since silicone resin powder does not stand out like silicone oil, a large amount can be added to the magnetic sealing resin. In addition, if surface treatment is applied to silicone resin powder, the silicone resin powder will react with the thermosetting resin in the magnetic sealing resin, so increase the amount of silicone resin powder added in the magnetic sealing resin. However, the strength of the magnetic sealing resin does not decrease much.

【図面の簡単な説明】[Brief explanation of drawings]

【図1】この発明の背景となり、かつ、この発明が適用
されるチップ型コイル素子の一例を示す断面図である。
FIG. 1 is a cross-sectional view showing an example of a chip-type coil element that forms the background of the present invention and to which the present invention is applied.

【図2】図1に示すチップ型コイル素子を得るための一
過程を示し、端子材上にコイルの巻回されたコアが固定
された状態を示す斜視図である。
FIG. 2 is a perspective view showing a process for obtaining the chip-type coil element shown in FIG. 1, and showing a state in which a core around which a coil is wound is fixed on a terminal material.

【図3】トランスファ・モールド工程を説明するための
断面図である。
FIG. 3 is a cross-sectional view for explaining a transfer molding process.

【符号の説明】[Explanation of symbols]

10  チップ型コイル素子 12  コア 16,18  つば 20  コイル 22,24  端子 26  磁性封止樹脂 10 Chip type coil element 12 core 16,18 Tsuba 20 Coil 22, 24 terminal 26 Magnetic sealing resin

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】  シリコン樹脂の粉末が添加された、磁
性封止樹脂。
1. A magnetic sealing resin to which silicone resin powder is added.
JP3140895A 1991-05-15 1991-05-15 Magnetic shielding resin Pending JPH04338613A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3140895A JPH04338613A (en) 1991-05-15 1991-05-15 Magnetic shielding resin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3140895A JPH04338613A (en) 1991-05-15 1991-05-15 Magnetic shielding resin

Publications (1)

Publication Number Publication Date
JPH04338613A true JPH04338613A (en) 1992-11-25

Family

ID=15279290

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3140895A Pending JPH04338613A (en) 1991-05-15 1991-05-15 Magnetic shielding resin

Country Status (1)

Country Link
JP (1) JPH04338613A (en)

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GB2361110A (en) * 2000-04-03 2001-10-10 Abb Ab An induction device
JP2007227426A (en) * 2006-02-21 2007-09-06 Nec Tokin Corp Magnetic admixture and inductor employing it
JP2008041691A (en) * 2006-08-01 2008-02-21 Nec Tokin Corp Compound magnetic material and its manufacturing method
JP2009170488A (en) * 2008-01-11 2009-07-30 Yoshizumi Fukui Method for manufacturing mold coil
JP2009228722A (en) * 2008-03-21 2009-10-08 Yokogawa Electric Corp Electropneumatic conversion module and valve positioner having this electropneumatic conversion module
JP2010010544A (en) * 2008-06-30 2010-01-14 Yoshizumi Fukui Method of manufacturing mold coil
JP2010118574A (en) * 2008-11-14 2010-05-27 Denso Corp Reactor, and method of manufacturing the same
US8354910B2 (en) * 2006-07-28 2013-01-15 Samsung Electronics Co., Ltd. Coil block and electronic device using the same
JP2021036013A (en) * 2019-08-30 2021-03-04 住友ベークライト株式会社 Resin composition and molded article

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JPS54129357A (en) * 1978-03-29 1979-10-06 Tdk Electronics Co Ltd Inductance element and method of producing same
JPS62192445A (en) * 1986-02-18 1987-08-24 Matsushita Electric Works Ltd Epoxy resin molding material for sealing
JPH01150304A (en) * 1987-12-07 1989-06-13 Murata Mfg Co Ltd Composite magnetic molding material

Cited By (16)

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US6198373B1 (en) 1997-08-19 2001-03-06 Taiyo Yuden Co., Ltd. Wire wound electronic component
GB2329762B (en) * 1997-08-19 2001-06-06 Taiyo Yuden Kk Wire wound electronic component
GB2345801B (en) * 1997-08-19 2001-08-08 Taiyo Yuden Kk Wire wound electronic component
GB2345801A (en) * 1997-08-19 2000-07-19 Taiyo Yuden Kk Wire wound electronic component
GB2361110A (en) * 2000-04-03 2001-10-10 Abb Ab An induction device
JP2007227426A (en) * 2006-02-21 2007-09-06 Nec Tokin Corp Magnetic admixture and inductor employing it
US8354910B2 (en) * 2006-07-28 2013-01-15 Samsung Electronics Co., Ltd. Coil block and electronic device using the same
JP4646238B2 (en) * 2006-08-01 2011-03-09 Necトーキン株式会社 Composite magnetic material and method for producing composite magnetic material
JP2008041691A (en) * 2006-08-01 2008-02-21 Nec Tokin Corp Compound magnetic material and its manufacturing method
JP2009170488A (en) * 2008-01-11 2009-07-30 Yoshizumi Fukui Method for manufacturing mold coil
JP4730847B2 (en) * 2008-01-11 2011-07-20 義純 福井 Molded coil manufacturing method
JP2009228722A (en) * 2008-03-21 2009-10-08 Yokogawa Electric Corp Electropneumatic conversion module and valve positioner having this electropneumatic conversion module
JP4718583B2 (en) * 2008-06-30 2011-07-06 義純 福井 Molded coil manufacturing method
JP2010010544A (en) * 2008-06-30 2010-01-14 Yoshizumi Fukui Method of manufacturing mold coil
JP2010118574A (en) * 2008-11-14 2010-05-27 Denso Corp Reactor, and method of manufacturing the same
JP2021036013A (en) * 2019-08-30 2021-03-04 住友ベークライト株式会社 Resin composition and molded article

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