JPH0349993B2 - - Google Patents
Info
- Publication number
- JPH0349993B2 JPH0349993B2 JP62202288A JP20228887A JPH0349993B2 JP H0349993 B2 JPH0349993 B2 JP H0349993B2 JP 62202288 A JP62202288 A JP 62202288A JP 20228887 A JP20228887 A JP 20228887A JP H0349993 B2 JPH0349993 B2 JP H0349993B2
- Authority
- JP
- Japan
- Prior art keywords
- aqueous solution
- electrolytic
- cathode
- anode
- electrolytic cell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007864 aqueous solution Substances 0.000 claims description 19
- 239000011651 chromium Substances 0.000 claims description 18
- 239000000376 reactant Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 7
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 6
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052794 bromium Inorganic materials 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000001308 synthesis method Methods 0.000 claims description 5
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 4
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 claims description 4
- 239000004917 carbon fiber Substances 0.000 claims description 4
- 230000005484 gravity Effects 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- 238000003786 synthesis reaction Methods 0.000 claims description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- 239000007772 electrode material Substances 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000006722 reduction reaction Methods 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 5
- 238000005868 electrolysis reaction Methods 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 229910001430 chromium ion Inorganic materials 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 230000008929 regeneration Effects 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 229910021555 Chromium Chloride Inorganic materials 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 238000005341 cation exchange Methods 0.000 description 2
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 230000001172 regenerating effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- UIURDDSZTJODOX-UHFFFAOYSA-N 1-ethenylbenzo[a]anthracene Chemical group C1=CC=CC2=CC3=C4C(C=C)=CC=CC4=CC=C3C=C21 UIURDDSZTJODOX-UHFFFAOYSA-N 0.000 description 1
- 229910021560 Chromium(III) bromide Inorganic materials 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000003014 ion exchange membrane Substances 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000001420 photoelectron spectroscopy Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000003115 supporting electrolyte Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62202288A JPS6447890A (en) | 1987-08-13 | 1987-08-13 | Electrolytic synthesis method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62202288A JPS6447890A (en) | 1987-08-13 | 1987-08-13 | Electrolytic synthesis method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6447890A JPS6447890A (en) | 1989-02-22 |
| JPH0349993B2 true JPH0349993B2 (ref) | 1991-07-31 |
Family
ID=16455057
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62202288A Granted JPS6447890A (en) | 1987-08-13 | 1987-08-13 | Electrolytic synthesis method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6447890A (ref) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB201119283D0 (en) * | 2011-11-08 | 2011-12-21 | Univ Glasgow | Apparatus and methods for the electrochemical generation of oxygen and/or hydrogen |
| CN104838044B (zh) * | 2012-11-15 | 2017-12-05 | 麦克德米德尖端有限公司 | 在强硫酸中电解产生锰(iii)离子 |
| CA2901589C (en) * | 2013-03-12 | 2019-01-22 | Macdermid Acumen, Inc. | Electrolytic generation of manganese (iii) ions in strong sulfuric acid |
| CN104451767A (zh) * | 2014-12-29 | 2015-03-25 | 甘肃银光聚银化工有限公司 | 一种氧化装置和方法 |
| JP6639224B2 (ja) * | 2015-12-25 | 2020-02-05 | カーリットホールディングス株式会社 | Ｌ−システイン鉱酸塩の製造方法 |
| JPWO2024106161A1 (ref) * | 2022-11-18 | 2024-05-23 |
-
1987
- 1987-08-13 JP JP62202288A patent/JPS6447890A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6447890A (en) | 1989-02-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5894077A (en) | Radioactive effluent treatment | |
| Sirés et al. | Electro-Fenton process: fundamentals and reactivity | |
| US20170226647A1 (en) | A device and method for the production of hydrogen peroxide | |
| CN104428449A (zh) | 包括三相界面以使水性电解质中的碳基气体反应的电解装置 | |
| US20100065420A1 (en) | Electrode, method of manufacture and use thereof | |
| EP0040031A1 (en) | Anode catalyst and generation of oxygen | |
| US5296107A (en) | Indirect cerium medicated electrosynthesis | |
| JPH0665773A (ja) | 電気触媒および電気触媒方法 | |
| JP2717535B2 (ja) | 有機廃棄物の処理方法およびそのための触媒／助触媒組成物 | |
| JPH02197590A (ja) | レドックス反応方法及びそのための電解槽 | |
| FI75193C (fi) | Foerfarande foer elektrolysering av serium(3)-sulfat. | |
| JPH07504712A (ja) | ４価チタン電解質およびこれにより得られる３価チタン還元剤 | |
| JPH0349993B2 (ref) | ||
| US3347761A (en) | Electropurification of salt solutions | |
| EP0362157B1 (en) | Process for converting ionic valence number and apparatus employed therefor | |
| US5181993A (en) | Process for converting ferrous ions to ferric ions | |
| JPH01162789A (ja) | 担体上に担持された金属の回収方法及び装置 | |
| JP2802276B2 (ja) | 電解処理方法と電解反応槽 | |
| Ogura | Catalytic conversion of carbon monoxide and carbon dioxide into methanol with photocells | |
| US4360416A (en) | Anode catalysts for electrolysis of brine | |
| JP3190384B2 (ja) | 着色有機系廃液の処理方法 | |
| EP0039608A1 (en) | Halogen evolution with improved anode catalyst | |
| US5705049A (en) | Indirect cerium mediated electrosynthesis | |
| JP3168954B2 (ja) | ハロゲン化水素と酸素を製造する方法 | |
| JPH05115879A (ja) | 染料水溶液の処理方法 |