JPH0340727B2 - - Google Patents
Info
- Publication number
- JPH0340727B2 JPH0340727B2 JP3834283A JP3834283A JPH0340727B2 JP H0340727 B2 JPH0340727 B2 JP H0340727B2 JP 3834283 A JP3834283 A JP 3834283A JP 3834283 A JP3834283 A JP 3834283A JP H0340727 B2 JPH0340727 B2 JP H0340727B2
- Authority
- JP
- Japan
- Prior art keywords
- vinyl aromatic
- weight
- aromatic compound
- amount
- block copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920002554 vinyl polymer Polymers 0.000 claims description 45
- -1 vinyl aromatic compound Chemical class 0.000 claims description 44
- 229920001400 block copolymer Polymers 0.000 claims description 25
- 150000001993 dienes Chemical class 0.000 claims description 15
- 238000006116 polymerization reaction Methods 0.000 claims description 15
- 239000000178 monomer Substances 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 239000003999 initiator Substances 0.000 claims description 3
- 150000002900 organolithium compounds Chemical class 0.000 claims description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 18
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
- 239000004793 Polystyrene Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 229920002223 polystyrene Polymers 0.000 description 7
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- 150000003512 tertiary amines Chemical class 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 3
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000006864 oxidative decomposition reaction Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- BTOVVHWKPVSLBI-UHFFFAOYSA-N 2-methylprop-1-enylbenzene Chemical compound CC(C)=CC1=CC=CC=C1 BTOVVHWKPVSLBI-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- UBJFKNSINUCEAL-UHFFFAOYSA-N lithium;2-methylpropane Chemical compound [Li+].C[C-](C)C UBJFKNSINUCEAL-UHFFFAOYSA-N 0.000 description 1
- WGOPGODQLGJZGL-UHFFFAOYSA-N lithium;butane Chemical compound [Li+].CC[CH-]C WGOPGODQLGJZGL-UHFFFAOYSA-N 0.000 description 1
- CETVQRFGPOGIQJ-UHFFFAOYSA-N lithium;hexane Chemical compound [Li+].CCCCC[CH2-] CETVQRFGPOGIQJ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- FLESAADTDNKLFJ-UHFFFAOYSA-N nickel;pentane-2,4-dione Chemical compound [Ni].CC(=O)CC(C)=O FLESAADTDNKLFJ-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- NHKJPPKXDNZFBJ-UHFFFAOYSA-N phenyllithium Chemical compound [Li]C1=CC=CC=C1 NHKJPPKXDNZFBJ-UHFFFAOYSA-N 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Graft Or Block Polymers (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3834283A JPS59166518A (ja) | 1983-03-10 | 1983-03-10 | 直鎖状ブロック共重合体 |
| US06/586,442 US4603155A (en) | 1983-03-10 | 1984-03-05 | Alkenyl aromatic compound-conjugated diene block copolymer and process for the production thereof |
| NLAANVRAGE8400773,A NL185781C (nl) | 1983-03-10 | 1984-03-09 | Blokcopolymeer van een alkenyl-aromatische verbinding en een geconjugeerd dieen, werkwijze voor het bereiden daarvan en gevormde voortbrengselen daaruit. |
| GB08406429A GB2138009B (en) | 1983-03-10 | 1984-03-12 | Block copolymer of an alkenyl aromatic compound and a conjugated diene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3834283A JPS59166518A (ja) | 1983-03-10 | 1983-03-10 | 直鎖状ブロック共重合体 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59166518A JPS59166518A (ja) | 1984-09-19 |
| JPH0340727B2 true JPH0340727B2 (OSRAM) | 1991-06-19 |
Family
ID=12522608
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3834283A Granted JPS59166518A (ja) | 1983-03-10 | 1983-03-10 | 直鎖状ブロック共重合体 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59166518A (OSRAM) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63270718A (ja) * | 1988-03-22 | 1988-11-08 | Asahi Chem Ind Co Ltd | ブロック共重合体 |
| JP4320364B2 (ja) | 2006-08-08 | 2009-08-26 | 旭化成ケミカルズ株式会社 | 水添ブロック共重合体及びその架橋用組成物 |
| JP5142406B2 (ja) | 2007-02-20 | 2013-02-13 | 旭化成ケミカルズ株式会社 | 衝撃吸収体組成物 |
| EP2239299B1 (en) | 2008-02-08 | 2014-06-11 | Asahi Kasei Chemicals Corporation | Thermoplastic elastomer composition and method for producing the same |
| JP5681486B2 (ja) | 2008-04-14 | 2015-03-11 | 旭化成ケミカルズ株式会社 | 粘接着性組成物 |
| WO2010067564A1 (ja) | 2008-12-10 | 2010-06-17 | 旭化成ケミカルズ株式会社 | 熱可塑性エラストマー組成物 |
| KR101310443B1 (ko) | 2009-03-12 | 2013-09-24 | 아사히 가세이 케미칼즈 가부시키가이샤 | 폴리프로필렌계 수지 조성물, 그의 성형품 및 그것을 이용한 자동차용 내외장 재료 |
| BR112012030389B1 (pt) | 2010-06-09 | 2020-11-17 | Nissan Motor Company Limited | composição de elastômero termoplástico, produto moldado por injeção, folha, material para interior de automóvel, laminado, e, painel de instrumentos |
| CN103459431B (zh) | 2011-05-27 | 2015-01-21 | 旭化成化学株式会社 | 氢化共轭二烯系共聚物的制造方法 |
| ES2613713T3 (es) | 2011-09-15 | 2017-05-25 | Asahi Kasei Kabushiki Kaisha | Composición reticulada, método para producir una composición reticulada y producto moldeado |
| KR20150028993A (ko) | 2012-07-25 | 2015-03-17 | 아사히 가세이 케미칼즈 가부시키가이샤 | 점접착제용 블록 공중합체 조성물 및 점접착제 조성물 |
| CN104918968B (zh) | 2013-01-16 | 2018-01-16 | 旭化成株式会社 | 聚合物的制造方法 |
| EA033260B1 (ru) | 2014-01-23 | 2019-09-30 | Асахи Касеи Кабусики Кайся | Блок-сополимерная композиция и клеевая композиция |
| ES2687399T3 (es) | 2014-01-23 | 2018-10-25 | Asahi Kasei Kabushiki Kaisha | Composición adhesiva y cinta adhesiva |
| KR101842818B1 (ko) | 2014-01-23 | 2018-03-27 | 아사히 가세이 가부시키가이샤 | 블록 공중합체 및 점접착제 조성물 |
| CN110023403B (zh) | 2017-01-24 | 2022-08-09 | 旭化成株式会社 | 热塑性弹性体组合物、栓体和容器 |
| JP6985395B2 (ja) | 2017-08-10 | 2021-12-22 | 旭化成株式会社 | 感圧型接着剤用組成物、感圧型接着剤用材料、感圧型接着剤の形成方法、感圧型接着剤、多層フィルム及び包装体 |
| EP3750932B1 (en) | 2018-02-09 | 2025-08-27 | Asahi Kasei Kabushiki Kaisha | Viscous adhesive composition comprising a block copolymer |
| DE102019107726B4 (de) | 2018-04-04 | 2024-09-26 | Asahi Kasei Kabushiki Kaisha | Zusatz für bitumenhaltige Dichtungsbahn, Verfahren zur Herstellung einer bitumenhaltigen Dichtungsbahn, Bitumenzusammensetzung und Verwendung der Bitumenzusammensetzung |
| DE102019119630B4 (de) | 2018-07-20 | 2024-02-29 | Asahi Kasei Kabushiki Kaisha | Thermoplastische Elastomerzusammensetzung, deren Verwendung, Stopfen und Behälter |
| JP7195417B2 (ja) | 2019-05-23 | 2022-12-23 | 旭化成株式会社 | 水添共重合体、粘着フィルム、樹脂組成物、及び成形体 |
| EP4032735A4 (en) | 2019-09-20 | 2023-09-27 | Mitsui Chemicals, Inc. | DISPLAY DEVICE |
| EP3875491A2 (en) | 2020-03-03 | 2021-09-08 | Asahi Kasei Kabushiki Kaisha | Block copolymer, asphalt composition, and modified asphalt mixture |
| WO2021261241A1 (ja) | 2020-06-22 | 2021-12-30 | 旭化成株式会社 | 水添共重合体、樹脂組成物、成形体、及び粘着性フィルム |
| EP4332189A3 (en) | 2020-07-13 | 2024-08-14 | Asahi Kasei Kabushiki Kaisha | Method for producing pressure-sensitive adhesive |
| US20240158626A1 (en) | 2021-03-31 | 2024-05-16 | Mitsui Chemicals, Inc. | Thermoplastic elastomer composition and application thereof |
| EP4382564A4 (en) | 2021-08-06 | 2025-07-23 | Mitsui Chemicals Inc | THERMOPLASTIC ELASTOMER COMPOSITION AND MOLDED BODY MADE THEREOF |
| US20240425702A1 (en) | 2021-10-25 | 2024-12-26 | Asahi Kasei Kabushiki Kaisha | Block Copolymer, Asphalt Composition, and Modified Asphalt Mixture |
| CN119698448A (zh) | 2022-03-18 | 2025-03-25 | 三井化学株式会社 | 热塑性弹性体组合物和热塑性弹性体组合物的制造方法 |
| EP4265646B1 (en) | 2022-04-18 | 2024-10-16 | Japan Elastomer Co., Ltd. | Crumb of block copolymer or hydrogenated product thereof and aspahlt composition |
| WO2023223766A1 (ja) | 2022-05-18 | 2023-11-23 | 旭化成株式会社 | 複層成形用の熱可塑エラストマー組成物、複層成形体、及び複層成形体の製造方法 |
| JPWO2024122591A1 (OSRAM) | 2022-12-07 | 2024-06-13 | ||
| WO2024177030A1 (ja) | 2023-02-21 | 2024-08-29 | 三井化学株式会社 | シート状表皮材、および当該表皮材を有する積層体 |
| EP4421121A1 (en) | 2023-02-24 | 2024-08-28 | Asahi Kasei Kabushiki Kaisha | Block copolymer, asphalt composition, and modified asphalt mixture |
-
1983
- 1983-03-10 JP JP3834283A patent/JPS59166518A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59166518A (ja) | 1984-09-19 |
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