JPH03276750A - Hybrid element and manufacture thereof - Google Patents

Hybrid element and manufacture thereof

Info

Publication number
JPH03276750A
JPH03276750A JP2078227A JP7822790A JPH03276750A JP H03276750 A JPH03276750 A JP H03276750A JP 2078227 A JP2078227 A JP 2078227A JP 7822790 A JP7822790 A JP 7822790A JP H03276750 A JPH03276750 A JP H03276750A
Authority
JP
Japan
Prior art keywords
indium
bump
electrodes
semiconductor chips
pair
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2078227A
Other languages
Japanese (ja)
Other versions
JP2546407B2 (en
Inventor
Toshio Yamagata
山形 敏男
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp filed Critical NEC Corp
Priority to JP2078227A priority Critical patent/JP2546407B2/en
Publication of JPH03276750A publication Critical patent/JPH03276750A/en
Application granted granted Critical
Publication of JP2546407B2 publication Critical patent/JP2546407B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/12Structure, shape, material or disposition of the bump connectors prior to the connecting process
    • H01L2224/13Structure, shape, material or disposition of the bump connectors prior to the connecting process of an individual bump connector
    • H01L2224/13001Core members of the bump connector
    • H01L2224/13099Material
    • H01L2224/131Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof
    • H01L2224/13101Material with a principal constituent of the material being a metal or a metalloid, e.g. boron [B], silicon [Si], germanium [Ge], arsenic [As], antimony [Sb], tellurium [Te] and polonium [Po], and alloys thereof the principal constituent melting at a temperature of less than 400°C
    • H01L2224/13109Indium [In] as principal constituent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/15Structure, shape, material or disposition of the bump connectors after the connecting process
    • H01L2224/16Structure, shape, material or disposition of the bump connectors after the connecting process of an individual bump connector
    • H01L2224/161Disposition
    • H01L2224/16135Disposition the bump connector connecting between different semiconductor or solid-state bodies, i.e. chip-to-chip
    • H01L2224/16145Disposition the bump connector connecting between different semiconductor or solid-state bodies, i.e. chip-to-chip the bodies being stacked
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/013Alloys
    • H01L2924/0132Binary Alloys
    • H01L2924/01322Eutectic Alloys, i.e. obtained by a liquid transforming into two solid phases

Landscapes

  • Solid State Image Pick-Up Elements (AREA)
  • Wire Bonding (AREA)

Abstract

PURPOSE:To prevent deterioration of characteristics such as an increase in noise caused by an increase in contact resistance, peeling between both a pair of semiconductor chips by bonding the periphery of semiconductor chips in which a base in contact of bump bonding electrodes with the chips is made of indium and an intermediate part is made of an indium-gallium alloy and bonded to the peripheries of the chips with adhesive. CONSTITUTION:A pair of opposed semiconductor chips 1, 2 are electrically connected to bump bonding electrodes 3, and mechanically bonded at the peripheries with adhesive 4. The electrodes 3 are made of indium at the bases 7, 8 in contact with the electrodes 5, 6 of the chips 1, 2, and an intermediate part 9 is made of indium-gallium alloy. Accordingly, the melting point of the indium-gallium alloy of eutectic composition is low to about 17 deg.C, the part 9 of the electrodes 3 is melted at a normal ambient temperature, and a problem of improper electric connection due to an oxide film by bonding by bumps made only of indium is eliminated. On the other hand, since the adhesive 4 of the periphery contributes to its mechanical bonding strength at the ambient temperature and the adhesive 4 and the solidified electrodes 3 contributes thereto at the time of operation cooled to 77K, a problem pf peeling is obviated.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は一対の半導体チップを相互のバンプ電極同士を
対向させて電気的9機械的に結合するハイブリッド素子
及びその製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a hybrid element in which a pair of semiconductor chips are electrically and mechanically coupled with their bump electrodes facing each other, and a method for manufacturing the hybrid element.

[従来の技術] 半導体基板上に赤外線検出素子が配設されている光電変
換用半導体チップと、検出信号を処理する回路が形成さ
れたシリコンIC半導体チップとを数千点以上の対応す
るバンプで結合したハイブリッド型赤外線イメージセン
サ−が知られている。
[Prior Art] A photoelectric conversion semiconductor chip in which an infrared detection element is disposed on a semiconductor substrate and a silicon IC semiconductor chip in which a circuit for processing a detection signal is formed are connected to each other by using more than several thousand corresponding bumps. Hybrid infrared image sensors are known.

こうしたバンプ結合は、例えば特開昭59−15516
2号に示されているように、両チップのそれぞれ対応す
る位置にインジウム等の軟質金属からなる円柱状のバン
プ結合電極を形成し、目合わせして熱圧着し、電気的か
つ機械的に結合するものである。
Such bump bonding is known, for example, in Japanese Patent Application Laid-open No. 59-15516.
As shown in No. 2, cylindrical bump bonding electrodes made of soft metal such as indium are formed at corresponding positions on both chips, aligned and bonded by thermocompression, and electrically and mechanically bonded. It is something to do.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

このとき、対応するバンプ電極同士は電気的。 At this time, the corresponding bump electrodes are electrically connected.

機械的に充分に結合されなければならないが、従来のバ
ンプ結合電極では必すしも充分ではなかった。一般に光
電変換用半導体チップでは温度を」―げると素子特性が
劣化するため、例えばl−1gcdTeでは印加できる
温度は100℃以下に制限される。
Although sufficient mechanical bonding is required, conventional bump-coupled electrodes have not always been sufficient. In general, when the temperature of a semiconductor chip for photoelectric conversion is increased, the device characteristics deteriorate, so for example, in the case of l-1gcdTe, the temperature that can be applied is limited to 100°C or less.

方、100℃以下で融解するものとしてガリウムや、イ
ンジウムとガリウムとの合金が知られているが、バンプ
形成プロセスの際の温度で融解してしまうなどの困難が
ある。従って通常はバンプ結合電極としてインジウムが
用いられ、結合は融解ではなく、あくまでも熱圧着によ
っている。しかし、このインジウムの表面に酸化皮膜が
形成されていると、加熱と加圧をしても酸化皮膜は破れ
にくく、これが結合の邪魔をして導通不良といった故障
や、接触抵抗の増加からくるノイズの増大といった特性
の劣化、さらには両チップ間の剥離を招き易い。
On the other hand, gallium and alloys of indium and gallium are known as materials that melt at temperatures below 100° C., but these have problems such as melting at the temperature during the bump formation process. Therefore, indium is usually used as the bump bonding electrode, and the bonding is not by melting but by thermocompression bonding. However, when an oxide film is formed on the surface of this indium, the oxide film is difficult to break even when heated and pressurized, and this interferes with the bonding, resulting in failures such as poor continuity and noise due to increased contact resistance. This tends to lead to deterioration of characteristics such as an increase in the number of chips, as well as peeling between the two chips.

本発明の目的は、上記の欠点を解決し、充分に結合でき
るハイブリッド素子及びその製造方法を提供することに
ある。
SUMMARY OF THE INVENTION An object of the present invention is to solve the above-mentioned drawbacks and provide a hybrid device that can be sufficiently combined and a method for manufacturing the same.

[課題を解決するための手段] 前記目的を達成するため、本発明に係るハイブリッド素
子においては、対向させた一対の半導体チップを電気的
に接続するバンプ結合電極を有するハイブリッド素子で
あって、 前記バンプ結合電極は、前記一対の半導体チップに接す
る基部かインジウムからなり、中間部がインジウムとガ
リウムとの合金からなるものであり、 さらに前記一対の半導体チップの周辺部を接着剤で機械
的に結合したものである。
[Means for Solving the Problem] In order to achieve the above-mentioned object, a hybrid element according to the present invention is a hybrid element having a bump coupling electrode that electrically connects a pair of semiconductor chips facing each other, the hybrid element comprising: The bump bonding electrode has a base portion in contact with the pair of semiconductor chips made of indium, a middle portion made of an alloy of indium and gallium, and a peripheral portion of the pair of semiconductor chips mechanically bonded with an adhesive. This is what I did.

また、本発明に係るハイブリッド素子は、一対の半導体
チップのそれぞれにインジウムからなるバンプ電極を形
成し、前記一対の半導体チップの少なくとも一方に、ガ
リウムの薄膜を形成した平滑な基板を対向接触させて前
記バンプ電極の接触部すなわち頭部を合金化してから前
記平滑な基板を剥離した後、前記一対の半導体チップを
対向して結合し、さらにその周辺部を接着剤で固定する
製造方法により得られる。
Further, in the hybrid element according to the present invention, a bump electrode made of indium is formed on each of a pair of semiconductor chips, and a smooth substrate on which a thin film of gallium is formed is brought into opposing contact with at least one of the pair of semiconductor chips. Obtained by a manufacturing method in which the contact portion, that is, the head of the bump electrode is alloyed, the smooth substrate is peeled off, the pair of semiconductor chips are bonded facing each other, and the peripheral portion thereof is further fixed with an adhesive. .

〔実施例〕〔Example〕

次に、本発明の実施例について図面を参照して説明する
Next, embodiments of the present invention will be described with reference to the drawings.

第1図は本発明のハイブリッド素子の一実施例を示す断
面図であり、第2図はバンプ結合電極の拡大断面図であ
る。
FIG. 1 is a sectional view showing an embodiment of the hybrid element of the present invention, and FIG. 2 is an enlarged sectional view of a bump-coupled electrode.

対向させた一対の半導体チップ1.2は、バンプ結合電
極3によって電気的に接続し、周辺部を接着剤4で機械
的に結合している。またバンプ結合電極3は半導体チッ
プ1,2のそれぞれの電極5,6に接する基部7,8は
インジウムとし、中間部9はインジウムとガリウムとの
合金としている。ここで、バンプ結合電極3の高さは約
20pm、また中間部9のインジウムとガリウムとの合
金厚さが約21、組成比はインジウムが約16%の共晶
組成としている。
A pair of opposing semiconductor chips 1.2 are electrically connected by bump bonding electrodes 3 and mechanically bonded at their peripheral portions by adhesive 4. Further, in the bump coupling electrode 3, the base portions 7 and 8 in contact with the respective electrodes 5 and 6 of the semiconductor chips 1 and 2 are made of indium, and the intermediate portion 9 is made of an alloy of indium and gallium. Here, the height of the bump bonding electrode 3 is approximately 20 pm, the thickness of the alloy of indium and gallium in the intermediate portion 9 is approximately 21, and the composition ratio is a eutectic composition in which indium is approximately 16%.

良く知られているように、共晶組成のインジウムとガリ
ウムとの合金の融点は約17℃と低く、通常の室温では
バンプ結合電極3の中間部9は融けた状態となっており
、従来のインジウムのみのバンプによる結合での酸化膜
による電気的な接続不良の問題はない。一方、機械的な
結合強度は室温では周辺部の接着剤4が、また77Kに
冷却した動作時には接着剤4と固体化したバンプ結合電
極3が寄与するため、剥離の問題もない。さらに、この
インジウムとガリウムとの合金の中間部により、両生導
体チップの熱膨張率の差による熱ストレスの影響を受け
にくいという利点もあり、時間的な劣化もないものとな
っている。
As is well known, the melting point of an alloy of indium and gallium with a eutectic composition is as low as about 17°C, and at normal room temperature, the middle part 9 of the bump bonded electrode 3 is in a molten state, which is different from the conventional one. There is no problem of electrical connection failure due to the oxide film when bonding using only indium bumps. On the other hand, the mechanical bonding strength is contributed by the adhesive 4 in the periphery at room temperature, and by the adhesive 4 and the solidified bump bonding electrode 3 during operation cooled to 77K, so there is no problem of peeling. Furthermore, the intermediate portion of the alloy of indium and gallium has the advantage that it is less susceptible to thermal stress due to the difference in thermal expansion coefficients of the bidirectional conductor chips, and there is no deterioration over time.

次に、このバンプ結合電極の形成方法を説明する。Next, a method for forming this bump bonding electrode will be explained.

第3図(a)〜(ロ)は本発明のハイブリッド素子の製
造方法の一実施例を工程順に示す部分拡大断面図である
FIGS. 3(a) to 3(b) are partially enlarged cross-sectional views showing one embodiment of the method for manufacturing a hybrid element of the present invention in the order of steps.

まず、第3図(a)に示すように従来の通常の形成方法
によって半導体チップ11の電極15上にインジウムか
らなるバンプ基部17を形成する。次いで、第3図(ハ
)に示すように、ガリウムの薄膜20を形成した平滑な
基板21を対向接触させる。このとき、ガリウムの薄膜
20は必ずしも融解している必要はなく、温度は室温か
ら35℃程度としておけば良い。
First, as shown in FIG. 3(a), a bump base 17 made of indium is formed on the electrode 15 of the semiconductor chip 11 by a conventional normal forming method. Next, as shown in FIG. 3(c), a smooth substrate 21 on which a gallium thin film 20 is formed is brought into opposing contact. At this time, the gallium thin film 20 does not necessarily need to be melted, and the temperature may be kept at about 35° C. from room temperature.

この状態で第3図0に示すようにガリウムの薄膜20と
バンプ基部I7の接触部25のインジウムを合金化させ
た後、第3図(ロ)に示すように平滑な基板21を剥離
することで、頭部22がインジウムとガリウムとの合金
からなるバンブ電極23の形成が完了する。一方半導体
チツブ12の電極16上には第3図(e)に示すように
インジウムのみからなるバンブ電極24を形成する。
In this state, as shown in FIG. 30, the gallium thin film 20 and indium at the contact portion 25 of the bump base I7 are alloyed, and then the smooth substrate 21 is peeled off as shown in FIG. 3(b). This completes the formation of the bump electrode 23 whose head 22 is made of an alloy of indium and gallium. On the other hand, a bump electrode 24 made only of indium is formed on the electrode 16 of the semiconductor chip 12, as shown in FIG. 3(e).

ここで、高さ20μmのバンプ結合電極3を形成しよう
とする場合は、インジウムからなるバンプ基部I7、及
びバンブ電極24の高さをそれぞれlopm程度とし、
ガリウムの薄膜20の膜厚をlpm程度としておけば良
い。また、ガリウムの簿膜20とバンプ基部17のイン
ジウムを合金化させる時間としては、温度によっても変
わるが、室温で10分程度でよい。
Here, when trying to form the bump coupling electrode 3 with a height of 20 μm, the heights of the bump base I7 made of indium and the bump electrode 24 are each about lopm,
The thickness of the gallium thin film 20 may be approximately lpm. Further, the time for alloying the gallium film 20 and the indium of the bump base 17 may vary depending on the temperature, but may be about 10 minutes at room temperature.

次に、第3図のに示すように両生導体チップ11゜12
を向い合わせ、目合わせして各々の対応するバンプ電極
23.24を接触させることでバンブ電極が接続され、
バンプ結合電極13の形成が完了する。
Next, as shown in FIG.
The bump electrodes are connected by facing each other, aligning them, and bringing the corresponding bump electrodes 23 and 24 into contact with each other.
Formation of bump coupling electrode 13 is completed.

このとき、バンブ電極23の頭部22のインジウムとガ
リウムとの合金は融けた状態となっておりバンブ電極2
4のインジウムと容易に合金化し、バンプ結合電極13
の中間部19となる。尚、このままでも従来のような酸
化膜の問題はなく、十分な電気接続を行えるが、さらに
これを加熱、加圧することでより完全に接続することが
できる。
At this time, the alloy of indium and gallium in the head 22 of the bump electrode 23 is in a molten state, and the bump electrode 23 is in a molten state.
Easily alloyed with indium of No. 4, bump bonding electrode 13
This is the middle part 19 of . It should be noted that even with this as it is, there is no problem with the oxide film as in the prior art, and a sufficient electrical connection can be made, but a more complete connection can be made by further heating and pressurizing this.

最後に、第3図@に示すように、結合した両生導体チッ
プII、 +2の周辺部を接着剤14で機械的に固定結
合し、ハイブリッド素子の製造が完了する。
Finally, as shown in FIG. 3, the peripheral portions of the combined amphibic conductor chips II and +2 are mechanically fixedly connected using adhesive 14, completing the production of the hybrid element.

ここで接着剤としては通常のエポキシ系接着剤でも、又
やや弾力のあるシリコン系接着剤でも良い。
The adhesive here may be a normal epoxy adhesive or a slightly elastic silicone adhesive.

なお、以上の実施例では一方の半導体チップのバンブ電
極の頭部のみをインジウムとガリウムとの合金としてい
るが、これを両方の半導体チップに適用しても全く同様
であることは言うまでもない。
In the above embodiment, only the head of the bump electrode of one semiconductor chip is made of an alloy of indium and gallium, but it goes without saying that the same effect can be obtained even if this is applied to both semiconductor chips.

〔発明の効果〕〔Effect of the invention〕

以上説明したように本発明によれば、バンブ電極の接続
部をインジウムとガリウムとの合金とし8− ており、従来のインジウムバンプ結合での酸化膜による
接続不良がないため、電気的に充分に接続され、かつ機
械強度の問題もない、充分に結合されたハイブリッド素
子が得られる。
As explained above, according to the present invention, the connection part of the bump electrode is made of an alloy of indium and gallium8-, and there is no connection failure due to the oxide film in conventional indium bump bonding, so it is electrically sufficient. A well-coupled hybrid element is obtained which is connected and has no mechanical strength problems.

【図面の簡単な説明】 第1図は本発明のハイブリッド素子の一実施例を示す断
面図、第2図はバンプ結合電極の拡大断面図、第3図(
a)〜■は本発明のハイブリッド素子の製造方法の一実
施例を工程順に示しす部分拡大断面図である。
[Brief Description of the Drawings] Fig. 1 is a sectional view showing one embodiment of the hybrid element of the present invention, Fig. 2 is an enlarged sectional view of a bump-coupled electrode, and Fig. 3 (
a) to {circle around (2)} are partially enlarged cross-sectional views showing one embodiment of the method for manufacturing a hybrid element of the present invention in the order of steps;

Claims (2)

【特許請求の範囲】[Claims] (1)対向させた一対の半導体チップを電気的に接続す
るバンプ結合電極を有するハイブリッド素子であって、 前記バンプ結合電極は、前記一対の半導体チップに接す
る基部がインジウムからなり、中間部がインジウムとガ
リウムとの合金からなるものであり、 さらに前記一対の半導体チップの周辺部を接着剤で機械
的に結合したことを特徴とするハイブリッド素子。
(1) A hybrid element having a bump coupling electrode that electrically connects a pair of opposing semiconductor chips, wherein the bump coupling electrode has a base portion in contact with the pair of semiconductor chips made of indium, and an intermediate portion made of indium. What is claimed is: 1. A hybrid element comprising an alloy of gallium and gallium, and further comprising: a peripheral portion of the pair of semiconductor chips mechanically bonded to each other with an adhesive.
(2)一対の半導体チップのそれぞれにインジウムから
なるバンプ電極を形成し、前記一対の半導体チップの少
なくとも一方に、ガリウムの薄膜を形成した平滑な基板
を対向接触させて前記バンプ電極の接触部すなわち頭部
を合金化してから前記平滑な基板を剥離した後、前記一
対の半導体チップを対向して結合し、さらにその周辺部
を接着剤で固定することを特徴とするハイブリッド素子
の製造方法。
(2) A bump electrode made of indium is formed on each of a pair of semiconductor chips, and a smooth substrate on which a thin film of gallium is formed is brought into opposing contact with at least one of the pair of semiconductor chips, so that the contact portion of the bump electrode is A method of manufacturing a hybrid element, comprising: alloying the head, peeling off the smooth substrate, bonding the pair of semiconductor chips facing each other, and further fixing the peripheral portions with an adhesive.
JP2078227A 1990-03-27 1990-03-27 Hybrid element and manufacturing method thereof Expired - Lifetime JP2546407B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2078227A JP2546407B2 (en) 1990-03-27 1990-03-27 Hybrid element and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2078227A JP2546407B2 (en) 1990-03-27 1990-03-27 Hybrid element and manufacturing method thereof

Publications (2)

Publication Number Publication Date
JPH03276750A true JPH03276750A (en) 1991-12-06
JP2546407B2 JP2546407B2 (en) 1996-10-23

Family

ID=13656165

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2078227A Expired - Lifetime JP2546407B2 (en) 1990-03-27 1990-03-27 Hybrid element and manufacturing method thereof

Country Status (1)

Country Link
JP (1) JP2546407B2 (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994018698A1 (en) * 1993-02-09 1994-08-18 Hans Peter Peloschek METHOD FOR ELECTRICALLY CONDUCTIVE CONNECTING AND MECHANICAL FASTENING OF ICs ON CONDUCTING PATTERNS OF SUBSTRATES AND THE APPLICATION THEREOF
JPH0758149A (en) * 1993-08-11 1995-03-03 Nec Corp Method for mounting chip part
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US7112468B2 (en) 1998-09-25 2006-09-26 Stmicroelectronics, Inc. Stacked multi-component integrated circuit microprocessor
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US5603981A (en) * 1993-10-14 1997-02-18 Fujitsu Limited Electrical connecting device and method for making same
US5610371A (en) * 1994-03-15 1997-03-11 Fujitsu Limited Electrical connecting device and method for making same
US6032852A (en) * 1997-09-22 2000-03-07 Trw Inc. Reworkable microelectronic multi-chip module
US6050476A (en) * 1997-09-22 2000-04-18 Trw Inc. Reworkable microelectronic multi-chip module
US7112468B2 (en) 1998-09-25 2006-09-26 Stmicroelectronics, Inc. Stacked multi-component integrated circuit microprocessor
WO2002007219A1 (en) * 2000-07-17 2002-01-24 Rohm Co., Ltd. Semiconductor device and its manufacturing method
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US6734556B2 (en) 2000-07-17 2004-05-11 Rohm Co., Ltd. Semiconductor device with chip-on-chip construction joined via a low-melting point metal layer
US7384863B2 (en) 2000-07-17 2008-06-10 Rohm Co., Ltd. Semiconductor device and method for manufacturing the same
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US6583514B2 (en) 2000-10-04 2003-06-24 Nec Corporation Semiconductor device with a binary alloy bonding layer
WO2005119776A1 (en) * 2004-06-04 2005-12-15 Zycube Co., Ltd. Semiconductor device having three-dimensional stack structure and method for manufacturing the same
JPWO2005119776A1 (en) * 2004-06-04 2008-04-03 株式会社ザイキューブ Semiconductor device having three-dimensional laminated structure and method for manufacturing the same
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US7906363B2 (en) 2004-08-20 2011-03-15 Zycube Co., Ltd. Method of fabricating semiconductor device having three-dimensional stacked structure
JP2011134770A (en) * 2009-12-22 2011-07-07 Sumitomo Electric Ind Ltd Detector, light-receiving element array, and method of manufacturing the detector
US8969851B2 (en) 2009-12-22 2015-03-03 Sumitomo Electric Industries, Ltd. Detection device, photodiode array, and method for manufacturing the same
JP2011146603A (en) * 2010-01-15 2011-07-28 Sumitomo Electric Ind Ltd Detection device, photodetector array, electronic apparatus, and methods of manufacturing the same
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