JPH0321571B2 - - Google Patents
Info
- Publication number
- JPH0321571B2 JPH0321571B2 JP10660684A JP10660684A JPH0321571B2 JP H0321571 B2 JPH0321571 B2 JP H0321571B2 JP 10660684 A JP10660684 A JP 10660684A JP 10660684 A JP10660684 A JP 10660684A JP H0321571 B2 JPH0321571 B2 JP H0321571B2
- Authority
- JP
- Japan
- Prior art keywords
- phenolic resin
- type phenolic
- novolak
- foam
- partially neutralized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000006260 foam Substances 0.000 claims description 50
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 29
- 229920001568 phenolic resin Polymers 0.000 claims description 29
- 239000005011 phenolic resin Substances 0.000 claims description 29
- 239000002253 acid Substances 0.000 claims description 24
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 24
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 12
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 229920003986 novolac Polymers 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 11
- 239000010680 novolac-type phenolic resin Substances 0.000 claims description 9
- 239000003381 stabilizer Substances 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 239000004088 foaming agent Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- -1 alkali metal acrylate Chemical class 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 14
- 238000005187 foaming Methods 0.000 description 10
- 239000004604 Blowing Agent Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- IVQVTRZCAXVNSG-UHFFFAOYSA-M sodium;prop-2-enoate;prop-2-enoic acid Chemical compound [Na+].OC(=O)C=C.[O-]C(=O)C=C IVQVTRZCAXVNSG-UHFFFAOYSA-M 0.000 description 5
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000001747 exhibiting effect Effects 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 230000003472 neutralizing effect Effects 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- MWRWFPQBGSZWNV-UHFFFAOYSA-N Dinitrosopentamethylenetetramine Chemical compound C1N2CN(N=O)CN1CN(N=O)C2 MWRWFPQBGSZWNV-UHFFFAOYSA-N 0.000 description 2
- 229930040373 Paraformaldehyde Natural products 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920002866 paraformaldehyde Polymers 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 239000008247 solid mixture Substances 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 description 1
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 125000002256 xylenyl group Chemical class C1(C(C=CC=C1)C)(C)* 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10660684A JPS60250046A (ja) | 1984-05-28 | 1984-05-28 | 低臭気性ノボラツク型フエノ−ル樹脂発泡体の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10660684A JPS60250046A (ja) | 1984-05-28 | 1984-05-28 | 低臭気性ノボラツク型フエノ−ル樹脂発泡体の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60250046A JPS60250046A (ja) | 1985-12-10 |
| JPH0321571B2 true JPH0321571B2 (enrdf_load_stackoverflow) | 1991-03-25 |
Family
ID=14437776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10660684A Granted JPS60250046A (ja) | 1984-05-28 | 1984-05-28 | 低臭気性ノボラツク型フエノ−ル樹脂発泡体の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60250046A (enrdf_load_stackoverflow) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019172741A (ja) * | 2018-03-27 | 2019-10-10 | 住友ベークライト株式会社 | フェノール樹脂成形材料および構造体 |
-
1984
- 1984-05-28 JP JP10660684A patent/JPS60250046A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60250046A (ja) | 1985-12-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1887032B1 (en) | Expandable resol-type phenolic resin molding material and phenolic resin foam | |
| GB1580565A (en) | Cured phenol-aldehyde resin foam | |
| JPS6142549A (ja) | フエノ−ル樹脂発泡体の製造方法 | |
| CA2388304C (en) | Cellular plastic material based on phenolic resin | |
| JPH0321571B2 (enrdf_load_stackoverflow) | ||
| JP4889084B2 (ja) | フェノール樹脂発泡体およびその製造方法 | |
| JP5400485B2 (ja) | 発泡性レゾール型フェノール樹脂成形材料及びそれを用いてなるフェノール樹脂発泡体 | |
| JP2008525565A (ja) | 高靱性フェノールフォーム | |
| US4350776A (en) | Method of making a low-friability, thermosetting foam | |
| US4713400A (en) | Foaming system for phenolic foams | |
| EP0229877B1 (en) | Improved foaming system for phenolic foams | |
| JP2551481B2 (ja) | 発泡用フェノール樹脂組成物 | |
| JPH0329252B2 (enrdf_load_stackoverflow) | ||
| JP4601855B2 (ja) | 発泡性フェノール系レゾール樹脂組成物 | |
| JPS59219343A (ja) | フエノ−ル樹脂発泡体の製造方法 | |
| JPH0310659B2 (enrdf_load_stackoverflow) | ||
| JP4776304B2 (ja) | フォーム製造用樹脂組成物、該組成物を用いたフォームの製造方法及びフォーム | |
| JPH058935B2 (enrdf_load_stackoverflow) | ||
| JPS6248978B2 (enrdf_load_stackoverflow) | ||
| JP2588777B2 (ja) | 発泡用フェノール樹脂組成物の製造方法 | |
| EP1222228B1 (en) | Cellular plastic material based on phenolic resin | |
| WO2004056911A2 (en) | A closed cell phenolic foam | |
| JP3555012B2 (ja) | フェノール系樹脂発泡性組成物及び該組成物を用いた発泡体の製造方法 | |
| JPH0329254B2 (enrdf_load_stackoverflow) | ||
| JPS5842215B2 (ja) | ケイリヨウタイノ セイゾウホウホウ |