JPH0319243B2 - - Google Patents
Info
- Publication number
- JPH0319243B2 JPH0319243B2 JP59169685A JP16968584A JPH0319243B2 JP H0319243 B2 JPH0319243 B2 JP H0319243B2 JP 59169685 A JP59169685 A JP 59169685A JP 16968584 A JP16968584 A JP 16968584A JP H0319243 B2 JPH0319243 B2 JP H0319243B2
- Authority
- JP
- Japan
- Prior art keywords
- graft
- irradiation
- monomer
- base material
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 claims description 13
- 239000000178 monomer Substances 0.000 claims description 13
- 229920000578 graft copolymer Polymers 0.000 claims description 12
- 125000000524 functional group Chemical group 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 9
- 230000005855 radiation Effects 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 238000010559 graft polymerization reaction Methods 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- -1 polyethylene Polymers 0.000 description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 230000005251 gamma ray Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 239000002033 PVDF binder Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 238000000944 Soxhlet extraction Methods 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-M hydroperoxide group Chemical group [O-]O MHAJPDPJQMAIIY-UHFFFAOYSA-M 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 125000000468 ketone group Chemical group 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 125000002081 peroxide group Chemical group 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920002620 polyvinyl fluoride Polymers 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- HRQGCQVOJVTVLU-UHFFFAOYSA-N bis(chloromethyl) ether Chemical compound ClCOCCl HRQGCQVOJVTVLU-UHFFFAOYSA-N 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical group NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- LMBWSYZSUOEYSN-UHFFFAOYSA-N diethyldithiocarbamic acid Chemical compound CCN(CC)C(S)=S LMBWSYZSUOEYSN-UHFFFAOYSA-N 0.000 description 1
- 125000002228 disulfide group Chemical group 0.000 description 1
- 229950004394 ditiocarb Drugs 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 239000012567 medical material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16968584A JPS6147714A (ja) | 1984-08-14 | 1984-08-14 | グラフト重合法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16968584A JPS6147714A (ja) | 1984-08-14 | 1984-08-14 | グラフト重合法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6147714A JPS6147714A (ja) | 1986-03-08 |
| JPH0319243B2 true JPH0319243B2 (fi) | 1991-03-14 |
Family
ID=15891001
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16968584A Granted JPS6147714A (ja) | 1984-08-14 | 1984-08-14 | グラフト重合法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6147714A (fi) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19611968A1 (de) * | 1995-03-31 | 1996-10-02 | Sumitomo Chemical Co | Verfahren zur Herstellung von Styrolpolymeren |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50145592A (fi) * | 1974-04-16 | 1975-11-21 | ||
| JPS5147092A (ja) * | 1974-10-19 | 1976-04-22 | Maruzen Oil Co Ltd | Gurafutokyojugotaino seizoho |
-
1984
- 1984-08-14 JP JP16968584A patent/JPS6147714A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50145592A (fi) * | 1974-04-16 | 1975-11-21 | ||
| JPS5147092A (ja) * | 1974-10-19 | 1976-04-22 | Maruzen Oil Co Ltd | Gurafutokyojugotaino seizoho |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6147714A (ja) | 1986-03-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0062059B1 (en) | Process for graft copolymerization of a pre-formed substrate | |
| JP2000026549A (ja) | ポリオレフィンのグラフトコポリマ―の製法 | |
| JP3312634B2 (ja) | キレート型イオン吸着膜および製造方法 | |
| US4652592A (en) | Method of producing shaped body of cross-linked fluorine-containing graft copolymer by using radiation | |
| JP3202067B2 (ja) | ビニルモノマーを粒状オレフィンポリマー上にグラフトする方法 | |
| EP0401993B1 (en) | Process for producing unsaturated copolymers | |
| US4256782A (en) | Treating method for giving hydrophilic property to the surface of hydrophobic polymer substrate | |
| JPS6145351B2 (fi) | ||
| US3759738A (en) | Graft polymeric substrate | |
| JPS596469B2 (ja) | 寸法安定性のすぐれた電池用隔膜の製造法 | |
| JPH0319243B2 (fi) | ||
| EP1421126A1 (en) | Process for preparing graft copolymer membranes | |
| US3201336A (en) | Graft polymerization utilizing ionizing radiation | |
| US3143521A (en) | Process for graft-copolymerizing | |
| JPS6258775B2 (fi) | ||
| JPS5851008B2 (ja) | グラフトキヨウジユウゴウタイノ セイゾウホウ | |
| JPH06271687A (ja) | イオン交換膜の製造方法 | |
| JPS60238328A (ja) | イオン交換膜を製造する方法 | |
| US3453195A (en) | Graft copolymers prepared by irradiating a halogen containing backbone copolymer with u.v. light in the presence of a vinyl monomer | |
| JPS6030339B2 (ja) | ４↓−メチル↓−１↓−ペンテン重合体の改質方法 | |
| JPH0380057B2 (fi) | ||
| JPS60149616A (ja) | ラジカル重合開始剤含有ポリマ−組成物の製造方法 | |
| JPS58463B2 (ja) | イオン交換膜の新規製造方法 | |
| Zhili et al. | Grafting of vinylimidazole into air-irradiated polymer films—2. Grafting into polyethylene | |
| RU2090574C1 (ru) | Привитой олефиновый полимер и способ его получения |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |