JPH03150149A - Manufacture of vibration-damping metal sheet used at ultra-high temperature - Google Patents
Manufacture of vibration-damping metal sheet used at ultra-high temperatureInfo
- Publication number
- JPH03150149A JPH03150149A JP28899289A JP28899289A JPH03150149A JP H03150149 A JPH03150149 A JP H03150149A JP 28899289 A JP28899289 A JP 28899289A JP 28899289 A JP28899289 A JP 28899289A JP H03150149 A JPH03150149 A JP H03150149A
- Authority
- JP
- Japan
- Prior art keywords
- powder
- steel
- super
- damping
- vibration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002184 metal Substances 0.000 title claims abstract description 37
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 37
- 238000013016 damping Methods 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 239000000956 alloy Substances 0.000 claims abstract description 12
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 12
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims description 4
- 229910000831 Steel Inorganic materials 0.000 abstract description 29
- 239000010959 steel Substances 0.000 abstract description 29
- 239000000843 powder Substances 0.000 abstract description 17
- 238000001816 cooling Methods 0.000 abstract description 2
- 229910052725 zinc Inorganic materials 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000011231 conductive filler Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利川分野〕
この発明は、常温から特に高温域にわたって制振性の大
きい超高温用制振金属板の製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial field in Icheon] The present invention relates to a method for producing a damping metal plate for ultra-high temperatures that has high damping properties over a range from room temperature to particularly high temperatures.
従来の制振金属板に溶接性(抵抗溶接)を持たせるため
、2枚の金属板の間に導電性フィラーを含む接着材層を
介在させた再溶接性複合制振金属板としては、例えば特
公昭60−912号公報や特開昭62−234917号
公報に開示されたものがある。In order to provide weldability (resistance welding) to conventional vibration-damping metal plates, a re-weldable composite vibration-damping metal plate in which an adhesive layer containing a conductive filler is interposed between two metal plates is available, for example. Some of them are disclosed in Japanese Patent Application Laid-open No. 60-912 and Japanese Patent Application Laid-Open No. 62-234917.
上記のうち、前者の例では、接着剤として酢酸ビニル系
やアクリル樹脂系その他の熱可塑性樹脂及びユリア樹脂
、メラミン樹脂その他の熱硬化性杓鮨を使用しており、
後者の例は同様な樹脂を液状にし、これに導電性フィラ
ーを混入した混合体を噴射式ノズルにより均一に分散し
、乾燥後、2枚の金属板を加圧ロール等で圧着して再溶
接性複合制振金属板を形成する方法を採っている。Among the above, in the former example, vinyl acetate, acrylic resin, and other thermoplastic resins, as well as urea resin, melamine resin, and other thermosetting resins are used as adhesives.
In the latter example, a similar resin is liquefied, a conductive filler is mixed in, and a mixture is uniformly dispersed using a spray nozzle. After drying, two metal plates are pressed together using a pressure roll or the like and re-welded. The method is to form a composite vibration-damping metal plate.
しかしながら、上記のような従来の複合型制振金属板は
、金属板の間に熱可塑性樹脂又は熱硬化性樹脂等の粘弾
性樹脂を介装して積層接着したものであって、このよう
な樹脂を使川しているために、11振作川における損失
係数特性は第2図のグラフ、■5■、■に示すように、
温度依存性の高いものしか得られてない、すなわち、2
は常温用、3は中温川、4は高温用として製造された制
振鋼板の損失係数特性を示したものであって、それぞれ
用途に応じた温度で良好な制振特性が得られるように樹
脂が選定されたものであるが、その特性の得られる温度
範囲は極めて狭く、さらに150℃以上の用途に対応で
きるような割振金属板は開発されていないため、適用範
囲が約150C以下に限定されるという問題点があった
。However, the conventional composite damping metal plates as described above are laminated and bonded with a viscoelastic resin such as a thermoplastic resin or a thermosetting resin interposed between the metal plates. Because the river is being used, the loss coefficient characteristics in the 11-day river are as shown in the graphs in Figure 2, ■5■, and ■.
Only those with high temperature dependence were obtained, i.e. 2
3 shows the loss coefficient characteristics of damping steel plates manufactured for normal temperature use, 3 for medium temperature use, and 4 for high temperature use.Resin is used to obtain good damping properties at the temperature appropriate for each use. was selected, but the temperature range in which these characteristics can be obtained is extremely narrow, and no distributed metal plate has been developed that can be used at temperatures above 150°C, so the range of application is limited to temperatures below about 150°C. There was a problem that
この発明は、このような従来の問題にかんがみてなされ
たものであって、金属板の接着剤として超塑性合金を使
用することにより、上記課題を解決することを目的とし
ている。This invention has been made in view of such conventional problems, and aims to solve the above problems by using a superplastic alloy as an adhesive for metal plates.
この発明は上記目的を達成するために、金属板の間に超
塑性合金を介装するとともに加熱して前記金属板を接着
し、一体化する超高温用制振金属板の製造方法を捉供す
るものである。In order to achieve the above-mentioned object, the present invention provides a method for manufacturing a vibration-damping metal plate for ultra-high temperatures, in which a superplastic alloy is interposed between metal plates, and the metal plates are bonded and integrated by heating. be.
この発明は、上記のような構成となっていて、例えば2
枚の金属板の接着剤として超塑性合金を使用したため、
従来、高温用として使用されていた制振金属板の適用温
度を大きく超え、特に300℃付近をki高とし、常温
から350℃以上にわたって損失係数の低下しない特性
を有する超高温用制振金属板として使用範囲を拡大でき
る。また、本発明によれば、第2図の実施結果に示すよ
うに、普通のZnめっき鋼板5に比して、その損失係数
は10倍以上高い制振鋼板を得ることができる。This invention has the above-mentioned configuration, and includes, for example, two
Because a superplastic alloy was used as an adhesive for two metal plates,
A damping metal plate for ultra-high temperatures that far exceeds the applicable temperature of damping metal plates conventionally used for high-temperature applications, has a high ki especially around 300°C, and has a characteristic that the loss coefficient does not decrease from room temperature to 350°C or higher. The range of use can be expanded as Furthermore, according to the present invention, as shown in the results of implementation in FIG. 2, it is possible to obtain a damping steel plate whose loss coefficient is ten times higher than that of the ordinary Zn-plated steel plate 5.
以下、この発明を図面およびグラフを参照して説明する
。第1図は本発明に係る超高温用制振金属板の製造ライ
ンのa2図を示したものであって、金属板として本実施
例においては、2枚の銅帯を使用した場合について説明
する。The present invention will be described below with reference to drawings and graphs. FIG. 1 shows an A2 diagram of a production line for a damping metal plate for ultra-high temperatures according to the present invention, and in this example, the case where two copper strips are used as the metal plates will be explained. .
図においーζ、la、lbはそれぞれ図外のアンコイラ
から供給される銅帯であって、これらの銅帯の相対向す
る面には、前もってZnめっきが施されている。2は超
塑性合金粉散布装置であって、この場合、超塑性合金粉
としてAl粉3をZnめっき鋼帯tb上に均一に散布す
る。そしてAN粉3を散布された鋼帯1bは、他方のア
ンコイラから送られたZnめっき鋼帯1aとデフレフク
ロール4の位置で重ね合わされるとともに八!粉を両銅
帯間に挟み込み、加熱炉5内へ送られる。重ね合わせた
鋼(iHa、lb、は炉5内において加熱され、調帯に
めっきされたZnのみが溶融して未溶融のAj!粉を混
入した状態となるか、あるいは上記Zn及びAl粉共、
溶融した状態となり、両銅帯はその間に形成される超塑
性合金層により接着される。このように、所要時間、所
要温度に加熱された後、2枚のw4帯1a、lbは加熱
炉5の出側において、加圧ロール6により圧着されて一
体化し、1枚の複合鋼帯(制振鋼帯)lcに形成される
とともに、冷却装置7を通過して冷却され、ピンチロー
ラ8を経てコイラー9に巻取られる。In the figure, ζ, la, and lb are copper strips supplied from an uncoiler (not shown), and Zn plating has been previously applied to the opposing surfaces of these copper strips. Reference numeral 2 denotes a superplastic alloy powder scattering device, in which Al powder 3 is uniformly dispersed as superplastic alloy powder onto the Zn-plated steel strip tb. Then, the steel strip 1b sprinkled with AN powder 3 is overlapped with the Zn-plated steel strip 1a sent from the other uncoiler at the position of the deflation crawl 4, and 8! The powder is sandwiched between both copper bands and sent into the heating furnace 5. The stacked steel (iHa, lb) is heated in the furnace 5, and only the Zn plated on the belt is melted and unmelted Aj! powder is mixed in, or the above Zn and Al powder are mixed together. ,
In the molten state, both copper strips are bonded by the superplastic alloy layer formed between them. After being heated to the required temperature for the required time, the two W4 strips 1a and lb are crimped and integrated by the pressure roll 6 on the exit side of the heating furnace 5, forming one composite steel strip ( The damping steel strip is formed into a damping steel strip) lc, cooled by passing through a cooling device 7, passed through a pinch roller 8, and wound around a coiler 9.
また、銅帯の間に介装する超塑性金属としてAl粉の代
わりに、第1図に一点鎖線で示したAj!箔を介装して
も、同様な制振鋼帯が得られる。In addition, instead of Al powder as the superplastic metal interposed between the copper strips, Aj! A similar damping steel strip can be obtained by interposing foil.
上記は、金属板として2枚のZnめっき鋼帯を使用した
例を示したが、金属板としてAl板を使用する場合は、
/l板間に介装する超塑性合金としてはZn粉などを使
用する。また、金属板としてAIl板と鋼板を複合する
場合は、鋼板をZnめっき鋼板とし、これにAj!板を
重ね合わせて加熱す乞。The above example shows an example in which two Zn-plated steel strips are used as the metal plates, but when using an Al plate as the metal plates,
As the superplastic alloy interposed between the /l plates, Zn powder or the like is used. In addition, when combining an Al plate and a steel plate as a metal plate, the steel plate is a Zn-plated steel plate, and Aj! Place the plates on top of each other and heat them.
以上、いずれの場合においても複合金属板となる金属板
の融点T mは八lの融点を考慮にいれてTm≧600
″Cであるとこを必要とする。In any of the above cases, the melting point Tm of the metal plate that becomes the composite metal plate is Tm≧600, taking into account the melting point of 8l.
``C.
次に、本発明による一つの実施例とその結果を示す。Next, one example according to the present invention and its results will be shown.
2枚の金属板として板厚0.8 waの鋼板を用い、そ
の内側片面に45 g / or以下の目付けでZnめ
っきを施した。そして、この鋼板間には第1図に示した
方法により、粒径50μのAj!粉を均一に散布し、加
熱炉5においてAr雰囲気中で500CX20secの
加熱を行い接着した。その結果、得たル1振鋼板の損失
係数と使用温度(″C)との関係は、第2図に示す通り
で、常温から350℃にわたって高い制振性を有するこ
とがわかる。なお、グラフ中5は1枚のみの片面Znめ
っき鋼板を示す。Steel plates with a thickness of 0.8 wa were used as the two metal plates, and one inner side of the plates was plated with Zn at a basis weight of 45 g/or or less. Then, by the method shown in Fig. 1, Aj! grain size of 50 μm is placed between the steel plates. The powder was uniformly spread and bonded by heating at 500C for 20 seconds in an Ar atmosphere in a heating furnace 5. As a result, the relationship between the loss coefficient and the operating temperature ("C) of the obtained steel sheet is as shown in Figure 2, and it can be seen that it has high vibration damping properties from room temperature to 350 °C. Number 5 indicates only one single-sided Zn-plated steel plate.
以上説明したように、本発明によれば、常温から350
°Cにわたって制振性を有する鋼板やその他の金属板が
得られ、従来の高温用と称する樹脂を介装した制振鋼板
の適用温度が150″C以下であったのに比べ、300
〜350℃においてその損失係数がほぼ匹敵できる超高
温用制振金属板とすることができた。これにより従来適
用できなかったエンジン周り部品、排気系部品の素材と
して使用できるようになり、大幅に用途範囲を拡大可能
となった。As explained above, according to the present invention, the
Steel plates and other metal plates with vibration damping properties can be obtained over a temperature range of 300°C, compared to 150"C or less for conventional vibration damping steel plates with resin interposed for high temperature use.
It was possible to obtain a damping metal plate for ultra-high temperatures whose loss coefficients are almost comparable at temperatures of up to 350°C. As a result, it can now be used as a material for engine-related parts and exhaust system parts, which could not previously be used, making it possible to significantly expand the range of applications.
第1図は本発明に係る超高温用制振金属板の製造ライン
概念図、第2図は本発明と従来例とを、その製品の適用
温度範囲と11失係数(制振性)について比較したグラ
フである。
la、lb・・・・・・金属板、lc・・・・・・制振
金属板。Figure 1 is a conceptual diagram of the production line for ultra-high temperature vibration damping metal plates according to the present invention, and Figure 2 compares the present invention and a conventional example with respect to the applicable temperature range and 11 lapse coefficient (damping performance) of the product. This is a graph. la, lb...metal plate, lc...vibration damping metal plate.
Claims (1)
熱により前記金属板を接着し一体化することを特徴とす
る超高温用制振金属板の製造方法。(1) A method for manufacturing a vibration-damping metal plate for ultra-high temperatures, which comprises interposing a superplastic alloy between metal plates and bonding and integrating the metal plates by heating.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP28899289A JPH03150149A (en) | 1989-11-07 | 1989-11-07 | Manufacture of vibration-damping metal sheet used at ultra-high temperature |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP28899289A JPH03150149A (en) | 1989-11-07 | 1989-11-07 | Manufacture of vibration-damping metal sheet used at ultra-high temperature |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH03150149A true JPH03150149A (en) | 1991-06-26 |
Family
ID=17737442
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP28899289A Pending JPH03150149A (en) | 1989-11-07 | 1989-11-07 | Manufacture of vibration-damping metal sheet used at ultra-high temperature |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH03150149A (en) |
-
1989
- 1989-11-07 JP JP28899289A patent/JPH03150149A/en active Pending
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