JPH0245600A - 液状過酸化水素組成物の安定化系 - Google Patents
液状過酸化水素組成物の安定化系Info
- Publication number
- JPH0245600A JPH0245600A JP15690589A JP15690589A JPH0245600A JP H0245600 A JPH0245600 A JP H0245600A JP 15690589 A JP15690589 A JP 15690589A JP 15690589 A JP15690589 A JP 15690589A JP H0245600 A JPH0245600 A JP H0245600A
- Authority
- JP
- Japan
- Prior art keywords
- aromatic amine
- free radical
- agent
- composition
- stabilizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 93
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 239000007788 liquid Substances 0.000 title claims description 24
- 239000002516 radical scavenger Substances 0.000 claims abstract description 52
- 150000004982 aromatic amines Chemical class 0.000 claims abstract description 45
- 230000000087 stabilizing effect Effects 0.000 claims abstract description 35
- 239000004094 surface-active agent Substances 0.000 claims abstract description 28
- 230000007760 free radical scavenging Effects 0.000 claims abstract description 27
- 125000005266 diarylamine group Chemical group 0.000 claims abstract description 5
- 239000013522 chelant Substances 0.000 claims abstract 4
- 239000002738 chelating agent Substances 0.000 claims description 43
- 238000004061 bleaching Methods 0.000 claims description 36
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 32
- 150000002978 peroxides Chemical class 0.000 claims description 32
- 229910052757 nitrogen Inorganic materials 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 18
- 125000003118 aryl group Chemical group 0.000 claims description 16
- 239000006081 fluorescent whitening agent Substances 0.000 claims description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 13
- 150000001768 cations Chemical class 0.000 claims description 11
- 238000009472 formulation Methods 0.000 claims description 11
- 229910001385 heavy metal Inorganic materials 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- -1 polyoxypropylene Polymers 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 150000001298 alcohols Chemical class 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000003205 fragrance Substances 0.000 claims description 6
- 125000000524 functional group Chemical group 0.000 claims description 6
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 6
- 230000006641 stabilisation Effects 0.000 claims description 6
- 238000011105 stabilization Methods 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- 150000003142 primary aromatic amines Chemical class 0.000 claims description 5
- 150000003336 secondary aromatic amines Chemical class 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 229920001400 block copolymer Polymers 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 125000005044 dihydroquinolinyl group Chemical group N1(CC=CC2=CC=CC=C12)* 0.000 claims 3
- 150000004989 p-phenylenediamines Chemical class 0.000 claims 3
- 125000003263 primary aromatic amine group Chemical group 0.000 claims 3
- 229920001451 polypropylene glycol Polymers 0.000 claims 1
- 239000007844 bleaching agent Substances 0.000 abstract description 20
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000975 dye Substances 0.000 description 26
- 229940123457 Free radical scavenger Drugs 0.000 description 24
- 150000003254 radicals Chemical class 0.000 description 20
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000003381 stabilizer Substances 0.000 description 8
- 150000001412 amines Chemical group 0.000 description 7
- 239000003352 sequestering agent Substances 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 239000003963 antioxidant agent Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 229910021645 metal ion Inorganic materials 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 230000002087 whitening effect Effects 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- 235000021286 stilbenes Nutrition 0.000 description 4
- 238000006467 substitution reaction Methods 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 239000001045 blue dye Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000008719 thickening Effects 0.000 description 3
- ZMLPKJYZRQZLDA-UHFFFAOYSA-N 1-(2-phenylethenyl)-4-[4-(2-phenylethenyl)phenyl]benzene Chemical group C=1C=CC=CC=1C=CC(C=C1)=CC=C1C(C=C1)=CC=C1C=CC1=CC=CC=C1 ZMLPKJYZRQZLDA-UHFFFAOYSA-N 0.000 description 2
- YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 239000001000 anthraquinone dye Substances 0.000 description 2
- 239000010692 aromatic oil Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- TVMXXLUFDNBORP-YHPRVSEPSA-L disodium;5-(4-phenyltriazol-2-yl)-2-[(e)-2-[4-(4-phenyltriazol-2-yl)-2-sulfonatophenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC(N2N=C(C=N2)C=2C=CC=CC=2)=CC=C1\C=C\C(C(=C1)S([O-])(=O)=O)=CC=C1N(N=1)N=CC=1C1=CC=CC=C1 TVMXXLUFDNBORP-YHPRVSEPSA-L 0.000 description 2
- 239000007850 fluorescent dye Substances 0.000 description 2
- 238000006897 homolysis reaction Methods 0.000 description 2
- 238000009897 hydrogen peroxide bleaching Methods 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- 150000001629 stilbenes Chemical class 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- IRFSXVIRXMYULF-UHFFFAOYSA-N 1,2-dihydroquinoline Chemical compound C1=CC=C2C=CCNC2=C1 IRFSXVIRXMYULF-UHFFFAOYSA-N 0.000 description 1
- JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-naphthylamine Chemical compound C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- 241000630665 Hada Species 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- LIKZXCROQGHXTI-UHFFFAOYSA-M acid blue 25 Chemical compound [Na+].C1=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C(S([O-])(=O)=O)C=C1NC1=CC=CC=C1 LIKZXCROQGHXTI-UHFFFAOYSA-M 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 150000004074 biphenyls Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical class OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000039 congener Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001236 detergent effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- PMPJQLCPEQFEJW-HPKCLRQXSA-L disodium;2-[(e)-2-[4-[4-[(e)-2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1\C=C\C1=CC=C(C=2C=CC(\C=C\C=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-HPKCLRQXSA-L 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000005204 hydroxybenzenes Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000001404 mediated effect Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229960003742 phenol Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 229910021654 trace metal Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3937—Stabilising agents
- C11D3/394—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Biochemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US21244788A | 1988-06-28 | 1988-06-28 | |
| US212,447 | 1988-06-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0245600A true JPH0245600A (ja) | 1990-02-15 |
Family
ID=22791058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15690589A Pending JPH0245600A (ja) | 1988-06-28 | 1989-06-21 | 液状過酸化水素組成物の安定化系 |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0349153A3 (fr) |
| JP (1) | JPH0245600A (fr) |
| AU (2) | AU3710489A (fr) |
| MX (1) | MX174330B (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007176931A (ja) * | 2005-11-30 | 2007-07-12 | Lion Corp | 殺ダニ方法および殺ダニ剤 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5180514A (en) * | 1985-06-17 | 1993-01-19 | The Clorox Company | Stabilizing system for liquid hydrogen peroxide compositions |
| ATE145424T1 (de) * | 1989-11-30 | 1996-12-15 | Clorox Co | Stabiles wässeriges oxidationswaschmittel |
| CA2049976C (fr) * | 1990-02-01 | 1997-01-14 | William G. Woods | Stabilisation de solutions aqueuses de peroxyde |
| US5180517A (en) * | 1990-11-05 | 1993-01-19 | United States Borax & Chemical Corporation | Stabilized liquid persalt bleach compositions |
| US5244593A (en) * | 1992-01-10 | 1993-09-14 | The Procter & Gamble Company | Colorless detergent compositions with enhanced stability |
| EP0672748B1 (fr) * | 1994-03-14 | 1999-09-01 | The Procter & Gamble Company | Compositions aqueuses fortement acides stables contenant des sels de persulfate |
| EP0751214A1 (fr) * | 1995-06-30 | 1997-01-02 | The Procter & Gamble Company | Compositions de blanchiment stables contenant des agents de blanchiment péroxydés |
| ATE277161T1 (de) * | 1995-07-05 | 2004-10-15 | Procter & Gamble | Vorbehandlung von wäsche mit verbesserter sicherheit für gewebe und farben |
| JP2000507294A (ja) | 1996-03-26 | 2000-06-13 | ビーエーエスエフ アクチェンゲゼルシャフト | 漂白及び繊維材料洗剤組成物の漂白効果強化剤 |
| DE69627667T2 (de) * | 1996-11-13 | 2004-02-19 | The Procter & Gamble Company, Cincinnati | Wässerige alkalische Peroxidbleichmittel enthaltende Zusammensetzungen |
| SE9604413D0 (sv) * | 1996-11-29 | 1996-11-29 | Eka Chemicals Ab | Chemical composition |
| DE19822391A1 (de) * | 1998-05-19 | 1999-11-25 | Henkel Kgaa | Wäßriges Bleichmittel |
| GB0418919D0 (en) * | 2004-08-25 | 2004-09-29 | Unilever Plc | Shading dyes |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB760315A (en) * | 1952-07-11 | 1956-10-31 | Ici Ltd | Improvements in and relating to the stabilisation of organic compounds |
| EP0137669B1 (fr) * | 1983-08-27 | 1988-07-06 | The Procter & Gamble Company | Compositions détergentes |
| DE3665482D1 (en) * | 1985-06-17 | 1989-10-12 | Clorox Co | Stabilized liquid hydrogen peroxide bleach compositions |
| US4764302A (en) * | 1986-10-21 | 1988-08-16 | The Clorox Company | Thickening system for incorporating fluorescent whitening agents |
-
1989
- 1989-06-14 EP EP89306007A patent/EP0349153A3/fr not_active Withdrawn
- 1989-06-21 JP JP15690589A patent/JPH0245600A/ja active Pending
- 1989-06-27 AU AU37104/89A patent/AU3710489A/en not_active Abandoned
- 1989-06-28 MX MX1663789A patent/MX174330B/es unknown
-
1992
- 1992-09-03 AU AU22132/92A patent/AU2213292A/en not_active Abandoned
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007176931A (ja) * | 2005-11-30 | 2007-07-12 | Lion Corp | 殺ダニ方法および殺ダニ剤 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0349153A2 (fr) | 1990-01-03 |
| AU3710489A (en) | 1990-01-04 |
| MX174330B (es) | 1994-05-09 |
| AU2213292A (en) | 1992-10-29 |
| EP0349153A3 (fr) | 1990-03-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4900468A (en) | Stabilized liquid hydrogen peroxide bleach compositions | |
| CA1296175C (fr) | Compositions liquides stabilisees d'agent de blanchiment a base de peroxyde d'hydrogene | |
| US5180514A (en) | Stabilizing system for liquid hydrogen peroxide compositions | |
| JPH0245600A (ja) | 液状過酸化水素組成物の安定化系 | |
| US4764302A (en) | Thickening system for incorporating fluorescent whitening agents | |
| US3671439A (en) | Oxygen bleach-activator systems stabilized with puffed borax | |
| US4828747A (en) | Suspending system for insoluble peroxy acid bleach | |
| CA2044953C (fr) | Composition tensioactive de blanchiment a paire d'ions fluorescents | |
| JPS5945601B2 (ja) | 過酸化水素水溶液 | |
| ES2349935T3 (es) | Nueva composición y procedimiento para el tratamiento de material de fibras. | |
| DE2422691A1 (de) | Stabile bleichmittel | |
| CA2016430C (fr) | Liquide acidique epaissi a l'aide d'amines de blanchiment fluorescents servant a vehiculer l'agent de blanchiment | |
| US4824592A (en) | Suspending system for insoluble peroxy acid bleach | |
| JPH05500040A (ja) | 過酸化水素水の安定化 | |
| US2362401A (en) | Detergent compositions | |
| JPH05502852A (ja) | 安定化した液状過塩漂白組成物 | |
| AU668936B2 (en) | Acidic activated bleaching compositon | |
| JPH0354159B2 (fr) | ||
| JP3583547B2 (ja) | 液体漂白剤組成物 | |
| JPS6177607A (ja) | 安定化された過炭酸ソ−ダ組成物 | |
| DE60003059T2 (de) | Waschmittelzusammensetzung | |
| DE69906530T2 (de) | Radikalabfänger | |
| JPH11189789A (ja) | 液体漂白性組成物 | |
| JPH0782592A (ja) | 液体漂白剤組成物 | |
| JPH01190795A (ja) | 洗浄漂白剤組成物 |