JPH02283429A - Mold for polyolefinic resin foam-molding - Google Patents
Mold for polyolefinic resin foam-moldingInfo
- Publication number
- JPH02283429A JPH02283429A JP1104674A JP10467489A JPH02283429A JP H02283429 A JPH02283429 A JP H02283429A JP 1104674 A JP1104674 A JP 1104674A JP 10467489 A JP10467489 A JP 10467489A JP H02283429 A JPH02283429 A JP H02283429A
- Authority
- JP
- Japan
- Prior art keywords
- mold
- steam
- foam
- molds
- diameter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000010097 foam moulding Methods 0.000 title claims description 13
- 229920005989 resin Polymers 0.000 title description 11
- 239000011347 resin Substances 0.000 title description 11
- 239000002245 particle Substances 0.000 claims abstract description 28
- 229920005672 polyolefin resin Polymers 0.000 claims description 14
- 239000011148 porous material Substances 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000005187 foaming Methods 0.000 abstract description 3
- 239000006260 foam Substances 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 7
- 238000005530 etching Methods 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- -1 polyethylene Polymers 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 239000010985 leather Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 238000004080 punching Methods 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012508 resin bead Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Landscapes
- Molding Of Porous Articles (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、ポリオレフィン系樹脂発泡成形用金型に関し
、さらに詳しくは、発泡粒子の粒界模様が隠され、外観
良好な発泡成形体を製造し得るポリオレフィン系樹脂発
泡成形用金型に関する。[Detailed Description of the Invention] [Industrial Field of Application] The present invention relates to a mold for polyolefin resin foam molding, and more specifically, to manufacturing a foam molded product with a good appearance in which grain boundary patterns of foamed particles are hidden. The present invention relates to a mold for polyolefin resin foam molding.
ポリオレフィン系樹脂発泡粒子をコア金型とキャビティ
ー金型とにより形成される型窩内に充填し、これを加熱
成形することにより箱状容器、緩衝材等種々のポリオレ
フィン系樹脂発泡成形体を得る方法が広く普及している
。Polyolefin resin foam particles are filled into a mold cavity formed by a core mold and a cavity mold, and then heated and molded to obtain various polyolefin resin foam molded products such as box-shaped containers and cushioning materials. The method is widely used.
ところが、これら型内発泡成形体の表面を観察すると、
発泡粒子同志が膨張融着した時に生じる粒界模様があり
、この模様により、これら型内発泡成形体は高級感がな
くなり、その用途が普及品ないし使い捨て用の製品に限
定されてしまうという問題があった。このような粒界模
様が生じる現象は、ポリオレフィン系樹脂の発泡膨張性
が低く型再現性が悪いために必然的に生じるものであっ
た。However, when observing the surface of these in-mold foamed products,
There is a grain boundary pattern that occurs when foamed particles expand and fuse together, and this pattern causes these in-mold foam molded products to lose their high-quality appearance, and their use is limited to popular or disposable products. there were. The phenomenon in which such a grain boundary pattern occurs is inevitably caused by the low foam expansion properties of polyolefin resins and poor mold reproducibility.
これを解決するものとして、成形容器の目視可能な表面
に、素材の表面の粒界模様の単位径と同等またはそれよ
りも狭いピッチの凹凸条より構成された幾何学模様をあ
らかじめ施すことにより、ずなわら、成形金型の内面に
その幾何学模様を設けておいて、視覚上成形品の表面凹
凸条からの反射を浮き出させ、その陰影中に発泡粒子の
粒界模様を混在、埋設させ、これによって樹脂成形品表
面が一様に美麗に仕上がっているように見せ掛け、−見
して発泡樹脂粒子素材による成形品と判別されないよう
にする技術が開示されている(実開昭63−10872
8号公報)。To solve this problem, a geometric pattern consisting of uneven stripes with a pitch equal to or narrower than the unit diameter of the grain boundary pattern on the surface of the material is applied in advance to the visible surface of the molded container. By providing the geometric pattern on the inner surface of the mold, the reflection from the uneven surface of the molded product is visually highlighted, and the grain boundary pattern of the expanded particles is mixed and buried in the shadow. , a technique has been disclosed in which the surface of a resin molded product appears uniformly and beautifully finished so that it cannot be distinguished from the molded product made of foamed resin particle material (Utility Model Application Publication No. 63-10872).
Publication No. 8).
(発明が解決しようとする課題〕
ところが、このような型内発泡成形においては型窩内に
加熱のための蒸気を送り込むための蒸気孔として、0゜
1〜0.3mmのスリットを設けた直径5〜10mmの
コアベントを埋め込むことが行われており、上記実開昭
63−108728号公報の金型では、このコアベント
については何の手当てもしておらず、成形体に蒸気孔の
跡があちこちに付いてしまい、本来の発泡粒子の粒界模
様は見る角度によって目立ってしまう問題と相俟って成
形体の美観を損ねるという問題は依然として解決されて
いない。(Problem to be Solved by the Invention) However, in such in-mold foam molding, a slit with a diameter of 0.1 to 0.3 mm is provided as a steam hole for sending heating steam into the mold cavity. A core vent of 5 to 10 mm is embedded in the mold, and in the mold of the above-mentioned Japanese Utility Model Publication No. 63-108728, no treatment was taken for this core vent, and the molded product was left with traces of steam holes here and there. The problem that the grain boundary pattern of the original expanded particles becomes noticeable depending on the viewing angle and the problem that the appearance of the molded product is spoiled has not yet been solved.
本発明は上記の点に鑑みなされたもので、その目的は、
発泡粒子の粒界模様が隠されるのみならず、蒸気孔の跡
も成形品の表面に残すことなく型内発泡成形を行ない得
るポリオレフィン系樹脂発泡成形用金型を提供すること
にある。The present invention has been made in view of the above points, and its purpose is to:
To provide a mold for polyolefin resin foam molding which not only hides the grain boundary pattern of expanded particles but also allows in-mold foam molding without leaving any traces of steam holes on the surface of the molded product.
本発明によれば、コア金型とキャビティー金型とにより
形成される型窩内に平均粒子径2n+m〜6 mmのポ
リオレフィン系樹脂発泡粒子を充填し、発泡成形体を製
造する金型において、該金型は多数の小径の蒸気孔が穿
設され、該蒸気孔の直径が0.5mm〜1.2mm、蒸
気孔のピッチが5mm〜20mm、i気孔の金型面に対
する開孔率が0.5%〜4%であり、かつ、該金型内面
にはシボ模様が設けられてなることを特徴とするポリオ
レフィン系樹脂発泡成形用金型が提供されるものである
。According to the present invention, in a mold for manufacturing a foam molded article by filling a mold cavity formed by a core mold and a cavity mold with polyolefin resin foam particles having an average particle diameter of 2n+m to 6 mm, The mold has a large number of small-diameter steam holes, the diameter of the steam holes is 0.5 mm to 1.2 mm, the pitch of the steam holes is 5 mm to 20 mm, and the porosity of the i-pores to the mold surface is 0. .5% to 4%, and a mold for polyolefin resin foam molding is provided, which is characterized in that the inner surface of the mold is provided with a textured pattern.
本発明に用いられるポリオレフィン系樹脂発泡粒子とし
ては、ポリエチレン、ポリプロピレン、これらの共重合
体、これらと共重合可能な他のモノマーとの共重合体
これらの混合物等より得られる発泡粒子が含まれる。ポ
リオレフィン系樹脂発泡粒子は、平均粒子径2mm〜6
mmのものが使用される。2mm未満では小さすぎて
発泡能が低く、発泡粒子間に窪みが発生し、発泡粒子相
互の融着性が悪くなったりまた外観上も好ましくない。The expanded polyolefin resin particles used in the present invention include polyethylene, polypropylene, copolymers thereof, and copolymers with other monomers copolymerizable with these.
Expanded particles obtained from mixtures of these and the like are included. The polyolefin resin foam particles have an average particle diameter of 2 mm to 6
mm is used. If it is less than 2 mm, it is too small and the foaming ability is low, depressions are formed between the foamed particles, the fusion properties between the foamed particles become poor, and the appearance is also unfavorable.
また、6Mを超えると成形体表面に樹脂粒子の形状に盛
り上がり外観が悪くなり好ましくない。Moreover, if it exceeds 6M, the surface of the molded product will bulge in the shape of resin particles, which will deteriorate the appearance, which is not preferable.
本発明の金型はコア金型とキャビティー金型とで構成さ
れ、これらの金型には多数の小径の蒸気孔が穿設されて
いる。そして、この蒸気孔の直径は0.5mm〜1.2
mmである。0.5 mm未満では加熱蒸気の供給が困
難になり、1.2mmを超えると蒸気孔の跡が目立ち好
ましくない。The mold of the present invention is composed of a core mold and a cavity mold, and these molds are provided with a large number of small-diameter steam holes. The diameter of this steam hole is 0.5 mm to 1.2 mm.
It is mm. If it is less than 0.5 mm, it will be difficult to supply heating steam, and if it exceeds 1.2 mm, the marks of the steam holes will be noticeable, which is not preferable.
蒸気孔間のピッチは5+++m〜20mmである。5胴
未満では金型に開ける孔の数が多いために金型製作に多
大の労力と費用を要することとなり、20mmを超える
と蒸気孔の数が少ないために蒸気加熱が困難になる。The pitch between steam holes is 5+++ m to 20 mm. If the diameter is less than 5 mm, the number of holes to be drilled in the mold will be large, requiring a great deal of labor and expense to manufacture the mold, and if the diameter exceeds 20 mm, the number of steam holes will be small, making steam heating difficult.
また、蒸気孔の金型面に対する開孔率は0.5%〜4%
である。0.5%未満ではポリオレフィン系樹脂発泡粒
子の発泡・融着に必要な蒸気量が確保できず、4%を超
える開孔率にしても開孔率を増やしただけの効果がなく
、経済的な利益もない。In addition, the porosity of the steam hole relative to the mold surface is 0.5% to 4%.
It is. If it is less than 0.5%, the amount of steam necessary for foaming and fusing the expanded polyolefin resin particles cannot be secured, and even if the porosity exceeds 4%, it will not have the effect of increasing the porosity, making it economical. There is no profit.
本発明の金型を構成する材質としては、アルミニウム系
金属が加工性、軽量性、伝熱性等の点で好ましい。As the material constituting the mold of the present invention, aluminum-based metal is preferable in terms of workability, lightness, heat conductivity, and the like.
本発明の金型内面にはシボ模様が付されている。The inner surface of the mold of the present invention has a grain pattern.
シボ模様としては、丸状、格子状、革目状、ダイヤカッ
ト状等の凹凸模様が好ましい。本発明の目的には革目状
のシボ模様が特に好ましい。As the grain pattern, an uneven pattern such as a round shape, a lattice shape, a leather grain shape, a diamond cut shape, etc. is preferable. For the purpose of the present invention, a leather grain pattern is particularly preferred.
金型にこのようなシボ模様を付すには、金型のエツチン
グによる方法、シボ模様の付いたパンチングメタルの金
型表面への貼り付けによる方法等により行われる。Such a textured pattern can be applied to a mold by etching the mold, by pasting punched metal with a textured pattern on the surface of the mold, or the like.
エツチングによる方法では、例えば、感光性樹脂シート
の貼り付けあるいは感光性樹脂の塗布に↓って金型面に
感光性樹脂層を形成後、模様のパターンが描かれたマス
クを被着して露光し、硬化させ、非硬化部を溶解除去す
る。次に、硬化樹脂層を通して薬液を作用させて金型面
をエツチングする。エツチング後硬化樹脂膜を剥がし、
金型表面を洗浄、乾燥する。In the etching method, for example, a photosensitive resin layer is formed on the mold surface by pasting a photosensitive resin sheet or coating the photosensitive resin, and then a mask with a pattern is attached and exposed. Then, the uncured portion is dissolved and removed. Next, a chemical solution is applied through the cured resin layer to etch the mold surface. After etching, peel off the cured resin film,
Clean and dry the mold surface.
ここで、上記エツチングは金型に蒸気孔を穿設する前後
のどちらで行なっても構わない。蒸気孔穿設後にエツチ
ングを行なう場合には、蒸気孔の部分に薬液が侵入しな
いように目止めを行なってもよい。Here, the above-mentioned etching may be performed either before or after forming the steam holes in the mold. When etching is performed after drilling the steam hole, the hole may be sealed to prevent chemical liquid from entering the hole.
また、パンチングメタルを貼り付ける場合は、パンチン
グメタルを貼り付けてからパンチングメタルと金型本体
を貫通する孔を開けることにより蒸気孔を設けてもよい
し、金型とパンチングメタルにそれぞれ孔を開けておき
、孔の位置を合せるように貼り付けてもよい。In addition, when pasting punching metal, you can create a steam hole by pasting the punching metal and then drilling a hole that passes through the punching metal and the mold body, or you can create a hole in the mold and punching metal separately. You may also attach it so that the holes are aligned.
〔作 用]
本発明の金型は、直径0.5mm〜1.2mmの蒸気孔
が5mm〜20mmのピッチで設けられ、蒸気孔の金型
面に対する開孔率が0.5%〜4%であるために、発泡
成形体の表面の蒸気孔の跡は見分は難く、さらに、金型
内面にシボ模様が付されているために、発泡成形体表面
には発泡粒子の粒子界面の模様が隠されてしまうととも
に上記蒸気孔の跡がこのシボ模様によりより一層見え難
いものとなる。よって、高級感のある美麗な外観を有す
る発泡成形体を得ることが可能になる。[Function] In the mold of the present invention, steam holes having a diameter of 0.5 mm to 1.2 mm are provided at a pitch of 5 mm to 20 mm, and the porosity of the steam holes with respect to the mold surface is 0.5% to 4%. Therefore, the traces of steam holes on the surface of the foamed molded product are difficult to distinguish, and furthermore, since the inner surface of the mold has a grain pattern, the pattern of the particle interface of the foamed particles can be seen on the surface of the foamed molded product. In addition to being hidden, the marks of the steam holes become even more difficult to see due to the grain pattern. Therefore, it becomes possible to obtain a foamed molded product having a beautiful appearance with a high-class feel.
次に実施例を挙げて本発明を説明する。 Next, the present invention will be explained with reference to Examples.
なお、開孔率(%)は、下記方法により求めた。Incidentally, the porosity (%) was determined by the following method.
実施例1
オートバイのサドルの形状の成形体が得られるような形
状としたアルミニウムダイカストによりコア金型とキャ
ビティー金型を作った。この両金型内面に厚さ約0.2
mmの感光性樹脂シートを貼り付は革目模様のパターン
が描かれたマスクを通して、紫外線を照射して露光し、
感光性樹脂を硬化させた。次し1で、未硬化の部分を溶
剤で溶解除去した後、塩化第二鉄溶液を作用させて、金
型表面の工・ンチング処理を行なった。エツチング後よ
く洗浄、乾燥し、次(、zで、下記の蒸気孔をト′リル
で開けて発泡成形用金型を得た。Example 1 A core mold and a cavity mold were made by aluminum die-casting so that a molded product in the shape of a motorcycle saddle could be obtained. The inner surface of both molds has a thickness of approximately 0.2
The photosensitive resin sheet with a diameter of 1.5 mm is pasted by exposing it to ultraviolet light through a mask with a leather grain pattern drawn on it.
The photosensitive resin was cured. Next, in step 1, after removing the uncured portion by dissolving it with a solvent, a ferric chloride solution was applied to process and etch the surface of the mold. After etching, it was thoroughly washed and dried, and then the following steam holes were opened with a drill to obtain a mold for foam molding.
直径(mm) : 0.8
ピッチ(mm) : 5
開孔率(%) : 2.2
以上のようにして得た金型を第1図に示すように発泡成
形装置に組み込み、下記の条件にて発泡成形を行なった
。Diameter (mm): 0.8 Pitch (mm): 5 Porosity (%): 2.2 The mold obtained as above was assembled into a foam molding machine as shown in Figure 1, and the following conditions were applied. Foam molding was performed.
原料:発泡ポリエチレン粒子
(発泡倍率20倍、平均粒子径4mm)成形含浸内圧:
0.8 kg/cJG蒸気加熱条件:正一方加熱0
.1 kg/c+ilG 3秒逆一方加熱0.3 kg
/ ci G 5秒両面加熱 1.1 kg/c+fl
G 3秒以上のようにして得られた成形体は、表面が革
目模様で覆われ、発泡ポリエチレン粒子の粒界模様は革
目模様に隠れており、さらに、蒸気孔の跡もわからず美
麗で高級感のある外観を有したものであった。Raw material: Foamed polyethylene particles (expansion ratio 20 times, average particle diameter 4mm) Molding impregnation internal pressure:
0.8 kg/cJG steam heating conditions: Positive one side heating 0
.. 1 kg/c+ilG 3 seconds reverse heating 0.3 kg
/ ci G 5 seconds double-sided heating 1.1 kg/c+fl
G The molded product obtained in the above manner for 3 seconds or more has a surface covered with a grain pattern, the grain boundary pattern of the foamed polyethylene particles is hidden in the grain pattern, and is beautiful with no visible traces of steam holes. It had a luxurious appearance.
実施例2
蒸気孔を直径1 、2 mm、ピッチ15mm、開孔率
0.6%とした以外は、実施例1と同様にしてオートバ
イのサドル形状のポリエチレン発泡粒子成形体を得た。Example 2 A polyethylene foam particle molded product in the shape of a motorcycle saddle was obtained in the same manner as in Example 1, except that the steam holes had a diameter of 1 mm or 2 mm, a pitch of 15 mm, and a porosity of 0.6%.
この成形体は実施例1と同様発泡粒子の粒界模様は革目
模様に隠れ、また、蒸気孔の跡もわからず美麗で高級感
のある外観を有し、更に、融着も良好であった。As in Example 1, the grain boundary pattern of the expanded particles was hidden by the leather grain pattern, and the molded product had a beautiful and luxurious appearance with no visible traces of steam holes, and also had good fusion bonding. Ta.
〔発明の効果]
本発明の金型によれば、発泡粒子の粒界模様が隠される
のみならず、蒸気孔の跡も成形品の表面に残すことなく
型内発泡成形を行なうことができる。[Effects of the Invention] According to the mold of the present invention, not only the grain boundary pattern of the expanded particles is hidden, but also in-mold foam molding can be performed without leaving any traces of steam holes on the surface of the molded product.
第1図は本発明の金型を装着した発泡成形装置の一例を
示す概略説明図である。
1−キャビティー金型、2−コア金型、3−充填機、4
−ポリオレフィン系樹脂ビーズ、訃−キャビティー側蒸
気弁、6−蒸気孔、7−コア側ドレイン弁、8−コア側
蒸気弁、9−キャビティー側ドレイン弁
特許出願人 旭化成工業株式会社FIG. 1 is a schematic explanatory diagram showing an example of a foam molding apparatus equipped with a mold according to the present invention. 1-cavity mold, 2-core mold, 3-filling machine, 4
-Polyolefin resin beads, -Cavity side steam valve, 6-Steam hole, 7-Core side drain valve, 8-Core side steam valve, 9-Cavity side drain valve Patent applicant Asahi Kasei Corporation
Claims (1)
に平均粒子系2mm〜6mmのポリオレフィン系樹脂発
泡粒子を充填し、発泡成形体を製造する金型において、
該金型は多数の小径の蒸気孔が穿設され、該蒸気孔の直
径が0.5mm〜1.2mm、蒸気孔のピッチが5mm
〜20mm、蒸気孔の金型面に対する開孔率が0.5%
〜4%であり、かつ、該金型内面にはシボ模様が設けら
れてなることを特徴とするポリオレフィン系樹脂発泡成
形用金型In a mold for producing a foamed molded product by filling foamed polyolefin resin particles with an average particle size of 2 mm to 6 mm into a mold cavity formed by a core mold and a cavity mold,
The mold has a large number of small diameter steam holes, the diameter of the steam holes is 0.5 mm to 1.2 mm, and the pitch of the steam holes is 5 mm.
~20mm, the open area ratio of the steam hole to the mold surface is 0.5%
-4%, and a mold for polyolefin resin foam molding, characterized in that the inner surface of the mold is provided with a textured pattern.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1104674A JPH02283429A (en) | 1989-04-26 | 1989-04-26 | Mold for polyolefinic resin foam-molding |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1104674A JPH02283429A (en) | 1989-04-26 | 1989-04-26 | Mold for polyolefinic resin foam-molding |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH02283429A true JPH02283429A (en) | 1990-11-20 |
Family
ID=14387021
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1104674A Pending JPH02283429A (en) | 1989-04-26 | 1989-04-26 | Mold for polyolefinic resin foam-molding |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH02283429A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003062849A (en) * | 2001-08-27 | 2003-03-05 | Kanegafuchi Chem Ind Co Ltd | Method for molding thermoplastic resin foamed molded object and molded object |
JP2009226871A (en) * | 2008-03-25 | 2009-10-08 | Sekisui Plastics Co Ltd | Antistatic thermoplastic resin foamed molding and its production process, molding die for producing antistatic thermoplastic resin foamed molding and molding device for producing antistatic thermoplastic resin foamed molding |
JP2014008659A (en) * | 2012-06-28 | 2014-01-20 | Yamamon:Kk | Vessel made of foamed resin |
WO2018100169A3 (en) * | 2016-12-01 | 2018-08-02 | Kurtz Gmbh | Crack-split moulding tool for producing a foam particle part and device for producing a foam particle part |
-
1989
- 1989-04-26 JP JP1104674A patent/JPH02283429A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003062849A (en) * | 2001-08-27 | 2003-03-05 | Kanegafuchi Chem Ind Co Ltd | Method for molding thermoplastic resin foamed molded object and molded object |
JP2009226871A (en) * | 2008-03-25 | 2009-10-08 | Sekisui Plastics Co Ltd | Antistatic thermoplastic resin foamed molding and its production process, molding die for producing antistatic thermoplastic resin foamed molding and molding device for producing antistatic thermoplastic resin foamed molding |
JP2014008659A (en) * | 2012-06-28 | 2014-01-20 | Yamamon:Kk | Vessel made of foamed resin |
WO2018100169A3 (en) * | 2016-12-01 | 2018-08-02 | Kurtz Gmbh | Crack-split moulding tool for producing a foam particle part and device for producing a foam particle part |
TWI730203B (en) * | 2016-12-01 | 2021-06-11 | 德商科茲股份有限公司 | Crack gap mould for producing a particle foam part together with an apparatus for producing a particle foam part |
US11697229B2 (en) | 2016-12-01 | 2023-07-11 | Kurtz Gmbh | Crack gap mold for producing a particle foam part together with an apparatus for producing a particle foam part |
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