JPH02243543A - ガラス繊維、その製造法およびその用途 - Google Patents
ガラス繊維、その製造法およびその用途Info
- Publication number
- JPH02243543A JPH02243543A JP1064391A JP6439189A JPH02243543A JP H02243543 A JPH02243543 A JP H02243543A JP 1064391 A JP1064391 A JP 1064391A JP 6439189 A JP6439189 A JP 6439189A JP H02243543 A JPH02243543 A JP H02243543A
- Authority
- JP
- Japan
- Prior art keywords
- alkali
- resistant glass
- glass fiber
- glass fibers
- strand
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003365 glass fiber Substances 0.000 title claims abstract description 78
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000003513 alkali Substances 0.000 claims abstract description 82
- 239000011159 matrix material Substances 0.000 claims abstract description 17
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 13
- 238000010558 suspension polymerization method Methods 0.000 claims abstract description 11
- 238000000576 coating method Methods 0.000 claims abstract description 9
- 239000011248 coating agent Substances 0.000 claims abstract description 7
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 5
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 5
- 239000000047 product Substances 0.000 abstract description 21
- 239000000178 monomer Substances 0.000 abstract description 13
- 239000000203 mixture Substances 0.000 abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 10
- 239000011083 cement mortar Substances 0.000 abstract description 6
- 238000000465 moulding Methods 0.000 abstract description 5
- 239000012736 aqueous medium Substances 0.000 abstract description 4
- 239000003505 polymerization initiator Substances 0.000 abstract description 4
- 239000004342 Benzoyl peroxide Substances 0.000 abstract description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract description 2
- 238000005520 cutting process Methods 0.000 abstract description 2
- 239000003381 stabilizer Substances 0.000 abstract description 2
- 239000000725 suspension Substances 0.000 abstract description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 15
- 238000000034 method Methods 0.000 description 15
- 238000005452 bending Methods 0.000 description 13
- 239000000378 calcium silicate Substances 0.000 description 12
- 229910052918 calcium silicate Inorganic materials 0.000 description 12
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 12
- 239000004568 cement Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000006116 polymerization reaction Methods 0.000 description 8
- 238000004513 sizing Methods 0.000 description 8
- 230000003014 reinforcing effect Effects 0.000 description 7
- 238000010557 suspension polymerization reaction Methods 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000004570 mortar (masonry) Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 239000011398 Portland cement Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- 206010061592 cardiac fibrillation Diseases 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000002600 fibrillogenic effect Effects 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- MKTRXTLKNXLULX-UHFFFAOYSA-P pentacalcium;dioxido(oxo)silane;hydron;tetrahydrate Chemical compound [H+].[H+].O.O.O.O.[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O MKTRXTLKNXLULX-UHFFFAOYSA-P 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920002319 Poly(methyl acrylate) Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229910003087 TiOx Inorganic materials 0.000 description 1
- ATMLPEJAVWINOF-UHFFFAOYSA-N acrylic acid acrylic acid Chemical compound OC(=O)C=C.OC(=O)C=C ATMLPEJAVWINOF-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- -1 catalog) Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920006015 heat resistant resin Polymers 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002954 polymerization reaction product Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 239000012047 saturated solution Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- SONHXMAHPHADTF-UHFFFAOYSA-M sodium;2-methylprop-2-enoate Chemical compound [Na+].CC(=C)C([O-])=O SONHXMAHPHADTF-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- HLLICFJUWSZHRJ-UHFFFAOYSA-N tioxidazole Chemical compound CCCOC1=CC=C2N=C(NC(=O)OC)SC2=C1 HLLICFJUWSZHRJ-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/1025—Coating to obtain fibres used for reinforcing cement-based products
- C03C25/103—Organic coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
- C03C13/001—Alkali-resistant fibres
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1064391A JPH02243543A (ja) | 1989-03-15 | 1989-03-15 | ガラス繊維、その製造法およびその用途 |
| ES9000760A ES2024093A6 (es) | 1989-03-15 | 1990-03-14 | Fibras de vidrio resistentes a los alcalis, procedimiento para su produccion y su uso. |
| GB9005850A GB2232988B (en) | 1989-03-15 | 1990-03-15 | "glass fibres, process for production thereof and use thereof" |
| FR9003327A FR2644449A1 (enrdf_load_stackoverflow) | 1989-03-15 | 1990-03-15 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1064391A JPH02243543A (ja) | 1989-03-15 | 1989-03-15 | ガラス繊維、その製造法およびその用途 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02243543A true JPH02243543A (ja) | 1990-09-27 |
Family
ID=13256972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1064391A Pending JPH02243543A (ja) | 1989-03-15 | 1989-03-15 | ガラス繊維、その製造法およびその用途 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPH02243543A (enrdf_load_stackoverflow) |
| ES (1) | ES2024093A6 (enrdf_load_stackoverflow) |
| FR (1) | FR2644449A1 (enrdf_load_stackoverflow) |
| GB (1) | GB2232988B (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010189263A (ja) * | 2009-02-13 | 2010-09-02 | Schott Ag | バリウム−フリーのｘ線不透過性ガラス及びその使用 |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0443734B1 (en) * | 1990-02-20 | 1993-11-03 | Minnesota Mining And Manufacturing Company | Coated zirconium oxide fibers |
| AU764593B2 (en) | 1999-02-15 | 2003-08-21 | Carl-Zeiss-Stiftung Trading As Schott Glaswerke | Glass with high proportion of zirconium-oxide and its uses |
| DE19945517B4 (de) * | 1999-02-15 | 2005-03-17 | Schott Ag | Hochzirconiumoxidhaltiges Glas und seine Verwendungen |
| DE19906240A1 (de) | 1999-02-15 | 2000-08-17 | Schott Glas | Hochzirkoniumoxidhaltiges Glas und dessen Verwendungen |
| DE102009008951B4 (de) | 2009-02-13 | 2011-01-20 | Schott Ag | Röntgenopakes bariumfreies Glas und dessen Verwendung |
| DE102009008954B4 (de) | 2009-02-13 | 2010-12-23 | Schott Ag | Röntgenopakes bariumfreies Glas und dessen Verwendung |
| DE102010007796B3 (de) | 2010-02-12 | 2011-04-14 | Schott Ag | Röntgenopakes bariumfreies Glas und dessen Verwendung |
| CN103087244B (zh) * | 2012-12-26 | 2015-06-24 | 海南必凯水性涂料有限公司 | 用于玻璃纤维浸涂的苯乙烯共聚乳液及其制备方法和应用 |
| FR3136761A1 (fr) * | 2022-06-15 | 2023-12-22 | Compagnie Generale Des Etablissements Michelin | Utilisation de fibres en composite verre-resine pour le renforcement du beton |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6054248B2 (ja) * | 1978-07-08 | 1985-11-29 | 日本板硝子株式会社 | 耐アルカリ性ガラス組成物 |
| JPS5638343A (en) * | 1979-09-06 | 1981-04-13 | Mitsubishi Monsanto Chem Co | Glass-fiber reinforced styrene resin composition |
-
1989
- 1989-03-15 JP JP1064391A patent/JPH02243543A/ja active Pending
-
1990
- 1990-03-14 ES ES9000760A patent/ES2024093A6/es not_active Expired - Fee Related
- 1990-03-15 FR FR9003327A patent/FR2644449A1/fr active Pending
- 1990-03-15 GB GB9005850A patent/GB2232988B/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010189263A (ja) * | 2009-02-13 | 2010-09-02 | Schott Ag | バリウム−フリーのｘ線不透過性ガラス及びその使用 |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2644449A1 (enrdf_load_stackoverflow) | 1990-09-21 |
| GB9005850D0 (en) | 1990-05-09 |
| GB2232988B (en) | 1992-07-29 |
| GB2232988A (en) | 1991-01-02 |
| ES2024093A6 (es) | 1992-02-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DK169699B1 (da) | Armeringsfibre og fremgangsmåde til fremstilling deraf | |
| US4778529A (en) | Cementitious compositions comprising a water soluble polymer and a cross-linking agent therefor | |
| Zhang et al. | Mechanical and thermal properties of denture PMMA reinforced with silanized aluminum borate whiskers | |
| JPH02243543A (ja) | ガラス繊維、その製造法およびその用途 | |
| CN111363077A (zh) | 一种聚合物水泥基材料及其制备方法与应用 | |
| Gad et al. | Influence of artificial aging and ZrO2 nanoparticle-reinforced repair resin on the denture repair strength | |
| JPH011704A (ja) | 中空重合体粒子の製造方法 | |
| JPH0129215B2 (enrdf_load_stackoverflow) | ||
| EP0235577A2 (en) | Acrylic fibres having improved dispersability in viscous organic or inorganic matrices | |
| GB1602695A (en) | Sized glass fibre strands particularly for reinforced cementitious products | |
| Mathew et al. | Flexural Strength of E-glass-reinforced PMMA | |
| JP3108431B2 (ja) | 成形物 | |
| AU2076200A (en) | Glass powder for glass ionomer cement | |
| US4119477A (en) | Size compositions for glass fiber reinforced cementitious products | |
| CN109486120B (zh) | 一种乙烯基树脂用玄武岩短切纤维的分散方法及其应用 | |
| JP2000309666A (ja) | ポリオレフィン系成形体及びその成形材料並びにその製造方法 | |
| JP2867087B2 (ja) | ポリプロピレン繊維および繊維補強セメント成型体 | |
| JPH09278503A (ja) | セメント補強繊維用集束剤、及びこれを塗布したセメント補強用繊維 | |
| JPS6125667B2 (enrdf_load_stackoverflow) | ||
| CN102335099A (zh) | 一种复合改性pmma | |
| JPH06192912A (ja) | セメント補強用繊維 | |
| JPS63162559A (ja) | 炭素繊維強化水硬性複合材料の製造方法 | |
| JP3084139B2 (ja) | 繊維強化水硬性成形物 | |
| JPS6366343B2 (enrdf_load_stackoverflow) | ||
| JP3365811B2 (ja) | 水硬性成形物の製造方法 |