JPH0222001B2 - - Google Patents
Info
- Publication number
- JPH0222001B2 JPH0222001B2 JP55031740A JP3174080A JPH0222001B2 JP H0222001 B2 JPH0222001 B2 JP H0222001B2 JP 55031740 A JP55031740 A JP 55031740A JP 3174080 A JP3174080 A JP 3174080A JP H0222001 B2 JPH0222001 B2 JP H0222001B2
- Authority
- JP
- Japan
- Prior art keywords
- iodine
- extraction
- examples
- amount
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 57
- 229910052740 iodine Inorganic materials 0.000 claims description 57
- 239000011630 iodine Substances 0.000 claims description 57
- 238000000034 method Methods 0.000 claims description 17
- 239000007864 aqueous solution Substances 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 6
- 238000000622 liquid--liquid extraction Methods 0.000 claims description 3
- 239000003758 nuclear fuel Substances 0.000 claims description 3
- 230000002285 radioactive effect Effects 0.000 claims description 3
- 238000000638 solvent extraction Methods 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 150000003077 polyols Chemical class 0.000 claims description 2
- 230000002209 hydrophobic effect Effects 0.000 claims 1
- 238000000605 extraction Methods 0.000 description 21
- 239000002904 solvent Substances 0.000 description 16
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 12
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
- 229910017604 nitric acid Inorganic materials 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 238000010828 elution Methods 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 125000004106 butoxy group Chemical class [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 125000002572 propoxy group Chemical class [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000003957 anion exchange resin Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000005337 ground glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229940071870 hydroiodic acid Drugs 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910001511 metal iodide Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- -1 molecular knots Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/13—Iodine; Hydrogen iodide
- C01B7/14—Iodine
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
- G21F9/12—Processing by absorption; by adsorption; by ion-exchange
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Extraction Or Liquid Replacement (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7908004A FR2452465A1 (fr) | 1979-03-30 | 1979-03-30 | Procede d'extraction de l'iode |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55130803A JPS55130803A (en) | 1980-10-11 |
| JPH0222001B2 true JPH0222001B2 (en:Method) | 1990-05-17 |
Family
ID=9223745
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3174080A Granted JPS55130803A (en) | 1979-03-30 | 1980-03-14 | Method of selectively extracting iodine from water solution |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4388231A (en:Method) |
| EP (1) | EP0017527B1 (en:Method) |
| JP (1) | JPS55130803A (en:Method) |
| AU (1) | AU523455B2 (en:Method) |
| BR (1) | BR8001906A (en:Method) |
| CA (1) | CA1137278A (en:Method) |
| DK (1) | DK151214C (en:Method) |
| ES (1) | ES490084A0 (en:Method) |
| FR (1) | FR2452465A1 (en:Method) |
| ZA (1) | ZA801863B (en:Method) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2452465A1 (fr) * | 1979-03-30 | 1980-10-24 | Ugine Kuhlmann | Procede d'extraction de l'iode |
| US6004465A (en) * | 1996-06-11 | 1999-12-21 | Pall Corporation | System and process for iodine recovery |
| US5962735A (en) * | 1998-03-06 | 1999-10-05 | Uop Llc | Method for treating an organic liquid contaminated with an iodide compound |
| US6398961B1 (en) | 2000-07-20 | 2002-06-04 | Ecolab Inc. | Device and method for sensing low level iodine in aqueous solution |
| USD536753S1 (en) * | 2000-11-09 | 2007-02-13 | Frank A Rongo | Calf exerciser |
| FR2832997B1 (fr) * | 2001-12-05 | 2004-05-14 | Commissariat Energie Atomique | Procede d'extraction de l'iode |
| JP4526777B2 (ja) * | 2003-04-04 | 2010-08-18 | ニッタ・ハース株式会社 | 水性コンディショニング液およびコンディショニング法 |
| JP4653968B2 (ja) * | 2004-04-28 | 2011-03-16 | 富士フイルムファインケミカルズ株式会社 | 無機ヨウ化物の回収方法 |
| RU2326810C1 (ru) * | 2006-09-12 | 2008-06-20 | Государственное образовательное учреждение высшего профессионального образования "Оренбургский государственный университет" | Способ извлечения йода |
| JP5446352B2 (ja) * | 2009-03-18 | 2014-03-19 | ダイキン工業株式会社 | ヨウ素の精製方法ならびにヨウ素の製造方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2931777A (en) * | 1956-08-16 | 1960-04-05 | Gen Aniline & Film Corp | Germicidal detergent compositions |
| US3880619A (en) * | 1974-09-05 | 1975-04-29 | Atomic Energy Commission | Solid sorbent for trapping iodine |
| US4013780A (en) * | 1975-11-17 | 1977-03-22 | Ethyl Corp | Recovery of iodine from brine with linear alkyl benzene solvents |
| FR2411801A1 (fr) * | 1977-12-14 | 1979-07-13 | Ugine Kuhlmann | Procede d'extraction de l'iode |
| FR2452465A1 (fr) * | 1979-03-30 | 1980-10-24 | Ugine Kuhlmann | Procede d'extraction de l'iode |
-
1979
- 1979-03-30 FR FR7908004A patent/FR2452465A1/fr active Granted
-
1980
- 1980-01-24 US US06/115,076 patent/US4388231A/en not_active Expired - Lifetime
- 1980-03-14 EP EP80400333A patent/EP0017527B1/fr not_active Expired
- 1980-03-14 JP JP3174080A patent/JPS55130803A/ja active Granted
- 1980-03-19 CA CA000347983A patent/CA1137278A/fr not_active Expired
- 1980-03-28 DK DK133980A patent/DK151214C/da not_active IP Right Cessation
- 1980-03-28 AU AU56936/80A patent/AU523455B2/en not_active Ceased
- 1980-03-28 ES ES490084A patent/ES490084A0/es active Granted
- 1980-03-28 ZA ZA00801863A patent/ZA801863B/xx unknown
- 1980-03-28 BR BR8001906A patent/BR8001906A/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ZA801863B (en) | 1981-04-29 |
| BR8001906A (pt) | 1980-11-25 |
| EP0017527B1 (fr) | 1982-05-19 |
| US4388231A (en) | 1983-06-14 |
| ES8101018A1 (es) | 1980-12-01 |
| EP0017527A1 (fr) | 1980-10-15 |
| AU5693680A (en) | 1980-10-02 |
| JPS55130803A (en) | 1980-10-11 |
| FR2452465A1 (fr) | 1980-10-24 |
| DK133980A (da) | 1980-10-01 |
| AU523455B2 (en) | 1982-07-29 |
| DK151214B (da) | 1987-11-16 |
| DK151214C (da) | 1988-07-04 |
| CA1137278A (fr) | 1982-12-14 |
| ES490084A0 (es) | 1980-12-01 |
| FR2452465B1 (en:Method) | 1981-03-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3900551A (en) | Selective extraction of metals from acidic uranium (vi) solutions using neo-tridecano-hydroxamic acid | |
| JPH0328376B2 (en:Method) | ||
| JPH0222001B2 (en:Method) | ||
| US4599221A (en) | Recovery of uranium from wet process phosphoric acid by liquid-solid ion exchange | |
| JPH10510924A (ja) | 放射性物質の汚染除去方法 | |
| US5508010A (en) | Method of separating fission molybdenum | |
| CN108342573A (zh) | 一种从含钼钨酸铵溶液中萃取分离钨钼的方法 | |
| JPH0124849B2 (en:Method) | ||
| EP2989222B1 (en) | A method for concentrating rare-earth metals in phosphogypsum | |
| US2902454A (en) | Solvent composition for recovery of metal values from aqueous solutions by solvent extraction | |
| US4872989A (en) | Selective removal of nitrate ions from salt solutions | |
| IL43501A (en) | Process for recovery of uranium from a solution containing phosphoric acid | |
| US5443731A (en) | Process for extracting technetium from alkaline solutions | |
| JP3303066B2 (ja) | スカンジウムの精製方法 | |
| JP3014186B2 (ja) | アルキルホスフェート溶液の浄化方法 | |
| JPH0688897A (ja) | ウランおよび照射済み核燃料の再処理の初期段階における核分裂生成物からクラウン化合物を用いてプルトニウムを分離する方法 | |
| US4185078A (en) | Extraction process for recovery of rhenium | |
| EP0002636B1 (fr) | Procédé de fixation de l'iode et sa préparation industrielle | |
| US2863717A (en) | Recovery of uranium values from copper-bearing solutions | |
| JPH0375617B2 (en:Method) | ||
| US4049771A (en) | Extraction process for recovery of rhenium | |
| JPS6111891B2 (en:Method) | ||
| JP2810981B2 (ja) | ヘキサシアノ鉄（ｉｉ）酸銅担持多孔性樹脂の製造方法 | |
| JP2667956B2 (ja) | ヘテロポリ酸塩系触媒からの触媒成分の回収方法 | |
| US4287159A (en) | Extraction process for the recovery of tungsten from low level sources |