JPH02182854A - Valve for light water reactor piping - Google Patents

Valve for light water reactor piping

Info

Publication number
JPH02182854A
JPH02182854A JP64000321A JP32189A JPH02182854A JP H02182854 A JPH02182854 A JP H02182854A JP 64000321 A JP64000321 A JP 64000321A JP 32189 A JP32189 A JP 32189A JP H02182854 A JPH02182854 A JP H02182854A
Authority
JP
Japan
Prior art keywords
valve
alloy
valve seat
light water
water reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP64000321A
Other languages
Japanese (ja)
Inventor
Yoshiteru Chiba
良照 千葉
Noriyuki Onaka
大中 紀之
Atsushi Oda
篤 小田
Kikuo Takeshima
菊男 竹島
Yoshiyuki Kojima
慶享 児島
Toshimi Matsumoto
松本 俊美
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP64000321A priority Critical patent/JPH02182854A/en
Publication of JPH02182854A publication Critical patent/JPH02182854A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00Energy generation of nuclear origin

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  • Sliding Valves (AREA)

Abstract

PURPOSE:To provide a valve excellent in resistance to corrosion and wear by forming one surface of a valve box or a valve disk seat with a specified Fe-based alloy and the other surface with a specified Ni-based alloy and combining the seats. CONSTITUTION:One surface of the seat 5 of the valve disk 6 or of the seat 7 of the valve box 4 is formed with a Cr-Ni-Mo-Fe-based Fe alloy, and the other surface with an Ni-Cr-B-Si-C-W-Fe-based Ni alloy. Both seats 5 and 7 are combined to fabricate a valve. The Fe-based alloy preferably contains, by weight, 20-30% Cr, 10-25% Ni, 5-15% Mo, 1-5% W, <=1% C and the balance Fe. Meanwhile, the Ni-based alloy preferably contains 7-15% Cr, 0.2-1.0 B, 3-7% Si, 2-5% Fe, 1.5-2.5% W, 0.7-1.5% C and the balance Ni.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、軽水炉配管用弁に係り、特に、耐摩耗及び耐
二ローション性に優れた弁に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a valve for light water reactor piping, and particularly to a valve with excellent wear resistance and lotion resistance.

〔従来の技術〕[Conventional technology]

従来の装置は、特開昭62−1837号公報に記載のよ
うに、弁座表面がCr−Ni−Fe系の鉄基析出硬化型
合金からなり、肉盛溶接後に高温での熱処理により析出
硬化させて硬さを保って、摩耗性を向上させている。し
かし、析出硬化熱処理による肉盛溶接部の割れ発生の恐
れがある事に対して考慮されていない。本発明は、化学
組成を変えることにより、析出硬化熱処理をせずに、耐
摩耗性、及び、耐腐食性に優れた弁座製作を可能にした
As described in JP-A-62-1837, the conventional device has a valve seat surface made of a Cr-Ni-Fe iron-based precipitation hardening alloy, which is precipitation hardened by heat treatment at a high temperature after overlay welding. This maintains hardness and improves abrasion resistance. However, no consideration is given to the possibility that cracks may occur in the overlay weld due to precipitation hardening heat treatment. The present invention has made it possible to manufacture a valve seat with excellent wear resistance and corrosion resistance without the need for precipitation hardening heat treatment by changing the chemical composition.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

従来の軽水炉配管用弁は、耐摩耗性、及び、耐重ローシ
ョン性を付与するためにCo基合金が肉盛溶接されてい
る。
Conventional valves for light water reactor piping are welded with a Co-based alloy overlay to provide wear resistance and heavy lotion resistance.

しかし、Co基合金は軽水炉の高温高圧水、あるいは、
蒸気の高速流体に接しているので、二ローションによっ
てCOが炉水中に溶出し、また、金属同士の摩耗によっ
てCoが炉水中に混入する。
However, Co-based alloys are used in high-temperature, high-pressure water of light water reactors,
Since it is in contact with a high-velocity fluid of steam, CO is eluted into the reactor water by the two lotions, and Co is mixed into the reactor water due to metal-to-metal abrasion.

これらのCoは炉心に入り6°COとなり、配管。These Co enters the reactor core and becomes 6° CO, which leads to piping.

タービン、その他の機器に循環、付着し、軽水炉プラン
ト全体の放射能を上げるという欠点がある。
It has the disadvantage that it circulates and adheres to turbines and other equipment, increasing the radioactivity of the entire light water reactor plant.

本発明の目的は、肉盛溶接材にCOを含まない合金を使
用し、耐重ローション、及び、耐摩耗性に優れた弁体弁
座、及び、弁箱弁座を提供することにある。
An object of the present invention is to provide a heavy-duty lotion, a valve body valve seat, and a valve body valve seat that use an alloy that does not contain CO as a build-up welding material and have excellent wear resistance.

〔課題を解決するための手段〕[Means to solve the problem]

上記目的は、Coを用いることなく、Co基合金と同等
の耐エロージヨン、及び、耐摩耗を得ることができるか
と研究開発を進めた。
For the above purpose, we conducted research and development to see if it would be possible to obtain erosion resistance and wear resistance equivalent to those of Co-based alloys without using Co.

摺動時に接触する弁座同士が同種系の材料であれば摩耗
量が多く、摩耗面の表面粗さも大になる。
If the valve seats that come into contact with each other during sliding are made of the same type of material, the amount of wear will be large and the surface roughness of the worn surfaces will also be large.

従って、異種材系の材料を弁座に用いることによりCo
基合金を用いることなくCo基合金同等の特性が得られ
る事を実験上判明し、本発明に至った。
Therefore, by using different materials for the valve seat, Co
It was experimentally found that properties equivalent to Co-based alloys can be obtained without using a base alloy, leading to the present invention.

〔作用〕[Effect]

本発明は、弁体弁座、あるいは、弁箱弁座の一方の弁座
表面がCr−Ni−Mo−Fe系のFe基からなり、他
の方の弁座表面をNi基合金にすることを特徴とする弁
である。耐腐食及び耐摩耗性の良好なCr−Ni−Mo
−Fe系Fe基合金と、耐腐食、及び、耐摩耗性の良好
なNi基合金とを組合せることにより、耐腐食及び耐摩
耗性に優れた弁が得られる。
The present invention provides that one valve seat surface of the valve body valve seat or the valve body valve seat is made of a Fe-based Cr-Ni-Mo-Fe system, and the other valve seat surface is made of a Ni-based alloy. This valve is characterized by: Cr-Ni-Mo with good corrosion and wear resistance
By combining a -Fe-based Fe-based alloy and a Ni-based alloy that has good corrosion resistance and wear resistance, a valve with excellent corrosion resistance and wear resistance can be obtained.

本発明に用いたC r −N i −M o −F e
系のFe基合金はオーステナイトステンレス鋼である。
C r -N i -Mo -F e used in the present invention
The Fe-based alloy of the series is austenitic stainless steel.

特に、重量比でCr20〜30%、Ni10〜25%、
Mo5〜15%、Wl〜5%、C1,Q以下及び残部F
eの組成をもつFe基合金で、耐腐食、及び、耐摩耗共
に優れているため、本発明の弁座に用いるのに好適であ
る。Crは耐腐食性向上のため必須であり、20%以上
は必要である。
In particular, 20 to 30% Cr, 10 to 25% Ni by weight,
Mo5~15%, Wl~5%, C1, Q and below and balance F
It is an Fe-based alloy having a composition of e, and has excellent corrosion resistance and wear resistance, so it is suitable for use in the valve seat of the present invention. Cr is essential for improving corrosion resistance, and 20% or more is required.

しかし、多量の含有はフェライトの生成を促し、硬度を
低下させるため30%以下とする。好ましくは25〜2
8%である。Niはフェライトの生成を抑制するために
、10%以上の添加は必要である。
However, since a large amount of content promotes the formation of ferrite and reduces hardness, the content is limited to 30% or less. Preferably 25-2
It is 8%. Ni needs to be added in an amount of 10% or more in order to suppress the formation of ferrite.

しかし、多量の含有はオーステナイトの生成を促し、強
度が不足するため、25%以下とする事が望ましい、好
ましくは、15〜20%である。
However, if the content is too large, it will promote the formation of austenite and the strength will be insufficient, so it is desirable that the content be 25% or less, preferably 15 to 20%.

Moは耐腐食性及び耐摩耗性を一反向上させるために必
要であるが過剰の添加は靭性を害するので5〜10%と
する。好ましくは8〜9%である。
Mo is necessary to improve corrosion resistance and wear resistance, but excessive addition impairs toughness, so the content is set at 5 to 10%. Preferably it is 8 to 9%.

Wは合金の硬さを向上させるために必要であるが過剰な
添加は靭性を害することから1〜5%とする。好ましく
は1.5〜2.5%である。Cは強度を向上させフェラ
イトの成牛を抑制する成分である。多量の含有は耐腐食
性、及び、延性を害することから1.0以下とする。好
ましくは0.2〜0.4%である。
W is necessary to improve the hardness of the alloy, but excessive addition impairs toughness, so it is limited to 1 to 5%. Preferably it is 1.5 to 2.5%. C is a component that improves strength and suppresses ferrite growth. Since a large amount of content impairs corrosion resistance and ductility, the content should be 1.0 or less. Preferably it is 0.2 to 0.4%.

他方のNi基合金はNi−Cr−B−Si −C−W−
Fe系で耐腐食、及び、耐重ローション性が優れた肉盛
合金として使用されている。上記のFe基合金と組合わ
せると耐摩耗性が良好となる。
The other Ni-based alloy is Ni-Cr-B-Si -C-W-
It is Fe-based and is used as a build-up alloy with excellent corrosion resistance and heavy lotion resistance. When combined with the above-mentioned Fe-based alloy, the wear resistance becomes good.

特に、Cr 7〜15%、80.2〜1.0%。In particular, Cr 7-15%, 80.2-1.0%.

Si3〜7%、C0,7〜1.2%、Fe2〜5%。Si3-7%, C0.7-1.2%, Fe2-5%.

W165〜2.5%で残部Niの組成をもつNi基合金
である。
It is a Ni-based alloy having a composition of 165 to 2.5% W and the balance being Ni.

Crは耐腐食性向上のための必須な元素である。Cr is an essential element for improving corrosion resistance.

最低5%を必要とするが、Crの含有量が15%を超え
ると、B及びCとの間に金属間化合物を形成し合金の靭
性を低下する。好ましくは、9〜11%である。Bは高
硬度の金属間化合物を形成し合金中に析出し、合金の硬
さを向上させると共に、肉盛溶接性を改善する働きをす
る。0.2%以下にすると肉盛溶接性が害になる。1.
0%以上にすると合金の靭性が低下する。好ましくは、
0.4〜0.5%が良い。
Although a minimum Cr content of 5% is required, if the Cr content exceeds 15%, an intermetallic compound is formed between B and C, reducing the toughness of the alloy. Preferably it is 9 to 11%. B forms a highly hard intermetallic compound and precipitates in the alloy, and functions to improve the hardness of the alloy and the overlay weldability. If it is less than 0.2%, overlay weldability will be impaired. 1.
If it exceeds 0%, the toughness of the alloy will decrease. Preferably,
0.4 to 0.5% is good.

SiはBと同じ働きをする。Si3%以下にすると肉盛
溶接性が害になる。、7%以上にすると合金の靭性が低
下する。好ましくは5〜6%が良い。
Si has the same function as B. If the Si content is less than 3%, overlay weldability will be impaired. , if it exceeds 7%, the toughness of the alloy will decrease. Preferably it is 5 to 6%.

Cは合金の硬さを向上させる働きをするが、Cの含有量
が0.7%以下では硬さが低下し、1.2%以上になる
と合金の靭性を低下させる。好ましくは、0.9〜1.
1%である。
C functions to improve the hardness of the alloy, but if the C content is 0.7% or less, the hardness decreases, and if it is 1.2% or more, the toughness of the alloy decreases. Preferably 0.9 to 1.
It is 1%.

FeはNi基合金に添加し、溶接性を向上させる。Fe is added to Ni-based alloys to improve weldability.

好ましくは、2〜3%が良い。Wは合金の基質部に分散
し、硬さを向上させる働きをするが、Wの含有量が2.
5% を超えると、合金の靭性を低下させる。好ましく
は2.0%である。
Preferably, 2 to 3% is good. W is dispersed in the matrix of the alloy and works to improve the hardness, but if the W content is 2.
If it exceeds 5%, the toughness of the alloy decreases. Preferably it is 2.0%.

このようなCr  Ni−Mo−Fe系のFe基合金及
びNi基合金は、例えば、弁箱弁座及び弁体弁座の表面
に肉盛溶接、ロー付、拡散接合、及び、ねじ止めでも良
く、弁箱弁座と弁体弁座の摺動面が前述の合金から構成
されていれば良い。
Such Cr Ni-Mo-Fe-based Fe-based alloys and Ni-based alloys may be applied, for example, to the surfaces of the valve body valve seat and the valve body valve seat by overlay welding, brazing, diffusion bonding, or screwing. It is sufficient that the sliding surfaces of the valve body valve seat and the valve body valve seat are made of the above-mentioned alloy.

〔実施例〕〔Example〕

以下、本発明の実施例を示す。 Examples of the present invention will be shown below.

第1表に供試材合金の化学組成を示す。Table 1 shows the chemical composition of the sample alloy.

Nα1〜Nα7は高周波真空溶解炉を用いて溶解後ガス
アトマイズ法により供試材合金の化学組成の粉末を製造
した。粉末の粒径は一70/+250メシュのものであ
る。その粉末を用いてプラズマ粉体肉盛溶接法で5US
304板材の上に二層、肉盛溶接を行った物から摩耗試
験片を採取した。摩耗条件は、面圧25,50,75及
び100Kg/cslとし。
For Nα1 to Nα7, powders having the chemical composition of the test material alloys were manufactured by a gas atomization method after melting using a high frequency vacuum melting furnace. The particle size of the powder is -70/+250 mesh. Using the powder, 5US was produced using the plasma powder overlay welding method.
Abrasion test pieces were taken from a 304 plate with two layers of overlay welding applied. The wear conditions were surface pressures of 25, 50, 75, and 100 kg/csl.

摩耗速度3 、1 m /lll1n、摩耗時間は0.
5 h  で水中で行い、摩耗体積域(d)、及び、摩
耗面の粗さを測定した。第1図に摩耗体積域を示す。第
1図により明らかなように、本発明のCr −N i 
−M o −F e系のFe基合金、及び、Ni−Cr
−B−5i−C−W−Fe系のNi基合金である翫1と
Na2の組合せが、NG2とNa 3及びNn 4とN
(L 6の組合せよりも優れていることを確認された。
Wear rate: 3.1 m/lll1n, wear time: 0.
The test was carried out in water for 5 hours, and the wear volume area (d) and the roughness of the wear surface were measured. Figure 1 shows the wear volume area. As is clear from FIG. 1, the Cr-N i of the present invention
-Mo-Fe-based Fe-based alloy and Ni-Cr
-B-5i-C-W-Fe-based Ni-based alloys 1 and Na2 have a combination of NG2 and Na3 and Nn4 and N
(It was confirmed that it was superior to the combination of L 6.

第2図は弁のシール性の生命である表面粗さを示す。Figure 2 shows surface roughness, which is the key to a valve's sealing performance.

第2図で明らかなように1本発明の組合せNQ1.及び
、Nα2の方が優れている事を確認した。
As is clear from FIG. 2, combination NQ1. of the present invention. It was also confirmed that Nα2 is superior.

次に、上記試料Nα1.2,3,4,6.7の合金を用
いて第2表に示す組合せで第3図に示す4B管用弁を製
作し、高温高圧水中で弁の開閉作動試験をし、作動試験
の開閉の回数は100回、面圧は225 Kg/ cJ
とし、弁の気密性を確認した。
Next, using the alloys of the above samples Nα1.2, 3, 4, and 6.7, a 4B pipe valve shown in FIG. However, the number of opening and closing operations in the operation test was 100 times, and the surface pressure was 225 Kg/cJ.
The airtightness of the valve was confirmed.

第   2   表 その結果を第2表に示す。第2表で明らかなように、弁
箱弁座にNα2合金、弁体弁座にNa 1の合金を使用
した弁は100回の開閉試験で水漏れは確認されず、気
密性を保持した。一方、弁箱弁座にNo2及びNα4.
弁体弁座にNα3及びNa 6は合金は、80回及び6
5回で気密性は破壊された。比較材としてCo基合金も
摩耗試験及び弁の開閉試験を行った。その結果本発明合
金の組合せと同等であることを確認した。
Table 2 The results are shown in Table 2. As is clear from Table 2, the valve using the Na2 alloy for the valve box valve seat and the Na1 alloy for the valve body valve seat maintained airtightness with no water leakage observed in 100 opening/closing tests. On the other hand, No.2 and No.4 on the valve seat of the valve box.
The alloys of Nα3 and Na6 on the valve body valve seat are 80 times and 6
The airtightness was destroyed after five attempts. As a comparison material, a Co-based alloy was also subjected to wear tests and valve opening/closing tests. As a result, it was confirmed that the combination was equivalent to the combination of the alloys of the present invention.

以上の結果、従来弁座に使用されているCo基合金を用
いた物と本発明合金組合せ弁と同等である事を確認した
The above results confirmed that the alloy combination valve of the present invention is equivalent to the valve seat using a Co-based alloy conventionally used for the valve seat.

〔発明の効果〕〔Effect of the invention〕

本発明によれば、軽水炉配管、及び、配管に接続されて
いる四辺機器の放射線を従来の半分以下におさえる事が
でき、定期検査時の作業時間を大幅に確保でき、より安
全な原子カプラントを製造することができる。
According to the present invention, it is possible to reduce the radiation of light water reactor piping and the equipment on all sides connected to the piping to less than half of the conventional level, and it is possible to significantly save work time during periodic inspections, resulting in a safer nuclear couplant. can be manufactured.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の一実施例の摩耗試験結果で体積域と摩
耗面圧の関係を示す図、第2図は摩耗試験結果で表面粗
さと摩耗面圧の関係を示す図、第3図は仕切弁の断面図
を示す。 1・・・ハンドル、2・・ボンネット、3・・・弁棒、
4・・・弁箱、5・・・弁体弁座、6・・・弁体、7・
・・弁箱弁座。 多 1 区 第 21¥1 4表のL−一 摩遺邑旬厘(勺シ′Cが9
Fig. 1 is a diagram showing the relationship between volume area and abrasion surface pressure based on the wear test results of one embodiment of the present invention, Fig. 2 is a diagram showing the relationship between surface roughness and abrasion surface pressure in the abrasion test result, and Fig. 3 is a diagram showing the relationship between surface roughness and abrasion surface pressure in the abrasion test result. shows a cross-sectional view of the gate valve. 1... Handle, 2... Bonnet, 3... Valve stem,
4... Valve box, 5... Valve body valve seat, 6... Valve body, 7...
...Bent box valve seat. Ta 1 Ward No. 21¥1 Table 4 L-Ichima Imura Shunrin (勺し'C is 9

Claims (1)

【特許請求の範囲】 1、軽水炉配管用弁の弁箱弁座、あるいは、弁体弁座の
一方の弁座表面がCr−Ni−Mo−Fe系のFe基か
らなり、他方の弁座表面がNi−Cr−B−Si−C−
W−Fe系のNi基合金の組合せからなることを特徴と
する軽水炉配管用弁。 2、特許請求項第1項のFe基合金は重量比でCr20
〜30%、Ni10〜25%、Mo5〜15%、W1〜
5%、C1.0%以下、及び残部Feの化学組成をもつ
ことを特徴とする軽水炉配管用弁。 3、特許請求項第1項のNi基合金は重量比でCr7〜
15%、B0.2〜1.0%、Si3〜7%、Fe2〜
5%、W1.5〜2.5%、C0.7〜1.2%及び残
部Niの化学組成をもつことを特徴とする軽水炉配管用
弁。 4、特許請求項第1項のFe基合金は重量比でCr20
〜30%、Ni10〜25%、Mo5〜15%、W1〜
5%、C1.0%以下及び残部Fe、Ni基合金は重量
比でCr7〜15%、B0.2〜1.0%、Si;3〜
7%、Fe2〜5%、W1.5〜2.5%、C;0.7
〜1.2%及び残部Niの化学組成をもち、溶接、ロー
付及び拡散接合で弁座を形成することを特徴とする軽水
炉配管用弁。
[Scope of Claims] 1. One valve seat surface of the valve body valve seat or valve body valve seat of a light water reactor piping valve is made of a Cr-Ni-Mo-Fe system Fe group, and the other valve seat surface is Ni-Cr-B-Si-C-
A valve for light water reactor piping, characterized in that it is made of a combination of a W-Fe-based Ni-based alloy. 2. The Fe-based alloy of claim 1 has a weight ratio of Cr20
~30%, Ni10~25%, Mo5~15%, W1~
A light water reactor piping valve characterized by having a chemical composition of 5% C, 1.0% or less of C, and the balance Fe. 3. The Ni-based alloy according to claim 1 has a weight ratio of Cr7 to
15%, B0.2-1.0%, Si3-7%, Fe2-
A light water reactor piping valve having a chemical composition of 5% W, 1.5 to 2.5% W, 0.7 to 1.2% C, and the balance Ni. 4. The Fe-based alloy according to claim 1 has a weight ratio of Cr20
~30%, Ni10~25%, Mo5~15%, W1~
5%, C1.0% or less and the balance Fe, Ni-based alloy has a weight ratio of Cr7 to 15%, B0.2 to 1.0%, Si; 3 to
7%, Fe2-5%, W1.5-2.5%, C; 0.7
1. A light water reactor piping valve having a chemical composition of ~1.2% Ni with the balance being Ni, and having a valve seat formed by welding, brazing, and diffusion bonding.
JP64000321A 1989-01-06 1989-01-06 Valve for light water reactor piping Pending JPH02182854A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP64000321A JPH02182854A (en) 1989-01-06 1989-01-06 Valve for light water reactor piping

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP64000321A JPH02182854A (en) 1989-01-06 1989-01-06 Valve for light water reactor piping

Publications (1)

Publication Number Publication Date
JPH02182854A true JPH02182854A (en) 1990-07-17

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP64000321A Pending JPH02182854A (en) 1989-01-06 1989-01-06 Valve for light water reactor piping

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011013164A (en) * 2009-07-03 2011-01-20 Toshiba Corp Scram valve of water pressure control unit

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011013164A (en) * 2009-07-03 2011-01-20 Toshiba Corp Scram valve of water pressure control unit

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