JPH04276038A - Valve for light water nuclear reactor - Google Patents

Valve for light water nuclear reactor

Info

Publication number
JPH04276038A
JPH04276038A JP3608891A JP3608891A JPH04276038A JP H04276038 A JPH04276038 A JP H04276038A JP 3608891 A JP3608891 A JP 3608891A JP 3608891 A JP3608891 A JP 3608891A JP H04276038 A JPH04276038 A JP H04276038A
Authority
JP
Japan
Prior art keywords
valve
valve seat
light water
seat part
welding
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP3608891A
Other languages
Japanese (ja)
Other versions
JP2637296B2 (en
Inventor
Kikuo Takeshima
竹島菊男
Makoto Kumagai
熊谷真
Yoshiteru Chiba
千葉良照
Hitoshi Honda
本田整
Katsumi Hirano
平野克己
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Okano Valve Mfg Co Ltd
Original Assignee
Hitachi Ltd
Okano Valve Mfg Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd, Okano Valve Mfg Co Ltd filed Critical Hitachi Ltd
Priority to JP3608891A priority Critical patent/JP2637296B2/en
Publication of JPH04276038A publication Critical patent/JPH04276038A/en
Application granted granted Critical
Publication of JP2637296B2 publication Critical patent/JP2637296B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Lift Valve (AREA)

Abstract

PURPOSE:To manufacture a valve for a light water nuclear reactor having a cobalt free valve seat material clad by welding improved in wear resistance and erosion resistance by using Ni-base alloy materials having different chemical compsn. and hardness for each surface clad material by welding on the valve seat part of a valve box and on the valve seat part of a valve disk. CONSTITUTION:An Ni base alloy forming either surface clad material by welding of the valve seat part of a valve box and the valve seat part of a valve disk has a chemical compsn. constituted of 10 to 15% Cr, 3 to 7% Si, <=10% Fe, 2 to 4% W and the balance Ni and has 40 to 55Hrc Rockwell hardness. The Ni base alloy forming the surface clad material by welding of the another one has a chemical compsn. constituted of 15 to 20% Cr, 5 to 10% Si, <=15% Fe, 1 to 3% W, 0.5 to 1.0% Sn and the balance Ni and has 50 to 60Hrc Rockwell hardness. By using a valve for a light water nuclear reactor constituted of the valve seat part of a valve box and the valve seat part of a valve disk like those in such a manner that it is set to a pipeline where it is directly connected to a nuclear reactor, the ratio of the amt. of radiation dose not in peripheral equipment can be suppressed to about less than 1/2 to that of the conventional one.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】本発明は、コバルトフリーの肉盛
弁座材を有する軽水原子炉用弁に係り、特に耐摩耗性及
び耐エロージョン性に優れた軽水原子炉用弁に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a light water reactor valve having a cobalt-free overlay valve seat material, and more particularly to a light water reactor valve having excellent wear resistance and erosion resistance.

【0002】0002

【従来の技術】従来、軽水原子炉用の弁の弁座部には、
耐摩耗性及び耐エロージョン性を付与するためにCo基
合金が肉盛溶接されている。しかし、Co基合金は、軽
水炉の高温高圧水に接していると、その腐蝕作用によっ
て金属表面からのCoが炉水中に溶出する。又、高速流
体によるエロージョンによって金属表面から侵食された
Coが炉水中に持込まれる。これらのCoは炉心中に入
り60Coとなり、配管、タービンその他の機器に循環
付着し、このため、軽水炉プラント全体の放射能が増え
、定検作業の被曝量が増大する欠点がある。
[Prior Art] Conventionally, the valve seat of a light water reactor valve has a
A Co-based alloy is overlay welded to provide wear resistance and erosion resistance. However, when a Co-based alloy comes into contact with high-temperature, high-pressure water of a light water reactor, Co from the metal surface is eluted into the reactor water due to its corrosive action. In addition, Co eroded from the metal surface by erosion caused by the high-speed fluid is brought into the reactor water. These Co enters the reactor core and becomes 60Co, which circulates and adheres to piping, turbines, and other equipment, which increases the radioactivity of the entire light water reactor plant and increases the amount of radiation exposure during periodic inspection work.

【0003】他方、弁の弁座部に用いるコバルトフリー
材としては、従来よりFe基合金やNi基合金が使用さ
れているが、耐摩耗性が不十分であった。例えば特開昭
62−1837号に記載のようにCr−Ni−Fe系の
鉄基合金と、Cr−Nb−Mo−Ni系のNi基合金の
組合せとしたものでは、肉盛溶接後の析出硬化熱処理が
非常にむつかしかった。また例えば特開昭62−130
792号に示すようにNi基合金同志の組合せとしたも
のでは、同一硬度の為、耐摺動摩耗性が弱いという問題
があった。
On the other hand, Fe-based alloys and Ni-based alloys have conventionally been used as cobalt-free materials for the valve seat portion of valves, but these have insufficient wear resistance. For example, in the combination of a Cr-Ni-Fe iron-based alloy and a Cr-Nb-Mo-Ni Ni-based alloy as described in JP-A No. 62-1837, precipitation after overlay welding Curing heat treatment was extremely difficult. For example, JP-A-62-130
As shown in No. 792, a combination of Ni-based alloys had the problem of poor sliding wear resistance because they had the same hardness.

【0004】0004

【発明が解決しようとする課題】以上の従来の問題点に
鑑み、本発明の目的は、肉盛溶接材にCoを含まない合
金を使用し、しかも、前記コバルトフリー材を用いてい
る従来技術の欠点を持たず、耐エロージョン性及び耐摩
耗性に優れた弁箱弁座部表面肉盛材および弁体弁座部表
面肉盛材を有する軽水原子炉用弁を提供することである
[Problems to be Solved by the Invention] In view of the above-mentioned conventional problems, an object of the present invention is to use an alloy that does not contain Co as an overlay welding material, and to overcome the conventional technology that uses the cobalt-free material. It is an object of the present invention to provide a light water reactor valve which does not have the above disadvantages and has a valve body valve seat surface overlay material and a valve body valve seat surface overlay material which have excellent erosion resistance and wear resistance.

【0005】[0005]

【課題を解決するための手段】上記目的を達成するため
、本発明者らは、Coを用いることなく、Co基合金と
同等の耐エロージョン及び耐摩耗性を有する材料を得る
ための研究開発を進めてきた結果、本発明に至った。 本発明は、軽水原子炉用弁の弁箱弁座部の表面肉盛材と
弁体弁座部の表面肉盛材とを、いずれも、Coを含まな
いNi基合金であって且つ互にその化学組成および硬度
が異なるものとしたことを特徴とする。これが、耐摩耗
性の向上及び該材料の良好な耐エロージョン性をもたら
すことを本発明者らは実験で確認することができ、Co
基合金と同等の耐摩耗性および耐エロージョン性が得ら
れることが判明した。
[Means for Solving the Problem] In order to achieve the above object, the present inventors conducted research and development to obtain a material that has erosion resistance and wear resistance equivalent to Co-based alloys without using Co. As a result of these efforts, we have arrived at the present invention. In the present invention, the surface overlay material of the valve seat part of the valve body and the surface overlay material of the valve seat part of the valve body of a valve for a light water reactor are both made of a Ni-based alloy that does not contain Co, and are mutually They are characterized by having different chemical compositions and hardnesses. The present inventors were able to confirm through experiments that this resulted in improved wear resistance and good erosion resistance of the material.
It was found that wear resistance and erosion resistance equivalent to that of the base alloy can be obtained.

【0006】[0006]

【作用】本発明によれば、弁体弁座の表面肉盛材と弁箱
弁座の表面肉盛材をいずれも、Cr−Si−Fe−W系
のNi基合金とし、且つロックウェル硬度HRCを一方
が40〜55とし、他方が50〜60とする。
[Operation] According to the present invention, both the surface build-up material of the valve body valve seat and the surface build-up material of the valve body valve seat are made of a Cr-Si-Fe-W based Ni-based alloy, and have Rockwell hardness. One side has an HRC of 40-55, and the other has an HRC of 50-60.

【0007】本発明における弁体弁座及び弁箱弁座に夫
々用いたCr−Si−Fe−W系のNi基合金は、一方
は、Cr10〜15%,Si3〜7%,Fe10%以下
,W2〜4%,B1%以下、C1%以下とし、他方は、
Cr15〜20%,Si5〜10%,Fe15%以下、
W1〜3%,Sn  0. 5〜1%,B1%以下,C
1%以下とする。
[0007] The Cr-Si-Fe-W Ni-based alloy used for the valve body valve seat and the valve body valve seat in the present invention is composed of 10 to 15% Cr, 3 to 7% Si, 10% or less Fe, W2 to 4%, B1% or less, C1% or less, and the other is,
Cr15-20%, Si5-10%, Fe15% or less,
W1-3%, Sn 0. 5-1%, B1% or less, C
1% or less.

【0008】Crは耐食性を維持するために10%は必
要である。但し、多量の含有はフェライトの生成を促す
ため最大でも20%とする。
[0008] 10% Cr is required to maintain corrosion resistance. However, since a large amount of content promotes the formation of ferrite, the maximum content is 20%.

【0009】Siは硬度と耐摩耗性を維持するために必
要であるが、多量に加えると靭性が低下し溶接施工性が
劣化するので、一方は3〜7%、他方は5〜10%とす
る。
[0009]Si is necessary to maintain hardness and wear resistance, but if added in large amounts, toughness decreases and weldability deteriorates, so one should be 3 to 7% and the other 5 to 10%. do.

【0010】Snは耐摩耗性を維持するのに必要である
ので、高硬度の方の合金に含有させる。しかし、多量に
加えると靭性が低下し溶接施工性が劣化するので0. 
5〜1%とする。
Since Sn is necessary to maintain wear resistance, it is included in the higher hardness alloy. However, if too much is added, the toughness will decrease and weldability will deteriorate, so 0.
5 to 1%.

【0011】BおよびCは不純物元素として含有される
が、多いと溶接施工性を劣化させるので1%以下に制限
して溶接時および溶接後の熱処理時に割れないようにす
る。
[0011] B and C are contained as impurity elements, but if they are present in large amounts, welding performance deteriorates, so they are limited to 1% or less to prevent cracking during welding and post-weld heat treatment.

【0012】なお、B,Cはいずれも合金の硬度を高め
る効果を有するが、耐摩耗性の維持のためにはSiで硬
度を高めるのが望ましいので、不純物として含有量を制
限する。
[0012] Both B and C have the effect of increasing the hardness of the alloy, but in order to maintain wear resistance, it is desirable to increase the hardness with Si, so their content is limited as impurities.

【0013】Fe,Wは、合金の硬さを調整するために
必要であるが、Feの多量の含有は硬度を低下させ、ま
た、Wは靭性を低下させることから、Feは、一方は1
0%以下、他方は15%以下とし、Wは、一方は2〜4
%,他方は1〜3%とする。
[0013] Fe and W are necessary to adjust the hardness of the alloy, but since a large amount of Fe decreases the hardness and W also decreases the toughness, Fe is
One is 0% or less, the other is 15% or less, and W is 2 to 4 on one side.
%, and the other is 1 to 3%.

【0014】上記説明したような硬度および化学組成の
相違したNi基合金を弁体弁座、弁箱弁座、更にはガイ
ド部にプラズマ粉体溶接、粉末溶射、溶接棒によるティ
グ又はガス溶接することで本発明の効果が得られる。 又、更に摩耗性を向上するために上記肉盛表面にセラミ
ックコーティングすることもできる。
Ni-based alloys having different hardnesses and chemical compositions as described above are applied to the valve body valve seat, valve body valve seat, and guide portion by plasma powder welding, powder spraying, TIG welding using a welding rod, or gas welding. In this way, the effects of the present invention can be obtained. Furthermore, the overlay surface may be coated with a ceramic coating to further improve wear resistance.

【0015】[0015]

【実施例】弁体の弁座材および弁箱の弁座材に用いる合
金として幾つかの供試材合金について実験した。表1に
供試材合金の化学組成を示す。
[Example] Experiments were conducted using several test alloys as alloys used for the valve seat material of the valve body and the valve seat material of the valve body. Table 1 shows the chemical composition of the sample alloy.

【0016】[0016]

【表1】[Table 1]

【0017】同表の■〜■の供試材については、高周波
真空溶解炉を用いて溶解後ガスアトマイズ法により供試
材合金の粉末を製造した。粉末の粒径は+70〜+21
0メッシュのものである。その粉末を用いてプラズマ粉
体肉盛溶接法でS25C(炭素鋼の一種)板材の上に2
層肉盛溶接を行ったものから摩耗試験片を採取し、それ
らのうち2つを組合せて摺動摩耗試験を行なった。摩耗
試験条件としては、面圧を2kg/mm2 および5.
 5kg/mm2 の2通りとし、摺動速度300mm
/minにて、摺動回数100回を室温中、300℃飽
和水中、及び300℃飽和蒸気中で実施し、試験終了後
の摺動面の荒れ状態を表面粗さで表す調査をした。表2
に表面粗さの測定結果を示す。
For the test materials ① to ② in the same table, powders of the test material alloys were produced by a gas atomization method after melting using a high frequency vacuum melting furnace. Powder particle size is +70~+21
0 mesh. Using the powder, we applied the plasma powder build-up welding method to two sheets of S25C (a type of carbon steel) plate material.
Abrasion test pieces were taken from those subjected to layer overlay welding, and two of them were combined to perform a sliding wear test. The wear test conditions were a surface pressure of 2 kg/mm2 and 5.
Two types of 5kg/mm2, sliding speed 300mm
/min, 100 times of sliding was carried out at room temperature, in 300°C saturated water, and in 300°C saturated steam, and the roughness of the sliding surface after the test was investigated, expressed as surface roughness. Table 2
Figure 2 shows the surface roughness measurement results.

【0018】[0018]

【表2】[Table 2]

【0019】室温水中、300℃飽和水中、および30
0℃飽和蒸気中で表面粗さ1. 0μRa以下のものは
、■−■の組合せであることが確認された。1. 0μ
Raの表面粗さは、弁座材として使用した場合、従来の
コバルト基合金の弁座材と同様のメインテナンスにて対
応可能な範囲のものである。
[0019] Room temperature water, 300°C saturated water, and 30°C
Surface roughness in saturated steam at 0°C: 1. It was confirmed that those with 0 μRa or less were a combination of ■-■. 1. 0μ
The surface roughness of Ra is within a range that can be maintained with the same maintenance as conventional cobalt-based alloy valve seat materials when used as a valve seat material.

【0020】次に、上記摩耗試験で結果の良好であった
合金■、■によって試験片を製作し、エロージョンおよ
び熱衝撃試験を実施した。エロージョン試験方法として
は、差圧240kg/cm2 の室温水を流量10L/
min(流速217m/s)で40時間、試験片の表面
に擦過させ、そのときのエロージョンによる試験片の重
量減と最大侵食深さを求めた。また、熱衝撃試験方法と
しては、外径550mm、厚さ100mmの鋼板の表面
に外径550mm、内径450mm、厚さ3. 5mm
に合金をプラズマ粉体肉盛してなる試験体を電気炉で3
00℃に加熱した状態から室温水中に投入し、急冷する
方法をとった。結果を表3に示す。
Next, test pieces were prepared using alloys (1) and (2) which had good results in the above wear test, and erosion and thermal shock tests were conducted. The erosion test method is to use room temperature water with a differential pressure of 240 kg/cm2 at a flow rate of 10 L/cm2.
The surface of the test piece was rubbed at a flow rate of 217 m/s for 40 hours, and the weight loss and maximum erosion depth of the test piece due to erosion at that time were determined. In addition, as a thermal shock test method, a steel plate with an outer diameter of 550 mm and an inner diameter of 450 mm and a thickness of 3. 5mm
A test specimen made by plasma powder overlaying of an alloy was heated in an electric furnace.
A method was used in which the sample was heated to 00°C and then poured into room temperature water to rapidly cool it. The results are shown in Table 3.

【0021】[0021]

【表3】[Table 3]

【0022】表3に示すように、合金■,■のエロージ
ョン量は実機の玉型弁の使用条件下で実用上十分な耐エ
ロージョン性があると判断できる。また、熱衝撃試験で
も合金■,■は8回の熱衝撃繰返しで異常がなかった。
As shown in Table 3, the erosion amounts of alloys (1) and (2) can be judged to have sufficient erosion resistance for practical use under the conditions of use of actual globe valves. Further, in the thermal shock test, alloys (1) and (2) showed no abnormality after 8 thermal shock cycles.

【0023】更に上記■,■の合金の一方を弁箱弁座、
他方を弁体弁座に用いて、図1に示す呼び径100mm
,150mm,250mmの仕切弁を製作し、開閉作動
試験及び気密性の試験を実施した。その結果を表4に示
す。
Furthermore, one of the alloys (1) and (2) above was used as a valve box valve seat,
The other side is used as the valve body valve seat, and the nominal diameter is 100 mm as shown in Figure 1.
, 150mm, and 250mm gate valves were manufactured, and an opening/closing operation test and an airtightness test were conducted. The results are shown in Table 4.

【0024】[0024]

【表4】[Table 4]

【0025】合金■,■を用いた材料の実弁面圧を模擬
した摺動試験によっても、摺動性が良好であることがわ
かった。
A sliding test simulating the actual valve surface pressure using alloys (1) and (2) revealed that the sliding properties were good.

【0026】[0026]

【発明の効果】本発明による軽水原子炉用弁は、軽水原
子炉の直接原子炉に流入する配管に設置して使用する 
 ことにより、周辺機器の放射線量率を従来の約  1
/2以下におさえる事ができ(Coが炉水中に入らない
ことに基づく)、定期検査時の被曝を低減し作業時間を
大巾に確保でき、より安全な原子力プラントの実現に寄
与することが可能になる。
[Effects of the Invention] The light water reactor valve according to the present invention is installed and used in a pipe that directly flows into the reactor of a light water reactor.
By doing so, the radiation dose rate of peripheral equipment can be reduced to approximately 1
/2 or less (based on the fact that Co does not enter the reactor water), reducing radiation exposure during periodic inspections and securing a large amount of work time, contributing to the realization of safer nuclear power plants. It becomes possible.

【図面の簡単な説明】[Brief explanation of the drawing]

【図1】本発明の1実施例となる4インチ用仕切弁の断
面図である。
FIG. 1 is a sectional view of a 4-inch gate valve according to an embodiment of the present invention.

【符号の説明】[Explanation of symbols]

1:ハンドル        2:ボンネット3:弁棒
            4:弁箱5:弁体弁座   
     6:弁体7:弁箱弁座
1: Handle 2: Bonnet 3: Valve stem 4: Valve box 5: Valve body valve seat
6: Valve body 7: Valve box valve seat

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】  弁箱弁座部の表面肉盛材と弁体弁座部
の表面肉盛材として、夫々、Ni−Cr−Si−Fe−
W系のNi基合金であって互に化学組成および硬度の異
なる材料を用いたことを特徴とする耐摩耗性および耐エ
ロージョン性のコバルトフリー肉盛弁座材を有する軽水
原子炉用弁。
Claim 1: Ni-Cr-Si-Fe-
A light water reactor valve having a wear-resistant and erosion-resistant cobalt-free built-up valve seat material, which is made of a W-based Ni-based alloy having different chemical compositions and hardnesses.
【請求項2】  弁箱弁座部および弁体弁座部のうち1
方の表面肉盛材をなすNi基合金はCr10〜15%,
Si3〜7%,Fe10%以下,W2〜4%及び残部N
iの化学組成からなり且つロックウェル硬度HRCが4
0〜55であり、他方の表面肉盛材をなすNi基合金は
Cr15〜20%,Si5〜10%,Fe15%以下、
W1〜3%,Sn 0. 5〜1. 0%及び残部Ni
の化学組成からなり且つロックウェル硬度HRCが50
〜60であることを特徴とする請求項1記載の軽水原子
炉用弁。
[Claim 2] One of the valve body valve seat portion and the valve body valve seat portion.
The Ni-based alloy that forms the surface welding material on the other hand contains 10 to 15% Cr,
Si 3-7%, Fe 10% or less, W 2-4% and balance N
It has a chemical composition of i and has a Rockwell hardness HRC of 4.
0 to 55, and the Ni-based alloy forming the other surface welding material has 15 to 20% Cr, 5 to 10% Si, 15% or less Fe,
W1-3%, Sn 0. 5-1. 0% and balance Ni
It has a chemical composition of and has a Rockwell hardness HRC of 50.
2. The light water reactor valve according to claim 1, wherein the valve is 60 to 60.
【請求項3】  Cr10〜15%,Si3〜7%,F
e10%以下,W2〜4%及び残部Niとした組成のN
i基合金を弁体ガイド部に設けたことを特徴とする請求
項2記載の軽水原子炉用弁。
[Claim 3] Cr10-15%, Si3-7%, F
N with a composition of e 10% or less, W 2 to 4%, and the balance Ni
3. The light water reactor valve according to claim 2, wherein the i-based alloy is provided in the valve body guide portion.
【請求項4】  前記ニッケル基合金の表面にセラミッ
クスコーティングを施して弁座部の耐摩耗性を更に向上
させたことを特徴とする請求項1,2又は3記載の軽水
原子炉用弁。
4. The light water reactor valve according to claim 1, wherein a ceramic coating is applied to the surface of the nickel-based alloy to further improve the wear resistance of the valve seat.
JP3608891A 1991-03-01 1991-03-01 Light water reactor valve Expired - Lifetime JP2637296B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3608891A JP2637296B2 (en) 1991-03-01 1991-03-01 Light water reactor valve

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3608891A JP2637296B2 (en) 1991-03-01 1991-03-01 Light water reactor valve

Publications (2)

Publication Number Publication Date
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112975084A (en) * 2021-03-26 2021-06-18 苏州热工研究院有限公司 Welding method for cobalt-free nickel-based alloy plasma surfacing for strengthening sealing surface of nuclear power valve

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112975084A (en) * 2021-03-26 2021-06-18 苏州热工研究院有限公司 Welding method for cobalt-free nickel-based alloy plasma surfacing for strengthening sealing surface of nuclear power valve

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