JPS58187663A - Valve - Google Patents

Valve

Info

Publication number
JPS58187663A
JPS58187663A JP7030182A JP7030182A JPS58187663A JP S58187663 A JPS58187663 A JP S58187663A JP 7030182 A JP7030182 A JP 7030182A JP 7030182 A JP7030182 A JP 7030182A JP S58187663 A JPS58187663 A JP S58187663A
Authority
JP
Japan
Prior art keywords
valve
valve seat
alloy
valve body
resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7030182A
Other languages
Japanese (ja)
Inventor
Naoto Kanbara
蒲原 尚登
Tatsuyoshi Aisaka
逢坂 達吉
Mitsuo Kawai
光雄 河合
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Tokyo Shibaura Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp, Tokyo Shibaura Electric Co Ltd filed Critical Toshiba Corp
Priority to JP7030182A priority Critical patent/JPS58187663A/en
Publication of JPS58187663A publication Critical patent/JPS58187663A/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16KVALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
    • F16K25/00Details relating to contact between valve members and seats
    • F16K25/04Arrangements for preventing erosion, not otherwise provided for

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Sliding Valves (AREA)

Abstract

PURPOSE:To increase the abrasion resistance and erosion resistance and to eliminate the discharging of cobalt particles or the like, by using a Ni-Cr-Nb-Mo-B alloy for the valve seat of a valve box and the valve seat of a valve body. CONSTITUTION:An alloy consisting of 10-45wt% Cr, 3-15wt% Nb, 20wt% or less Mo, 0.01-2.0wt% B and the balance of Ni is used at least for the surfaces of the valve seat of a valve box and the valve seat of a valve body. In comparison with prior Ni-base abrasion resistant and erosion resistant alloys, a valve excellent in abrasion resistance and erosion resistance can be obtained. In addition in the present valve, as cobalt is not discharged, the valve is suitably used for opening or closing a passage of various plants in chemistry and nuclear power.

Description

【発明の詳細な説明】 〔発明の技術分野〕 本発明は耐摩耗性および耐エロージヨン性に優れた弁に
関する。
DETAILED DESCRIPTION OF THE INVENTION [Technical Field of the Invention] The present invention relates to a valve with excellent wear resistance and erosion resistance.

〔発明の技術的背景とその問題点〕[Technical background of the invention and its problems]

弁は普通、弁箱、弁体、弁座、弁棒、ボンネット、ハン
ドル等から成シ立ってお〉、流れの開閉および調節は、
弁箱内において弁体が作動し、弁箱内の流路に設けられ
た弁座に弁体の弁座が離接して流路を開閉することによ
シ行われる。従って。
A valve usually consists of a valve body, a valve body, a valve seat, a valve stem, a bonnet, a handle, etc., and the opening, closing, and regulation of flow are
This is accomplished by operating a valve body within the valve box, and opening and closing the flow path by bringing the valve seat of the valve body into and out of contact with a valve seat provided in a flow path within the valve box. Therefore.

肉汁塵の表面は機械的接触を繰り返し受け、さらに流体
の衝突によるエロージョンを受けることから。
The surface of meat juice dust is subjected to repeated mechanical contact and further undergoes erosion due to fluid collisions.

Co−Cr−N1−W系合金いわゆるステライトが肉盛
り溶接されて広く用いられてきたが、コバルト資源の枯
渇対策、化学プラントの反応制御、原子カプラントの安
全性向上等の観点から、コバルト粒子またはコバルトイ
オンの放出低減を目的として、N1を基体とした耐摩耗
・耐エロージヨン合金を弁箱の弁座および/または弁体
の弁座に使用した弁が開発されている。しかしながら、
 Ni基耐摩耗・耐エロージヨン合金は、従来のCo基
合金に比べて耐摩耗性および耐エロージヨン性が劣って
おり、弁としての性能が十分ではない問題点を有してい
る。
Co-Cr-N1-W alloy, so-called stellite, has been widely used by overlay welding, but from the viewpoint of measures against depletion of cobalt resources, reaction control in chemical plants, and improvement of safety in atomic couplants, cobalt particles or In order to reduce the release of cobalt ions, valves have been developed in which a wear-resistant and erosion-resistant alloy based on N1 is used for the valve seat of the valve body and/or the valve seat of the valve body. however,
Ni-based wear and erosion-resistant alloys have inferior wear resistance and erosion resistance compared to conventional Co-based alloys, and have the problem of insufficient performance as valves.

〔発明の目的〕[Purpose of the invention]

本発明は、上記した問題点全解消する九めになされたも
ので、弁箱の弁座および/lたは弁体の弁座にNi −
Cr −Nb −Mo −B系合金を使用することによ
り、各種プラントにおいてコバルト粒子tたはコバルト
イオンの放出が実質的に皆無であリ、かつ、耐摩耗性お
よび耐エロージヨン性に優れた弁t−提供することを目
的とするものである。
The present invention has been made to solve all the above-mentioned problems, and the valve seat of the valve body and/or the valve seat of the valve body are coated with Ni-
By using the Cr-Nb-Mo-B alloy, there is virtually no release of cobalt particles or cobalt ions in various plants, and the valve has excellent wear resistance and erosion resistance. - It is intended to provide.

〔発明の概要〕[Summary of the invention]

本発明の弁は、弁箱および/iたは弁体の弁座の少なく
とも表面が、クロム(Cr ) 10重45重量−,ニ
オブ(Nb ) 3〜15重量−、モリブデン(Mo 
) 20重1に一以下、ホウ素(B)0.01〜2.0
重を饅および残部がニッケル(Nl)から成る合金であ
ることt−%徴とするものである。
In the valve of the present invention, at least the surface of the valve body and the valve seat of the valve body is made of chromium (Cr) 10 to 45 weight, niobium (Nb) 3 to 15 weight, molybdenum (Mo
) Boron (B) 0.01 to 2.0, less than 1 in 20 parts
The weight is t-% indicating that the alloy is made of rice and the balance is nickel (Nl).

以下において2本発明をさらに詳しく説明する。The two inventions will be explained in more detail below.

本発明の弁は、弁箱内に設けられた弁座に弁体の弁座が
m接して流路を開閉するものであればいかなるものでも
よく9例えば、玉形弁、仕切弁。
The valve of the present invention may be of any type as long as the valve seat of the valve body contacts the valve seat provided in the valve box to open and close a flow path.9For example, a globe valve or a gate valve may be used.

スウィング式逆止め弁等のものが適合する。かかる弁に
、上記組成から成る合金を弁箱の弁座および/または弁
体の弁座に使用する。
Swing type check valves, etc. are suitable. In such a valve, an alloy having the above composition is used for the valve seat of the valve body and/or the valve seat of the valve body.

本発明の弁に使用される弁座の合金組成の限定理由につ
いて説明する。まずCrは耐食性および合金の素地全強
化する九めに必畳な成分で、その組成比が10−未満で
は効果が不十分であり、また79r費の耐摩耗性が得ら
れない。
The reasons for limiting the alloy composition of the valve seat used in the valve of the present invention will be explained. First of all, Cr is the ninth essential component that completely strengthens the corrosion resistance and the alloy matrix, and if its composition ratio is less than 10-1, the effect is insufficient and the wear resistance of 79R cannot be obtained.

NbはNiと反応して合金の素地の強化と耐摩耗性およ
び耐エロージヨン性の向上に寄与する成分であるが、そ
の量が3チ未満では効果が不十分でまた15チを超える
と靭性の低下がみられ材料の機械的強度が損なわれるか
らである。M・は耐食性の向上と合金素地音強化し耐摩
耗性および耐エロージヨン性の向上に寄与するものであ
るが、20儂を超えると合金の靭性の低下がみられるか
らである。Bij溶融溶融湯流れ性の同上と合金素地全
強化し耐摩耗性および耐エロージヨン性の向上に寄与す
るものであるが、その電が0.011未満では効果が不
十分で、また2%を超えると合金の靭性の低下がみられ
るからである。
Nb is a component that reacts with Ni and contributes to strengthening the alloy base and improving wear resistance and erosion resistance. However, if the amount is less than 3 inches, the effect is insufficient, and if it exceeds 15 inches, the toughness deteriorates. This is because the mechanical strength of the material is impaired. M. improves corrosion resistance and strengthens the alloy's base sound, contributing to improvements in wear resistance and erosion resistance, but if it exceeds 20 degrees, the toughness of the alloy decreases. It contributes to improving wear resistance and erosion resistance by completely strengthening the alloy base and improving the flowability of Bij molten metal, but if the electric current is less than 0.011, the effect is insufficient, and if it exceeds 2%. This is because the toughness of the alloy decreases.

しかして本発明に係る弁の弁座用合金は、 Nbの一部
tタンタル(T& )で置換してもよい。またNlの一
部を鉄(F・)で置換すること、 Meの一部をタング
ステン(W)に置換することもできる。
Thus, in the valve seat alloy of the valve according to the present invention, a portion of Nb may be replaced with tantalum (T&). Further, part of Nl can be replaced with iron (F.), and part of Me can be replaced with tungsten (W).

さらに溶解時に添加する脱酸、脱窒剤としてのマンガン
(Mn )やけい素(Sl)等【含んでいても差支えな
い。
In addition, manganese (Mn) and silicon (Sl) as deoxidizing and denitrifying agents added during melting may be included.

〔発明の実施例〕[Embodiments of the invention]

まず1表−1に示す組成(重量比)の素材?t%周波真
空誘導溶解炉を用いて溶解鋳造し9得られた3植類の鋳
造品から試験片を切り出して特性評価試験全行なった。
First, is the material with the composition (weight ratio) shown in Table 1? Test pieces were cut out from the three types of castings obtained by melting and casting using a t% frequency vacuum induction melting furnace, and all characteristic evaluation tests were conducted.

その結果を表−1に示す。The results are shown in Table-1.

同時に比較例として、N1−Cr−B糸自溶合金(試料
4 L Nl −Cr −Mo−8重糸合金(試料5)
谷の5種類についても、同様に試験を行ない、その結果
を表−1に併せて示した。
At the same time, as comparative examples, N1-Cr-B thread self-fluxing alloy (sample 4), Nl-Cr-Mo-8 heavy thread alloy (sample 5)
Similar tests were conducted for the five types of valleys, and the results are also shown in Table 1.

特性評価試験としては、超音波振動方式によるキャビテ
ーションエロージョン試験およびアムスラー型による摩
耗試験を行なった。キャビテーションエロージョン試験
は学振法に準じて3時間行ない、また、アムスラー型に
よる摩耗試験は試験荷重30kp、摺動摩耗距離100
0m、潤滑剤として水(1匡/秒)を使用して行なった
。なお1表−1における損耗tは、試験による試験片の
重量減少(〜)を試験時間(分)と密度<tpyes’
)iで除し比値にI X 10’を乗したもので時間当
シの体積減少量を示すものであり、また摩耗量は、試験
による試験片の重量減少! (”l/ ) t−示すも
のである。
As a characteristic evaluation test, a cavitation erosion test using an ultrasonic vibration method and a wear test using an Amsler type were performed. The cavitation erosion test was conducted for 3 hours according to the Jakushin Law, and the wear test using the Amsler type was carried out at a test load of 30 kp and a sliding wear distance of 100.
0 m, using water (1 square/second) as a lubricant. In addition, the wear t in Table 1 is defined as the weight loss (~) of the test piece due to the test, the test time (minutes) and the density <tpyes'
) The ratio value divided by i is multiplied by I x 10', which indicates the amount of volume reduction over time, and the amount of wear is the weight loss of the test piece due to the test! ("l/) t-indicates.

表−−1 これからは9本発明の弁に使用されるNi −Cr−N
b −No −B系合金が、比較例のものに比べて。
Table--1 From now on, 9 Ni-Cr-N used in the valve of the present invention
b -No -B alloy compared to that of the comparative example.

摩耗量が看しく少なく、かつ損耗量も少ないことがわか
る。
It can be seen that the amount of wear and tear is noticeably small.

上記実施例の試料10合金を、弁箱お↓び弁体の各弁座
に肉盛り#接して、WJ1図に示す呼び径lOO■の仕
切弁t−製作し、開閉動作後の弁の気密性全試験し友。
The sample 10 alloy of the above example was put in contact with each valve seat of the valve box and valve body to make a gate valve with a nominal diameter lOO■ as shown in Figure WJ1, and the valve was airtight after opening and closing operations. A friend who has undergone a complete sexual examination.

図においてlは弁箱、2は弁箱の9Pm、3は弁体、4
は弁体の弁座、5は弁体。
In the figure, l is the valve box, 2 is 9Pm of the valve box, 3 is the valve body, and 4
is the valve seat of the valve body, and 5 is the valve body.

6はボンネット、7はハンドルを示す。また比較例とし
て、上記比較例の試料40合金を用いて同一構造の仕切
弁を製作し、同一条件下にて試験し次。その結果ir表
−2に併せて示す。
6 indicates a bonnet, and 7 indicates a handle. As a comparative example, a gate valve of the same structure was manufactured using the sample 40 alloy of the comparative example, and tested under the same conditions. The results are also shown in IR Table-2.

なお、開閉動作は9面圧2v12の負荷状態で600回
行ない、気密性試験は、室温水および300℃高圧水を
通水し、出口側の漏れを測定した。
The opening/closing operation was performed 600 times under a load of 9 surface pressures of 2v12, and the airtightness test was performed by passing room temperature water and high pressure water at 300° C. and measuring leakage on the outlet side.

表−2 弁は、比較例のものに比べて気密性が高く、耐摩耗性に
優れていることが確認された。
Table 2 It was confirmed that the valves had higher airtightness and superior wear resistance than those of the comparative example.

また、上記実施例の試料3の合金を、弁箱および弁体の
各弁座に肉盛り溶接して、第2図に示す呼び径25−の
玉形fft−製作し、高圧水に対する耐エロージヨン性
を試験した。図において11は弁箱、12Fi弁箱の弁
座、13は弁体、14は弁体ノ弁座、  15は弁棒、
16はボンネット、17はハンドルを示す、オ良比較例
として、上記比較例の試料4の合金を用いて同一構造の
玉形弁を製作し、同一条件下にて試験した。その結果を
表−3に併せて示す。
In addition, the alloy of Sample 3 of the above example was overlay welded to each valve seat of the valve body and valve body to fabricate a sphere with a nominal diameter of 25 mm as shown in Fig. 2, and to provide erosion resistance against high pressure water. tested for sex. In the figure, 11 is the valve box, 12 is the valve seat of the Fi valve box, 13 is the valve body, 14 is the valve seat of the valve body, 15 is the valve stem,
Reference numeral 16 indicates a bonnet, and reference numeral 17 indicates a handle. As a good comparative example, a globe valve with the same structure was manufactured using the alloy of sample 4 of the comparative example, and was tested under the same conditions. The results are also shown in Table-3.

なお、試験は、あらかじめ弁体の弁座の2ケ所につけた
深さ2箇1幅2饋のV溝の幅を、差圧400 kg7c
m2.流速450 m/see、  50 ℃温水の1
00時間通水後に測定して行なった。
In addition, in the test, the width of the V-groove, which was made in advance at two places on the valve seat of the valve body, with two depths and two widths, was subjected to a differential pressure of 400 kg7c.
m2. Flow rate 450 m/see, 50 ℃ hot water 1
The measurement was carried out after passing water for 00 hours.

表−3 表−3から明らからように1本発明に係る玉形弁は、比
較例のものに比べて二に−ジョン損耗が少なく、耐エロ
ージヨン性に優れていることがわかる。
Table 3 As is clear from Table 3, it can be seen that the globe valve according to the present invention has significantly less wear and tear on the joists than the comparative example, and has excellent erosion resistance.

〔発明の効果〕〔Effect of the invention〕

以上の結果から明らかなように1本発1jliK係る弁
は、弁箱の弁座および/lたは弁体の弁座に使用するN
1−Cr−Nb −Mo−1系合金の耐摩耗性および耐
工p−ジョ/性が高いえめ、従来の姐基耐摩耗・耐エロ
ージヨン合金を使用し九弁に比べて、耐摩耗性および耐
エロージヨン性に優れた弁を得ることができる。また、
コバルト會放出しないことKよシ、化学および原子力等
の各種のプラントの流路の開閉に好適な弁である。
As is clear from the above results, the valve according to the one-shot 1jliK has a large number of N used for the valve seat of the valve body and/or the valve seat of the valve body.
Since the 1-Cr-Nb-Mo-1 alloy has high wear resistance and mechanical resistance, it has better wear resistance and erosion resistance compared to the conventional 9-valve using a wear-resistant and erosion-resistant alloy. A valve with excellent erosion resistance can be obtained. Also,
This valve does not release cobalt and is suitable for opening and closing flow paths in various chemical and nuclear plants.

【図面の簡単な説明】[Brief explanation of the drawing]

図面は本発明の実施例を示し、第1図は仕切弁の縦断面
図、第2図は玉形弁の縦断面図である。 1.11・・・弁箱、2.12・・・弁箱の弁座、3゜
13・・・弁体、4.14・・・弁体の弁座、5,15
・・・弁棒、6,16・・・ボンネット、7.17・・
・ハンドル。
The drawings show embodiments of the present invention, with FIG. 1 being a longitudinal sectional view of a gate valve, and FIG. 2 being a longitudinal sectional view of a globe valve. 1.11...Valve box, 2.12...Valve seat of the valve box, 3゜13...Valve body, 4.14...Valve seat of the valve body, 5,15
...Valve stem, 6,16...Bonnet, 7.17...
·handle.

Claims (1)

【特許請求の範囲】[Claims] 弁箱および/lたは弁体の弁座の少なくとも表面が、ク
ロム(Cr ) 10〜45重量慢、ニオブ(Nb )
 3〜15重量−、モリブデン(M・)201量−以下
、ホウ素(B)0.01〜2.0重量IIシよび残部が
ニッケル(N1)からなる合金であることを特徴とする
弁。
At least the surface of the valve body and the valve seat of the valve body is made of chromium (Cr) 10-45%, niobium (Nb).
3 to 15% by weight, molybdenum (M.) 201% by weight or less, boron (B) 0.01 to 2.0% by weight, and the balance consisting of nickel (N1).
JP7030182A 1982-04-28 1982-04-28 Valve Pending JPS58187663A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7030182A JPS58187663A (en) 1982-04-28 1982-04-28 Valve

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7030182A JPS58187663A (en) 1982-04-28 1982-04-28 Valve

Publications (1)

Publication Number Publication Date
JPS58187663A true JPS58187663A (en) 1983-11-01

Family

ID=13427495

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7030182A Pending JPS58187663A (en) 1982-04-28 1982-04-28 Valve

Country Status (1)

Country Link
JP (1) JPS58187663A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4754950A (en) * 1984-10-30 1988-07-05 Kabushiki Kaisha Toshiba Valve
US4776566A (en) * 1987-07-10 1988-10-11 Henry Vogt Machine Co. Raised hardface overlay valve seat
US5633094A (en) * 1994-10-28 1997-05-27 Hitachi, Ltd. Valve having facing layers of co-free Ni-base Alloy

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4754950A (en) * 1984-10-30 1988-07-05 Kabushiki Kaisha Toshiba Valve
US4776566A (en) * 1987-07-10 1988-10-11 Henry Vogt Machine Co. Raised hardface overlay valve seat
US5633094A (en) * 1994-10-28 1997-05-27 Hitachi, Ltd. Valve having facing layers of co-free Ni-base Alloy

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