JPH0148894B2 - - Google Patents
Info
- Publication number
- JPH0148894B2 JPH0148894B2 JP56146995A JP14699581A JPH0148894B2 JP H0148894 B2 JPH0148894 B2 JP H0148894B2 JP 56146995 A JP56146995 A JP 56146995A JP 14699581 A JP14699581 A JP 14699581A JP H0148894 B2 JPH0148894 B2 JP H0148894B2
- Authority
- JP
- Japan
- Prior art keywords
- caprolactam
- water
- evaporator
- concentrated
- recovered
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 175
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 54
- 125000004122 cyclic group Chemical group 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 21
- 238000005406 washing Methods 0.000 claims description 17
- 238000004821 distillation Methods 0.000 claims description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 15
- 239000004677 Nylon Substances 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 8
- 229920001778 nylon Polymers 0.000 claims description 8
- 238000001704 evaporation Methods 0.000 claims description 7
- 235000011007 phosphoric acid Nutrition 0.000 claims description 7
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 239000010408 film Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 6
- 229920002292 Nylon 6 Polymers 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 230000008020 evaporation Effects 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- -1 cyclic lactam Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
- C07D201/02—Preparation of lactams
- C07D201/12—Preparation of lactams by depolymerising polyamides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
- C07D201/16—Separation or purification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/187,864 US4311642A (en) | 1980-09-17 | 1980-09-17 | Recovery of caprolactam from nylon 6 oligomers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5781458A JPS5781458A (en) | 1982-05-21 |
| JPH0148894B2 true JPH0148894B2 (enExample) | 1989-10-20 |
Family
ID=22690811
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56146995A Granted JPS5781458A (en) | 1980-09-17 | 1981-09-17 | Recovery of caprolactam from nylon 6 oligomer |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4311642A (enExample) |
| EP (1) | EP0048340B1 (enExample) |
| JP (1) | JPS5781458A (enExample) |
| KR (1) | KR860000829B1 (enExample) |
| CA (1) | CA1157020A (enExample) |
| DE (1) | DE3173977D1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4767503A (en) * | 1983-08-29 | 1988-08-30 | Allied Corporation | Removal of light impurities from caprolactam by distillation with water |
| US5169870A (en) * | 1991-06-21 | 1992-12-08 | Basf Corporation | Reclaiming ε-caprolactam from nylon 6 carpet |
| DE4211609A1 (de) * | 1991-08-30 | 1993-03-04 | Bayer Ag | Gewinnung von caprolactam durch thermische spaltung von polyamid 6 |
| DE4216848A1 (de) * | 1992-05-21 | 1993-11-25 | Basf Ag | Verfahren zur Rückgewinnung von Caprolactam aus Polycaprolactam |
| EP0608454B1 (de) * | 1993-01-28 | 1997-08-13 | POLYMER ENGINEERING GmbH | Verfahren und Vorrichtung zur Herstellung von Polyamid 6 aus Polyamid-Abfällen |
| US5457197A (en) * | 1994-04-08 | 1995-10-10 | Alliedsignal Inc. | Monomer recovery from multi-component materials |
| US5495015A (en) * | 1994-12-12 | 1996-02-27 | Basf Aktiengesellschaft | Process for producing caprolactam through hydrolytic cleavage of molten polycaprolactam |
| US5656757A (en) * | 1995-08-10 | 1997-08-12 | Alliedsignal Inc. | Monomer recovery from multi-component materials |
| DE19648747A1 (de) * | 1996-11-25 | 1998-05-28 | Basf Ag | Verfahren zur Rückgewinnung von Caprolactam und seinen Oligomeren aus wässrigen Polycaprolactam-Extrakten |
| NL1005942C2 (nl) * | 1997-05-01 | 1998-11-03 | Dsm Nv | Depolymeriseren van polyamiden. |
| US5990306A (en) * | 1997-09-03 | 1999-11-23 | Alliedsignal Inc. | Process for the purification of caprolactam obtained from the depolymerization of polyamide-containing carpet |
| WO2000050394A2 (en) * | 1999-02-26 | 2000-08-31 | Dsm N.V. | A process for recovering caprolactam and steam |
| DE10251798A1 (de) * | 2002-11-07 | 2004-05-19 | Bayer Ag | Verfahren zur Herstellung von Polyamid 6 mit geringem Dimergehalt |
| US9193865B2 (en) | 2012-09-27 | 2015-11-24 | E I Du Pont De Nemours And Company | Polyamides having improved anti-delamination |
| US9023903B2 (en) | 2012-09-27 | 2015-05-05 | E I Du Pont De Nemours And Company | Reinforced polyamides having improved anti-delamination |
| US9109114B2 (en) | 2012-09-27 | 2015-08-18 | E I Du Pont De Nemours And Company | Polyamides having improved anti-delamination |
| CN107051345A (zh) * | 2017-01-25 | 2017-08-18 | 江苏永通新材料科技有限公司 | 一种用于生产聚酰胺切片的低聚物分离器 |
| JP6902157B2 (ja) * | 2017-08-01 | 2021-07-14 | アドバンシックス・レジンズ・アンド・ケミカルズ・リミテッド・ライアビリティ・カンパニーＡｄｖａｎｓｉｘ Ｒｅｓｉｎｓ ＆ Ｃｈｅｍｉｃａｌｓ Ｌｌｃ | ポリアミドの環状オリゴマーを重合するための方法 |
| AU2023246631A1 (en) * | 2022-04-01 | 2024-10-10 | Basf Se | Separation of impurities in a process for hydrolytically depolymerizing a polyamide |
| WO2025238077A1 (en) * | 2024-05-15 | 2025-11-20 | Basf Se | Process for separating high boilers from polyamide 6 depolymerization mixtures |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD59094A (enExample) * | ||||
| US3245964A (en) * | 1962-11-13 | 1966-04-12 | Allied Chem | Continuous extraction of poly-e-caproamide |
| US3182055A (en) * | 1963-02-18 | 1965-05-04 | Allied Chem | Regeneration of e-caprolactam from polyamides |
| US3294756A (en) * | 1963-05-01 | 1966-12-27 | Allied Chem | Continuous polymerization of epsilon-caprolactam |
| US3266165A (en) * | 1964-10-01 | 1966-08-16 | Allied Chem | Process and apparatus for segregative drying of nylon-6 |
| NL135959C (enExample) * | 1964-12-23 | |||
| US3373145A (en) * | 1965-04-29 | 1968-03-12 | Allied Chem | Washing of polymer particulates by regular periodic ebb and flow of aqueous solvent |
| US3600381A (en) * | 1968-05-09 | 1971-08-17 | Teijin Ltd | Caprolactam purification process |
| AU434985B2 (en) * | 1969-12-15 | 1973-04-18 | Tevin Limited | Process for obtaining purified caprolactam bythe purification of oligomer-containing impure epsilon caprolactam |
| DE2135085C3 (de) * | 1971-07-14 | 1981-12-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Wiedergewinnung von Caprolactam aus einem Gemisch, das Caprolactam und dessen Oligomere enthält |
| US4107160A (en) * | 1977-08-24 | 1978-08-15 | Zimmer Aktiengesellschaft | Continuous process for the recovery of caprolactam |
-
1980
- 1980-09-17 US US06/187,864 patent/US4311642A/en not_active Expired - Lifetime
-
1981
- 1981-08-17 DE DE8181106355T patent/DE3173977D1/de not_active Expired
- 1981-08-17 EP EP81106355A patent/EP0048340B1/en not_active Expired
- 1981-09-14 CA CA000385778A patent/CA1157020A/en not_active Expired
- 1981-09-15 KR KR1019810003431A patent/KR860000829B1/ko not_active Expired
- 1981-09-17 JP JP56146995A patent/JPS5781458A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| EP0048340B1 (en) | 1986-03-05 |
| JPS5781458A (en) | 1982-05-21 |
| EP0048340A1 (en) | 1982-03-31 |
| US4311642A (en) | 1982-01-19 |
| DE3173977D1 (en) | 1986-04-10 |
| KR860000829B1 (ko) | 1986-07-02 |
| KR830007546A (ko) | 1983-10-21 |
| CA1157020A (en) | 1983-11-15 |
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