JPH0131464B2 - - Google Patents
Info
- Publication number
- JPH0131464B2 JPH0131464B2 JP55178641A JP17864180A JPH0131464B2 JP H0131464 B2 JPH0131464 B2 JP H0131464B2 JP 55178641 A JP55178641 A JP 55178641A JP 17864180 A JP17864180 A JP 17864180A JP H0131464 B2 JPH0131464 B2 JP H0131464B2
- Authority
- JP
- Japan
- Prior art keywords
- composition
- lubricant
- weight
- sizing composition
- silane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 claims description 107
- 238000004513 sizing Methods 0.000 claims description 87
- 239000003365 glass fiber Substances 0.000 claims description 64
- 239000000314 lubricant Substances 0.000 claims description 35
- 229920000642 polymer Polymers 0.000 claims description 33
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 25
- 229910000077 silane Inorganic materials 0.000 claims description 25
- 150000004756 silanes Chemical class 0.000 claims description 22
- 229920002635 polyurethane Polymers 0.000 claims description 20
- 239000004814 polyurethane Substances 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 16
- 125000000524 functional group Chemical group 0.000 claims description 16
- 229920005862 polyol Polymers 0.000 claims description 10
- 150000003077 polyols Chemical class 0.000 claims description 9
- -1 polytetrafluoroethylene fluorocarbon Polymers 0.000 claims description 9
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 9
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 7
- 229920001225 polyester resin Polymers 0.000 claims description 6
- 239000004645 polyester resin Substances 0.000 claims description 6
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920001281 polyalkylene Polymers 0.000 claims description 4
- 229920001169 thermoplastic Polymers 0.000 claims description 4
- 239000004416 thermosoftening plastic Substances 0.000 claims description 4
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 3
- 229920002873 Polyethylenimine Polymers 0.000 claims description 2
- 239000004815 dispersion polymer Substances 0.000 claims description 2
- 229920006267 polyester film Polymers 0.000 claims description 2
- 239000007787 solid Substances 0.000 description 16
- 239000000463 material Substances 0.000 description 10
- 239000004816 latex Substances 0.000 description 8
- 229920000126 latex Polymers 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000007822 coupling agent Substances 0.000 description 7
- 238000002845 discoloration Methods 0.000 description 7
- 230000005855 radiation Effects 0.000 description 7
- 239000004952 Polyamide Substances 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 238000007539 photo-oxidation reaction Methods 0.000 description 5
- 229920002647 polyamide Polymers 0.000 description 5
- 229920003009 polyurethane dispersion Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000012963 UV stabilizer Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229910001651 emery Inorganic materials 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 230000005484 gravity Effects 0.000 description 4
- 239000012948 isocyanate Substances 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000011152 fibreglass Substances 0.000 description 3
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 229920005749 polyurethane resin Polymers 0.000 description 3
- 230000003014 reinforcing effect Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 150000001565 benzotriazoles Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 150000002148 esters Chemical group 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000156 glass melt Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 229920006264 polyurethane film Polymers 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- PQJZHMCWDKOPQG-UHFFFAOYSA-N 2-anilino-2-oxoacetic acid Chemical class OC(=O)C(=O)NC1=CC=CC=C1 PQJZHMCWDKOPQG-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- 229920003270 Cymel® Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- 229920002176 Pluracol® Polymers 0.000 description 1
- 229920002166 Pluracol® V 10 Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229920001911 maleic anhydride grafted polypropylene Polymers 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000002184 metal Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920000307 polymer substrate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 238000003878 thermal aging Methods 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Landscapes
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP55178641A JPS57100945A (en) | 1980-12-16 | 1980-12-16 | Sizing composition, glass fiber sized therewith and reinforcement polymer reinforced with same fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP55178641A JPS57100945A (en) | 1980-12-16 | 1980-12-16 | Sizing composition, glass fiber sized therewith and reinforcement polymer reinforced with same fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57100945A JPS57100945A (en) | 1982-06-23 |
| JPH0131464B2 true JPH0131464B2 (pt) | 1989-06-26 |
Family
ID=16052005
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP55178641A Granted JPS57100945A (en) | 1980-12-16 | 1980-12-16 | Sizing composition, glass fiber sized therewith and reinforcement polymer reinforced with same fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57100945A (pt) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1264997A (en) * | 1984-07-30 | 1990-01-30 | Mikhail Milad Girgis | Flexible, chemically treated bundles of fibers and process |
| CA1290994C (en) * | 1984-07-30 | 1991-10-22 | Mikhail Milad Girgis | Flexible, chemically treated bundles of fibers, woven and nonwoven fabrics and coated fabrics thereof |
| JPH0431344A (ja) * | 1990-05-25 | 1992-02-03 | Asahi Fiber Glass Co Ltd | 熱可塑性樹脂補強用ガラス繊維束並びに繊維補強樹脂体の製造法 |
| JPH06287029A (ja) * | 1993-03-31 | 1994-10-11 | Ikeda Bussan Co Ltd | ガラス繊維、ガラス繊維シート、および内装材 |
| DE102004060799A1 (de) * | 2004-12-17 | 2006-06-29 | Bayer Materialscience Ag | Thermoplastische Polyurethane und deren Verwendung |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5130635A (ja) * | 1974-09-06 | 1976-03-16 | Matsushita Electric Ind Co Ltd | Sekyunenshokinotenkasochi |
| JPS526393A (en) * | 1975-07-05 | 1977-01-18 | Mihara Kankyo Gijutsu Kk | Regenerator of active carbon |
| US4046794A (en) * | 1972-04-14 | 1977-09-06 | Union Carbide Corporation | Urea silicon product and uses thereof |
-
1980
- 1980-12-16 JP JP55178641A patent/JPS57100945A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4046794A (en) * | 1972-04-14 | 1977-09-06 | Union Carbide Corporation | Urea silicon product and uses thereof |
| JPS5130635A (ja) * | 1974-09-06 | 1976-03-16 | Matsushita Electric Ind Co Ltd | Sekyunenshokinotenkasochi |
| JPS526393A (en) * | 1975-07-05 | 1977-01-18 | Mihara Kankyo Gijutsu Kk | Regenerator of active carbon |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57100945A (en) | 1982-06-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4271229A (en) | Sizing composition to yield sized glass fibers with improved UV stability | |
| CN108726898B (zh) | 一种增强尼龙树脂的玻璃纤维用浸润剂及其制备方法 | |
| CN110294600B (zh) | 一种玻璃纤维浸润剂及其制备方法和应用 | |
| JP2008503424A (ja) | フィラメントワインディング用エポキシサイズ組成物 | |
| CN110950548B (zh) | 一种环氧树脂用高浸透性玻璃纤维浸润剂及其制备方法和应用 | |
| US4382991A (en) | Sizing composition and sized strand useful as reinforcement | |
| JP2009084116A (ja) | ガラス繊維用集束剤、ガラス繊維、ガラス繊維の製造方法及びガラス繊維強化熱可塑性樹脂材料 | |
| EP0559865B1 (en) | Glass size compositions and glass fibers coated therewith | |
| KR101863488B1 (ko) | 유리섬유용 집속제 조성물 | |
| US3882068A (en) | Sizing composition for glass fibers of polypropylene emulsion and silane coupling agent | |
| EP0027942B1 (de) | Schlichtemittel für Glasfasern, damit beschlichtete Glasfasern und Verfahren zu ihrer Herstellung sowie Glasfaserverbundwerkstoffe | |
| US20140178685A1 (en) | Sizing Composition for Charges Used in Thermoplastic Polymeric Material Reinforcement, Reinforced Polymeric Materials and Method of Manufacture | |
| KR0184587B1 (ko) | 유리 호제 조성물 및 이것으로 피복된 유리섬유 | |
| JPH0131464B2 (pt) | ||
| JPH01298044A (ja) | 熱硬化性樹脂マトリックスの強化のための化学的に処理されたガラス繊維 | |
| US4301052A (en) | Sizing composition and sized strand useful as reinforcement for reinforced molded composites having improved physical properties | |
| JP2000335942A (ja) | ポリアセタール樹脂補強用のガラス繊維集束剤およびそれを用いたガラス繊維束 | |
| US4381640A (en) | Process for the production of reinforced rubber articles | |
| US3790437A (en) | Polyvinyl alcohol fiber reinforced polyurethane compositions and products therefrom | |
| JPH08319373A (ja) | 有機物の補強用オイリングしたガラス繊維 | |
| US5120780A (en) | Glass fiber size composition and synthetic organosilane lubricants used therein | |
| CA1164132A (en) | Sizing composition to yield sized glass fibers with improved uv stability | |
| JP2021063307A (ja) | 繊維集束剤、繊維材料、成形材料、及び成形品 | |
| JP2000281391A (ja) | ガラス繊維集束剤、ガラス繊維およびそれを含有するポリプロピレン樹脂組成物 | |
| EP0244430B1 (en) | Polyester emulsion |