JPH0130832B2 - - Google Patents
Info
- Publication number
- JPH0130832B2 JPH0130832B2 JP4936686A JP4936686A JPH0130832B2 JP H0130832 B2 JPH0130832 B2 JP H0130832B2 JP 4936686 A JP4936686 A JP 4936686A JP 4936686 A JP4936686 A JP 4936686A JP H0130832 B2 JPH0130832 B2 JP H0130832B2
- Authority
- JP
- Japan
- Prior art keywords
- carbon disulfide
- dithiolane
- reaction
- thione
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 claims description 42
- 238000006243 chemical reaction Methods 0.000 claims description 11
- XCWPBWWTGHQKDR-UHFFFAOYSA-N 1,3-dithiolane-2-thione Chemical class S=C1SCCS1 XCWPBWWTGHQKDR-UHFFFAOYSA-N 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- VOVUARRWDCVURC-UHFFFAOYSA-N thiirane Chemical compound C1CS1 VOVUARRWDCVURC-UHFFFAOYSA-N 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 2
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 27
- 238000000262 chemical ionisation mass spectrometry Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- CXYRUNPLKGGUJF-OZVSTBQFSA-M pamine Chemical compound [Br-].C1([C@@H](CO)C(=O)OC2C[C@@H]3[N+]([C@H](C2)[C@@H]2[C@H]3O2)(C)C)=CC=CC=C1 CXYRUNPLKGGUJF-OZVSTBQFSA-M 0.000 description 3
- QMQSSUMAIXESIR-UHFFFAOYSA-N 4,4-dimethyl-1,3-dithiolane-2-thione Chemical compound CC1(C)CSC(=S)S1 QMQSSUMAIXESIR-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 229940125904 compound 1 Drugs 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- FHCPAXDKURNIOZ-UHFFFAOYSA-N tetrathiafulvalene Chemical compound S1C=CSC1=C1SC=CS1 FHCPAXDKURNIOZ-UHFFFAOYSA-N 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- KGUJXUWJUOETGS-UHFFFAOYSA-N 1-sulfanylidenedithiolane Chemical class S=S1CCCS1 KGUJXUWJUOETGS-UHFFFAOYSA-N 0.000 description 1
- XRWMHJJHPQTTLQ-UHFFFAOYSA-N 2-(chloromethyl)thiirane Chemical compound ClCC1CS1 XRWMHJJHPQTTLQ-UHFFFAOYSA-N 0.000 description 1
- MBNVSWHUJDDZRH-UHFFFAOYSA-N 2-methylthiirane Chemical compound CC1CS1 MBNVSWHUJDDZRH-UHFFFAOYSA-N 0.000 description 1
- OQOIYECUXDNABI-UHFFFAOYSA-N 2-phenylthiirane Chemical compound C1SC1C1=CC=CC=C1 OQOIYECUXDNABI-UHFFFAOYSA-N 0.000 description 1
- XJCWNDPNURTXMH-UHFFFAOYSA-N 4-(chloromethyl)-1,3-dithiolane-2-thione Chemical compound ClCC1CSC(=S)S1 XJCWNDPNURTXMH-UHFFFAOYSA-N 0.000 description 1
- OVMVMMNHNMZUAS-UHFFFAOYSA-N 4-methyl-1,3-dithiolane-2-thione Chemical compound CC1CSC(=S)S1 OVMVMMNHNMZUAS-UHFFFAOYSA-N 0.000 description 1
- UNAVLWYSWPISLX-UHFFFAOYSA-N 4-phenyl-1,3-dithiolane-2-thione Chemical compound S1C(=S)SCC1C1=CC=CC=C1 UNAVLWYSWPISLX-UHFFFAOYSA-N 0.000 description 1
- PQWJNIJNYRPOAA-UHFFFAOYSA-N 7-thiabicyclo[4.1.0]heptane Chemical compound C1CCCC2SC21 PQWJNIJNYRPOAA-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 150000004662 dithiols Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 description 1
- 229940116357 potassium thiocyanate Drugs 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000012970 tertiary amine catalyst Substances 0.000 description 1
- ZWZVWGITAAIFPS-UHFFFAOYSA-N thiophosgene Chemical compound ClC(Cl)=S ZWZVWGITAAIFPS-UHFFFAOYSA-N 0.000 description 1
- HIZCIEIDIFGZSS-UHFFFAOYSA-L trithiocarbonate Chemical compound [S-]C([S-])=S HIZCIEIDIFGZSS-UHFFFAOYSA-L 0.000 description 1
- 239000012989 trithiocarbonate Substances 0.000 description 1
Landscapes
- Heterocyclic Compounds Containing Sulfur Atoms (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4936686A JPS62207268A (ja) | 1986-03-06 | 1986-03-06 | 1,3−ジチオラン−2−チオン誘導体の製造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4936686A JPS62207268A (ja) | 1986-03-06 | 1986-03-06 | 1,3−ジチオラン−2−チオン誘導体の製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62207268A JPS62207268A (ja) | 1987-09-11 |
JPH0130832B2 true JPH0130832B2 (xx) | 1989-06-22 |
Family
ID=12829018
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP4936686A Granted JPS62207268A (ja) | 1986-03-06 | 1986-03-06 | 1,3−ジチオラン−2−チオン誘導体の製造方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62207268A (xx) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7541319B2 (en) * | 2004-10-26 | 2009-06-02 | Chemtura Corporation | 1,3-dithiolane-2-thione additives for lubricants and fuels |
KR100832128B1 (ko) | 2007-04-20 | 2008-05-27 | 경희대학교 산학협력단 | 알킬렌트리티오카보네이트의 제조방법 |
KR100898319B1 (ko) | 2007-05-29 | 2009-05-20 | 경희대학교 산학협력단 | 이미다졸륨 할로겐화합물을 이용한알킬렌트리티오카보네이트의 제조방법 |
JP5858212B2 (ja) * | 2011-03-31 | 2016-02-10 | 和光純薬工業株式会社 | 環状トリチオカーボネートの製造方法 |
-
1986
- 1986-03-06 JP JP4936686A patent/JPS62207268A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS62207268A (ja) | 1987-09-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EXPY | Cancellation because of completion of term |