JPH01134426A - Thin film transistor for driving liquid crystal display - Google Patents

Thin film transistor for driving liquid crystal display

Info

Publication number
JPH01134426A
JPH01134426A JP62292098A JP29209887A JPH01134426A JP H01134426 A JPH01134426 A JP H01134426A JP 62292098 A JP62292098 A JP 62292098A JP 29209887 A JP29209887 A JP 29209887A JP H01134426 A JPH01134426 A JP H01134426A
Authority
JP
Japan
Prior art keywords
wiring
liquid crystal
crystal display
thin film
film transistor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP62292098A
Other languages
Japanese (ja)
Inventor
Yasushi Kawabuchi
靖 河渕
Hitoshi Onuki
仁 大貫
Kunio Miyazaki
邦夫 宮崎
Katsuhiko Shioda
塩田 勝彦
Motoji Taki
滝 元司
Masaaki Kitajima
雅明 北島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP62292098A priority Critical patent/JPH01134426A/en
Publication of JPH01134426A publication Critical patent/JPH01134426A/en
Pending legal-status Critical Current

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  • Liquid Crystal (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)
  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
  • Thin Film Transistor (AREA)

Abstract

PURPOSE:To increase the area of a liquid crystal part and to improve display quality by forming wiring of >=1 kind of alloy among Al-Pd, Mg, Li, Be, Mn, Fe, etc., and forming a film, and annealing it in an oxygen atmosphere. CONSTITUTION:At least either of gate wiring 2 and data wiring 3 has an aluminum alloy layer on a transition metal layer by containing at least one of palladium, magnesium, lithium, beryllium, manganese, iron, cobalt, nickel, copper, lanthanum, and cerium by 0.005-1wt.% in total and aluminum for the rest. Fine working is easily performed because Pd, etc., is dispersed uniformly in the Al wiring films 2 and 3, the anticorrosiveness is improved, and the reliability of the element is improved. Consequently, thin film transistor wiring for driving the liquid crystal display is made thin, the picture element area rate of the liquid crystal display is increased above 70%, and the moisture-resisting reliability of the display device is improved.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、液晶ディスプレイ駆動用薄膜トランジスタに
係り、特にその配線材料に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a thin film transistor for driving a liquid crystal display, and particularly to a wiring material thereof.

〔従来の技術〕[Conventional technology]

従来の液晶ディスプレイ駆動用薄膜トランジスタは、配
線材料に純アルミニウムまたはアルミニウムーシリコン
合金が使われていた。この種の技術については1例えば
特開昭61−93488号に述べられている。
Conventional thin film transistors for driving liquid crystal displays have used pure aluminum or aluminum-silicon alloy as the wiring material. This type of technique is described in, for example, Japanese Patent Laid-Open No. 61-93488.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

従来、液晶ディスプレイ駆動用薄膜トランジスタにおけ
るゲート配線およびデータ配線は、純アルミニウムで形
成されていた。そのため素子を形成する際の熱応力によ
ってヒロックができたり。
Conventionally, gate wiring and data wiring in a thin film transistor for driving a liquid crystal display have been formed of pure aluminum. As a result, hillocks can form due to thermal stress during device formation.

エツチングの際に余分が腐食が起こったりしていた。こ
の対策として配線幅を10μm以上に太くし、層間絶縁
膜の厚さも0.5 μm以上と厚くする必要があり、各
トランジスタの小型化とディスプレイの大型化に対する
障害になっていた。また信頼性試験でアルミニウム配線
が電気的に腐食を起こす問題があった。
Corrosion occurred due to the excess during etching. To counter this, it was necessary to increase the wiring width to 10 μm or more and the thickness of the interlayer insulating film to 0.5 μm or more, which became an obstacle to miniaturizing each transistor and increasing the size of the display. Additionally, there was a problem in which the aluminum wiring was electrically corroded during reliability tests.

本発明の目的は、AQ配線膜の微細加工性を改善し、ヒ
ロックを形成しにくい配線材料を使ってトランジスタ素
子を小型化することによって、液晶部分の面積を広げ表
示画質を向上させるとともに、ディスプレイ面積を大型
化することにある。
The purpose of the present invention is to improve the microfabricability of the AQ wiring film and miniaturize the transistor element by using a wiring material that does not easily form hillocks, thereby increasing the area of the liquid crystal part and improving the display quality. The goal is to increase the area.

同時にAQ配線膜の腐食性を高め、表示素子の信頼性を
向上させることにある。
At the same time, the purpose is to increase the corrosion resistance of the AQ wiring film and improve the reliability of the display element.

〔問題点を解決するための手段〕[Means for solving problems]

上記目的は、配線をA Q −P d 、 M g 、
 L i 。
For the above purpose, the wiring is AQ-Pd, Mg,
Li.

Be、Mn、Fe、Co、Ni、Cu、La及びCeの
1つ以上の合金で形成し、膜形成後、酸素雰囲気中でア
ニールすることにより、達成される。
This is achieved by forming the film from an alloy of one or more of Be, Mn, Fe, Co, Ni, Cu, La, and Ce, and annealing in an oxygen atmosphere after film formation.

腐食性を高める合金元素としてPd等をAQ配線膜中に
均一に分散させるため、微細加工を容易に行う事ができ
るようになるとともに、腐食性が向上し、素子の信頼性
が改善できる。またAQにPd等を添加することによっ
てAQ基地の結晶粒径を細かくすることができるため、
ヒロックの発生を抑制することができる。特にAQ−P
d合金配線膜においては、パターニング後、酸素雰囲気
中でアニールする事により、AQ膜表面にPd○を形成
して表面保護絶縁膜あるいは層間絶縁膜との密着性を高
めることができる。その結果、水分の侵入によるAQ配
線膜の腐食を防止できる。
Since Pd or the like is uniformly dispersed in the AQ wiring film as an alloying element that increases corrosivity, microfabrication can be easily performed, corrosivity is improved, and device reliability can be improved. Also, by adding Pd etc. to AQ, the crystal grain size of the AQ base can be made finer.
The occurrence of hillocks can be suppressed. Especially AQ-P
In the d alloy wiring film, by annealing in an oxygen atmosphere after patterning, Pd◯ can be formed on the surface of the AQ film to improve adhesion with the surface protection insulating film or the interlayer insulating film. As a result, corrosion of the AQ wiring film due to moisture intrusion can be prevented.

AQ合合金におけるPd、Mg、Li、Be。Pd, Mg, Li, Be in AQ alloy.

Mn、Fe、Co、Ni、Cu、La及びCeの少なく
とも1つの量は合計で0.005〜1重量%とすること
が好ましく、特に0.01〜0.5重量%の範囲が好ま
しい。
The total amount of at least one of Mn, Fe, Co, Ni, Cu, La and Ce is preferably from 0.005 to 1% by weight, particularly preferably from 0.01 to 0.5% by weight.

アニール温度は、層間絶縁膜或は半導体膜の形成温度よ
りも高く、ガラスの結晶化温度よりも低い温度範囲とす
ることが好ましい。
The annealing temperature is preferably in a temperature range higher than the formation temperature of the interlayer insulating film or semiconductor film and lower than the crystallization temperature of glass.

〔作用〕[Effect]

AQ配線を加工するためのエツチングの際、レジスト剥
離液、あるいは後工程の水洗における腐食が問題になる
が、これを解決するため、AfiにPd等を添加するこ
とによって腐食性を改善した。
During etching to process AQ wiring, corrosion caused by the resist stripping solution or water washing in the post-process becomes a problem, but in order to solve this problem, the corrosivity was improved by adding Pd or the like to Afi.

またAQ裏表面発生するヒロックを抑制することができ
るため、配線幅を細くできるとともに、層間絶縁膜、保
護膜を薄くすることが可能となり、ガラス基板上の液晶
表示部分の面積を70%以上に増すことができ表示画質
を向上させることができる。また、AQ−Pd合金配線
の壜台、それと表面保護絶縁膜あるいは眉間絶縁膜との
密着性を高めることができ、水分の侵入によるへ〇配線
膜の腐食を防止し、表示素子の信頼性を高くすることが
できるため、画面を5インチ以上に大型化することがで
きる。
In addition, since hillocks that occur on the back surface of the AQ can be suppressed, the wiring width can be made thinner, and the interlayer insulating film and protective film can be made thinner, reducing the area of the liquid crystal display portion on the glass substrate to more than 70%. The display image quality can be improved. In addition, it is possible to improve the adhesion between the AQ-Pd alloy wiring bottle base and the surface protection insulating film or the glabella insulating film, preventing corrosion of the wiring film due to moisture intrusion, and improving the reliability of the display element. Since the height can be increased, the screen can be increased to 5 inches or more.

〔実施例〕〔Example〕

以下、本発明の実施例によって説明する。第1図は液晶
ディスプレイ駆動用薄膜トランジスタの断面構造を示し
ている。第1図において、1はガラス基板、2はゲート
配線、3はデータ配線、4はI T O(Indium
 Tin 0xide)透明1素電極、5はゲート絶縁
膜、6は半導体膜、7は素子表面を保護するパッシベー
ション膜、8は液晶、9は表面ITO透明電極、10は
ガラス板で構成されている。このうち2,3の配線はク
ロム又はタングステン等の遷移金属層の上にAQ−Pd
合金を重ねた構造になっており、ケミカル ベーパ デ
ポジション(CVD) 、It子ビーム蒸着、スパッタ
法等により厚さ1000〜5000人堆積させる。
The present invention will be explained below using examples. FIG. 1 shows a cross-sectional structure of a thin film transistor for driving a liquid crystal display. In FIG. 1, 1 is a glass substrate, 2 is a gate wiring, 3 is a data wiring, and 4 is an ITO (Indium
It consists of a transparent element electrode (5), a gate insulating film, 6 a semiconductor film, 7 a passivation film that protects the element surface, 8 a liquid crystal, 9 a surface ITO transparent electrode, and 10 a glass plate. A few of these wirings are made of AQ-Pd on a transition metal layer such as chromium or tungsten.
It has a structure in which alloys are layered, and is deposited to a thickness of 1,000 to 5,000 layers using chemical vapor deposition (CVD), Itron beam evaporation, sputtering, etc.

第2図は第1図の素子を形成する過程でAQ配線形成後
の熱処理の有無による素子の耐湿信頼性を温度40℃、
湿度95%の条件で評価したものである。AQ−0,3
重量%Pd合金配線形成後、O2中でアニールを行った
素子の耐湿信頼性が最も高く、N2中でアニールを行っ
たものもそれと同等の耐湿信頼性を示す。一方、アニー
ルを行なわなかった素子では時間とともにAJ配線の腐
食が起こり不良率が増してゆく。この原因はアニール無
だと絶縁膜とAQとの間に隙間ができ、そこに水分が侵
入して電気化学的な腐食が加速され断線するためである
Figure 2 shows the moisture resistance reliability of the element at a temperature of 40°C and with or without heat treatment after forming the AQ wiring in the process of forming the element shown in Figure 1.
The evaluation was performed under the condition of 95% humidity. AQ-0,3
The device annealed in O2 after forming the wt% Pd alloy wiring has the highest moisture resistance reliability, and the device annealed in N2 also exhibits the same moisture resistance reliability. On the other hand, in devices that have not been annealed, corrosion of the AJ wiring occurs over time and the defective rate increases. The reason for this is that without annealing, a gap is created between the insulating film and the AQ, and moisture enters the gap, accelerating electrochemical corrosion and causing disconnection.

第3図は絶縁膜形成時にAQ配線上に形成されるヒロッ
ク密度について、本発明によるAQ合金配線と従来の純
AJ配線とを比較し、Pd添加量を横軸に整理した結果
を示す、AllにPdを添加することによって配線膜中
の原子移動が抑制され、ヒロック密度が大幅に減少する
Figure 3 shows the results of comparing the hillock density formed on the AQ wiring during the formation of the insulating film between the AQ alloy wiring according to the present invention and the conventional pure AJ wiring, and arranging the amount of Pd added on the horizontal axis. By adding Pd to the wiring film, the movement of atoms in the wiring film is suppressed, and the hillock density is significantly reduced.

第4図は本発明によりAQ配線の信頼性が高まり、配線
幅が細くなった結果、画素面積率が増す効果を示してい
る。第4図から明らかなように。
FIG. 4 shows the effect of increasing the pixel area ratio as a result of the present invention increasing the reliability of the AQ wiring and reducing the wiring width. As is clear from Figure 4.

従来のAQ−8i合金では10μmあった配線幅が、本
発明のAQ−Pd合金では1μm以下と細くできるため
、液晶駆動部分の画素面積を大きくとることができる。
The wiring width, which was 10 μm in the conventional AQ-8i alloy, can be reduced to 1 μm or less in the AQ-Pd alloy of the present invention, so the pixel area of the liquid crystal driving portion can be increased.

またPdを0.01重量%添加するだけで十分効果があ
り、酸素雰囲気中で200℃−10分間のアニールを施
すことによって、より一層の画素面積率向上の効果がみ
られる。
Further, adding 0.01% by weight of Pd is sufficient, and by annealing at 200° C. for 10 minutes in an oxygen atmosphere, the effect of further improving the pixel area ratio can be seen.

なお、ゲート配線、およびデータ配線としてAQ配線の
ヒロック密度を低減させる添加元素はPdが最も効果が
あるが、Mg、Li、Be。
Note that Pd is the most effective additive element for reducing the hillock density of AQ wiring as gate wiring and data wiring, but Mg, Li, and Be may also be used.

Mn、Fe、Co、Ni、Cu、La、Ceの少なくと
も1つを添加した場合にも効果がある。第5図にこれら
の元素を添加したAfi′合金と純AQの絶縁膜形成時
に発生するヒロック密度を示す。
It is also effective to add at least one of Mn, Fe, Co, Ni, Cu, La, and Ce. FIG. 5 shows the hillock density that occurs when forming an insulating film of Afi' alloy to which these elements are added and pure AQ.

いずれの合金添加もヒロックの抑制に効果があることが
分かる。
It can be seen that addition of any alloy is effective in suppressing hillocks.

〔発明の効果〕〔Effect of the invention〕

本発明によれば、ヒロック密度が低く、耐湿信頼性に優
れ、1μm以下の配線に加工できる液晶ディスプレイ用
配線膜が得られる。その結果、液晶ディスプレイ駆動用
薄膜トランジスタ配線を細くでき、液晶ディスプレイの
画素面積率を70%以上にすることができ、ディスプレ
イ装置の耐湿信頼性を向上させることができる。
According to the present invention, a wiring film for a liquid crystal display can be obtained that has a low hillock density, excellent moisture resistance reliability, and can be processed into wiring of 1 μm or less. As a result, the thin film transistor wiring for driving the liquid crystal display can be made thinner, the pixel area ratio of the liquid crystal display can be increased to 70% or more, and the moisture resistance reliability of the display device can be improved.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の実施例の構造を示した断面図、第2図
はアニールの有無による耐湿信頼性試験結果を示す特性
図、第3図はパラジウムによるヒロック密度の低減効果
を示す特性図、第4−はアニールの有無と画素面積率と
の関係を示す特性図、第5図は各種配線材料とヒロック
密度との関係を示す特性図である。 1・・・ガラス基板、2・・・ゲート配線、3・・・デ
ータ配線、4・・・ITO透明画素電極、5・・・ゲー
ト絶縁膜。 6・・・半導体膜、7・・・パッシベーション膜、8・
・・液$ 1 回 / −6□2ス縁 2− ケートam 3−−データ両巴脈 6−− 串1ト飼ト咲 7−−lザツンベーシタンー屹 10−一 カ′クス4に 拭e吟ItQ(幻 ra 1,4’−(Hθ
Figure 1 is a cross-sectional view showing the structure of an example of the present invention, Figure 2 is a characteristic diagram showing the results of moisture resistance reliability tests with and without annealing, and Figure 3 is a characteristic diagram showing the effect of palladium on reducing hillock density. , 4- is a characteristic diagram showing the relationship between the presence or absence of annealing and the pixel area ratio, and FIG. 5 is a characteristic diagram showing the relationship between various wiring materials and hillock density. DESCRIPTION OF SYMBOLS 1... Glass substrate, 2... Gate wiring, 3... Data wiring, 4... ITO transparent pixel electrode, 5... Gate insulating film. 6... Semiconductor film, 7... Passivation film, 8.
...liquid $ 1 time / -6 □ 2 s rim 2 - kate am 3 - - data both sides 6 - - skewer 1 to feed tosaki 7 - l zatsumbashitan - 屹 10 - 1 c'ax 4 NiwieginItQ(phantom ra 1,4'-(Hθ

Claims (1)

【特許請求の範囲】 1、ゲート配線及びデータ配線を具備する液晶ディスプ
レイ駆動用薄膜トランジスタにおいて、前記ゲート配線
及びデータ配線の少なくとも一方が遷移金属層上に、パ
ラジウムとマグネシウムとリチウムとベリリウムとマン
ガンと鉄とコバルトとニッケルと銅とランタン及びセリ
ウムの少なくとも1つを合計で0.005〜1重量%含
み、残部アルミニウムの合金よりなるアルミニウム合金
層を有することを特徴とする液晶ディスプレイ駆動用薄
膜トランジスタ。 2、特許請求の範囲第1項において、前記アルミニウム
合金層が膜形成後、アニールされていることを特徴とす
る液晶ディスプレイ駆動用薄膜トランジスタ。
[Claims] 1. In a thin film transistor for driving a liquid crystal display, which includes a gate wiring and a data wiring, at least one of the gate wiring and the data wiring includes palladium, magnesium, lithium, beryllium, manganese, and iron on a transition metal layer. 1. A thin film transistor for driving a liquid crystal display, comprising an aluminum alloy layer containing a total of 0.005 to 1% by weight of at least one of cobalt, nickel, copper, lanthanum, and cerium, and the balance being aluminum. 2. The thin film transistor for driving a liquid crystal display according to claim 1, wherein the aluminum alloy layer is annealed after being formed.
JP62292098A 1987-11-20 1987-11-20 Thin film transistor for driving liquid crystal display Pending JPH01134426A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62292098A JPH01134426A (en) 1987-11-20 1987-11-20 Thin film transistor for driving liquid crystal display

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62292098A JPH01134426A (en) 1987-11-20 1987-11-20 Thin film transistor for driving liquid crystal display

Publications (1)

Publication Number Publication Date
JPH01134426A true JPH01134426A (en) 1989-05-26

Family

ID=17777519

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62292098A Pending JPH01134426A (en) 1987-11-20 1987-11-20 Thin film transistor for driving liquid crystal display

Country Status (1)

Country Link
JP (1) JPH01134426A (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0425162A2 (en) * 1989-10-25 1991-05-02 AT&T Corp. Improved aluminum metallization for semiconductor devices
JPH04323872A (en) * 1991-04-23 1992-11-13 Kobe Steel Ltd Material for semiconductor device
US5296653A (en) * 1991-12-09 1994-03-22 Kabushiki Kaisha Toshiba Device having a multi-layered conductor structure
JPH0745555A (en) * 1993-07-27 1995-02-14 Kobe Steel Ltd Semiconductor electrode and manufacturing method thereof as well as semiconductor film forming sputtering target
JPH088256A (en) * 1994-06-22 1996-01-12 Sony Corp Wiring structure for semiconductor device and transistor array for display element
US5726720A (en) * 1995-03-06 1998-03-10 Canon Kabushiki Kaisha Liquid crystal display apparatus in which an insulating layer between the source and substrate is thicker than the insulating layer between the drain and substrate
US5830786A (en) * 1993-02-22 1998-11-03 Semiconductor Energy Laboratory Co., Ltd. Process for fabricating electronic circuits with anodically oxidized scandium doped aluminum wiring
US5976641A (en) * 1991-03-07 1999-11-02 Kabushiki Kaisha Kobe Seiko Sho A1 alloy films and melting A1 alloy sputtering targets for depositing A1 alloy films
KR100670060B1 (en) * 2000-04-20 2007-01-16 삼성전자주식회사 Manufacturing method of a thin film transistor array panel for a liquid crystal display
KR100845705B1 (en) * 2006-05-31 2008-07-10 가부시키가이샤 고베 세이코쇼 Thin film transistor substrate and display device
USRE41975E1 (en) 1995-10-12 2010-11-30 Kabushiki Kaisha Toshiba Interconnector line of thin film, sputter target for forming the wiring film and electronic component using the same
USRE45481E1 (en) 1995-10-12 2015-04-21 Kabushiki Kaisha Toshiba Interconnector line of thin film, sputter target for forming the wiring film and electronic component using the same
JP2015165563A (en) * 2014-02-07 2015-09-17 株式会社神戸製鋼所 Wiring film for flat panel displays, and aluminium alloy sputtering target

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JPS5612751A (en) * 1979-07-11 1981-02-07 Toshiba Corp Production of semiconductor device
JPS571241A (en) * 1980-06-03 1982-01-06 Toshiba Corp Integrated circuit device
JPS5928553A (en) * 1982-08-11 1984-02-15 Hitachi Ltd Corrosion resistant aluminum electronic material
JPS5974650A (en) * 1982-09-20 1984-04-27 インタ−ナシヨナル ビジネス マシ−ンズ コ−ポレ−シヨン Method of forming mutial connection metal system

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Publication number Priority date Publication date Assignee Title
JPS5612751A (en) * 1979-07-11 1981-02-07 Toshiba Corp Production of semiconductor device
JPS571241A (en) * 1980-06-03 1982-01-06 Toshiba Corp Integrated circuit device
JPS5928553A (en) * 1982-08-11 1984-02-15 Hitachi Ltd Corrosion resistant aluminum electronic material
JPS5974650A (en) * 1982-09-20 1984-04-27 インタ−ナシヨナル ビジネス マシ−ンズ コ−ポレ−シヨン Method of forming mutial connection metal system

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0425162A2 (en) * 1989-10-25 1991-05-02 AT&T Corp. Improved aluminum metallization for semiconductor devices
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