JPH0112466B2 - - Google Patents
Info
- Publication number
- JPH0112466B2 JPH0112466B2 JP55160202A JP16020280A JPH0112466B2 JP H0112466 B2 JPH0112466 B2 JP H0112466B2 JP 55160202 A JP55160202 A JP 55160202A JP 16020280 A JP16020280 A JP 16020280A JP H0112466 B2 JPH0112466 B2 JP H0112466B2
- Authority
- JP
- Japan
- Prior art keywords
- coating
- added
- calcium
- finished
- seafood
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 28
- 235000010323 ascorbic acid Nutrition 0.000 claims description 24
- 239000011248 coating agent Substances 0.000 claims description 22
- 238000000576 coating method Methods 0.000 claims description 19
- 235000014102 seafood Nutrition 0.000 claims description 17
- 150000000996 L-ascorbic acids Chemical class 0.000 claims description 13
- 229960005070 ascorbic acid Drugs 0.000 claims description 11
- 239000011668 ascorbic acid Substances 0.000 claims description 11
- -1 organic acid calcium salt Chemical class 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 229940023462 paste product Drugs 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 235000019465 surimi Nutrition 0.000 description 14
- 239000000203 mixture Substances 0.000 description 9
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 8
- 235000013372 meat Nutrition 0.000 description 7
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-araboascorbic acid Natural products OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 6
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 6
- 239000001527 calcium lactate Substances 0.000 description 6
- 229960002401 calcium lactate Drugs 0.000 description 6
- 235000011086 calcium lactate Nutrition 0.000 description 6
- 235000010350 erythorbic acid Nutrition 0.000 description 6
- 239000004318 erythorbic acid Substances 0.000 description 6
- 229940026239 isoascorbic acid Drugs 0.000 description 6
- 239000004471 Glycine Substances 0.000 description 4
- YBHQCJILTOVLHD-YVMONPNESA-N Mirin Chemical compound S1C(N)=NC(=O)\C1=C\C1=CC=C(O)C=C1 YBHQCJILTOVLHD-YVMONPNESA-N 0.000 description 4
- 229960005069 calcium Drugs 0.000 description 4
- 235000011194 food seasoning agent Nutrition 0.000 description 4
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 3
- 102000002322 Egg Proteins Human genes 0.000 description 3
- 108010000912 Egg Proteins Proteins 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 241000276498 Pollachius virens Species 0.000 description 3
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 3
- 239000001354 calcium citrate Substances 0.000 description 3
- 229960004256 calcium citrate Drugs 0.000 description 3
- 159000000007 calcium salts Chemical class 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 235000014103 egg white Nutrition 0.000 description 3
- 210000000969 egg white Anatomy 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 239000005457 ice water Substances 0.000 description 3
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 3
- 235000013923 monosodium glutamate Nutrition 0.000 description 3
- 239000004223 monosodium glutamate Substances 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 235000013337 tricalcium citrate Nutrition 0.000 description 3
- 239000004278 EU approved seasoning Substances 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- 235000019658 bitter taste Nutrition 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 235000021096 natural sweeteners Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229920001592 potato starch Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 235000019640 taste Nutrition 0.000 description 2
- FTLYMKDSHNWQKD-UHFFFAOYSA-N (2,4,5-trichlorophenyl)boronic acid Chemical compound OB(O)C1=CC(Cl)=C(Cl)C=C1Cl FTLYMKDSHNWQKD-UHFFFAOYSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 239000004378 Glycyrrhizin Substances 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 244000228451 Stevia rebaudiana Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 235000013334 alcoholic beverage Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 235000021120 animal protein Nutrition 0.000 description 1
- 239000008122 artificial sweetener Substances 0.000 description 1
- 235000021311 artificial sweeteners Nutrition 0.000 description 1
- 235000019606 astringent taste Nutrition 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000004227 calcium gluconate Substances 0.000 description 1
- 229960004494 calcium gluconate Drugs 0.000 description 1
- 235000013927 calcium gluconate Nutrition 0.000 description 1
- NEEHYRZPVYRGPP-UHFFFAOYSA-L calcium;2,3,4,5,6-pentahydroxyhexanoate Chemical compound [Ca+2].OCC(O)C(O)C(O)C(O)C([O-])=O.OCC(O)C(O)C(O)C(O)C([O-])=O NEEHYRZPVYRGPP-UHFFFAOYSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 229940099112 cornstarch Drugs 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- LPLVUJXQOOQHMX-UHFFFAOYSA-N glycyrrhetinic acid glycoside Natural products C1CC(C2C(C3(CCC4(C)CCC(C)(CC4C3=CC2=O)C(O)=O)C)(C)CC2)(C)C2C(C)(C)C1OC1OC(C(O)=O)C(O)C(O)C1OC1OC(C(O)=O)C(O)C(O)C1O LPLVUJXQOOQHMX-UHFFFAOYSA-N 0.000 description 1
- 229960004949 glycyrrhizic acid Drugs 0.000 description 1
- UYRUBYNTXSDKQT-UHFFFAOYSA-N glycyrrhizic acid Natural products CC1(C)C(CCC2(C)C1CCC3(C)C2C(=O)C=C4C5CC(C)(CCC5(C)CCC34C)C(=O)O)OC6OC(C(O)C(O)C6OC7OC(O)C(O)C(O)C7C(=O)O)C(=O)O UYRUBYNTXSDKQT-UHFFFAOYSA-N 0.000 description 1
- 235000019410 glycyrrhizin Nutrition 0.000 description 1
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 239000008172 hydrogenated vegetable oil Substances 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000014594 pastries Nutrition 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 1
- 235000019828 potassium polyphosphate Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- HELXLJCILKEWJH-NCGAPWICSA-N rebaudioside A Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@]12C(=C)C[C@@]3(C1)CC[C@@H]1[C@@](C)(CCC[C@]1([C@@H]3CC2)C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HELXLJCILKEWJH-NCGAPWICSA-N 0.000 description 1
- 229940085605 saccharin sodium Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000013580 sausages Nutrition 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 235000019710 soybean protein Nutrition 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L17/00—Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
- A23L17/70—Comminuted, e.g. emulsified, fish products; Processed products therefrom such as pastes, reformed or compressed products
Description
本発明は品質の改良された水産ねり製品および
その製造法、ならびに水産ねり製品用の品質改良
剤に関する。
コーテイングアスコルビン酸類を水産ねり製品
に添加することによりたとえば、従来の殺菌剤も
しくは保存剤の代替品として使用されるグリシン
に由来する渋味や、エビ様の悪臭などによる風味
の劣化の防止あるいは併用するコーテイング有機
酸類のコーテイング剤として使用される硬化油の
ろう臭、しぶ味やえぐ味、さらには重合リン酸塩
類のしぶ味、えぐ味などを減少、また水産ねり製
品にカツオ風の風味がで、さらにケーシングかま
ぼこ、リテーナーかまぼこなどの真空密封包装製
品などの包装製品や坐りかまぼこなどに対して特
に保存性が向上するなどの効果が発揮される。
このような効果を奏するこれらアスコルビン酸
類を添加した水産ねり製品は日時の経過とともに
着色し、その商品が著しく損われるという欠点が
ある。
また、水産ねり製品にグリシンのようなアミノ
酸と糖が共存する場合、加熱によつていわゆるメ
イラード反応を起こし着色の原因となることもあ
る。
本発明者らは、これら欠点を解決するために鋭
意研究した結果、本発明を完成するに至つた。
すなわち、本発明は(1) コーテイングアスコル
ビン酸類と可食性の有機酸カルシウム塩を添加し
てなる水産ねり製品、(2) 仕上ねり肉にコーテイ
ングアスコルビン酸類と可食性の有機酸カルシウ
ム塩とをカルシウムとして仕上りねり肉に対し約
0.01〜0.3重量%添加することを特徴とする水産
ねり製品の製造法、ならびに(3) コーテイングア
スコルビン酸類と可食性の有機カルシウム塩とを
含有してなる水産ねり製品用品質改良剤、であ
る。
本発明の対象とする水産ねり製品とは、たとえ
ばかまぼこ、ちくわ、はんぺん、天ぷら、魚肉ソ
ーセージ、魚肉ハムなどの魚肉加工食品が挙げら
れる。
次に、本発明で使用されるコーテイングアスコ
ルビン酸類の製造法としては、微粉砕したアスコ
ルビン酸、エリソルビン酸あるいはこれらのナト
リウム塩などのアスコルビン酸類を融点40〜90℃
程度の植物性または動物性の硬化油、たとえば菜
種硬化油、ひまし油硬化油、鯨油硬化油、牛脂硬
化油、ヤシ油硬化油などを主剤とし、必要に応じ
てステアリン酸、パルミチン酸などの炭素数12〜
24の飽和脂肪酸やソルビタンモノパルミテート、
ソルビタンセスキオレートなどのソルビタン脂肪
酸エステル、ワツクスを適宜併用したコーテイン
グ剤で回転円板型遠心アトマイザー又はスプレー
式装置を用いて造粒することにより製造すことが
できる。本発明においては、アスコルビン酸類1
部に対して0.8〜10部、好ましくは0.8〜3部程度
のコーテイング剤を用いて造粒したコーテイング
アスコルビン酸類を用いるのが好ましく、またそ
の粒径としては通常50〜300μ程度のものが適当
である。
次に、本発明で使用される可食性の有機カルシ
ウム塩としては、乳酸カルシウム、クエン酸カル
シウムグルコン酸カルシウムなどが挙げられる。
本発明において、コーテイングアスコルビン酸
類は、アスコルビン酸および(または)エリソル
ビン酸として仕上りねり肉に対して0.01〜0.3重
量%、好ましくは約0.05〜0.2重量%使用され、
一方、可食性の有機酸カルシウム塩はカルシウム
として仕上りねり肉に対して0.01〜0.3重量%、
好ましくは約0.1〜0.2重量%程度使用される。カ
ルシウム塩の添加量は上記の添加範囲よりも少な
いと着色等の品質低下を防止する効果が顕著では
なく、逆に多い場合には苦みが生ずるなどの現象
がみられ好ましくない。
コーテイングアスコルビン酸類および可食性の
有機酸カルシウム塩は、水産ねり製品の製造工程
中に添加され均一に混和されるが、その添加時期
や添加方法については特に制限はなく、また両者
は各々単独で添加してもよいし混合物で添加して
もよい。通常は、水産ねり製品に必要に応じて添
加される下記に示すような他の添加剤と共に仕上
りねり肉(すり身)に添加混和するのが適当であ
る。
本発明においては、本目的を阻害しない限り、
従来より水産ねり製品に添加されるリン酸塩類
(たとえば、ポリリン酸ナトリウム、ポリリン酸
カリウム、ピロリン酸ナトリウム、ピロリン酸カ
リウム)、天然甘味料(たとえば、砂糖、ブドウ
糖、果糖、乳糖)、人工甘味料(たとえば、グリ
チルリチン、ステビヤ、サツカリンナトリウム)、
その他香辛料、香料、天然調味料、化学調味料、
糊料、殺菌剤、大豆蛋白質、小麦蛋白質、動物性
蛋白質(例、卵白)、酒類、野菜などを適宜添加
してもよい。
本発明方法によれば、原料ねり肉に、コーテイ
ングアスコルビン酸類を添加して製造された水産
ねり製品は、アスコルビン酸類に由来する変色が
防止され、また風味も改善され、足や弾力が何ら
損われず商品性が一段と向上し、しかも変質防止
された食品衛生上きわめて安全である。
次に、本発明を参考例、実験例および実施例に
よりさらに具体的に説明する。
なお以下の%(パーセント)はいづれも重量/
重量パーセントを表わす。
参考例 1
あらかじめ75℃にて加温溶解された牛脂硬化油
70部に微粒末状アスコルビン酸30部を加え、ミキ
サーにてよく撹拌し、均一にしたペースト状混合
物を65〜70℃に保温し、ポンプにて遠心式噴霧装
置に送り、24℃に調温された室内に噴霧粒造し
た。この粒末を50メツシユにて篩過し、コーテイ
ングアスコルビン酸を得た。
同様な方法により、エリソルビン酸を使用して
コーテイングエリソルビン酸を得た。
以下の実験例および実施例においては、上の方
法で得たコーテイングアスコルビン酸あるいはエ
リソルビン酸を用いた。
実験例 1
スケソウ冷凍すり身(特A)6Kg、氷水2.7Kg、
食塩190g、バレイシヨデンプン520g、グルタミ
ン酸ナトリウム70g、砂糖70g、重合リン酸塩20
g、みりん230g、複合調味料100gからなる原料
配合で、常法にもとづき、かまぼこ用仕上りすり
身を製造した。この仕上りすり身を8等分し、
各々に第1表に示す添加剤を加えてよく混合した
後、塩化ビニール製のケーシングチユーブ(折径
45mm)に詰め13℃で18時間坐り処理し、次いで85
℃、40分間加熱処理後、冷却して8種類のかまぼ
こを製造した。
これらかまぼこの着色度および品質状態を第1
表に示した。着色度の表示は、日本電色工業(株)製
の色差計を用い、U.C.S.(等色差表色系)L、a、
b表色系のうち、かまぼこ色相(黄色系)に相当
するb値を測定してあらわした。
The present invention relates to a seafood paste product with improved quality, a method for producing the same, and a quality improver for seafood paste products. Coating By adding ascorbic acids to seafood paste products, for example, it can be used to prevent deterioration of flavor due to astringency caused by glycine, which is used as a substitute for conventional disinfectants or preservatives, and bad shrimp-like odor, or to use it in combination. Coating: Reduces the waxy odor, astringent and harsh taste of hydrogenated oils used as coating agents for organic acids, as well as the astringent and acrid taste of polymerized phosphates, and imparts a bonito-like flavor to seafood paste products. Furthermore, it is particularly effective in improving the preservability of packaged products such as vacuum-sealed packaging products such as casing kamaboko and retainer kamaboko, and sitting kamaboko. Marine paste products to which these ascorbic acids are added, which have such effects, have the disadvantage that they become discolored over time, resulting in significant damage to the product. Furthermore, when amino acids such as glycine and sugar coexist in seafood paste products, heating may cause the so-called Maillard reaction, which may cause coloration. The present inventors have completed the present invention as a result of intensive research to solve these drawbacks. That is, the present invention provides (1) a seafood batter product in which coating ascorbic acids and an edible organic acid calcium salt are added, and (2) a finished battered meat coated with an ascorbic acid and an edible organic acid calcium salt as calcium. Approx. for finished minced meat
The present invention provides a method for producing a seafood paste product characterized by adding 0.01 to 0.3% by weight, and (3) a quality improver for a seafood paste product containing a coating ascorbic acid and an edible organic calcium salt. The seafood paste products targeted by the present invention include processed fish foods such as kamaboko, chikuwa, hanpen, tempura, fish sausage, and fish ham. Next, as a method for producing the coating ascorbic acids used in the present invention, ascorbic acids such as finely pulverized ascorbic acid, erythorbic acid, or their sodium salts are heated to a melting point of 40 to 90°C.
The main ingredient is a certain degree of hydrogenated vegetable or animal oil, such as hydrogenated rapeseed oil, hydrogenated castor oil, hydrogenated whale oil, hydrogenated beef tallow oil, hydrogenated coconut oil, etc., and if necessary, carbon number such as stearic acid or palmitic acid. 12~
24 saturated fatty acids and sorbitan monopalmitate,
It can be produced by granulation using a rotating disk type centrifugal atomizer or spray type device with a coating agent that appropriately uses a sorbitan fatty acid ester such as sorbitan sesquiolate and wax. In the present invention, ascorbic acids 1
It is preferable to use coated ascorbic acids that are granulated using a coating agent of 0.8 to 10 parts, preferably 0.8 to 3 parts, and the particle size is usually about 50 to 300μ. be. Next, edible organic calcium salts used in the present invention include calcium lactate, calcium citrate, calcium gluconate, and the like. In the present invention, the coating ascorbic acids are used as ascorbic acid and/or erythorbic acid in an amount of 0.01 to 0.3% by weight, preferably about 0.05 to 0.2% by weight, based on the finished minced meat,
On the other hand, edible organic acid calcium salt is 0.01 to 0.3% by weight of finished minced meat as calcium.
It is preferably used in an amount of about 0.1 to 0.2% by weight. If the amount of calcium salt added is less than the above-mentioned addition range, the effect of preventing deterioration of quality such as discoloration will not be significant, whereas if it is in a large amount, phenomena such as bitterness may occur, which is not preferable. Coating ascorbic acids and edible organic acid calcium salts are added and mixed uniformly during the manufacturing process of seafood paste products, but there are no particular restrictions on when or how they are added, and they can be added individually. or may be added as a mixture. Usually, it is appropriate to add and mix it into the finished minced meat (surimi) along with other additives shown below that are added to the seafood paste product as needed. In the present invention, as long as this purpose is not hindered,
Phosphates (e.g., sodium polyphosphate, potassium polyphosphate, sodium pyrophosphate, potassium pyrophosphate), natural sweeteners (e.g., sugar, glucose, fructose, lactose), and artificial sweeteners traditionally added to seafood paste products (e.g. glycyrrhizin, stevia, saccharin sodium),
Other spices, fragrances, natural seasonings, chemical seasonings,
Thickening agents, fungicides, soybean protein, wheat protein, animal protein (eg, egg white), alcoholic beverages, vegetables, etc. may be added as appropriate. According to the method of the present invention, the seafood paste product produced by adding coating ascorbic acids to the raw pastry meat is prevented from discoloration caused by ascorbic acids, has improved flavor, and has no loss of texture or elasticity. The product's marketability has further improved, and deterioration is prevented, making it extremely safe in terms of food hygiene. Next, the present invention will be explained in more detail using reference examples, experimental examples, and examples. All percentages below are based on weight/
Represents weight percentage. Reference example 1 Hydrogenated beef tallow oil heated and melted at 75℃ in advance
Add 30 parts of fine powder ascorbic acid to 70 parts, stir well with a mixer, keep the homogeneous paste mixture at 65-70℃, send it to a centrifugal spray device with a pump, and adjust the temperature to 24℃. Spray granulation was carried out in the room where the product was placed. This powder was sieved through a 50-mesh sieve to obtain coating ascorbic acid. In a similar manner, coating erythorbic acid was obtained using erythorbic acid. In the following experimental examples and examples, coating ascorbic acid or erythorbic acid obtained by the above method was used. Experimental example 1 Frozen pollock surimi (special A) 6 kg, ice water 2.7 kg,
Salt 190g, potato starch 520g, monosodium glutamate 70g, sugar 70g, polymerized phosphate 20g
Finished surimi for kamaboko was produced using a conventional method using a raw material mixture consisting of 230 g of mirin, 230 g of mirin, and 100 g of composite seasoning. Divide this finished surimi into 8 equal parts,
After adding the additives shown in Table 1 to each and mixing well, insert a casing tube made of vinyl chloride (folded diameter
45mm) and saturated for 18 hours at 13℃, then 85℃
After heat treatment at ℃ for 40 minutes, the mixture was cooled to produce eight types of kamaboko. The degree of coloring and quality of these kamaboko
Shown in the table. The degree of coloring is displayed using a color difference meter manufactured by Nippon Denshoku Kogyo Co., Ltd., using UCS (uniform color system) L, a,
Of the b color system, the b value corresponding to the kamaboko hue (yellow color) was measured and expressed.
【表】
第1表から明らかなように、コーテイングアス
コルビン酸を単独で添加した試料区(1)はb値が高
く着色が認められるが、乳酸カルシウムを本発明
の添加範囲で併用した試料区(5)、(6)および(7)は白
くて良好であつた。試料区(8)のように、乳酸カル
シウムの添加量が多くなると着色は防止できるも
のの、苦みが強くなり、かまぼこの品質として不
適当であつた。
実施例 1
スケソウ冷凍すり身(特A)10Kg、食塩310g、
グルタミン酸ナトリウム120g、複合調味料150
g、グリシン200g、本みりん300g、卵白500g、
氷水5Kg、バレイシヨデンプンン900g及び参考
例1で製造したコーテイングエリソルビン酸52g
からなる原料配合で、常法にもとづき仕上りすり
身を製造した。この仕上りすり身を2等分し、そ
の一方にはクエン酸カルシウムを仕上りすり身に
対し0.5%(カルシウムとして0.105%)添加して
よく混合し、他方は対照とした。各すり身を150
g程度ずつ板付け成形し、13℃で15時間坐り処理
後、リテーナに詰め85℃、45分間蒸煮しリテーナ
かまぼこを製造した。
この結果、クエン酸カルシウム添加区は非常に
白く品質が良好であつたのに対し、対照区は黄か
つ色に着色し不良であつた。
実施例 2
スケソウ冷凍すり身(特A)8Kg、エソ落身2
Kg、食塩320g、グルタミン酸ナトリウム100g、
コーンスターチ700g、卵白300g、みりん300g、
天然甘味製剤10g、氷水4Kg、参考例1で製造し
たコーテイングアスコルビン酸40gおよびソルビ
ン酸製剤75gからなる原料配合で、常法にもとづ
き仕上りすり身を製造した。この仕上りすり身を
2等分し、一方には仕上りすり身に対し乳酸カル
シウムを0.2%(カルシウムとして0.026%)を加
えてよく混合し、他方は対照とした。次いで、各
すり身を塩化ビニール製ケーシングチユーブ(折
径45cm)に詰め、直ちに45℃、50分間坐りを行つ
た後、85℃で45分間加熱し、ケーシングかまぼこ
を製造した。これらの製品を8〜10℃に12日間保
管後、着色度をしらべた。
その結果、乳酸カルシウム添加区はほとんど着
色がなく良好な品質であつたのに対し、対照区は
全体に暗かつ色に着色し不良であつた。
実施例 3
つぎの組成からなる水産ねり製品用品質改良剤
を調製した。
コーテイングアスコルビン酸(参考例1で製造し
たもの) ……15%
乳酸カルシウム ……26%
グリシン ……59%
包装かまぼこの製造に際し、本組成物を仕上り
ねり肉に対し2%添加し均一に混和して常法によ
り製造したところ、得られたかまぼこは10日間保
存後も着色が認められず良好な品質であつた。[Table] As is clear from Table 1, sample group (1) in which coating ascorbic acid was added alone had a high b value and coloration was observed, but sample group (1) in which coating calcium lactate was added within the range of the present invention ( 5), (6) and (7) were white and in good condition. As in sample group (8), when the amount of calcium lactate added was large, discoloration could be prevented, but the bitterness became strong and the quality of kamaboko was inappropriate. Example 1 Frozen pollock surimi (Special A) 10kg, salt 310g,
Monosodium glutamate 120g, complex seasoning 150g
g, glycine 200g, hon mirin 300g, egg white 500g,
5 kg of ice water, 900 g of potato starch, and 52 g of coating erythorbic acid produced in Reference Example 1
Finished surimi was produced according to a conventional method using a raw material composition consisting of: This finished surimi was divided into two equal parts, and 0.5% calcium citrate (0.105% as calcium) was added to one half of the finished surimi and mixed well, and the other half was used as a control. 150 each Surimi
The kamaboko was molded onto a plate in portions of approximately 1.5 g, and after sitting at 13°C for 15 hours, it was packed in a retainer and steamed at 85°C for 45 minutes to produce caged kamaboko. As a result, the calcium citrate added area was very white and of good quality, whereas the control area was yellow and poor quality. Example 2 Frozen pollock surimi (Special A) 8kg, Esochi minami 2
Kg, salt 320g, monosodium glutamate 100g,
700g cornstarch, 300g egg white, 300g mirin,
Finished surimi was produced according to a conventional method using a raw material composition consisting of 10 g of a natural sweetener, 4 kg of ice water, 40 g of the coating ascorbic acid prepared in Reference Example 1, and 75 g of a sorbic acid preparation. This finished surimi was divided into two equal parts, and 0.2% calcium lactate (0.026% as calcium) was added to one half of the finished surimi and mixed well, and the other half was used as a control. Next, each surimi was packed into a vinyl chloride casing tube (folded diameter: 45 cm), immediately kept at 45°C for 50 minutes, and then heated at 85°C for 45 minutes to produce casing kamaboko. After storing these products at 8-10°C for 12 days, the degree of coloration was examined. As a result, the calcium lactate added group had almost no coloration and was of good quality, whereas the control group was dark and colored as a whole and was poor. Example 3 A quality improver for seafood paste products having the following composition was prepared. Coating Ascorbic acid (manufactured in Reference Example 1) ...15% Calcium lactate ...26% Glycine ...59% When manufacturing packaged kamaboko, 2% of this composition is added to the finished minced meat and mixed uniformly. The kamaboko obtained was of good quality with no coloration observed even after storage for 10 days.
Claims (1)
機酸カルシウム塩を添加してなる水産ねり製品。 2 仕上りねり肉にコーテイングアスコルビン酸
類と可食性の有機酸カルシウム塩とをカルシウム
として仕上りねり肉に対し約0.01〜0.3重量%添
加することを特徴とする水産ねり製品の製造法。 3 コーテングアスコルビン酸類と可食性の有機
酸カルシウム塩とを含有してなる水産ねり製品用
品質改良剤。[Claims] 1. A seafood paste product obtained by adding a coating ascorbic acid and an edible organic acid calcium salt. 2. A method for producing a seafood batter product, which comprises adding coating ascorbic acids and edible organic acid calcium salts as calcium in an amount of about 0.01 to 0.3% by weight to the finished batter. 3. Coating A quality improver for seafood paste products containing ascorbic acids and an edible organic acid calcium salt.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55160202A JPS5783262A (en) | 1980-11-13 | 1980-11-13 | Fish paste product, its preparation, and agent for improving quality of fish paste product |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55160202A JPS5783262A (en) | 1980-11-13 | 1980-11-13 | Fish paste product, its preparation, and agent for improving quality of fish paste product |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5783262A JPS5783262A (en) | 1982-05-25 |
JPH0112466B2 true JPH0112466B2 (en) | 1989-03-01 |
Family
ID=15709992
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP55160202A Granted JPS5783262A (en) | 1980-11-13 | 1980-11-13 | Fish paste product, its preparation, and agent for improving quality of fish paste product |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5783262A (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57105163A (en) * | 1980-12-22 | 1982-06-30 | Takeda Chem Ind Ltd | Quality improver for broiled marine paste product and improvement of quality of broiled marine paste product |
EP0250074A3 (en) * | 1986-05-20 | 1989-04-19 | Oscar Mayer Foods Corporation | A foodstuff having a surface coating of lactate salt |
JP2619678B2 (en) * | 1988-03-29 | 1997-06-11 | 東和化成工業株式会社 | Quality improving agent for adding frozen surimi and method for producing frozen surimi using the same |
US5223302A (en) * | 1992-08-25 | 1993-06-29 | Kraft General Foods, Inc. | Meat products having improved moisture retention and method for making same |
-
1980
- 1980-11-13 JP JP55160202A patent/JPS5783262A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS5783262A (en) | 1982-05-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA1270691A (en) | Algin/calcium gel structured meat products | |
CA1054845A (en) | Intermediate moisture meats | |
US3940500A (en) | Flavoring seafood with S-methyl methionine salt | |
CA1083403A (en) | Mixes and processes for preparing meat products | |
US4590079A (en) | Method and composition for preventing discoloration of meat products | |
JPH08238073A (en) | Composition for edible meat processing and method for treating processed edible meat | |
HU201864B (en) | Method for producing flavouring material | |
JPH0112466B2 (en) | ||
JPS642350B2 (en) | ||
JPS58201964A (en) | Composition for fish and cattle meat paste product and preparation of fish or cattle meat paste product | |
JPH11164675A (en) | Preservative for food and preservation of food | |
JPS58146260A (en) | Composition of fish paste and making method for the same | |
JPS5894366A (en) | Seasoning preparation | |
JP2516097B2 (en) | New kneaded product and its manufacturing method | |
JPH0112467B2 (en) | ||
JPS6313662B2 (en) | ||
JP3394571B2 (en) | Squid-like batter and its manufacturing method | |
RU2165164C2 (en) | Food additive for obtaining food product in jelly, in particular, meat product | |
JPH0642821B2 (en) | Powder oyster use composition and method for producing the same, and method for maintaining freshness of fresh food using the powder oyster use composition | |
JP3212745B2 (en) | Porridge containing edible meat | |
JPH0652B2 (en) | Quality improver for paste products and method for producing paste products | |
JPS5951263B2 (en) | Dipeptide sweetener-containing oil and fat composition | |
JPS6231901B2 (en) | ||
JPS6240987B2 (en) | ||
JPS6344863A (en) | Formed seasoning |