JPS6240987B2 - - Google Patents
Info
- Publication number
- JPS6240987B2 JPS6240987B2 JP55066804A JP6680480A JPS6240987B2 JP S6240987 B2 JPS6240987 B2 JP S6240987B2 JP 55066804 A JP55066804 A JP 55066804A JP 6680480 A JP6680480 A JP 6680480A JP S6240987 B2 JPS6240987 B2 JP S6240987B2
- Authority
- JP
- Japan
- Prior art keywords
- coating
- acid
- sorbic acid
- sorbic
- erythorbic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011248 coating agent Substances 0.000 claims description 36
- 235000010199 sorbic acid Nutrition 0.000 claims description 30
- 238000000576 coating method Methods 0.000 claims description 29
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 24
- 239000004334 sorbic acid Substances 0.000 claims description 24
- 229940075582 sorbic acid Drugs 0.000 claims description 24
- 235000014102 seafood Nutrition 0.000 claims description 17
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 16
- 235000010350 erythorbic acid Nutrition 0.000 claims description 14
- 239000000796 flavoring agent Substances 0.000 claims description 11
- 235000019634 flavors Nutrition 0.000 claims description 11
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 10
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-araboascorbic acid Natural products OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 claims description 10
- 239000004318 erythorbic acid Substances 0.000 claims description 10
- 229940026239 isoascorbic acid Drugs 0.000 claims description 10
- 239000004471 Glycine Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- 150000003398 sorbic acids Chemical class 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 15
- 235000019465 surimi Nutrition 0.000 description 12
- 239000000654 additive Substances 0.000 description 7
- 239000001530 fumaric acid Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 7
- 235000019645 odor Nutrition 0.000 description 6
- 235000010352 sodium erythorbate Nutrition 0.000 description 6
- 239000004320 sodium erythorbate Substances 0.000 description 6
- RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 description 6
- 229940023462 paste product Drugs 0.000 description 5
- 235000019640 taste Nutrition 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 4
- -1 alkali metal salts Chemical class 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 229920003002 synthetic resin Polymers 0.000 description 4
- 239000000057 synthetic resin Substances 0.000 description 4
- 239000003760 tallow Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 241000251468 Actinopterygii Species 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- 235000015278 beef Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 2
- 235000017491 Bambusa tulda Nutrition 0.000 description 2
- 239000004278 EU approved seasoning Substances 0.000 description 2
- 244000082204 Phyllostachys viridis Species 0.000 description 2
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 239000008122 artificial sweetener Substances 0.000 description 2
- 235000021311 artificial sweeteners Nutrition 0.000 description 2
- 239000011425 bamboo Substances 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 235000019658 bitter taste Nutrition 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 235000011194 food seasoning agent Nutrition 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000005457 ice water Substances 0.000 description 2
- 239000002075 main ingredient Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 235000013923 monosodium glutamate Nutrition 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 2
- 239000004302 potassium sorbate Substances 0.000 description 2
- 235000010241 potassium sorbate Nutrition 0.000 description 2
- 229940069338 potassium sorbate Drugs 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- 229940073490 sodium glutamate Drugs 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- FTLYMKDSHNWQKD-UHFFFAOYSA-N (2,4,5-trichlorophenyl)boronic acid Chemical compound OB(O)C1=CC(Cl)=C(Cl)C=C1Cl FTLYMKDSHNWQKD-UHFFFAOYSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 1
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- 239000004378 Glycyrrhizin Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- YBHQCJILTOVLHD-YVMONPNESA-N Mirin Chemical compound S1C(N)=NC(=O)\C1=C\C1=CC=C(O)C=C1 YBHQCJILTOVLHD-YVMONPNESA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 244000228451 Stevia rebaudiana Species 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 235000013334 alcoholic beverage Nutrition 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 235000021120 animal protein Nutrition 0.000 description 1
- 235000019606 astringent taste Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 235000014103 egg white Nutrition 0.000 description 1
- 210000000969 egg white Anatomy 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000011087 fumaric acid Nutrition 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229960002449 glycine Drugs 0.000 description 1
- LPLVUJXQOOQHMX-UHFFFAOYSA-N glycyrrhetinic acid glycoside Natural products C1CC(C2C(C3(CCC4(C)CCC(C)(CC4C3=CC2=O)C(O)=O)C)(C)CC2)(C)C2C(C)(C)C1OC1OC(C(O)=O)C(O)C(O)C1OC1OC(C(O)=O)C(O)C(O)C1O LPLVUJXQOOQHMX-UHFFFAOYSA-N 0.000 description 1
- 229960004949 glycyrrhizic acid Drugs 0.000 description 1
- UYRUBYNTXSDKQT-UHFFFAOYSA-N glycyrrhizic acid Natural products CC1(C)C(CCC2(C)C1CCC3(C)C2C(=O)C=C4C5CC(C)(CCC5(C)CCC34C)C(=O)O)OC6OC(C(O)C(O)C6OC7OC(O)C(O)C(O)C7C(=O)O)C(=O)O UYRUBYNTXSDKQT-UHFFFAOYSA-N 0.000 description 1
- 235000019410 glycyrrhizin Nutrition 0.000 description 1
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 235000021096 natural sweeteners Nutrition 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000014594 pastries Nutrition 0.000 description 1
- 229940099402 potassium metaphosphate Drugs 0.000 description 1
- 235000019828 potassium polyphosphate Nutrition 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- HELXLJCILKEWJH-NCGAPWICSA-N rebaudioside A Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@]12C(=C)C[C@@]3(C1)CC[C@@H]1[C@@](C)(CCC[C@]1([C@@H]3CC2)C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HELXLJCILKEWJH-NCGAPWICSA-N 0.000 description 1
- 229940085605 saccharin sodium Drugs 0.000 description 1
- 235000019643 salty taste Nutrition 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 235000013580 sausages Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 235000019983 sodium metaphosphate Nutrition 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
Description
本発明は水産ねり製品の保存性および風味の改
良法に関する。
従来、竹輪や蒲鉾などの水産ねり製品の保存剤
あるいは殺菌剤としてコーテイングソルビン酸、
ソルビン酸、ソルビン酸カリウムなどのソルビン
酸類やグリシンなどが使用されている。しかしこ
れらの添加剤の使用により水産ねり製品の品質が
低下するという欠点があつた。たとえば、ソルビ
ン酸は特有のしぶ味を有しており水産ねり製品の
風味をそこない、またすり身のPHを低下させ製品
の弾力に対して悪影響をおよぼす。このソルビン
酸の欠点を改善するものとして微粉砕したソルビ
ン酸を融点40℃以上の硬化油類を主剤とするコー
テイング剤で被覆したコーテイングソルビン酸が
近年使用されはじめた。しかしながら、コーテイ
ングソルビン酸の添加によりコーテイング剤とし
て使用される硬化油類に主として由来するろう
臭、えぐ臭、えぐ味、しぶ味などの好ましくない
臭いや味が認められ、水産ねり製品の風味を著し
く低下させるという欠点がある。グリシンは特に
0.5%以上添加されると得られた水産ねり製品は
風味が劣化するばかりか、渋味や苦味、エビ様の
悪臭を生じ、また高温加熱時淡黄色に変色して品
性を失つてしまうため、到底実用的ではなく、こ
のためグリシンを添加するとしても品質を損わな
い程度のごく少量しか添加し得ないことが、本発
明者らの研究によつてわかつた。
本発明者らは、これら欠点を悉く解決するため
に鋭意研究した結果、本発明を完成するに至つ
た。
すなわち、本発明は水産ねり製品の製造に際
し、仕上がりねり肉量に対して、コーテイングエ
リソルビン酸類(エリソルビン酸として)を0.02
〜0.2重量%とソルビン酸類(ソルビン酸とし
て)を0.02〜0.2重量%および(または)グリシ
ンを0.4〜2.5重量%の割合で混和することを特徴
とする水産ねり製品の保存性および風味の改良法
である。
本発明の対象とする水産ねり製品とは、たとえ
ば蒲鉾、竹輪、てんぷら、はんぺん、魚肉ソーセ
ージなどの魚肉加工食品が挙げられる。これらの
ねり製品は無包装のものでも、ケーシング蒲鉾、
リテーナー蒲鉾、真空包装蒲鉾などの合成樹脂な
どの袋内に密封したものでもよいが、特に包装製
品に有効である。また出来上がり製品(または仕
上がりねり肉)のPHが弱酸性、中性あるいは弱ア
ルカリ性のものでもよい。
次に、本発明にいうコーテイングソルビン酸類
としては、エリソルビン酸やエリソルビン酸ナト
リウムなどのアルカリ金属塩などを、たとえば後
述するコーテイング加工したものが挙げられ、ま
たソルビン酸類としてはコーテイングソルビン
酸、ソルビン酸、ソルビン酸カリウムなどのアル
カリ金属塩などが挙げられる。
本発明で使用されるコーテイングソルビン酸は
従来公知の方法、すなわち微粉砕したソルビン酸
を融点40〜90℃程度の植物性または動物性の硬化
油、たとえば菜種硬化油、ひまし硬化油、鯨油硬
化油、牛脂硬化油、ヤシ油硬化油などを主剤と
し、ステアリン酸、パルミチン酸などの炭素数12
〜24の飽和脂肪酸やソルビタンモノパルミテー
ト、ソルビタンセスキオレートなどのソルビタン
脂肪酸エステルを適宜併用したコーテイング剤で
回転円板型遠心アトマイザーなどを用いてコーテ
イングすることにより製造することがきる。
このような製造法によれば、ソルビン酸1部に
対して0.7〜10部程度のコーテイング剤を用いて
ソルビン酸をコーテイングすることができるが、
コーテイング剤を多量に用いたコーテイングソル
ビン酸を使用すると好ましくない風味を有する硬
化油が多量にねり製品に添加されることになり、
またコーテイング剤が少量すぎるとソルビン酸が
十分にコーテイングされない場合もあるため、一
般にソルビン酸1部に対してコーテイング剤0.8
〜3部程度の割合でコーテイングしたものを使用
するのが好ましい。
また、コーテイングエリソルビン酸やコーテイ
ングエリソルビン酸ナトリウムなどはコーテイン
グソルビン酸と同様のコーテイング剤を用いて同
様の方法により製造することができるが、本発明
においては、エリソルビン酸またはエリソルビン
酸ナトリウム1部に対して0.8〜3部程度のコー
テイング剤を用いてコーテイングしたコーテイン
グエリソルビン酸またはエリソルビン酸ナトリウ
ムを用いるのが好ましい。またその粒径としては
通常50〜300μ程度のものが適当である。このよ
うなコーテイングエリソルビン酸類はリテーナー
蒲鉾、スワリ蒲鉾などの長時間加工を要するねり
製品においても製造工程中での分解変化が起りに
くく、効果的に作用する効果がある。さらに、前
述したとおりグリシン含有水産ねり製品は、加熱
処理に際して品質を低下させている事から考えて
も加熱処理時に溶解し、その効力を発する様にコ
ーテイング加工されたエリソルビン酸類が特に適
している。
本発明においてはコーテイングエリソルビン酸
とソルビン酸類および(または)グリシンが水産
ねり製品の製造工程中に水産ねり製品に添加され
均一に混和される。これら添加物の添加時期や添
加方法については特に制限はなく一般に、次に述
べるような添加剤と同時に又は仕上りすり身の調
製時に添加混和するのが適当である。
本発明の水産ねり製品に際し、本目的を阻害し
ない限り、従来より水産ねり製品に添加されてい
るりん酸塩類(例、ポリリン酸ナトリウム、ポリ
リン酸カリウム、ピロリン酸ナトリウム、ピロリ
ン酸カリウム、メタリン酸ナトリウム、メタリン
酸カリウム)、有機酸類(例、フマル酸、クエン
酸、酒石酸、リンゴ酸、フマル酸モノナトリウ
ム)やこれらのコーテイング有機酸類、天然甘味
料(例、砂糖、ブドウ糖、果糖、乳糖)、人工甘
味料(例、サツカリンナトリウム、グリチルリチ
ン、ステビヤ)、その香料、香辛料、化学調味
料、天然調味料、糊料、殺菌剤、大豆蛋白質、小
麦蛋白質、動物性蛋白質(例、卵白)、酒類、野
菜などを適宜添加してもよい。
得られたねり肉を適宜成形し、あるいは合成樹
脂製の袋等に充填したのち、常法のごとく加熱処
理して製品を製造する。ところで水産ねり製品を
袋詰した場合には、通常特有の臭いが付き、品質
上好ましくない。この特異臭はフマル酸を添加す
ることにより防止しうる。通常フマル酸は仕上り
ねり肉量に対し約0.02〜0.2%(重量)を添加す
るとよく、殊にコーテイング加工したフマル酸を
使用すると特に良い効果が認められる。
さらに、本発明において炭素数8〜12のノルマ
ル飽和脂肪酸モノグリセライドを仕上りねり肉量
に対し約0.02〜0.08%(重量)の割合で併用する
と変質防止効果が一層増強される。
本発明により製造された水産ねり製品は、コー
テイングソルビン酸、コーテイングエリソルビン
酸類および通常併用されるコーテイング有機酸類
のコーテイング剤として使用される硬化油のろう
臭、えぐ臭、しぶ味、にが味、えぐ味、などや、
ソルビン酸、リン酸塩類に由来するしぶ味、えぐ
味などが減少され、また本発明のようにきわめて
多量のグリシンが添加されても製品の風味は何ら
損われないばかりか製品にカツオ風の風味がで、
さらにはケーシング蒲鉾やリテーナー蒲鉾などの
密封包装製品などにおいて特に保存性が高められ
るなどの効果が認められる。
以下に実験例および実施例を挙げて、本発明を
具体的に説明する。
なお、実験例および実施例において使用された
コーテイングソルビン酸、コーテイングフマル
酸、コーテイングエリソルビン酸およびコーテイ
ングエリソルビン酸ナトリウムはそれぞれ次のと
おり製造されたものである。
コーテイングソルビン酸:ソルビン酸40部と牛脂
硬化油60部を用いて噴霧造粒したもの
コーテイングフマル酸:フマル酸30部と牛脂硬化
油70部を用いて噴霧造粒したもの
コーテイングソルビン酸およびコーテイングエリ
ソルビン酸ナトリウム:エリソルビン酸またはエ
リソルビン酸ナトリウム30部と牛脂硬化油70部
を用いて噴霧造粒したもの
実験例 1
スケソー冷凍スリ身6Kg、氷水2.9Kg、バレイ
シヨ澱粉400g、食塩156g、砂糖52g、グリタミ
ン酸ソーダ52g、ミリン80mlおよび重合リン酸塩
16gの原料配合にて常法通り製造した仕上りスリ
身に第1表および第2表に記載の添加剤をそれぞ
れ加え、よく混合した後、合成樹脂チーブにケー
シング詰とし、40℃の温水中で40分間スワリを行
つた後、85℃の熱水中で45分間加熱処理して製造
した高温スワリかまぼこを24時間室温に放置した
ものについて習熟したパネル10名により比較試験
を行つた。その結果は第1表および第2表に示す
とおりであつた。
The present invention relates to a method for improving the shelf life and flavor of seafood paste products. Conventionally, coating sorbic acid,
Sorbates such as sorbic acid and potassium sorbate, and glycine are used. However, the use of these additives had the disadvantage that the quality of seafood paste products deteriorated. For example, sorbic acid has a characteristic astringent taste that impairs the flavor of seafood paste products, and also lowers the pH of surimi, which has an adverse effect on the elasticity of the product. In order to improve this drawback of sorbic acid, coating sorbic acid, in which finely ground sorbic acid is coated with a coating agent whose main ingredient is a hydrogenated oil with a melting point of 40° C. or higher, has recently begun to be used. However, due to the addition of coating sorbic acid, undesirable odors and tastes such as waxy, acrid, acrid, and musty tastes mainly derived from the hydrogenated oils used as coating agents were observed, and the flavor of seafood paste products was significantly affected. It has the disadvantage of lowering Glycine is especially
If more than 0.5% is added, the resulting seafood paste product will not only deteriorate in flavor, but will also develop an astringent, bitter, and shrimp-like odor, and will turn pale yellow and lose its quality when heated at high temperatures. The inventors' research has revealed that this is completely impractical, and that even if glycine is added, it can only be added in a very small amount that does not impair quality. The present inventors have completed the present invention as a result of intensive research to solve all of these drawbacks. That is, in the present invention, when manufacturing seafood batter products, the amount of coating erythorbic acids (as erythorbic acid) is 0.02% of the amount of finished batter.
A method for improving the shelf life and flavor of seafood paste products, characterized by mixing ~0.2% by weight with sorbic acids (as sorbic acid) in a proportion of 0.02-0.2% by weight and/or glycine in a proportion of 0.4-2.5% by weight. It is. The seafood paste products targeted by the present invention include, for example, processed fish foods such as kamaboko, chikuwa, tempura, hanpen, and fish sausage. These pastry products can be unwrapped, casing kamaboko,
It may be sealed in a bag made of synthetic resin, such as retainer kamaboko or vacuum-packed kamaboko, but it is particularly effective for packaged products. Further, the pH of the finished product (or finished batter) may be weakly acidic, neutral or slightly alkaline. Next, the coating sorbic acids referred to in the present invention include those obtained by coating erythorbic acid, alkali metal salts such as sodium erythorbate, etc., as described below, and examples of the sorbic acids include coating sorbic acids, sorbic acid, Examples include alkali metal salts such as potassium sorbate. The coating sorbic acid used in the present invention can be obtained by a conventionally known method, that is, finely ground sorbic acid is mixed with a vegetable or animal hydrogenated oil having a melting point of about 40 to 90°C, such as hydrogenated rapeseed oil, hydrogenated castor oil, hydrogenated whale oil. The main ingredients are oil, hydrogenated beef tallow oil, hydrogenated coconut oil, etc., and 12 carbon atoms such as stearic acid and palmitic acid.
It can be produced by coating using a rotating disc type centrifugal atomizer or the like with a coating agent containing 24 saturated fatty acids and sorbitan fatty acid esters such as sorbitan monopalmitate and sorbitan sesquiolate. According to such a production method, sorbic acid can be coated using about 0.7 to 10 parts of coating agent per 1 part of sorbic acid.
Coatings using large amounts of coating agentsWhen using sorbic acid, large amounts of hydrogenated oil with an unpleasant flavor are added to the batter product.
Also, if the coating agent is too small, the sorbic acid may not be coated sufficiently, so generally 0.8 parts of the coating agent is applied to 1 part of sorbic acid.
It is preferable to use one coated at a ratio of about 3 parts to 3 parts. Furthermore, coating erythorbic acid, coating sodium erythorbate, etc. can be produced using the same coating agent and the same method as coating sorbic acid, but in the present invention, 1 part of erythorbic acid or sodium erythorbate It is preferable to use coated erythorbic acid or sodium erythorbate coated with about 0.8 to 3 parts of a coating agent. Moreover, the particle size is usually about 50 to 300 μm. Such coating erythorbic acids are effective in preventing decomposition changes during the manufacturing process, even in pasted products such as retainer kamaboko and suwari kamaboko that require long processing. Furthermore, as mentioned above, considering that the quality of glycine-containing seafood paste products is reduced during heat treatment, erythorbic acids that are coated to dissolve during heat treatment and exhibit their effectiveness are particularly suitable. In the present invention, coating erythorbic acid, sorbic acids, and/or glycine are added to the seafood paste product during the manufacturing process of the seafood paste product and mixed uniformly. There are no particular restrictions on the timing or method of adding these additives, and in general, it is appropriate to add and mix them at the same time as the following additives or when preparing the finished surimi. When making the seafood paste product of the present invention, phosphates that have been conventionally added to seafood paste products (e.g., sodium polyphosphate, potassium polyphosphate, sodium pyrophosphate, potassium pyrophosphate, sodium metaphosphate) may be used as long as they do not impede the purpose. , potassium metaphosphate), organic acids (e.g. fumaric acid, citric acid, tartaric acid, malic acid, monosodium fumarate) and their coatings, natural sweeteners (e.g. sugar, glucose, fructose, lactose), artificial Sweeteners (e.g., saccharin sodium, glycyrrhizin, stevia), flavorings, spices, chemical seasonings, natural seasonings, thickeners, fungicides, soy protein, wheat protein, animal protein (e.g., egg white), alcoholic beverages, Vegetables etc. may be added as appropriate. The obtained batter is shaped as appropriate or filled into a synthetic resin bag or the like, and then heat-treated in a conventional manner to produce a product. By the way, when seafood paste products are packaged in bags, they usually have a characteristic odor, which is unfavorable in terms of quality. This peculiar odor can be prevented by adding fumaric acid. Generally, fumaric acid is preferably added in an amount of about 0.02 to 0.2% (by weight) based on the amount of finished batter, and especially good effects are observed when coated fumaric acid is used. Further, in the present invention, when a normal saturated fatty acid monoglyceride having 8 to 12 carbon atoms is used in a proportion of about 0.02 to 0.08% (by weight) based on the amount of finished battered meat, the deterioration prevention effect is further enhanced. The seafood paste product produced according to the present invention has a waxy odor, acrid odor, a salty taste, a bitter taste, and an acrid taste due to the hydrogenated oil used as a coating agent for coating sorbic acid, coating erythorbic acid, and coating organic acids that are usually used in combination. taste, etc.
The bitter taste and harsh taste derived from sorbic acid and phosphates are reduced, and even when a very large amount of glycine is added as in the present invention, the flavor of the product is not impaired at all, and the product has a bonito-like flavor. Gade,
Furthermore, it has been found to be particularly effective in improving the shelf life of sealed packaged products such as casing kamaboko and retainer kamaboko. The present invention will be specifically explained below with reference to Experimental Examples and Examples. The coating sorbic acid, coating fumaric acid, coating erythorbic acid, and coating sodium erythorbate used in the experimental examples and examples were each manufactured as follows. Coating sorbic acid: Spray granulated using 40 parts sorbic acid and 60 parts hydrogenated beef tallow Coating fumaric acid: Spray granulated using 30 parts fumaric acid and 70 parts hydrogenated tallow oil Coating sorbic acid and coating erythorbine Sodium acid: Spray granulated using 30 parts of erythorbic acid or sodium erythorbate and 70 parts of hydrogenated beef tallow Experimental example 1 6 kg of frozen sukeso fish, 2.9 kg of ice water, 400 g of potato starch, 156 g of salt, 52 g of sugar, glitamic acid 52g of soda, 80ml of Mirin and polymerized phosphate
The additives listed in Tables 1 and 2 were added to the finished surimi prepared in a conventional manner using 16 g of raw materials, mixed well, packed in a synthetic resin tube in casings, and placed in hot water at 40°C. A comparative test was conducted by 10 experienced panelists on high-temperature Suwari kamaboko prepared by heating in 85°C hot water for 45 minutes after swariing for 40 minutes, and leaving it at room temperature for 24 hours. The results were as shown in Tables 1 and 2.
【表】【table】
【表】
(注) 表中、+は良好、−は不良であり、それぞ
れ数の大きい程良好または不良となること
を示す。
実験例 2
スケソー冷凍スリ身(C級)27Kg、冷水8Kg、
小麦粉5Kg、ぶどう糖40g、グルタミン酸ソーダ
260g、人工甘味料製剤30g、食塩780gおよび重
合リン酸塩80gの原料配合にて、製造した仕上り
スリ身を10等分し各区分ごとに第3表に記載の添
加剤をそれぞれ加え、よく混合した後、クシに巻
付け電熱式焼炉により常法通り焼き上げ竹輪を製
造した。24時間室温にて放置したものをパネル評
価した。その結果は第3表に示すとおりであつ
た。[Table] (Note) In the table, + means good and - means bad.
The higher the number, the better or worse.
shows.
Experimental example 2 Sukeso frozen surimi (C grade) 27Kg, cold water 8Kg,
5 kg of flour, 40 g of glucose, sodium glutamate
Divide the finished surimi into 10 equal parts, add the additives listed in Table 3 to each category, and mix well. After that, the pieces were wrapped around a comb and baked in an electric kiln in a conventional manner to produce bamboo leaves. Panel evaluation was carried out after leaving it at room temperature for 24 hours. The results were as shown in Table 3.
【表】【table】
【表】
実施例 1
スケソー冷凍スリ身(特級)27Kg、氷水15Kg、
バレイシヨ澱粉2Kg、食塩780g、砂糖260g、グ
リタミン酸ソーダ260g、ミリン400ml及び重合リ
ン酸塩80gの原料配合にて製造した仕上りスリ身
を10等分し各々の区分ごとに第4表に記載の添加
剤をそこに示す量でそれぞれ加え、よく混合した
後、板付けし合成樹脂シートで包装し、10℃で24
時間、スワリを行つた後、蒸煮しリテーナーかま
ぼこを試作した。それを一昼夜室温に放置し、そ
の風味をパネルテストにより評価した。なお35℃
のフランキ中にて保存試験を行つた。その結果は
第4表に示すとおりであつた。[Table] Example 1 Frozen Sukeso Surimi (special grade) 27Kg, ice water 15Kg,
Divide the finished surimi into 10 equal parts and add the ingredients listed in Table 4 to each category. After adding the indicated amount of each agent and mixing well, attach it to a board, wrap it in a synthetic resin sheet, and store it at 10℃ for 24 hours.
After a few hours of swari, I made a prototype of steamed retainer kamaboko. It was left at room temperature for a day and night, and its flavor was evaluated by a panel test. In addition, 35℃
A storage test was conducted in Franchi. The results were as shown in Table 4.
【表】【table】
【表】
実施例 2
スケソー冷凍スリ身(C級)5.4Kg、冷水1.2
Kg、小麦粉1.2Kg、ぶどう糖6g、グリタミン酸
ソーダ60g、人工甘味料製剤5g、食塩120gお
よび重合リン酸塩15gの原料配合にて製造した仕
上りスリ身を4等分し各々の区分ごとに第5表に
記載の添加剤をそれぞれ加えよく混合し成形後
130℃程度の油の中で7分間揚げた後、一昼夜室
温にて放置しその風味をパネルテストにより評価
した。その結果は第5表に示すとおりであつた。[Table] Example 2 Frozen Sukeso Surimi (C grade) 5.4Kg, cold water 1.2
Divide the finished surimi into four equal parts, and divide the finished surimi into four equal parts. After adding the additives listed in the table and mixing well,
After frying in oil at about 130°C for 7 minutes, the pieces were left at room temperature overnight and their flavor was evaluated by a panel test. The results were as shown in Table 5.
【表】【table】
【表】
実施例 3
スケソー冷凍スリ身(C級)5.4Kg、冷水1
Kg、小麦粉1Kg、ぶどう糖7g、グリタミン酸ソ
ーダ70g、人工甘味料製剤4g、食塩140gおよ
び重合リン酸塩12gの原料配合にて製造した仕上
りスリ身を5等分し、各区分ごとに第6表に記載
の添加剤を、そこに示す量でそれぞれ加えよく混
合した後、クシに巻付け電熱式焼炉により常法に
もとづき焼き上げ竹輪を製造した。その製品を24
時間室温にて放置後、習熟したパネル10名により
最も良いを10点、最も不良を1点として採点しそ
の品質を評価した。その結果は第6表に示すとお
りであつた。[Table] Example 3 Frozen Sukeso Surimi (C grade) 5.4Kg, cold water 1
The finished surimi produced using the raw material combination of 1 kg of wheat flour, 7 g of glucose, 70 g of sodium glutamate, 4 g of artificial sweetener preparation, 140 g of salt, and 12 g of polymerized phosphate is divided into 5 equal parts, and Table 6 is shown for each division. The additives described in 1. were added in the amounts indicated therein, mixed well, and then wrapped around a comb and baked in an electric kiln to produce bamboo shoots according to a conventional method. 24 products
After being left at room temperature for an hour, the quality was evaluated by 10 experienced panelists, with 10 points being the best and 1 point being the worst. The results were as shown in Table 6.
Claims (1)
量に対してコーテイングエリソルビン酸類(エリ
ソルビン酸として)を0.02〜0.2重量%とソルビ
ン酸類(ソルビン酸として)を0.02〜0.2重量%
および(または)グリシンを0.4〜2.5重量%の割
合で混和することを特徴とする水産ねり製品の保
存性および風味の改良法。1. When manufacturing seafood paste products, coating erythorbic acids (as erythorbic acid) and sorbic acids (as sorbic acid) at 0.02 to 0.2% by weight and 0.02 to 0.2% by weight, respectively, based on the amount of finished batter.
and/or a method for improving the shelf life and flavor of seafood paste products, characterized by incorporating glycine in a proportion of 0.4 to 2.5% by weight.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6680480A JPS56164771A (en) | 1980-05-19 | 1980-05-19 | Improvement of preservation and flavor of marine paste product |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6680480A JPS56164771A (en) | 1980-05-19 | 1980-05-19 | Improvement of preservation and flavor of marine paste product |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS56164771A JPS56164771A (en) | 1981-12-17 |
JPS6240987B2 true JPS6240987B2 (en) | 1987-09-01 |
Family
ID=13326413
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6680480A Granted JPS56164771A (en) | 1980-05-19 | 1980-05-19 | Improvement of preservation and flavor of marine paste product |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS56164771A (en) |
-
1980
- 1980-05-19 JP JP6680480A patent/JPS56164771A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS56164771A (en) | 1981-12-17 |
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