JPS642350B2 - - Google Patents
Info
- Publication number
- JPS642350B2 JPS642350B2 JP54155239A JP15523979A JPS642350B2 JP S642350 B2 JPS642350 B2 JP S642350B2 JP 54155239 A JP54155239 A JP 54155239A JP 15523979 A JP15523979 A JP 15523979A JP S642350 B2 JPS642350 B2 JP S642350B2
- Authority
- JP
- Japan
- Prior art keywords
- ascorbic acid
- acid
- coating
- product
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 40
- 235000010323 ascorbic acid Nutrition 0.000 claims description 23
- 239000011668 ascorbic acid Substances 0.000 claims description 20
- 229960005070 ascorbic acid Drugs 0.000 claims description 20
- 239000011248 coating agent Substances 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 11
- 235000014102 seafood Nutrition 0.000 claims description 11
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 claims description 8
- 235000010378 sodium ascorbate Nutrition 0.000 claims description 8
- 229960005055 sodium ascorbate Drugs 0.000 claims description 8
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 235000013372 meat Nutrition 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 150000007513 acids Chemical class 0.000 claims description 4
- 238000002845 discoloration Methods 0.000 claims description 4
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 8
- 235000019465 surimi Nutrition 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 5
- 239000004471 Glycine Substances 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 241000251468 Actinopterygii Species 0.000 description 3
- 150000000996 L-ascorbic acids Chemical class 0.000 description 3
- YBHQCJILTOVLHD-YVMONPNESA-N Mirin Chemical compound S1C(N)=NC(=O)\C1=C\C1=CC=C(O)C=C1 YBHQCJILTOVLHD-YVMONPNESA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 239000005457 ice water Substances 0.000 description 3
- 235000013923 monosodium glutamate Nutrition 0.000 description 3
- 229940023462 paste product Drugs 0.000 description 3
- 229920001592 potato starch Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229940073490 sodium glutamate Drugs 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- 239000004278 EU approved seasoning Substances 0.000 description 2
- 235000011054 acetic acid Nutrition 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 235000019606 astringent taste Nutrition 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 235000011194 food seasoning agent Nutrition 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 235000011087 fumaric acid Nutrition 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 235000019830 sodium polyphosphate Nutrition 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 235000019640 taste Nutrition 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- FTLYMKDSHNWQKD-UHFFFAOYSA-N (2,4,5-trichlorophenyl)boronic acid Chemical compound OB(O)C1=CC(Cl)=C(Cl)C=C1Cl FTLYMKDSHNWQKD-UHFFFAOYSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- PHOQVHQSTUBQQK-SQOUGZDYSA-N D-glucono-1,5-lactone Chemical compound OC[C@H]1OC(=O)[C@H](O)[C@@H](O)[C@@H]1O PHOQVHQSTUBQQK-SQOUGZDYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 239000004378 Glycyrrhizin Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 244000228451 Stevia rebaudiana Species 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000013334 alcoholic beverage Nutrition 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 235000021120 animal protein Nutrition 0.000 description 1
- 239000008122 artificial sweetener Substances 0.000 description 1
- 235000021311 artificial sweeteners Nutrition 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000014103 egg white Nutrition 0.000 description 1
- 210000000969 egg white Anatomy 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229960002598 fumaric acid Drugs 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 235000012209 glucono delta-lactone Nutrition 0.000 description 1
- 239000000182 glucono-delta-lactone Substances 0.000 description 1
- 229960003681 gluconolactone Drugs 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- LPLVUJXQOOQHMX-UHFFFAOYSA-N glycyrrhetinic acid glycoside Natural products C1CC(C2C(C3(CCC4(C)CCC(C)(CC4C3=CC2=O)C(O)=O)C)(C)CC2)(C)C2C(C)(C)C1OC1OC(C(O)=O)C(O)C(O)C1OC1OC(C(O)=O)C(O)C(O)C1O LPLVUJXQOOQHMX-UHFFFAOYSA-N 0.000 description 1
- 229960004949 glycyrrhizic acid Drugs 0.000 description 1
- UYRUBYNTXSDKQT-UHFFFAOYSA-N glycyrrhizic acid Natural products CC1(C)C(CCC2(C)C1CCC3(C)C2C(=O)C=C4C5CC(C)(CCC5(C)CCC34C)C(=O)O)OC6OC(C(O)C(O)C6OC7OC(O)C(O)C(O)C7C(=O)O)C(=O)O UYRUBYNTXSDKQT-UHFFFAOYSA-N 0.000 description 1
- 235000019410 glycyrrhizin Nutrition 0.000 description 1
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 description 1
- 229940093915 gynecological organic acid Drugs 0.000 description 1
- 239000008172 hydrogenated vegetable oil Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 125000005341 metaphosphate group Chemical group 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 235000021096 natural sweeteners Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000014594 pastries Nutrition 0.000 description 1
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 description 1
- 235000019828 potassium polyphosphate Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 229940048084 pyrophosphate Drugs 0.000 description 1
- HELXLJCILKEWJH-NCGAPWICSA-N rebaudioside A Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@]12C(=C)C[C@@]3(C1)CC[C@@H]1[C@@](C)(CCC[C@]1([C@@H]3CC2)C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HELXLJCILKEWJH-NCGAPWICSA-N 0.000 description 1
- 229940085605 saccharin sodium Drugs 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000013580 sausages Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- -1 sorbitan fatty acid esters Chemical class 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
Description
本発明は水産ねり製品のアスコルビン酸に由来
する変色の防止法に関する。
コーテイングアスコルビン酸やアスコルビン酸
ナトリウムを水産ねり製品に添加することにより
たとえば、従来の殺菌剤もしくは保存剤の代替品
として使用されるグリシンに由来する渋味や、エ
ビ様の悪臭などによる風味の劣化の防止あるいは
併用するコーテイング有機酸類のコーテイング剤
として使用される硬化油のろう臭、しぶ味やえぐ
味、さらには重合リン酸塩類のしぶ味、えぐ味な
どを減少、また水産ねり製品にカツオ風の風味が
で、さらにケーシングかまぼこ、リテーナーかま
ぼこなどの真空密封包装製品などの包装製品や坐
りかまぼこなどに対して特に保存性が向上するな
どの効果が発揮される。
このような効果を奏するこれらアスコルビン酸
類を添加した水産ねり製品は日時の経過とともに
着色し、その商品が著しく損われるという欠点が
ある。
本発明者らは、この欠点を解決するために鋭意
研究した結果、本発明を完成するに至つた。
すなわち、本発明は仕上りねり肉にコーテイン
グアスコルビン酸および(または)アスコルビン
酸ナトリウムを混和して水産ねり製品を製造する
に際し、これらをアスコルビン酸として仕上りね
り肉に対して0.01〜0.3重量%添加し、さらにア
スコルビン酸以外の可食性酸を添加して、その製
品のPHを6.5〜7.0になるように調整することを特
徴とする水産ねり製品の変色防止法である。
本発明の対象とする水産ねり製品とは、たとえ
ばかまぼこ、ちくわ、はんぺん、天ぷら、魚肉ソ
ーセージ、魚肉ハムなどの魚肉加工食品が挙げら
れる。
次に、本発明で使用されるコーテイングアスコ
ルビン酸の製造法としては、微粉砕したアスコル
ビン酸を40〜90℃程度の植物性または動物性の硬
化油、たとえば菜種硬化油、ひまし油硬化油、鯨
油硬化油、牛脂硬化油、ヤシ油硬化油などを主剤
とし、必要に応じてステアリン酸、パルミチン酸
などの炭素数12〜24の飽和脂肪酸やソルビタンモ
ノパルミテート、ソルビタンセスキオレートなど
のソルビタン脂肪酸エステル、ワツクスを適宜併
用したコーテイング剤で回転円板型遠心アトマイ
ザー又はスプレー式装置を用いて造粒することに
より製造することができる。本発明においては、
アスコルビン酸1部に対して0.8〜10部、好まし
くは0.8〜3部程度のコーテイング剤を用いて造
粒したコーテイングアスコルビン酸を用いるのが
好ましく、またその粒径としては通常50〜300μ
程度ものが適当である。
また、アスコルビン酸ナトリウムは、食品衛生
上安全な品質のもので入手しやすい市販品を使用
すればよい。通常、コーテイングアスコルビン酸
および(または)アスコルビン酸ナトリウムは、
アスコルビン酸として仕上りねり肉に対して0.01
〜0.3重量%程度、好ましくは約0.02〜0.2重量%
使用される。
次に、水産ねり製品のPHが6.5〜7.0になるよう
に調整するために使用されるアスコルビン酸以外
の可食性酸としては、たとえばフマル酸、酒石
酸、グルコノデルタラクトン、リンゴ酸、第一リ
ン酸ナトリウム、ソルビン酸、クエン酸、酸性ピ
ロリン酸塩、酸性メタリン酸塩、粉末酢酸、フマ
ル酸一ナトリウムなど、好ましくはこれら酸類
を、公知方法に従い前述のコーテイング剤などを
用いてコーテイングを施したものが挙げられる。
またグルコン酸、酢酸、乳酸などの常温で液状の
ものも使用できる。
本発明においては、コーテイングアスコルビン
酸やアスコルビン酸ナトリウムおよび前記酸類が
水産ねり製品にその製造工程中に添加され均一に
混和されるが、その添加時期や添加方法について
は特に制限はなく、一般に次に述べるような添加
剤と同時に又は仕上りねり肉(すり身)に添加混
和するのが適当である。
本発明の方法においては、本目的を阻害しない
限り、従来より水産ねり製品に添加されるリン酸
塩類(たとえば、ポリリン酸ナトリウム、ポリリ
ン酸カリウム、ピロリン酸ナトリウム、ピロリン
酸カリウム)、天然甘味料(たとえば、砂糖、ブ
ドウ糖、果糖、乳糖)、人工甘味料(たとえば、
グリチルリチン、ステビヤ、サツカリンナトリウ
ム)、その他香辛料、香料、天然調味料、化学調
味料、糊料、殺菌剤、大豆蛋白質、小麦蛋白質、
動物性蛋白質(例、卵白)、酒類、野菜などを適
宜添加してもよい。
本発明方法によれば、原料ねり肉に、コーテイ
ングアスコルビン酸および(または)アスコルビ
ン酸ナトリウムを添加して製造された水産ねり製
品は、これらアスコルビン酸に由来する変色が防
止され、また風味も改善され、足や弾力が何ら損
われず商品性が一段と向上し、しかも変質防止さ
れた食品衛生上きわめて安全である。
次に、本発明を参考例、実験例および実施例に
よりさらに具体的に説明する。
なお以下の%(パーセント)はいづれも重量/
重量パーセントを表わす。
参考例
あらかじめ75℃にて加温溶解させた牛脂硬化油
70部に微粒末状アスコルビン酸30部を加え、ミキ
サーにてよく撹拌し、均一にしたペースト状混合
物を65〜70℃に保温し、ポンプにて遠心式噴霧装
置に送り、24℃に調温された室内に噴霧粒造し
た。この粒末を50メツシユにて篩過し、コーテイ
ングアスコルビン酸を得た。
以下実験例および実施例には、本コーテイング
アスコルビン酸を使用した。
実験例
スケソー冷凍スリ身特級12Kg、食塩360g、バ
レイシヨデンプン840g、グルタミン酸ソーダ120
g、重合リン酸塩18g、氷水4Kg、砂糖120g、
グリシン120g、及びミリン240gの原料配合にて
常法の通り製造したスリ身を等分し第1表に従い
各々コーテイングアスコルビン酸、アスコルビン
酸ナトリウム、及びフマル酸を添加よく混合し、
板付形成した後、常法に基づきリテーナーかまぼ
こを製造した。
この検体を4℃に15日間保管しその着色度を観
察した。その結果は第1表に示すとおりである。
The present invention relates to a method for preventing discoloration of seafood paste products caused by ascorbic acid. Coating By adding ascorbic acid or sodium ascorbate to seafood paste products, for example, the astringency caused by glycine, which is used as a substitute for conventional disinfectants or preservatives, and the deterioration of flavor due to shrimp-like odor can be reduced. Coatings that are used in conjunction with or in conjunction with organic acids to reduce the waxy odor, astringency, and acrid taste of hydrogenated oils used as coating agents, as well as the astringent and acrid taste of polymerized phosphates. It has a flavor and is particularly effective in improving the preservability of packaged products such as vacuum-sealed packaged products such as casing kamaboko and retainer kamaboko, and sitting kamaboko. Marine paste products to which these ascorbic acids are added, which have such effects, have the disadvantage that they become discolored over time, resulting in significant damage to the product. The present inventors conducted intensive research to solve this drawback, and as a result, completed the present invention. That is, in the present invention, when a coating ascorbic acid and/or sodium ascorbate is mixed with finished minced meat to produce a seafood paste product, 0.01 to 0.3% by weight of these as ascorbic acids are added to the finished minced meat, This is a method for preventing discoloration of seafood paste products, which is characterized by adding an edible acid other than ascorbic acid to adjust the pH of the product to 6.5 to 7.0. The seafood paste products targeted by the present invention include processed fish foods such as kamaboko, chikuwa, hanpen, tempura, fish sausage, and fish ham. Next, as a method for producing the coating ascorbic acid used in the present invention, finely pulverized ascorbic acid is heated to about 40 to 90°C using a hydrogenated vegetable or animal oil, such as hydrogenated rapeseed oil, hydrogenated castor oil, or hydrogenated whale oil. The main ingredients are oil, hydrogenated beef tallow oil, hydrogenated coconut oil, etc., and if necessary, saturated fatty acids with 12 to 24 carbon atoms such as stearic acid and palmitic acid, sorbitan fatty acid esters such as sorbitan monopalmitate and sorbitan sesquiolate, and wax. It can be produced by granulation using a rotating disc type centrifugal atomizer or a spray type device with a coating agent in combination with the appropriate amount. In the present invention,
It is preferable to use coated ascorbic acid that is granulated using a coating agent of 0.8 to 10 parts, preferably 0.8 to 3 parts, per 1 part of ascorbic acid, and the particle size is usually 50 to 300μ.
A moderate amount is appropriate. In addition, sodium ascorbate may be a commercially available product that is safe in terms of food hygiene and is easily available. Typically, coating ascorbic acid and/or sodium ascorbate is
Ascorbic acid: 0.01 for finished minced meat
~0.3% by weight, preferably about 0.02-0.2% by weight
used. Next, examples of edible acids other than ascorbic acid used to adjust the pH of seafood paste products to 6.5 to 7.0 include fumaric acid, tartaric acid, glucono delta-lactone, malic acid, and phosphorous acid. Sodium sorbic acid, citric acid, acid pyrophosphate, acid metaphosphate, powdered acetic acid, monosodium fumarate, etc., preferably coated with these acids using the above-mentioned coating agent or the like according to a known method. can be mentioned.
Also, those that are liquid at room temperature such as gluconic acid, acetic acid, and lactic acid can be used. In the present invention, coating ascorbic acid, sodium ascorbate, and the above-mentioned acids are added to the seafood paste product during the manufacturing process and mixed uniformly, but there are no particular restrictions on the timing or method of addition, and generally the following It is appropriate to add and mix it with the additives mentioned above or in the finished minced meat (surimi). In the method of the present invention, phosphates conventionally added to seafood paste products (e.g., sodium polyphosphate, potassium polyphosphate, sodium pyrophosphate, potassium pyrophosphate), natural sweeteners ( For example, sugar, glucose, fructose, lactose), artificial sweeteners (e.g.
glycyrrhizin, stevia, saccharin sodium), other spices, fragrances, natural seasonings, chemical seasonings, glues, fungicides, soy protein, wheat protein,
Animal protein (eg, egg white), alcoholic beverages, vegetables, etc. may be added as appropriate. According to the method of the present invention, the seafood paste product produced by adding coating ascorbic acid and/or sodium ascorbate to the raw pastry meat is prevented from discoloration caused by these ascorbic acids, and has an improved flavor. The product's product quality is further improved without any loss of elasticity or elasticity, and it is extremely safe from a food hygiene perspective as deterioration is prevented. Next, the present invention will be explained in more detail using reference examples, experimental examples, and examples. All percentages below are based on weight/
Represents weight percentage. Reference example Hydrogenated beef tallow oil heated and dissolved in advance at 75℃
Add 30 parts of fine powder ascorbic acid to 70 parts, stir well with a mixer, keep the homogeneous paste mixture at 65-70℃, send it to a centrifugal spray device with a pump, and adjust the temperature to 24℃. Spray granulation was carried out in the room where the product was placed. This powder was sieved through a 50-mesh sieve to obtain coating ascorbic acid. The present coating ascorbic acid was used in the following experimental examples and examples. Experimental example Frozen Surimi special grade 12kg, salt 360g, potato starch 840g, sodium glutamate 120g
g, polymerized phosphate 18g, ice water 4Kg, sugar 120g,
Surimi prepared in a conventional manner using a raw material composition of 120 g of glycine and 240 g of mirin was divided into equal parts, and coating ascorbic acid, sodium ascorbate, and fumaric acid were added to each according to Table 1 and mixed well.
After forming the plate, a retainer kamaboko was manufactured according to a conventional method. This sample was stored at 4°C for 15 days and its degree of coloration was observed. The results are shown in Table 1.
【表】
通りコーテイング処理を行つたものを使
用。
実施例 1
スケソー冷凍スリ身特級6000g、グルタミン酸
ソーダ60g、食塩120g、バレイシヨデンプン300
g、氷水2000g、ポリリン酸ナトリウム9g、ミ
リン60g、砂糖90g、及びグリシン30gの原料配
合にて常法に基づきスリ身を製造した。このスリ
身を等分し第2表の通り添加しよく混合した後、
折径90mmケーシングに充填し高温坐り加熱を行
い、高温坐りかまぼこを製造した。この検体を2
5℃に5日間保管しその着色度を比較した。その
結果は第2表に示すとおりである。[Table] Use the one that has been coated as shown.
Example 1 6000g of frozen Surimi special grade Sukeso, 60g of sodium glutamate, 120g of salt, 300g of potato starch
Surimi was prepared in a conventional manner using the following ingredients: g, 2000 g of ice water, 9 g of sodium polyphosphate, 60 g of mirin, 90 g of sugar, and 30 g of glycine. After dividing this surimi into equal parts and adding them as shown in Table 2 and mixing well,
It was filled into a casing with a folded diameter of 90 mm and heated at a high temperature to produce a high-temperature sitting kamaboko. This sample is 2
The samples were stored at 5°C for 5 days and the degree of coloration was compared. The results are shown in Table 2.
【表】【table】
【表】
実施例 2
スケソー冷凍スリ身特級6Kg、食塩120g、バ
レイシヨデンプン300g、グルタミン酸ソーダ60
g、重合リン酸塩10g、氷水1.5Kg、砂糖100g、
グリシン60g、ミリン120gの原料配合にて常法
の通り製造したスリ身を等分し第3表に記載の添
加剤を各々加え、よく混合し板付成形し13℃にて
20時間坐りを行つた後、リテーナーにセツトし85
℃45分蒸煮しリテーナー成形かまぼこを製造し
た。この検体を10℃に10日間保管しその着色度を
観察した。その結果は第3表に示すとおりであ
る。[Table] Example 2 Frozen Surimi special grade 6kg, salt 120g, potato starch 300g, sodium glutamate 60g
g, polymerized phosphate 10g, ice water 1.5Kg, sugar 100g,
Divide the surimi into equal parts using a conventional method using a raw material composition of 60 g of glycine and 120 g of mirin, add the additives listed in Table 3, mix well, form into a plate, and heat at 13°C.
After sitting for 20 hours, put on a retainer 85
The mixture was steamed at ℃ for 45 minutes to produce retainer-shaped kamaboko. This sample was stored at 10°C for 10 days and its degree of coloration was observed. The results are shown in Table 3.
【表】【table】
【表】
* 実験例と同様のもの使用
[Table] * Use the same items as in the experimental example
Claims (1)
および(または)アスコルビン酸ナトリウムを混
和して水産ねり製品を製造するに際し、これらを
アスコルビン酸として仕上りねり肉に対して0.01
〜0.3重量%添加し、さらにアスコルビン酸以外
の可食性酸を添加して、その製品のPHを6.5〜7.0
になるように調整することを特徴とする水産ねり
製品の変色防止法。1. When producing seafood paste products by mixing coating ascorbic acid and/or sodium ascorbate with finished minced meat, these are added as ascorbic acid to the finished minced meat at a rate of 0.01.
Add ~0.3% by weight and further add edible acids other than ascorbic acid to bring the product's pH to 6.5-7.0
A method for preventing discoloration of seafood paste products, which is characterized by adjusting the color so that
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15523979A JPS5678577A (en) | 1979-11-29 | 1979-11-29 | Prevention of change of color of aquatic paste food product |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15523979A JPS5678577A (en) | 1979-11-29 | 1979-11-29 | Prevention of change of color of aquatic paste food product |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5678577A JPS5678577A (en) | 1981-06-27 |
JPS642350B2 true JPS642350B2 (en) | 1989-01-17 |
Family
ID=15601571
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15523979A Granted JPS5678577A (en) | 1979-11-29 | 1979-11-29 | Prevention of change of color of aquatic paste food product |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5678577A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5911163A (en) * | 1982-07-08 | 1984-01-20 | Nippon Suisan Kaisha Ltd | Preparation of fibrous kamaboko-like food packed in container |
US4971821A (en) * | 1985-01-28 | 1990-11-20 | American National Can Company | Method of thermally processing seafood and package having the seafood therein |
JPH0827853A (en) * | 1994-07-18 | 1996-01-30 | Akira Niimura | Sink for removing oil on water surface in washing place |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5739698B2 (en) * | 1975-02-04 | 1982-08-23 |
-
1979
- 1979-11-29 JP JP15523979A patent/JPS5678577A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS5678577A (en) | 1981-06-27 |
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