JP7443339B2 - 効力の増強された農薬組成物 - Google Patents
効力の増強された農薬組成物 Download PDFInfo
- Publication number
- JP7443339B2 JP7443339B2 JP2021512110A JP2021512110A JP7443339B2 JP 7443339 B2 JP7443339 B2 JP 7443339B2 JP 2021512110 A JP2021512110 A JP 2021512110A JP 2021512110 A JP2021512110 A JP 2021512110A JP 7443339 B2 JP7443339 B2 JP 7443339B2
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- methyl
- potassium
- hydrogen atom
- halogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000000203 mixture Substances 0.000 title claims description 107
- 239000000575 pesticide Substances 0.000 title claims description 10
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 99
- 201000010099 disease Diseases 0.000 claims description 96
- -1 POA alkyl ether Chemical class 0.000 claims description 76
- 150000003839 salts Chemical class 0.000 claims description 51
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 47
- 239000002689 soil Substances 0.000 claims description 45
- 239000003905 agrochemical Substances 0.000 claims description 38
- KGVPNLBXJKTABS-UHFFFAOYSA-N hymexazol Chemical compound CC1=CC(O)=NO1 KGVPNLBXJKTABS-UHFFFAOYSA-N 0.000 claims description 36
- 239000002904 solvent Substances 0.000 claims description 30
- 239000002736 nonionic surfactant Substances 0.000 claims description 28
- 239000012872 agrochemical composition Substances 0.000 claims description 27
- 241000894006 Bacteria Species 0.000 claims description 26
- 239000003795 chemical substances by application Substances 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 25
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 25
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 claims description 22
- 241000223218 Fusarium Species 0.000 claims description 22
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 21
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 20
- 239000002253 acid Substances 0.000 claims description 19
- 239000012752 auxiliary agent Substances 0.000 claims description 19
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 19
- 241000233639 Pythium Species 0.000 claims description 18
- 239000003945 anionic surfactant Substances 0.000 claims description 18
- 230000000694 effects Effects 0.000 claims description 17
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 16
- 150000002148 esters Chemical class 0.000 claims description 16
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 15
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 13
- 235000000346 sugar Nutrition 0.000 claims description 13
- 241001444083 Aphanomyces Species 0.000 claims description 12
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 claims description 12
- 241001361634 Rhizoctonia Species 0.000 claims description 11
- 150000003973 alkyl amines Chemical class 0.000 claims description 11
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 9
- 150000005215 alkyl ethers Chemical class 0.000 claims description 9
- 239000011591 potassium Substances 0.000 claims description 9
- 229910052700 potassium Inorganic materials 0.000 claims description 9
- 235000011181 potassium carbonates Nutrition 0.000 claims description 9
- 241000221662 Sclerotinia Species 0.000 claims description 8
- 235000010235 potassium benzoate Nutrition 0.000 claims description 8
- 239000004300 potassium benzoate Substances 0.000 claims description 8
- 229940103091 potassium benzoate Drugs 0.000 claims description 8
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 claims description 7
- 239000001103 potassium chloride Substances 0.000 claims description 7
- 235000011164 potassium chloride Nutrition 0.000 claims description 7
- 235000010333 potassium nitrate Nutrition 0.000 claims description 7
- 239000004323 potassium nitrate Substances 0.000 claims description 7
- LPEKGGXMPWTOCB-UHFFFAOYSA-N 8beta-(2,3-epoxy-2-methylbutyryloxy)-14-acetoxytithifolin Natural products COC(=O)C(C)O LPEKGGXMPWTOCB-UHFFFAOYSA-N 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 6
- ODQWQRRAPPTVAG-GZTJUZNOSA-N doxepin Chemical compound C1OC2=CC=CC=C2C(=C/CCN(C)C)/C2=CC=CC=C21 ODQWQRRAPPTVAG-GZTJUZNOSA-N 0.000 claims description 6
- 229940116333 ethyl lactate Drugs 0.000 claims description 6
- WEFZXWJJPHGTTN-UHFFFAOYSA-N methyl 5-(dimethylamino)-2-methyl-5-oxopentanoate Chemical compound COC(=O)C(C)CCC(=O)N(C)C WEFZXWJJPHGTTN-UHFFFAOYSA-N 0.000 claims description 6
- 229940057867 methyl lactate Drugs 0.000 claims description 6
- 235000010241 potassium sorbate Nutrition 0.000 claims description 6
- 239000004302 potassium sorbate Substances 0.000 claims description 6
- 229940069338 potassium sorbate Drugs 0.000 claims description 6
- ILVGAIQLOCKNQA-UHFFFAOYSA-N propyl 2-hydroxypropanoate Chemical compound CCCOC(=O)C(C)O ILVGAIQLOCKNQA-UHFFFAOYSA-N 0.000 claims description 6
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 5
- MNHVNIJQQRJYDH-UHFFFAOYSA-N 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound N1=CNC(=S)N1CC(C1(Cl)CC1)(O)CC1=CC=CC=C1Cl MNHVNIJQQRJYDH-UHFFFAOYSA-N 0.000 claims description 5
- 241000222199 Colletotrichum Species 0.000 claims description 5
- 241001344133 Magnaporthe Species 0.000 claims description 5
- YKBZOVFACRVRJN-UHFFFAOYSA-N dinotefuran Chemical compound [O-][N+](=O)\N=C(/NC)NCC1CCOC1 YKBZOVFACRVRJN-UHFFFAOYSA-N 0.000 claims description 5
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 5
- 230000000361 pesticidal effect Effects 0.000 claims description 5
- IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 claims description 5
- 159000000000 sodium salts Chemical class 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims description 5
- 229940005740 hexametaphosphate Drugs 0.000 claims description 4
- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 4
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 4
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims description 4
- 239000001508 potassium citrate Substances 0.000 claims description 4
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 claims description 4
- PHZLMBHDXVLRIX-UHFFFAOYSA-M potassium lactate Chemical compound [K+].CC(O)C([O-])=O PHZLMBHDXVLRIX-UHFFFAOYSA-M 0.000 claims description 4
- 239000001521 potassium lactate Substances 0.000 claims description 4
- 235000011085 potassium lactate Nutrition 0.000 claims description 4
- 229960001304 potassium lactate Drugs 0.000 claims description 4
- RWPGFSMJFRPDDP-UHFFFAOYSA-L potassium metabisulfite Chemical compound [K+].[K+].[O-]S(=O)S([O-])(=O)=O RWPGFSMJFRPDDP-UHFFFAOYSA-L 0.000 claims description 4
- 235000010263 potassium metabisulphite Nutrition 0.000 claims description 4
- 235000015870 tripotassium citrate Nutrition 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 239000005825 Prothioconazole Substances 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- CWJSHJJYOPWUGX-UHFFFAOYSA-N chlorpropham Chemical compound CC(C)OC(=O)NC1=CC=CC(Cl)=C1 CWJSHJJYOPWUGX-UHFFFAOYSA-N 0.000 claims description 3
- 230000002708 enhancing effect Effects 0.000 claims description 3
- 239000003337 fertilizer Substances 0.000 claims description 3
- ZYMPPJSBWZSRMU-UHFFFAOYSA-N octan-3-yl 2-hydroxypropanoate Chemical compound CCCCCC(CC)OC(=O)C(C)O ZYMPPJSBWZSRMU-UHFFFAOYSA-N 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 125000003367 polycyclic group Chemical group 0.000 claims description 3
- VXPLXMJHHKHSOA-UHFFFAOYSA-N propham Chemical compound CC(C)OC(=O)NC1=CC=CC=C1 VXPLXMJHHKHSOA-UHFFFAOYSA-N 0.000 claims description 3
- WOSNCVAPUOFXEH-UHFFFAOYSA-N thifluzamide Chemical compound S1C(C)=NC(C(F)(F)F)=C1C(=O)NC1=C(Br)C=C(OC(F)(F)F)C=C1Br WOSNCVAPUOFXEH-UHFFFAOYSA-N 0.000 claims description 3
- 229940062627 tribasic potassium phosphate Drugs 0.000 claims description 3
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 38
- 125000005843 halogen group Chemical group 0.000 claims 24
- 125000004093 cyano group Chemical group *C#N 0.000 claims 22
- 229910052736 halogen Inorganic materials 0.000 claims 20
- 150000002367 halogens Chemical class 0.000 claims 20
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 12
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims 10
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 claims 8
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 8
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims 8
- 125000004414 alkyl thio group Chemical group 0.000 claims 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 8
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 8
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims 6
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims 6
- 125000004916 (C1-C6) alkylcarbonyl group Chemical group 0.000 claims 6
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 claims 6
- 125000003545 alkoxy group Chemical group 0.000 claims 6
- 125000004432 carbon atom Chemical group C* 0.000 claims 6
- 229910052801 chlorine Inorganic materials 0.000 claims 6
- 125000001309 chloro group Chemical group Cl* 0.000 claims 6
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 6
- 125000001424 substituent group Chemical group 0.000 claims 6
- 125000004769 (C1-C4) alkylsulfonyl group Chemical group 0.000 claims 4
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 claims 4
- 125000006650 (C2-C4) alkynyl group Chemical group 0.000 claims 4
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims 4
- 125000002947 alkylene group Chemical group 0.000 claims 4
- 125000004995 haloalkylthio group Chemical group 0.000 claims 4
- 229910052739 hydrogen Inorganic materials 0.000 claims 4
- 239000001257 hydrogen Substances 0.000 claims 4
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 4
- 229910052757 nitrogen Inorganic materials 0.000 claims 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 4
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims 4
- CSHOPPGMNYULAD-UHFFFAOYSA-N 1-tridecoxytridecane Chemical compound CCCCCCCCCCCCCOCCCCCCCCCCCCC CSHOPPGMNYULAD-UHFFFAOYSA-N 0.000 claims 2
- WIGIPJGWVLNDAF-UHFFFAOYSA-N 8-methyl-1-(8-methylnonoxy)nonane Chemical compound CC(C)CCCCCCCOCCCCCCCC(C)C WIGIPJGWVLNDAF-UHFFFAOYSA-N 0.000 claims 2
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 claims 2
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 claims 2
- 150000001204 N-oxides Chemical class 0.000 claims 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N N-phenyl amine Natural products NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims 2
- 125000003342 alkenyl group Chemical group 0.000 claims 2
- 125000005138 alkoxysulfonyl group Chemical group 0.000 claims 2
- 125000003282 alkyl amino group Chemical group 0.000 claims 2
- 125000004448 alkyl carbonyl group Chemical group 0.000 claims 2
- 125000005196 alkyl carbonyloxy group Chemical group 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000005278 alkyl sulfonyloxy group Chemical group 0.000 claims 2
- 125000005332 alkyl sulfoxy group Chemical group 0.000 claims 2
- 125000005530 alkylenedioxy group Chemical group 0.000 claims 2
- 125000005529 alkyleneoxy group Chemical group 0.000 claims 2
- 125000000304 alkynyl group Chemical group 0.000 claims 2
- 125000004103 aminoalkyl group Chemical group 0.000 claims 2
- 125000004429 atom Chemical group 0.000 claims 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N benzopyrrole Natural products C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims 2
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims 2
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 claims 2
- LFQRKUIOSYPVFY-UHFFFAOYSA-L dipotassium diacetate Chemical compound [K+].[K+].CC([O-])=O.CC([O-])=O LFQRKUIOSYPVFY-UHFFFAOYSA-L 0.000 claims 2
- 125000000262 haloalkenyl group Chemical group 0.000 claims 2
- 125000004692 haloalkylcarbonyl group Chemical group 0.000 claims 2
- 125000004441 haloalkylsulfonyl group Chemical group 0.000 claims 2
- 125000000232 haloalkynyl group Chemical group 0.000 claims 2
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 claims 2
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 claims 2
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 claims 2
- UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical group [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 claims 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims 2
- 229940093956 potassium carbonate Drugs 0.000 claims 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims 2
- 229910052939 potassium sulfate Inorganic materials 0.000 claims 2
- 235000011151 potassium sulphates Nutrition 0.000 claims 2
- 238000006467 substitution reaction Methods 0.000 claims 2
- 125000004434 sulfur atom Chemical group 0.000 claims 2
- 125000004001 thioalkyl group Chemical group 0.000 claims 2
- 125000005034 trifluormethylthio group Chemical group FC(S*)(F)F 0.000 claims 2
- 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 claims 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims 2
- 229910000160 potassium phosphate Inorganic materials 0.000 claims 1
- 235000011009 potassium phosphates Nutrition 0.000 claims 1
- 239000003112 inhibitor Substances 0.000 description 80
- 241000196324 Embryophyta Species 0.000 description 76
- 239000004094 surface-active agent Substances 0.000 description 43
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 29
- 238000012360 testing method Methods 0.000 description 27
- 230000015572 biosynthetic process Effects 0.000 description 25
- 241000233866 Fungi Species 0.000 description 21
- 239000004009 herbicide Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 230000006378 damage Effects 0.000 description 18
- 239000000417 fungicide Substances 0.000 description 18
- 238000009472 formulation Methods 0.000 description 16
- 240000007594 Oryza sativa Species 0.000 description 15
- 235000007164 Oryza sativa Nutrition 0.000 description 15
- 235000009566 rice Nutrition 0.000 description 15
- 239000004480 active ingredient Substances 0.000 description 14
- 230000001580 bacterial effect Effects 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 14
- 239000000843 powder Substances 0.000 description 14
- 241000233629 Phytophthora parasitica Species 0.000 description 13
- 241000223221 Fusarium oxysporum Species 0.000 description 12
- 102000019315 Nicotinic acetylcholine receptors Human genes 0.000 description 12
- 108050006807 Nicotinic acetylcholine receptors Proteins 0.000 description 12
- 241000813090 Rhizoctonia solani Species 0.000 description 12
- 235000014113 dietary fatty acids Nutrition 0.000 description 12
- 239000000194 fatty acid Substances 0.000 description 12
- 229930195729 fatty acid Natural products 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 241000588702 Pectobacterium carotovorum subsp. carotovorum Species 0.000 description 11
- 241000233679 Peronosporaceae Species 0.000 description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 11
- 238000002156 mixing Methods 0.000 description 11
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 10
- 241000221785 Erysiphales Species 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 238000005507 spraying Methods 0.000 description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 244000052769 pathogen Species 0.000 description 9
- 102000012440 Acetylcholinesterase Human genes 0.000 description 8
- 108010022752 Acetylcholinesterase Proteins 0.000 description 8
- 241000589155 Agrobacterium tumefaciens Species 0.000 description 8
- 241001529387 Colletotrichum gloeosporioides Species 0.000 description 8
- 235000002595 Solanum tuberosum Nutrition 0.000 description 8
- 244000061456 Solanum tuberosum Species 0.000 description 8
- 229940022698 acetylcholinesterase Drugs 0.000 description 8
- 150000001408 amides Chemical class 0.000 description 8
- 238000010790 dilution Methods 0.000 description 8
- 239000012895 dilution Substances 0.000 description 8
- 230000002363 herbicidal effect Effects 0.000 description 8
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 8
- 230000005787 mitochondrial ATP synthesis coupled electron transport Effects 0.000 description 8
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 241000193738 Bacillus anthracis Species 0.000 description 7
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 7
- 206010027146 Melanoderma Diseases 0.000 description 7
- 241000589623 Pseudomonas syringae pv. syringae Species 0.000 description 7
- 235000021536 Sugar beet Nutrition 0.000 description 7
- 239000003963 antioxidant agent Substances 0.000 description 7
- 235000006708 antioxidants Nutrition 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 150000003903 lactic acid esters Chemical class 0.000 description 7
- 102000000452 Acetyl-CoA carboxylase Human genes 0.000 description 6
- 108010016219 Acetyl-CoA carboxylase Proteins 0.000 description 6
- 108010018763 Biotin carboxylase Proteins 0.000 description 6
- 240000008067 Cucumis sativus Species 0.000 description 6
- 239000005754 Cyazofamid Substances 0.000 description 6
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 6
- 240000003768 Solanum lycopersicum Species 0.000 description 6
- 235000002597 Solanum melongena Nutrition 0.000 description 6
- 244000061458 Solanum melongena Species 0.000 description 6
- 240000008042 Zea mays Species 0.000 description 6
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 6
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 6
- 239000002518 antifoaming agent Substances 0.000 description 6
- 229910000278 bentonite Inorganic materials 0.000 description 6
- 235000005822 corn Nutrition 0.000 description 6
- YXKMMRDKEKCERS-UHFFFAOYSA-N cyazofamid Chemical compound CN(C)S(=O)(=O)N1C(C#N)=NC(Cl)=C1C1=CC=C(C)C=C1 YXKMMRDKEKCERS-UHFFFAOYSA-N 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 6
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- 239000002641 tar oil Substances 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 description 1
- ZZYSLNWGKKDOML-UHFFFAOYSA-N tebufenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(=CC=2)C(C)(C)C)=C1Cl ZZYSLNWGKKDOML-UHFFFAOYSA-N 0.000 description 1
- LWLJEQHTPVPKSJ-UHFFFAOYSA-N tebufloquin Chemical compound C1=C(C(C)(C)C)C=C2C(OC(=O)C)=C(C)C(C)=NC2=C1F LWLJEQHTPVPKSJ-UHFFFAOYSA-N 0.000 description 1
- AWYOMXWDGWUJHS-UHFFFAOYSA-N tebupirimfos Chemical compound CCOP(=S)(OC(C)C)OC1=CN=C(C(C)(C)C)N=C1 AWYOMXWDGWUJHS-UHFFFAOYSA-N 0.000 description 1
- ROZUQUDEWZIBHV-UHFFFAOYSA-N tecloftalam Chemical compound OC(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C(=O)NC1=CC=CC(Cl)=C1Cl ROZUQUDEWZIBHV-UHFFFAOYSA-N 0.000 description 1
- XQTLDIFVVHJORV-UHFFFAOYSA-N tecnazene Chemical compound [O-][N+](=O)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl XQTLDIFVVHJORV-UHFFFAOYSA-N 0.000 description 1
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
- IUQAXCIUEPFPSF-UHFFFAOYSA-N tembotrione Chemical compound ClC1=C(COCC(F)(F)F)C(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O IUQAXCIUEPFPSF-UHFFFAOYSA-N 0.000 description 1
- WWJZWCUNLNYYAU-UHFFFAOYSA-N temephos Chemical compound C1=CC(OP(=S)(OC)OC)=CC=C1SC1=CC=C(OP(=S)(OC)OC)C=C1 WWJZWCUNLNYYAU-UHFFFAOYSA-N 0.000 description 1
- DOMXUEMWDBAQBQ-WEVVVXLNSA-N terbinafine Chemical compound C1=CC=C2C(CN(C\C=C\C#CC(C)(C)C)C)=CC=CC2=C1 DOMXUEMWDBAQBQ-WEVVVXLNSA-N 0.000 description 1
- 229960002722 terbinafine Drugs 0.000 description 1
- IROINLKCQGIITA-UHFFFAOYSA-N terbutryn Chemical compound CCNC1=NC(NC(C)(C)C)=NC(SC)=N1 IROINLKCQGIITA-UHFFFAOYSA-N 0.000 description 1
- FZXISNSWEXTPMF-UHFFFAOYSA-N terbutylazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)(C)C)=N1 FZXISNSWEXTPMF-UHFFFAOYSA-N 0.000 description 1
- IWVCMVBTMGNXQD-UHFFFAOYSA-N terramycin dehydrate Natural products C1=CC=C2C(O)(C)C3C(O)C4C(N(C)C)C(O)=C(C(N)=O)C(=O)C4(O)C(O)=C3C(=O)C2=C1O IWVCMVBTMGNXQD-UHFFFAOYSA-N 0.000 description 1
- QQDYOLJZDUADHV-CJNGLKHVSA-N tetflupyrolimet Chemical compound FC1=C(C=CC=C1)NC(=O)[C@H]1C(N(C[C@@H]1C1=CC(=CC=C1)C(F)(F)F)C)=O QQDYOLJZDUADHV-CJNGLKHVSA-N 0.000 description 1
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 1
- UBCKGWBNUIFUST-YHYXMXQVSA-N tetrachlorvinphos Chemical compound COP(=O)(OC)O\C(=C/Cl)C1=CC(Cl)=C(Cl)C=C1Cl UBCKGWBNUIFUST-YHYXMXQVSA-N 0.000 description 1
- LITQZINTSYBKIU-UHFFFAOYSA-F tetracopper;hexahydroxide;sulfate Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[Cu+2].[O-]S([O-])(=O)=O LITQZINTSYBKIU-UHFFFAOYSA-F 0.000 description 1
- MLGCXEBRWGEOQX-UHFFFAOYSA-N tetradifon Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C1=CC(Cl)=C(Cl)C=C1Cl MLGCXEBRWGEOQX-UHFFFAOYSA-N 0.000 description 1
- KNDVJPKNBVIKML-UHFFFAOYSA-N tetraniliprole Chemical compound CNC(=O)C1=CC(C#N)=CC(C)=C1NC(=O)C1=CC(CN2N=C(N=N2)C(F)(F)F)=NN1C1=NC=CC=C1Cl KNDVJPKNBVIKML-UHFFFAOYSA-N 0.000 description 1
- 239000004308 thiabendazole Substances 0.000 description 1
- 235000010296 thiabendazole Nutrition 0.000 description 1
- 229960004546 thiabendazole Drugs 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- NWWZPOKUUAIXIW-FLIBITNWSA-N thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 description 1
- XSKZXGDFSCCXQX-UHFFFAOYSA-N thiencarbazone-methyl Chemical compound COC(=O)C1=CSC(C)=C1S(=O)(=O)NC(=O)N1C(=O)N(C)C(OC)=N1 XSKZXGDFSCCXQX-UHFFFAOYSA-N 0.000 description 1
- AHTPATJNIAFOLR-UHFFFAOYSA-N thifensulfuron-methyl Chemical group S1C=CC(S(=O)(=O)NC(=O)NC=2N=C(OC)N=C(C)N=2)=C1C(=O)OC AHTPATJNIAFOLR-UHFFFAOYSA-N 0.000 description 1
- DNVLJEWNNDHELH-UHFFFAOYSA-N thiocyclam Chemical compound CN(C)C1CSSSC1 DNVLJEWNNDHELH-UHFFFAOYSA-N 0.000 description 1
- BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 description 1
- OPASCBHCTNRLRM-UHFFFAOYSA-N thiometon Chemical compound CCSCCSP(=S)(OC)OC OPASCBHCTNRLRM-UHFFFAOYSA-N 0.000 description 1
- YFNCATAIYKQPOO-UHFFFAOYSA-N thiophanate Chemical compound CCOC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OCC YFNCATAIYKQPOO-UHFFFAOYSA-N 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 1
- MBNMHBAJUNHZRE-UHFFFAOYSA-M thiosultap monosodium Chemical compound [Na+].OS(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O MBNMHBAJUNHZRE-UHFFFAOYSA-M 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- VJQYLJSMBWXGDV-UHFFFAOYSA-N tiadinil Chemical compound N1=NSC(C(=O)NC=2C=C(Cl)C(C)=CC=2)=C1C VJQYLJSMBWXGDV-UHFFFAOYSA-N 0.000 description 1
- 229950007146 tigolaner Drugs 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 description 1
- RSOBJVBYZCMJOS-CYBMUJFWSA-N tolprocarb Chemical compound FC(F)(F)COC(=O)N[C@@H](C(C)C)CNC(=O)C1=CC=C(C)C=C1 RSOBJVBYZCMJOS-CYBMUJFWSA-N 0.000 description 1
- HYVWIQDYBVKITD-UHFFFAOYSA-N tolylfluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=C(C)C=C1 HYVWIQDYBVKITD-UHFFFAOYSA-N 0.000 description 1
- IYMLUHWAJFXAQP-UHFFFAOYSA-N topramezone Chemical compound CC1=C(C(=O)C2=C(N(C)N=C2)O)C=CC(S(C)(=O)=O)=C1C1=NOCC1 IYMLUHWAJFXAQP-UHFFFAOYSA-N 0.000 description 1
- DQFPEYARZIQXRM-LTGZKZEYSA-N tralkoxydim Chemical compound C1C(=O)C(C(/CC)=N/OCC)=C(O)CC1C1=C(C)C=C(C)C=C1C DQFPEYARZIQXRM-LTGZKZEYSA-N 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- XOPFESVZMSQIKC-UHFFFAOYSA-N triasulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)OCCCl)=N1 XOPFESVZMSQIKC-UHFFFAOYSA-N 0.000 description 1
- NKNFWVNSBIXGLL-UHFFFAOYSA-N triazamate Chemical compound CCOC(=O)CSC1=NC(C(C)(C)C)=NN1C(=O)N(C)C NKNFWVNSBIXGLL-UHFFFAOYSA-N 0.000 description 1
- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 description 1
- IQGKIPDJXCAMSM-UHFFFAOYSA-N triazoxide Chemical compound N=1C2=CC=C(Cl)C=C2[N+]([O-])=NC=1N1C=CN=C1 IQGKIPDJXCAMSM-UHFFFAOYSA-N 0.000 description 1
- YMXOXAPKZDWXLY-QWRGUYRKSA-N tribenuron methyl Chemical group COC(=O)[C@H]1CCCC[C@@H]1S(=O)(=O)NC(=O)N(C)C1=NC(C)=NC(OC)=N1 YMXOXAPKZDWXLY-QWRGUYRKSA-N 0.000 description 1
- ZOKXUAHZSKEQSS-UHFFFAOYSA-N tribufos Chemical compound CCCCSP(=O)(SCCCC)SCCCC ZOKXUAHZSKEQSS-UHFFFAOYSA-N 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- QFNFRZHOXWNWAQ-UHFFFAOYSA-N triclopyricarb Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NC(Cl)=C(Cl)C=C1Cl QFNFRZHOXWNWAQ-UHFFFAOYSA-N 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
- IMEVJVISCHQJRM-UHFFFAOYSA-N triflusulfuron-methyl Chemical group COC(=O)C1=CC=CC(C)=C1S(=O)(=O)NC(=O)NC1=NC(OCC(F)(F)F)=NC(N(C)C)=N1 IMEVJVISCHQJRM-UHFFFAOYSA-N 0.000 description 1
- RROQIUMZODEXOR-UHFFFAOYSA-N triforine Chemical compound O=CNC(C(Cl)(Cl)Cl)N1CCN(C(NC=O)C(Cl)(Cl)Cl)CC1 RROQIUMZODEXOR-UHFFFAOYSA-N 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- KVEQCVKVIFQSGC-UHFFFAOYSA-N tritosulfuron Chemical compound FC(F)(F)C1=NC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(F)(F)F)=N1 KVEQCVKVIFQSGC-UHFFFAOYSA-N 0.000 description 1
- DBHVHTPMRCXCIY-UHFFFAOYSA-N tyclopyrazoflor Chemical compound N1=C(Cl)C(N(C(=O)CCSCCC(F)(F)F)CC)=CN1C1=CC=CN=C1 DBHVHTPMRCXCIY-UHFFFAOYSA-N 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 235000016788 valerian Nutrition 0.000 description 1
- DBXFMOWZRXXBRN-LWKPJOBUSA-N valifenalate Chemical compound CC(C)OC(=O)N[C@@H](C(C)C)C(=O)NC(CC(=O)OC)C1=CC=C(Cl)C=C1 DBXFMOWZRXXBRN-LWKPJOBUSA-N 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000005943 zeta-Cypermethrin Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229940048462 zinc phosphide Drugs 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P3/00—Fungicides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Toxicology (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
すなわち本発明は、以下に示すことができる。
(B)下記(b1)~(b4)から選択される少なくとも1種の助剤と、
を含む、農薬組成物。
(b1)糖エステル型、アルキルアミン型、アルキルフェノール型及びエーテル型からなる群より選択される少なくとも1種の非イオン系界面活性剤
(b2)カルボン酸型アニオン系界面活性剤
(b3)カリウム塩(ただし、ヒドロキシイソキサゾールのカリウム塩を除く。)
(b4)アミド系溶剤及び乳酸エステル系溶剤からなる群より選択される少なくとも1種の溶剤
[2] (b1)非イオン界面活性剤が、POEソルビタン脂肪酸エステル、アルコキシル化脂肪族アミン、POEアルキルフェニルエーテルおよびPOEアルキルエーテルから選択される少なくとも1種である[1]に記載の農薬組成物。
[3] (b2)カルボン酸型アニオン界面活性剤が、ポリカルボン酸塩およびポリカルボン酸共重合物ナトリウム塩から選択される少なくとも1種である[1]または[2]に記載の農薬組成物。
[4] (b3)カリウム塩が、塩化カリウム、炭酸カリウム、硝酸カリウムおよび安息香酸カリウムから選択される少なくとも1種である[1]~[3]のいずれかに記載の農薬組成物。
[5] (b4)溶剤が、メチル-5-ジメチルアミノ-2-メチル-5-オキソペンタン酸メチル、乳酸メチル、乳酸エチル、および乳酸プロピルから選択される少なくとも1種である[1]~[4]のいずれかに記載の農薬組成物。
[6] (B)助剤は、前記(b1)~前記(b4)から選択される2種以上含む、[1]~[5]のいずれかに記載の農薬組成物。
[7] 更にピカルブトラゾクス、シアゾファミド及びアミスルブロムからなる群より選択される少なくとも1種の化合物若しくはその塩を含む、[1]~[6]のいずれかに記載の農薬組成物。
[8] [1]~[6]のいずれかに記載の農薬組成物を含む、植物病害に対する防除剤。
[9] 前記植物病害が、Aphanomyces(アファノマイセス)属菌、Pythium(ピシウム)属菌、Fusarium(フザリウム)属菌、Rhizoctonia(リゾクトニア)属菌、Screlotium(スクレロチウム)属菌、Cochiliobolus(コクリオボルス)属菌、Collletotrichum(コレトトリカム)属菌、Magnaporthe(マグナポルセ)属菌、Rosellinia(ロセリニア)属菌、Sclerotinia(スクレロチニア)属菌のいずれかによって引き起こされる病害である、[8]に記載の防除剤。
[10] [7]に記載の農薬組成物を含む、植物病害に対する防除剤。
[11] 前記植物病害が、Aphanomyces(アファノマイセス)属菌、Pythium(ピシウム)属菌、Fusarium(フザリウム)属菌、Rhizoctonia(リゾクトニア)属菌、Screlotium(スクレロチウム)属菌、Cochiliobolus(コクリオボルス)属菌、Collletotrichum(コレトトリカム)属菌、Magnaporthe(マグナポルセ)属菌、Rosellinia(ロセリニア)属菌、Sclerotinia(スクレロチニア)属菌、Rhizopus(リゾプス)属菌、Phytophthora(ファイトフトラ)属菌、Albugo(アルブゴ) 属菌、Bremia(ブレミア)属菌、Peronospora(フェロノスフォラ)属菌、Pseudoperonospora(シュードフェロノスフォラ)属菌、Plasmopara(プラズモパラ)属菌、Sclerospora(スクレロスフォラ)属菌、Plasmodiophora(プラズモディオフォラ)属菌、Spongospora(スポンゴスポラ)属菌のいずれかによって引き起こされる病害である、[10]に記載の防除剤。
[12] [1]~[7]のいずれかに記載の農薬組成物を栽培土壌または植物へ施用する植物病害防除方法。
[13] 植物への前記施用が、[1]~[7]のいずれかに記載の農薬組成物の、植物体または植物種子との接触又は当該植物の作付けに係る栽培土壌への含有又は当該植物の根若しくは地下茎への接触によるものである[12]記載の植物病害防除方法。
[14] (A)ヒドロキシイソキサゾール又はその塩と、(B)下記(b1)~(b4)から選択される少なくとも1種の助剤と、を植物体へ施用する、防除効果増強方法。
(b1)糖エステル型、アルキルアミン型、アルキルフェノール型及びエーテル型からなる群より選択される少なくとも1種の非イオン系界面活性剤
(b2)カルボン酸型アニオン系界面活性剤
(b3)カリウム塩(ただし、ヒドロキシイソキサゾールのカリウム塩を除く。)
(b4)アミド系溶剤及び乳酸エステル系溶剤からなる群より選択される少なくとも1種の溶剤
[15] [1]~[7]のいずれかに記載の農薬組成物を含む、除草剤薬害軽減剤。
[16] [1]~[7]のいずれかに記載の農薬組成物を栽培土壌または植物へ施用する除草剤薬害軽減方法。
[17] 植物への前記施用が、[1]~[7]のいずれかに記載の農薬組成物の、当該植物種子との接触又は当該植物の作付けに係る栽培土壌への含有又は当該植物の根若しくは地下茎への接触によるものである[16]記載の除草剤薬害軽減方法。
である。
次に、本発明の植物病害防除効果が増強された農薬組成物について説明する。
(B)助剤としては、(b1)非イオン系界面活性剤、アニオン系界面活性剤である(b2)カルボン酸型アニオン系界面活性剤、(b3)カリウム塩(ただし、ヒドロキシイソキサゾールのカリウム塩を除く。)、および(b4)溶剤から選択される少なくとも1種を含むことができ、2種以上含むことが好ましい。
具体的な商品例としては、ニューカルゲンD-941、ニューカルゲンD-945A、ニューカルゲンD-945E、ニューカルゲンD-945T、ニューカルゲンD-3020(以上、竹本油脂株式会社製)、Witcamine4130A、ADSEE AB600、ADSEE AB615、ADSEE AB650(以上、Akzo Nobel社製)、ソルポールT-10、ソルポールT-15、ソルポールT-20、ソルポールT-26、フォスファノールRA-600(以上、東邦化学工業株式会社製)、ニューコールTA-420、ニューコール2320、ニューコール2306Y、ニューコールNT-12、ニューコール714(日本乳化剤株式会社製)、レオドールTW-0320V、エマルゲン108、エマノーン1112(以上、花王社製)、ノイゲンEA-87、ノイゲンEA-137、ノイゲンEA-157、ノイゲンEA-177、ノイゲンEA-207D、ノイゲンTDS-70、ノイゲンSD-80、ノイゲンET-165、ダイヤノールCDE、DKS NL-50、DKS NL-70(以上、第一工業製薬株式会社)、ALKAMULS T80、SOPROPHOR BSU(以上、Solvay社製)、NIKKOL BL-2、NIKKOL BL-42(以上、日光ケミカルズ社製)、TANEMUL PS16(以上、TANATEX社製)
などが挙げられる。
具体的な商品例としてはソルポール7248S(東邦化学工業株式会社製)、ロビスゲンGD-54R、ロビスゲンGD-65R、ロビスゲンF-200(以上、センカ株式会社製)、ニューカルゲンWG-5、ニューカルゲンTG-90、アグロサーフWG-5200(以上、竹本油脂株式会社製)、などが挙げられる。
具体的な商品例としては塩化カリウム、炭酸カリウム、硝酸カリウム、安息香酸カリウム(以上、富士フィルム和光純薬株式会社製)などが挙げられる。
具体的な商品例としてはRHODIASOLV POLARCLEAN(ソルベイ日華株式会社製)、PURASOLV EHL、PURASOLV ML、PURASOLV EL、PURASOLV NPL(以上、Corbion社製)などが挙げられる。
本発明の組成物に更に使用できるカチオン系界面活性剤としては、アンモニウム型界面活性剤、ベンザルコニウム型界面活性剤などが挙げられる。
pH調節剤は、通常、水で0.1~5規定の適当な濃度に希釈し、その希釈液を0.01~10重量%添加することにより使用される。
使用する水は、例えば精製水、蒸留水、イオン交換水、純水、超純水、滅菌水、ろ過水など特に限定されず、どのような水も使用することができる。
本発明の組成物は、下記の種類の植物病害に対して有効である。以下に具体的病害及びその病原菌を示すが、これらに限定されるものではない。
1種又はそれ以上を組合せて使用することができるが、これらに限定されるものではない。
ベノミル(benomyl)、カルベンダジム(carbendazim)、フベリダゾール(fuberidazole)、チアベンダゾール(thiabendazole)、チオファネート(thiophanate)、チオファネートメチル(thiophanate-methyl)、ジエトフェンカルブ(diethofencarb)、ゾキサミド(zoxamide)、エタボキサム(ethaboxam)、ペンシクロン(pencycuron)、フルオピコリド(fluopicolide)、フェナマクリル(phenamacril)等の有糸核分裂および細胞分裂阻害剤;
ベノダニル(benodanil)、ベンゾビンジフルピル(benzovindiflupyr)、ビキサフェン(bixafen)、ボスカリド(boscalid)、カルボキシン(carboxin)、フェンフラム(fenfuram)、フルオピラム(fluopyram)、フルトラニル(flutolanil)、フルキサピロキサド(fluxapyroxad)、フラメトピル(furametpyr)、イソフェタミド(isofetamid)、イソピラザム(isopyrazam)、メプロニル(mepronil)、オキシカルボキシン(oxycarboxin)、ペンチオピラド(penthiopyrad)、ペンフルフェン(penflufen)、ピジフルメトフェン(pydiflumetofen)、セダキサン(sedaxane)、チフルザミド(thifluzamide)、ピラジフルミド(pyraziflumid)、イソフルシプラム(isoflucypram)、フルインダピル(fluindapyr)、インピルフルキサム(inpyrfluxam)、ピラプロポイン(pyrapropoyne)等のコハク酸脱水素酵素阻害剤(SDHI剤);
アゾキシストロビン(azoxystrobin)、クモキシストロビン(coumoxystrobin)、ジモキシストロビン(dimoxystrobin)、エノキサストロビン(enoxastrobin)、ファモキサドン(famoxadone)、フェンアミドン(fenamidone)、フェナミンストロビン(fenaminstrobin)、フルフェノキシストロビン(flufenoxystrobin)、フルオキサストロビン(fluoxastrobin)、クレソキシムメチル(kresoxim-methyl)、マンデストロビン(mandestrobin)、メトミノストロビン(metominostrobin)、オリサストロビン(orysastrobin)、ピコキシストロビン(picoxystrobin)、ピラクロストロビン(pyraclostrobin)、ピラメトストロビン(pyrametostrobin)、ピラオキシストロビン(pyraoxystrobin)、ピリベンカルブ(pyribencarb)、トリクロピリカルブ(triclopyricarb)、トリフロキシストロビン(trifloxystrobin)、メチルテトラプロール(metyltetraprole)等のキノン外部阻害剤(QoI剤):
アミスルブロム(amisulbrom)、シアゾファミド(cyazofamid)、フェンピコキサミド(fenpicoxamid)等のキノン内部阻害剤(QiI剤)
ビナパクリル(binapacryl)、メプチルジノカップ(meptyldinocap)、ジノカップ(dinocap)、フルアジナム(fluazinam)等の酸化的リン酸化脱共役阻害剤;
アメトクトラジン(ametoctradin)等のキノン外部スチグマテリン結合サブサイト阻害剤(QoSI剤);
シプロジニル(cyprodinil)、メパニピリム(mepanipyrim)、ピリメタニル(pyrimethanil)等のアミノ酸生合成阻害剤;
ストレプトマイシン(streptomycin)、ブラストサイジンS(blasticidin-S)、オキシテトラサイクリン(oxytetracycline)、カスガマイシン(kasugamycin)等のタンパク質生合成阻害剤;
フェンピクロニル(fenpiclonil)、フルジオキソニル(fludioxonil)、キノキシフェン(quinoxyfen)、プロキナジド(proquinazid)、クロゾリネート(chlozolinate)、ジメタクロン(dimethachlone)、イプロジオン(iprodione)、プロシミドン(procymidone)、ビンクロゾリン(vinclozolin)等のシグナル伝達阻害剤;
エジフェンホス(edifenphos)、イプロベンホス(iprobenfos)、ピラゾホス(pyrazophos)、ビフェニル(biphenyl)、クロロネブ(chloroneb)、ジクロラン(dicloran)、イソプロチオラン(isoprothiolane)、キントゼン(quintozene)、テクナゼン(tecnazene)、トルクロホスメチル(tolclofos-methyl)、エトリジアゾール(echlomezol or etridiazole)、ヨードカルブ(iodocarb)、プロパモカルブ(propamocarb)、プロチオカルブ(prothiocarb)、フルオキサピプロリン(fluoxapiprolin)、オキサチアピプロリン(oxathiapiprolin)等の脂質および細胞膜生合成阻害剤;
アザコナゾール(azaconazole)、ビテルタノール(bitertanol)、ブロムコナゾール(bromuconazole)、シプロコナゾール(cyproconazole)、ジフェノコナゾール(difenoconazole)、ジニコナゾール(diniconazole)、ジニコナゾールM(diniconazole-M)、[b-12.8]エポキシコナゾール(epoxiconazole)、エタコナゾール(etaconazole)、フェナリモル(fenarimol)、フェンブコナゾール(fenbuconazole)、フルキンコナゾール(fluquinconazole)、キンコナゾール(quinconazole)、フルシラゾール(flusilazole)、フルトリアホール(flutriafol)、ヘキサコナゾール(hexaconazole)、イマザリル(imazalil)、イミベンコナゾール(imibenconazole)、イプコナゾール(ipconazole)、メトコナゾール(metconazole)、ミクロブタニル(myclobutanil)、ヌアリモール(nuarimol)、オキスポコナゾール(oxpoconazole)、オキスポコナゾールフマル酸塩(oxpoconazole fumarate)、ペフラゾエート(pefurazoate)、ペンコナゾール(penconazole)、プロクロラズ(prochloraz)、プロピコナゾール(propiconazole)、プロチオコナゾール(prothioconazole)、ピリフェノックス(pyrifenox)、ピリソキサゾール(pyrisoxazole)、シメコナゾール(simeconazole)、テブコナゾール(tebuconazole)、テトラコナゾール(tetraconazole)、トリアジメホン(triadimefon)、トリアジメノール(triadimenol)、トリフルミゾール(triflumizole)、トリホリン(triforine)、トリチコナゾール(triticonazole)、メフェントリフルコナゾール(mefentrifluconazole)、イプフェントリフルコナゾール(ipfentrifluconazole)等の脱メチル化阻害剤(DMI剤);
アルジモルフ(aldimorph)、ドデモルフ(dodemorph)、フェンプロピモルフ(fenpropimorph)、トリデモルフ(tridemorph)、フェンプロピジン(fenpropidin)、ピペラリン(piperalin)、スピロキサミン(spiroxamine)等のアミン系殺菌剤;
フェンヘキサミド(fenhexamid)、フェンピラザミン(fenpyrazamine)等のステロール生合成のC4位脱メチル化における3-ケト還元酵素阻害剤;
ピリブチカルブ(pyributicarb)、[b-15.2]ナフチフィン(naftifine)、[b-15.3]テルビナフィン(terbinafine)等のステルール生合成のスクアレンエポキシダーゼ阻害剤;
ポリオキシン類(polyoxins)、ジメトモルフ(dimethomorph)、フルモルフ(flumorph)、ピリモルフ(pyrimorph)、ベンチアバリカルブ(benthiavalicarb)、ベンチアバリカルブイソプロピル(benthivalicarb-isopropyl)、イプロバリカルブ(iprovalicarb)、マンジプロパミド(mandipropamid)、バリフェナレート(valifenalate)等の細胞壁生合成阻害剤;
フサライド(phthalide or fthalide)、ピロキロン(pyroquilone)、トリシクラゾール(tricyclazole)、カルプロパミド(carpropamid)、ジクロシメット(diclocymet)、フェノキサニル(fenoxanil)、トルプロカルブ(tolprocarb)等のメラニン生合成阻害剤;
アシベンゾラルSメチル(acibenzolar-S-methyl)、プロベナゾール(probenazole)、チアジニル(tiadinil)、イソチアニル(isotianil)、ラミナリン(laminarin)、ジクロベンチアゾクス(dichlobentiazox)等の宿主植物抵抗性誘導剤;
マンコゼブ、マンゼブ(mancozeb or manzeb)、マンネブ(maneb)、メチラム(metiram)、プロピネブ(propineb)、チウラム(thiram)、ジネブ(zineb)、ジラム(ziram)、フェルバム(ferbam)等のジチオカーバメート系殺菌剤;
キャプタン(captan)、キャプタホール(captafol)、ホルペット(folpet)、フルオロホルペット(fluorofolpet)等;
フタルイミド系殺菌剤:
グアザチン(guazatine)、イミノクタジン(iminoctadine)、イミノクタジンアルベシル酸塩(iminoctadine albesilate)、イミノクタジン三酢酸塩(iminoctadine triacetate)等のグアニジン系殺菌剤;
塩基性塩化銅(copper oxychloride)、水酸化第二銅(copper(II) hydroxide)、塩基性硫酸銅(copper hydroxide sulfate)、有機銅化合物(organocopper compound)、ドデシルベンゼンスルホン酸ビスエチレンジアミン銅錯塩[II](dodecylbenzenesulphonic acid bisethylenediamine copper [II] salt、DBEDC)、硫黄(sulphur)、フルオルイミド(fluoroimide)、ジクロフルアニド(dichlofluanid)、トリルフルアニド(tolylfluanid)、アニラジン(anilazine)、ジチアノン(dithianon)、キノメチオナート(chinomethionat or quinomethionate)、ハウチワマメ苗木の子葉からの抽出物(BLAD)、クロロタロニル(chlorothalonil)等の多作用点接触活性型殺菌剤;
ジピメチトロン(dipymetitrone)、ブピリメート(bupirimate)、ジメチリモール(dimethirimol)、エチリモール(ethirimol)、酢酸トリフェニルスズ(fentin acetate)、塩化トリフェニルスズ(fentin chloride)、水酸化トリフェニルスズ(fentin hydroxide)、オキソリニック酸(oxolinic acid)、オクチリノン(octhilinone)、ホセチル(fosetyl)、亜リン酸(phosphorous acid)、亜リン酸のナトリウム塩(sodium phosphite)、亜リン酸のアンモニウム塩(ammonium phosphite)、亜リン酸のカリウム塩(potassium phosphite)、D-タガトース(D-tagatose)、テクロフタラム(tecloftalam)、トリアゾキシド(triazoxide)、フルスルファミド(flusulfamide)、ジクロメジン(diclomezine)、シルチオファム(silthiofam)、ジフルメトリム(diflumetorim)、メタスルホカルブ(methasulfocarb)、シフルフェナミド(cyflufenamid)、メトラフェノン(metrafenone)、ピリオフェノン(pyriofenone)、ドジン(dodine)、フルチアニル(flutianil)、フェリムゾン(ferimzone)、テブフロキン(tebufloquin)、バリダマイシン類(validamycins)、シモキサニル(cymoxanil)、ピカルブトラゾクス(picarbutrazox)、キノフメリン(Quinofumelin)、アミノピリフェン(aminopyrifen)、ピリダクロメチル(pyridachlometyl)、イプフルフェノキン(ipflufenoquin)、フルオピモミド(fluopimomide)、フロリルピコキサミド(florylpicoxamid)等のその他の殺菌剤が挙げられる。
アセフェート(acephate)、アザメチホス(azamethiphos)、アジンホス-メチル(azinphos-methyl)、アジンホス-エチル(azinphos-ethyl)、エセフォン(ethephon)、カズサホス(cadusafos)、クロルエトキシホス(chlorethoxyfos)、クロルフェンビンホス(chlorfenvinphos)、クロルメホス(chlormephos)、クロルピリホス(chlorpyrifos)、クロルピリホス-メチル(chlorpyrifos-methyl)、クマホス(coumaphos)、シアノホス(cyanophos)、デメトン-S-メチル(demeton-S-methyl)、ダイアジノン(diazinon)、ジクロフェンチオン(dichlofenthion)、ジクロルボス(dichlorvos)、ジクロトホス(dicrotophos)、ジメトエート(dimethoate)、ジメチルビンホス(dimethylvinphos)、ジスルホトン(disulfoton)、O-エチル O-4-ニトロフェニル フェニルホスホノチオアート(O-ethyl O-4-nitrophenyl phenylphosphonothioate)、エチオン(ethion)、エトプロホス(ethoprophos)、ファムフール(famphur)、フェナミホス(fenamiphos)、フェニトロチオン(fenitrothion)、フェンチオン(fenthion)、ホスチアゼート(fosthiazate)、ヘプテノホス(heptenophos)、イソフェンホス-メチル(isofenphos-methyl)、イソカルボホス(Isocarbophos)、イソキサチオン(isoxathion)、マラチオン(malathion)、メカルバム(mecarbam)、メタミドホス(methamidophos)、メチダチオン(methidathion)、メビンホス(mevinphos)、モノクロトホス(monocrotophos)、ナレッド(naled)、オメトエート(omethoate)、オキシデメトン-メチル(oxydemeton-methyl)、パラチオン(parathions)、パラチオン-メチル(parathion-methyl)、フェントエート(phenthoate)、ホレート(phorate)、ホサロン(phosalone)、ホスメット(phosmet)、ホスファミドン(phosphamidon)、ホキシム(phoxim)、ピリミホス-メチル(pirimiphos-methyl)、プロフェノホス(profenofos)、プロペタンホス(propetamphos)、プロチオホス(prothiofos)、ピラクロホス(pyraclofos)、ピリダフェンチオン(pyridaphenthion)、キナルホス(quinalphos)、スルホテップ(sulfotep)、テブピリムホス(tebupirimfos)、テメホス(temephos)、テルブホス(terbufos)、チオメトン(thiometon)、トリアゾホス(triazophos)、トリクロルホン(trichlorfon)、バミドチオン(vamidothion)、クロルチオン(chlorothion)、ブロムフェンビンホス(bromfenvinfos)、ブロモホス(bromophos)、ブロモホス-エチル(bromophos-ethyl)、ブタチオホス(butathiofos)、カルボフェノチオン(carbophenothion)、クロルホキシム(chlorphoxim)、スルプロホス(sulprofos)、ジアミダホス(diamidafos)、テトラクロルビンホス(tetrachlorvinphos)、プロパホス(propaphos)、メスルフェンホス(mesulfenfos)、ジオキサベンゾホス(dioxabenzofos)、エトリムホス(etrimfos)、オキシデプロホス(oxydeprofos)、ホルモチオン(formothion)、フェンスルホチオン(fensulfothion)、イサゾホス(isazofos)、イミシアホス(imicyafos)、イサミドホス(isamidofos)、チオナジン(thionazin)、ホスチエタン(fosthietan)等の有機リン系アセチルコリンエステラーゼ(AChE)阻害剤;
クロルデン(chlordane)、エンドスルファン(endosulfan)、リンデン(lindane)、ジエノクロル(dienochlor)、エチプロール(ethiprole)、フィプロニル(fipronil)、[アセトプロール(acetoprole)等のGABA作動性塩素イオンチャネルブロッカー;
アクリナトリン(acrinathrin)、アレスリン[(1R)-アイソマー](allethrin[(1R)-isomer])、ビフェントリン(bifenthrin)、ビオアレスリン(bioallethrin)、ビオアレスリン S-シクロペンテニル アイソマー(bioallethrin S-cyclopentenyl isomer)、ビオレスメトリン(bioresmethrin)、シクロプロトリン(cycloprothrin)、シフルトリン(cyfluthrin)、ベータ-シフルトリン(beta-cyfluthrin)、シハロトリン(cyhalothrin)、ガンマ-シハロトリン(gamma-cyhalothrin)、ラムダ-シハロトリン(lambda-cyhalothrin)、シペルメトリン(cypermethrin)、アルファ-シペルメトリン(alpha-cypermethrin)、ベータ-シペルメトリン(beta-cypermethrin)、セタ-シペルメトリン(theta-cypermethrin)、ゼダ-シペルメトリン(zeta-cypermethrin)、シフェノトリン[(1R)-トランス-アイソマー](cyphenothrin[(1R)-trans-isomer])、デルタメトリン(deltamethrin)、エンペントリン[(EZ)-(1R)-アイソマー](empenthrin[(EZ)-(1R)-isomer])、エスフェンバレレート(esfenvalerate)、エトフェンプロックス(ethofenprox)、フェンプロパトリン(fenpropathrin)、フェンバレレート(fenvalerate)、フルシトリネート(flucythrinate)、フルメトリン(flumethrin)、タウ-フルバリネート(tau-fluvalinate)、ハルフェンプロックス(halfenprox)、イミプロトリン(imiprothrin)、メトトリン(methothrin)、メトフルトリン(metofluthrin)、イプシロン-メトフルトリン(epsilon-metofluthrin)、モンフルオロトリン(momfluorothrin)、イプシロン-モンフルオロトリン(epsilon-momfluorothrin)、ペルメトリン(permethrin)、フェノトリン[(1R)-トランス-アイソマー](phenothrin[(1R)-trans-isomer])、プラレトリン(prallethrin)、レスメトリン(resmethrin)、カデトリン(kadethrin)、シラフルオフェン(silafluofen)、テフルトリン(tefluthrin)、テトラメトリン(tetramethrin)、テトラメトリン[(1R)-アイソマー](tetramethrin[(1R)-isomer])、トラロメトリン(tralomethrin)、トランスフルトリン(transfluthrin)、ZXI8901(3-(4-bromophenoxy)phenyl]-cyanomethyl 4-(difluoromethoxy)-α-(1-methylethyl)benzeneacetate)、バイオペルメトリン(biopermethrin)、フラメトリン(furamethrin)、プロフルトリン(profluthrin)、フルブロシトリネート(flubrocythrinate)、ジメフルトリン(dimefluthrin)、DDT(dichloro-diphenyl-trichloroethane)、メトキシクロル(methoxychlor)、フェノトリン(phenothrin)、フルバリネート(fluvalinate)等のナトリウムチャネルモジュレーター;
アセタミプリド(acetamiprid)、クロチアニジン(clothianidin)、ジノテフラン(dinotefuran)、イミダクロプリド(imidacloprid)、ニテンピラム(nitenpyram)、チアクロプリド(thiacloprid)、チアメトキサム(thiamethoxam)、ニコチン(nicotine)、硫酸ニコチン(nicotine sulfate)、スルホキサフロル(sulfoxaflor)、フルピラジフロン(flupyradifurone)、トリフルメゾピリム(triflumezopyrim)等のニコチン性アセチルコリン受容体(nAChR)競合的モジュレーター;
スピノサド(spinosad)、スピネトラム(spinetoram)等のニコチン性アセチルコリン受容体(nAChR)アロステリックモジュレーター;
アバメクチン(abamectin)、エマメクチン安息香酸塩(emamectin benzoate)、レピメクチン(lepimectin)、ミルベメクチン(milbemectin)等のグルタミン酸作動性塩素イオンチャネル(GluCl) アロステリックモジュレーター;
ヒドロプレン(hydroprene)、キノプレン(kinoprene)、メトプレン(methoprene)、フェノキシカルブ(fenoxycarb)、ピリプロキシフェン(pyriproxyfen)等の幼若ホルモン類似剤;
臭化メチル(methyl bromide)、クロルピクリン(chloropicrin)、クリオライト(cryolite)、フッ化スルフリル(sulfuryl fluoride)、ホウ砂(borax)、ホウ酸(boric acid)、オクタホウ酸ニナトリウム塩(disodium octaborate)、メタホウ酸ナトリウム塩(sodium metaborate)吐酒石(tartar emetic)、ダゾメット(dazomet)、メタム(metam)、カーバムナトリウム塩(metham sodium)等の非特異的(マルチサイト)阻害剤;
ピメトロジン(pymetrozine)、ピリフルキナゾン(pyrifluquinazon)、アフィドピロペン(Afidopyropen)の弦音器官TRPVチャネルモジュレーター;
クロフェンテジン(clofentezine)、ジフロビダジン(diflovidazin)、ヘキシチアゾクス(hexythiazox)、エトキサゾール(etoxazole)等のダニ類成長阻害剤;
ジアフェンチウロン(diafenthiuron)、アゾシクロチン(azocyclotin)、シヘキサチン(cyhexatin)、フェンブタチンオキシド(fenbutatin oxide)、プロパルギット(propargite)、テトラジホン(tetradifon)等のミトコンドリアATP合成酵素阻害剤;
クロルフェナピル(chlorfenapyl)、DNOC(dinitro-ortho-cresol)、ビナパクリル(binapacryl)、スルフルラミド(sulfluramid)等のプロトン勾配を撹乱する酸化的リン酸化脱共役剤;
ベンスルタップ(bensultap)、カルタップ塩酸塩(cartap hydrochloride)、チオシクラム(thiocyclam)、モノスルタップ(monosultap)等のニコチン性アセチルコリン受容体(nAChR)チャネルブロッカー;
ビストリフルロン(bistrifluron)、クロルフルアズロン(chlorfluazuron)、ジフルベンズロン(diflubenzuron)、フルシクロクスロン(flucycloxuron)、フルフェノクスロン(flufenoxuron)、ヘキサフルムロン(hexaflumuron)、ルフェヌロン(lufenuron)、ノバルロン(novaluron)、ノビフルムロン(noviflumuron)、テフルベンズロン(teflubenzuron)、トリフルムロン(triflumuron)等のキチン生合成阻害剤タイプ0;
ブプロフェジン(buprofezin)等のキチン生合成阻害剤タイプ1;
シロマジン(cyromazine)等のハエ目昆虫脱皮阻害剤;
クロマフェノジド(chromafenozide)、ハロフェノジド(halofenozide)、メトキシフェノジド(methoxyfenozide)、テブフェノジド(tebufenozide)等の脱皮ホルモン(エクダイソン)受容体アゴニスト;
アミトラズ(amitraz)等のオクトパミン受容体アゴニスト;
ヒドラメチルノン(hydramethylnon)、アセキノシル(acequinocyl)、フルアクリピリム(fluacrypyrim)、ビフェナゼート(bifenazate)等のミトコンドリア電子伝達系複合体III阻害剤;
フェナザキン(fenazaquin)、フェンピロキシメート(fenpyroximate)、ピリダベン(pyridaben)、ピリミジフェン(pylimidifen)、テブフェンピラド(tebufenpyrad)、トルフェンピラド(tolfenpyrad)、ロテノン(rotenone)等のミトコンドリア電子伝達系複合体I阻害剤(METI);
インドキサカルブ(indoxacarb)、メタフルミゾン(metaflumizone)等の電位依存性ナトリウムチャネルブロッカー;
スピロジクロフェン(spirodiclofen)、スピロメシフェン(spiromesifen)、スピロテトラマト(spirotetramat)等のアセチルCoAカルボキシラーゼ阻害剤;
リン化アルミニウム(aluminum phosphide)、リン化カルシウム(calcium phosphide)、リン化水素(phosphine)、リン化亜鉛(zinc phosphide)、シアン化カルシウム(calcium cyanide)、シアン化ナトリウム(potassium cyanide)、シアン化カリウム(sodium cyanide)等のミトコンドリア電子伝達系複合体IV阻害剤;
シエノピラフェン(cyenopyrafen)、シフルメトフェン(cyflumetofen)、ピフルブミド(pyflubumide)等のミトコンドリア電子伝達系複合体II阻害剤;
クロラントラニリプロール(chlorantraniliprole)、[シアントラニリプロール(cyantraniliprole)、フルベンジアミド(flubendiamide)、シクラニリプロール(cyclaniliprole)等のリアノジン受容体モジュレーター;
フロニカミド(flonicamid)等の弦音器官モジュレーター 標的部位未特定;
ブロフラニリド(broflanilide)、フルキサメタミド(fluxametamide)等のGABA作動性塩化物イオン(塩素イオン)チャネルアロステリックモジュレーター:
アザジラクチン(azadirachtin)、ベンゾキシメート(benzoximate)、フェニソブロモレート(phenisobromolate)、キノメチオナート(chinomethionat)、ジコホル(dicofol)、ピリダリル(pyridalyl)、ブロモプロピレート(bromopropylate)、トリアザメート(triazamate)、ジシクラニル(dicyclanil)、ジノブトン(dinobuton)、ジノカップ(dinocap)、シアン化水素(hydrogen cyanide)、ヨウ化メチル(methyl iodide)、カランジン(karanjin)、]塩化水銀(mercury chloride)、メチルイソチオシアネート(methyl isothiocyanate)、ペンタクロロフェノール(pentachlorophenol)、ホスフィン(phosphine)、ピペロニル ブトキシド(piperonyl butoxide)、ポリナクチン複合体(polynactins)、サバディラ(sabadilla)、スルコフロン塩(スルコフロン-ナトリウム(sulcofuron-sodium))、トリブホス(tribufos)、アルドリン(aldrin)、アミジチオオン(amidithion)、アミドチオエート(amidothioate)、アミノカルブ(aminocarb)、アミトン(amiton)、アラマイト(aramite)、]アチダチオン(athidathion)、アゾトエート(azothoate)、ポリスルフィドバリウム(barium polysulphide)、ベンクロチアズ(benclothiaz)、5-(1,3-ベンゾジオキソール-5-イル)-3-ヘキシルシクロヘキサ-2-エノン(5-(1,3-benzodioxole-5-yl)-3-hexylcyclohexa-2-enone)、1,1-ビス(4-クロロフェニル)-2-エトキシエタノール(1,1-bis(4-chlorophenyl)-2-ethoxyethanol)、ブトネート(butonate)、ブトピロノキシル(butopyronoxyl)、2-(2-ブトキシエトキシ)エチル チオシアナート(2-(2-butoxyethoxy)ethyl thiocyanate)、カンフェクロル(camphechlor)、クロルベンシド(chlorbenside)、クロルデコン(chlordecone)、クロルジメホルム(chlordimeform)、クロルフェネトール(chlorfenethol)、クロルフェンソン(chlorfenson)、フルアズロン(fluazuron)、メタアルデヒド(metaldehyde)、ビアラホス(bialaphos)、塩酸レバミゾール(levamisol)、アミドフルメト(amidoflumet)、ピラフルプロール(pyrafluprole)、ピリプロール(pyriprole)、トラロピリル(tralopyril)、フルピラゾフォス(flupyrazofos)、ジオフェノラン(diofenolan)、クロルベンジレート(chlorobenzilate)、フルフェンジン(flufenzine)、ベンゾメート(benzomate)、フルフェネリム(flufenerim)、アルベンダゾール(albendazole)、オキシベンダゾール(oxibendazole)、フェンベンダゾール(fenbendazole)、メタム・ナトリウム(metam-sodium)、1,3-ジクロロプロペン(1,3-dichloropropene)、フロメトキン(flometoquin)、テトラニリプロール(tetraniliprole)、ジクロロメゾチアズ(dicloromezotiaz)、エチレンジブロマイド(ethylene dibromide)、アクリロニトリル(acrylonitrile)、ビス(2-クロロエチル)エーテル(bis(2-chloroethyl)ether)、1-ブロモ-2-クロロエタン(1-bromo-2-chloroethane)、3-ブロモ-1-クロロプロパ-1-エン(3-bromo-1-chloroprop-1-ene)、ブロモシクレン(bromocyclen)、二硫化炭素(carbon disulfide)、四塩化炭素(tetrachloromethane)、ネマデクチン(nemadectin)、シミアゾール(cymiazole)カルシウム ポリスルフィド(calcium polysulfide)、サイトカイニン(cytokinin)、2-(オクチルチオ)エタノール、オレイン酸カリウム(potassium oleate)、オレイン酸ナトリウム(sodium oleate)、マシン油(machine oil)、]タール油(tar oil)、アナバシン(anabasine)、酒石酸モランテル(morantel tartrate)、除虫菊(ピレトリン(pyrethrum))、ナタネ油(rape seed oil)、ダイズレチシン(soybean lecithin)、デンプン(starch)、ヒドロキシプロピルデンプン(hydroxypropylstarch)、脂肪酸グリセリド(decanoyloctanoylglycerol)、プロピレングリコールモノ脂肪酸エステル(propylene glycol fatty acid ester)、ケイソウ土(diatomite)。アフォキソラネル(afoxolaner)、フルアザインドリジン(fluazaindolizine)、シハロジアミド(cyhalodiamide)、チオキサザフェン(tioxazafen)、フルヘキサフォン(fluhexafon)、フルララネル(fluralaner)、テトラクロラントラニリプロール(tetrachlorantraniliprole)、サロラネル(sarolaner)、ロチラネル(lotilaner)、チゴラネル(tigolaner)、シクロキサプリド(cycloxaprid)、フルエンスルホン(fluensulfone)、TPIC(tripropyl isocyanurate)、D-D(1,3-Dichloropropene)、ペルオキソカルボナート(peroxocarbonate)、MB-599(verbutin)、ビス(2,3,3,3-テトラクロロプロピル)エーテル(bis(2,3,3,3-tetrachloropropyl) ether)、DCIP(bis(2-chloro-1-methylethyl)ether)、ENT-8184(N-(2-Ethylhexyl)bicyclohept-5-ene-2,3-dicarboximide)、Bayer 22408(O,O-diethyl O-naphthalimido phosphorothioate)、Bayer 32394(tris(1-dodecyl-3-methyl-2-phenylbenzimidazolium)hexacyanoferrate)、ベンズピリモキサン(benzpyrimoxan)、アシノナピル(acynonapyr)、フルピリミン(flupyrimin)、チクロピラゾフロール(tyclopyrazoflor)、オキサゾスルフィル(oxazosulfyl)、スピロピジオン(spiropidion)、イソシクロセラム(isocycloseram)、ジンプロピリダズ(dimpropyridaz)等のその他の剤が挙げられる。
アミドスルフロン(amidosulfuron)、アジムスルフロン(azimusulfuron)、ベンスルフロンメチル(bensulfuron-methyl)、ビスピリバックNa塩(bispyribac-sodium)、クロリムロンエチル(chlorimuron-ethyl)、クロルスルフロン(chlorsulfuron)、シノスルフロン(cinosulfuron)、クロランスラムメチル(cloransulam-methyl)、シクロスルファムロン(cyclosulfamuron)、ジクロスラム(diclosulam)、エタメトスルフロンメチル(ethametsulfuron-methyl)、エトキシスルフロン(ethoxysulfuron)、フラザスルフロン(flazasulfuron)、フロラスラム(florasulam)、フルカルバゾン(flucarbazone)、フルセトスルフロン(flucetosulfuron)、フルメツラム(flumetsulam)、フルピルスルフロンメチルナトリウム塩(flupyrsulfuron-methyl-sodium)、ホラムスルフロン(foramsulfuron)、ハロスルフロンメチル(halosulfuron-methyl)、イマザメタベンズメチル(imazamethabenz-methyl)、イマザモックス(imazamox)、イマザピック(imazapic)、イマザピル(imazapyr)、イマザキン(imazaquin)、イマゼタピル(imazethapyr)、イマゾスルフロン(imazosulfuron)、ヨードスルフロンメチルナトリウム塩(iodosulfuron-methyl-sodium)、メソスルフロンメチル(mesosulfuron-methyl)、メタゾスルフロン(metazosulfuron)、メトスラム(metosulam)、メトスルフロンメチル(metsulfuron-methyl)、ニコスルフロン(nicosulfuron)、オルソスルファムロン(orthosulfamuron)、オキサスルフロン(oxasulfuron)、ペノキススラム(penoxsulam)、プリミスルフロンメチル(primisulfuron-methyl)、プロポキシカルバゾン(propoxycarbazone)、プロピリスルフロン(propyrisulfuron)、プロスルフロン(prosulfuron)、ピラゾスルフロン(pyrazosulfuron)、ピリベンゾキシム(pyribenzoxim)、ピリフタリド(pyriftalid)、ピリミノバックメチル(pyriminobac-methyl)、ピリミスルファン(pyrimisulfan)、ピリチオバック(pyrithiobac)、ピロキススラム(pyroxsulam)、リムスルフロン(rimsulfuron)、スルホメツロン(sulfometuron)、スルホスルフロン(sulfosulfuron)、チエンカルバゾンメチル(thiencarbazone-methyl)、チフェンスルフロンメチル(thifensulfuron-methyl)、トリアファモン(triafamone)、トリアスルフロン(triasulfuron)、トリベヌロンメチル(tribenuron-methyl)、トリフロキシスルフロン(trifloxysulfuron)、トリフルスルフロンメチル(triflusulfuron-methyl)、トリトスルフロン(tritosulfuron)、等のアセト乳酸合成酵素(ALS)阻害剤;
アメトリン(ametryn)、アミカルバゾン(amicarbazone)、アトラジン(atrazine)、ベンタゾン(bentazone)、ブロマシル(bromacil)、ブロモキシニル(bromoxynil)、クロリダゾン(chloridazon)、クロロトルロン(chlorotoluron)、シアナジン(cyanazine)、デスメディファム(desmedipham)、ジメタメトリン(dimethametryn)、ジウロン(DCMU)(diuron)、フルオメツロン(fluometuron)、ヘキサジノン(hexadinone)、アイオキシニル(ioxynil)、イソプロツロン(isoproturon)、レナシル(lenacil)、リニュロン(linuron)、メタミトロン(metamitron)、メタベンズチアズロン(methabenzthiazuron)、メトブロムロン(metobromuron)、メトリブジン(metribuzin)、フェンメディファム(phenmedipham)、プロメトリン(prometryn)、プロパニル(propanil)、ピリデート(pyridate)、シマジン(simazine)、テブチウロン(tebuthiuron)、ターバシル(terbacil)、テルブチラジン(terbuthylazine)、テルブトリン(terbutryn)、等の光合成(光化学系II)阻害剤;
ジクワット(diquat)、パラコート(paraquat)、等の光化学系I電子変換系除草剤;
アシフルオフェン(acifluorfen)、ビフェノックス(bifonox)、ブタフェナシル(butafenacil)、カルフェントラゾンエチル(carfentrazone-ethyl)、シニドンエチル(cinidon-ethyl)、シクロピラニル(cyclopyranil)、フルミクロラックペンチル(flumiclorac-pentyl)、フルミオキサジン(flumioxazin)、ホメサフェン(fomesafen)、ラクトフェン(lactofen)、オキサジアルギル(oxadiargyl)、オキサジアゾン(oxadiazon)、オキシフルオルフェン(oxyfluorfen)、ペントキサゾン(pentoxazone)、ピラクロニル(pyraclonil)、ピラフルフェンエチル(pyraflufen-ethyl)、サフルフェナシル(saflufenacil)、スルフェントラゾン(sulfentrazone)、チアフェナシル(tiafenacil)、トリフルジモキサジン(trifludimoxadin)、等のプロトポルフィリノーゲン酸化酵素(PPO)阻害;
ベフルブタミド(beflubutamid)、ジフルフェニカン(diflufenican)、フルリドン(fluridone)、フルロクロリドン(flurochloridone)、フルルタモン(flurtamone)、ノルフルラゾン(norflurazon)、ピコリナフェン(picolinafen)、等のフィトエン脱飽和酵素系(PDS)でのカロチノイド生合成阻害剤;
ベンゾビシクロン(benzobicyclon)、ベンゾフェナップ(benzofenap)、ビシクロピロン(bicyclopyrone)、フェンキノトリオン(fenquinotrione)、イソキサフルトール(isoxaflutole)、ランコトリオンナトリウム塩(lancotrione sodium)、メソトリオン(mesotrione)、ピラスルフォトール(pyrasulfotole)、ピラゾレート(pyrazolynate)、ピラゾキシフェン(pyrazoxyfen)、スルコトリオン(sulcotrione)、テフリルトリオン(tefuryltrione)、テンボトリオン(tembotrione)、トルピラレート(tolpyralate)、トプラメゾン(topramezone)、等の4-ヒドロキシフェニルピルビン酸ジオキシゲナーゼ(4-HPPD)阻害剤;
アクロニフェン(aclonifen)、アミトロール(amitrole)、フルオメツロン(fluometuron)等のカロチノイド生合成(標的部位不明)阻害剤;
ビクスロゾン(bixlozone)、クロマゾン(clomazone)、等の1-デオキシ-D-キシルロース-5-リン酸(DOXP)合成酵素阻害剤;
グリホサート(glyphosate)、等のEPSP合成酵素阻害剤;
ビアラホス(bilanafos)、グルホシネート(glufosinate)、等のグルタミン合成酵素阻害剤;アシュラム(asulam)等のDHP(ジヒドロプテロイン酸)合成酵素阻害剤;
ベンフルラリン(benfluralin)、ブタミホス(butamifos)、ブトラリン(butralin)、クロルタールジメチル(chlorthal-dimethyl)、エタルフルラリン(ethalfluralin)、オリザリン(oryzalin)、ペンディメタリン(pendimethalin)、プロピザミド(propyzamide)、チアゾピル(thiazopyr)、トリフルラリン(trifluralin)、等の微小管重合阻害剤;
カルベタミド(carbetamide)、IPC(クロルプロファム)(chlorpropham)、プロファム(propham)等の有糸分裂・微小管形成阻害剤;
アセトクロール(acetochlor)、アラクロール(alachlor)、ブタクロール(butachlor)、カフェンストロール(cafenstrole)、ジメタクロール(dimethachlor)、ジメテナミド(dimethenamid)、エスプロカルブ(esprocarb)、フェノキサスルホン(fenoxasulfone)、フェントラザミド(fentrazamide)、フルフェナセット(flufenacet)、イプフェンカルバゾン(ipfencarbazone)、メフェナセット(mefenacet)、メタザクロール(metazachlor)、メトラクロール(metolachlor)、ペトキサミド(pethoxamid)、プレチラクロール(pretilachlor)、プロパクロール(propachlor)、ピロキサスルホン(pyroxasulfone)、テニルクロール(thenylchlor)、等のVLCFA阻害剤;
ジクロベニル(dichlobenil)、フルポキサム(flupoxam)、イソキサベン(isoxaben)、等の細胞壁(セルロース)合成阻害剤;
DNBP(ジノセブ)(dinoseb)、ジノテルブ(dinoterb)、DNOC等のアンカップリング(膜破壊)系除草剤;
ベンフレセート(benfuresate)、ブチレート(butylate)、EPTC(EPTC)、エトフメセート(ethofumesate)、モリネート(molinate)、等の脂質合成(非ACCase)阻害剤;
2,4-D、2,4-DB、アミノピラリド(aminopyralid)、ベナゾリンエチル(benazolin-ethyl)、クロメプロップ(clomeprop)、クロピラリド(clopyralid)、ジカンバ(dicamba)、ジクロルプロップ(dichlorprop)、フロルピラウキシフェンベンジル(florpyrauxifen-benzyl)、フルロキシピル(fluroxypyr)、ハラウキシフェンメチル(halauxifen-methyl)、MCPA(MCPA)、MCPB(MCPB)、メコプロップ(mecoprop)、ピクロラム(picloram)、トリクロピル(triclopyl)、等のインドール酢酸様活性(合成オーキシン)系除草剤;
ジフルフェンゾピル(diflufenzopyr)、等のオーキシン移動阻害剤;
アクロニフェン(aclonifen)、アニロホス(anilofos)、アシュラム(asulam)、ブロモブチド(bromobutide)、シンメチリン(cinmethylin)、クミルロン(cumyluron)、シクロピリモレート(cyclopyrimorate)、ダイムロン(daimuron)、ジフェンゾクワット(difenzoquat)、ジチオピル(dithiopyr)、ドレクスレラ モノセラス(drechslera monoceras)、エンドタール(endothal)、エトキシフェン(ethoxyfen)、エトベンザニド(etobenzanid)、インダノファン(indanofan)、ナプロパミド(napropamide)、ナプタラム(naptalam)、オルベンカルブ(orbencarb)、オキサジクロメホン(oxaziclomefone)、ペラルゴン酸(pelargonic acid)、プロジアミン(prodiamine)、プロスルホカルブ(prosulfocarb)、ピリブチカルブ(pyributicarb)、キンクロラック(quinclorac)、キンメラック(quinmerac)、キノクラミン(quinoclamine)、テトフルピロリメット(tetflupyrolimet)、テトラピオン(tetrapion)、チオベンカルブ(thiobencarb)、トリアレート(triallate)、等のその他の除草剤等を挙げることができる。
本発明の組成物の施用方法としては、組成物を植物体または植物種子と接触させる、または植物の作付けに係る栽培土壌に含有させることにより植物の根または地下茎に接触させる、すなわち具体的には組成物の植物体への茎葉散布処理、苗箱処理、土壌表面への散布処理、土壌表面への散布処理後の土壌混和、土壌中への注入処理、土壌中での注入処理後の土壌混和、土壌潅注処理、土壌潅注処理後の土壌混和、植物種子への吹き付け処理、植物種子への塗沫処理、植物種子への浸漬処理または植物種子への粉衣処理等があげられるが、通常当業者が利用するどの様な施用方法にても十分な効力を発揮する。
また、下記実施例および試験例において、「部」は、「質量部」を表すものとする。
実施例で用いた成分は以下のとおりである。
(B)助剤
(b1)非イオン系界面活性剤
(b1-1:糖エステル型非イオン系界面活性剤)
ニューカルケ゛ン D-941:POEソルヒ゛タンモノラウレート、竹本油脂社製
ニューカルケ゛ン D-945A:POEソルヒ゛タンモノオレエート、竹本油脂社製
ニューカルケ゛ン D-945T:POEソルヒ゛タントリオレエート、竹本油脂社製
ニューカルケ゛ン D-945E:POEソルヒ゛タン脂肪酸エステル、竹本油脂社製
レオト゛ール TW-O320V:POEソルヒ゛タントリオレエート、花王社製
ALKAMULS T80:POEソルヒ゛タンモノオレイン酸エステル、Solvay社製
ニューカルケ゛ン D-3020:ホ゜リオキシアルキレンホ゜リアルキレンホ゜リアミン(20%水溶液)、竹本油脂社製
タ゛イヤノール CDE:ヤシ油脂肪酸シ゛エタノールアミト゛(1:1型)、第一工業製薬社製
ADSEE AB650:牛脂アミンエトキシレート/フ゜ロホ゜キシレート、Nouryon 社製
Witcamine 4130A:アルコキシル化脂肪族アミン、Nouryon社製
ノイケ゛ン EA-207D:POEスチレン化フェニルエーテル、第一工業製薬社製
ソルホ゜ール T-10:POE(9)トリスチリルフェニルエーテル、東邦化学工業社製
NIKKOL BL-2:POE(2)ラウリルエーテル、日光ケミカルズ社製
NIKKOL BL-42:POE(4.2)ラウリルエーテル、日光ケミカルズ社製
TANEMUL PS16:POAトリスチリルフェニルエーテル、TANATEX社製
ノイケ゛ン TDS-70:POEトリテ゛シルエーテル、第一工業製薬社製
DKS NL-50:POEラウリルエーテル、第一工業製薬社製
SOPROPHOR BSU:POEトリスチリルフェニルエーテル(16EO)、Solvay社製
エマルケ゛ン 108:POEラウリルエーテル、花王社製
エマノーン 1112:PEGモノラウレート、花王社製
ニューコール 2320:POEアルキルエーテル(C12,C13)、日本乳化剤社製
ニューコール 2306Y :POAアルキルエーテル(C12,C13)、日本乳化剤社製
ニューコール NT-12:POAアルキルエーテル(C12,C14,二級アルコール)、日本乳化剤社製
ニューコール 714:POE多環フェニルエーテル、日本乳化剤社製
ノイケ゛ン SD-80:POEイソテ゛シルエーテル、第一工業製薬社製
ノイケ゛ン ET-165:POEアルキルエーテル、第一工業製薬社製
DKS NL-70:POEラウリルエーテル、第一工業製薬社製
フォスファノール RA-600:POEアルキルエーテルリン酸80%+POEアルキルエーテル20%、東邦化学工業社製
ニューカルケ゛ン TG-90:特殊ホ゜リカルホ゛ン酸Na(40%水溶液)、竹本油脂社製
ソルホ゜ール 7248S:ホ゜リカルホ゛ン酸塩(40%)、東邦化学工業社製
ロヒ゛スケ゛ン F-200:ホ゜リカルホ゛ン酸共重合物ナトリウム塩(27%)、センカ社製
ロヒ゛スケ゛ン GD-65R:ホ゜リカルホ゛ン酸塩(アクリル系アニオンホ゜リマー)(45%)、センカ社製
ソルビン酸カリウム、ピロ亜硫酸カリウム、酢酸カリウム、リン酸二水素カリウム、安息香酸カリウム、第三リン酸カリウム、フタル酸水素カリウム、ヘキサメタリン酸カリウム、クエン酸三カリウム、硝酸カリウム、炭酸カリウム、乳酸カリウム、炭酸カリウム、酢酸カリウム
(b4-1:アミド系溶剤)
RHODIASOLV POLARCLEAN:メチル-5-ジメチルアミノ-2-メチル-5-オキソペンタン酸メチル、Solvay社製
(b4-2:乳酸エステル系溶剤)
PURASOLV EHL:乳酸エチルヘキシル、Corbion社製
PURASOLV ML:乳酸メチル、Corbion社製
PURASOLV EL:乳酸エチル、Corbion社製
PURASOLV NPL:乳酸プロピル、Corbion社製
ヒドロキシイソキサゾールカリウム塩をフリー酸換算で30部、およびイオン交換水を70部均一に混合し、農薬組成物を得た。表-1、表-2に成分組成を示す。
ヒドロキシイソキサゾールカリウム塩をフリー酸換算で30部、ニューカルゲン D-941を5部、およびイオン交換水を65部均一に混合し、農薬組成物を得た。試験例1および2の試験結果を表-1に示す。
表-1に記載の組成とした以外は実施例1と同様に農薬組成物を得た。試験例1および2の試験結果を表-1に示す。
表-1に記載の組成とした以外は実施例1と同様に農薬組成物を得た。試験例1および2の試験結果を表-1、試験例1および3の試験結果を表-2に示す。
ヒドロキシイソキサゾールカリウム塩をフリー酸換算で30部、ニューカルゲン D-945Eを2.5部、ロビスゲンF-200を7.5部、およびイオン交換水を60部均一に混合し、農薬組成物を得た。試験例1および3の試験結果を表-2に示す。
表-2に記載の組成とした以外は実施例59と同様に農薬組成物を得た。試験例1および3の試験結果を表-2に示す。
更にピカルブトラゾクスを20部混合する以外は実施例59~112と同様に農薬組成物を得た。
更にシアゾファミドを20部混合する以外は実施例59~112と同様に農薬組成物を得た。
更にアミスルブロムを20部混合する以外は実施例59~112と同様に農薬組成物を得た。
イネ苗立枯病菌(Pythium graminicola)をシバ種子培地で25℃、10日間培養した接種源を、床土を含むポット(5×5×6cm)の表層に接種した。供試製剤を500倍、1000倍となるように水で希釈した薬液をポット当たり約10mL(500ml/箱相当)均一に潅注した後、浸種および催芽したイネ種子(品種:コシヒカリ)を乾燥籾として約3g量(150g/箱相当)播種した。28℃、3日間育苗器中で出芽させた後、発病を促進するために2日間、5℃の低温処理を行った。低温処理後、ガラス温室内で育苗管理した。播種10日後にポット中の発病面積を指標に被害度を調査し、被害度から防除価を算出した。
(被害度)
0:発病なし
1:発病面積1 ~20%
2:発病面積 21~40%
3:発病面積 41~60%
4:発病面積 61~80%
5:発病面積 80~100%
(防除価)
防除価=100{1-(n/N)}
N=無処理区の被害度、n=各区の被害度
さらに、ヒドロキシイソキサゾールのみを含む処方(比較例1)に対する防除価の向上の程度を以下の基準を指標として評価した。
(基準)
A:比較例1の同じ希釈倍率のものと比較し、500倍希釈または1000倍希釈のいずれかで防除価1以上の向上
B:比較例1の同じ希釈倍率のものと比較し、500倍希釈または1000倍希釈のいずれも同等の防除価
C:比較例1の同じ希釈倍率のものと比較し、500倍希釈または1000倍希釈のいずれも劣る防除価
ペレット化されたテンサイ種子(品種:Jamon)120粒重をガラス瓶に入れた後、供試製剤を水で3倍希釈した薬液を、対ペレット種子重2.3%の割合(24ga.i./U相当)で、噴霧処理した。その後、育苗箱(32×24cm)に薬剤が処理された種子を播種し、ガラス温室内で静置した。播種21日後に、健全苗数、立枯苗数を調査し、立枯苗率を算出し、立枯苗率から防除価を算出した。
(立枯苗率)
100×(立枯苗数/健全苗数)
(防除価)
防除価=100{1-(n/N)}
N=無処理区の立枯苗率、n=各区の立枯苗率
さらに、ヒドロキシイソキサゾールのみを含む処方(比較例1)に対し、本発明の処方による防除価の向上の程度を以下の基準を指標として評価した。
(基準)
A:比較例1と比べ、防除価1以上の向上
B:比較例1と比べ、同等の防除価
C:比較例1と比べ、劣る防除価
イネ苗立枯病菌(Fusarium spp.)をえん麦培地で25℃、21日間培養した後、供試土壌に混和して汚染土壌を作成、床土としてポット(5×5×6cm)に充填した。供試製剤を500倍、1000倍となるように水で希釈した薬液をポット当たり約10mL(500ml/箱相当)均一に潅注した後、浸種および催芽したイネ種子(品種:コシヒカリ)を乾燥籾として約3g量(150g/箱相当)播種した。28℃、3日間育苗器中で出芽させた後、発病を促進するために3日間、5℃の低温処理を行った。低温処理後、ガラス温室内で育苗管理した。播種12日後にポット中の発病面積を指標に被害度を調査し、被害度から防除価を算出した。被害度、防除価の算出および基準は試験例1と同様に行った。
希釈倍率を500倍とする以外は試験例1と同様に試験を実施した。
(基準)
A:比較例1と比べ、防除価1以上の向上
B:比較例1と比べ、同等の防除価
C:比較例1と比べ、劣る防除価
Claims (9)
- (A)ヒドロキシイソキサゾール又はその塩と、
(B)下記(b1)~(b4)から選択される少なくとも1種の助剤と、
を含む、農薬組成物であって、
(b1)糖エステル型、アルキルアミン型、アルキルフェノール型及びエーテル型からなる群より選択される少なくとも1種の非イオン系界面活性剤、
(b2)カルボン酸型アニオン系界面活性剤、
(b3)炭酸カリウム、安息香酸カリウム、ソルビン酸カリウム、ピロ亜硫酸カリウム、第三リン酸カリウム、フタル酸水素カリウム、ヘキサメタリン酸カリウム、クエン酸三カリウム、乳酸カリウム、および酢酸カリウムから選択される少なくとも1種のカリウム塩、
(b4)メチル-5-ジメチルアミノ-2-メチル-5-オキソペンタン酸メチル、乳酸メチル、乳酸エチル、乳酸エチルヘキシル、および乳酸プロピルから選択される少なくとも1種の溶剤、
前記アルキルフェノール型非イオン系界面活性剤は、POEスチレン化フェニルエーテルおよびPOEトリスチリルフェニルエーテルから選択される少なくとも1種であり、
前記エーテル型非イオン系界面活性剤は、POEラウリルエーテル、POAトリスチリルフェニルエーテル、POEトリデシルエーテル、POEトリスチリルフェニルエーテル、PEGモノラウレート、POEアルキルエーテル、POAアルキルエーテル、POE多環フェニルエーテル、POEイソデシルエーテル、およびPOEアルキルエーテルリン酸から選択される少なくとも1種である、農薬組成物。
(ただし、以下の(i)~(xi)の場合を除く。
(i)下記一般式(I)で表されるイミダゾール系化合物を含む場合
(式中、Rは炭素数1~6のアルキル基又は炭素数1~6のアルコキシ基であり、nは1~5の整数である)
(ii)下記一般式(I)で表されるインドール系化合物を含む場合
〔式中、R1及びR2はそれぞれ独立して、C1-4アルキルであるか、又はR1とR2とが一緒になって形成するC4-6アルキレン若しくはC4-6アルキレンオキシであり;Yは水素原子、ハロゲン、シアノ基、ニトロ基、C1-4アルキルスルホニル、C1-4アルキル、C1-4アルコキシ、C1-4アルキルチオ、C1-4ハロアルキル、C1-4ハロアルコキシ又はC1-4ハロアルキルチオであり;R3及びR4はそれぞれ独立して、水素原子、C1-4アルキル、C3-6シクロアルキル、C2-4アルケニル、C2-4アルキニル、C1-4アルコキシ、C1-4アルキルチオ、ハロゲン、C1-4ハロアルキル、ニトロ基、シアノ基、ホルミル基又はC1-4アルコキシカルボニルであり;R5、R6、R7及びR8はそれぞれ独立して、水素原子、C1-4アルキル、C2-4アルケニル、C2-4アルキニル、C1-4アルコキシ、C1-4アルキルチオ、C1-4ハロアルキル、C1-4ハロアルコキシ、C1-4ハロアルキルチオ、C2-4ハロアルケニル、C2-4ハロアルキニル、C1-4アルコキシカルボニル、C1-4アルキルカルボニル、C1-4ハロアルキルカルボニル、C1-4アルキルカルボニルオキシ、C1-4アルキルスルホニル、C1-4ハロアルキルスルホニル、C1-4アルキルスルホキシ、C1-4アルコキシスルホニル、C1-4アルキルスルホニルオキシ、シアノ基、水酸基、ニトロ基、ホルミル基若しくはハロゲンであるか、又はR5、R6、R7及びR8のうちの2つが一緒になって形成するハロゲンで置換されてもよいC1-3アルキレンジオキシ基若しくはC3-6アルキレンである〕
(iii)下記式(I)で表されるオキシム置換アミド化合物、そのN-オキシド又はその塩を含む場合
[式中、G1は、下記のG1-1、G1-2、G1-3、G1-4、G1-5、G1-6、G1-7、G1-8又はG1-9で表される構造を表し、
G2は、下記のG2-1又はG2-2で表される構造を表し、
Wは、酸素原子又は硫黄原子を表し、
X1は、ハロゲン原子、ニトロ、メチル、ジフルオロメチル又はトリフルオロメチルを
表し、
X2は、水素原子を表し、さらにG1がG1-8で表される構造を表し、且つX1がトリフルオロメチルを表す場合には、X2はハロゲン原子を表してもよく、
X3は、水素原子又はメチルを表し、
X4は、水素原子又はハロゲン原子を表し、
X5は、水素原子を表し、
Y1は、水素原子、ハロゲン原子、メチル、トリフルオロメチル又はメトキシを表し、
Y2は、水素原子、ハロゲン原子、シアノ、C1~C6アルコキシ、メチルチオ、メチルスルフィニル又はメチルスルホニルを表し、
Y3は、水素原子、ハロゲン原子、シアノ、C1~C4アルキル、トリフルオロメチル、C2~C4アルケニル、C2~C6アルキニル、R6によって任意に置換された(C2~C6)アルキニル、-OR7a、C1~C4アルキルチオ、-C(R8)=NOR9又はフェニルを表し、
Y4は、水素原子又はハロゲン原子を表し、
Y5は、水素原子を表し、
R1は、C1~C6アルキル、ハロ(C1~C4)アルキル、R10によって置換された(C1~C4)アルキル、C3~C6シクロアルキル、C3~C6アルケニル、ハロ(C3~C4)アルケニル、C3~C6アルキニル又はフェニルを表し、
R2は、水素原子、メチル又はエチルを表し、ただし、G1がG1-1で表される構造を表し、X1が塩素原子を表し、X2、X3及びX5が水素原子を表し、X4が水素原子又は塩素原子を表し、且つG2がG2-1で表される構造を表し、Y3が塩素原子を表し、Y1、Y2、Y4及びY5が水素原子を表す場合には、R2はメチル又はエチルを表し、
R3は、水素原子又はメチルを表すか、或いは、R2とR3とは一緒になってシクロプロピル環を形成してもよいことを表し、
R4は、水素原子、ハロ(C1~C4)アルキルチオ、C1~C4アルキルカルボニル又はC1~C4アルコキシカルボニルを表し、
R5は、メチルを表し、
R6は、ハロゲン原子、C3~C6シクロアルキル、ヒドロキシ(C3~C6)シクロアルキル、C5~C6シクロアルケニル、-OH、-OR7b、C1~C4アルキルカルボニルオキシ、C1~C4アルキルスルホニルオキシ、C1~C4アルキルチオ、トリメチルシリル、-C(R8)=NOR9、フェニル又は(Z)mによって置換されたフェニルを表し、
R7a及びR7bは、各々独立して、C1~C4アルキル、ハロ(C1~C4)アルキル、C1~C4アルコキシ(C1~C2)アルキル、C3~C4アルキニル又は(Z)mによって置換されたフェニルを表し、
R8は、水素原子又はメチルを表し、
R9は、メチル又はエチルを表し、
R10は、シアノ、C3~C6シクロアルキル、C1~C4アルコキシ、C1~C4アルキルチオ、トリメチルシリル、-C(R11)=NOR12、フェニル又は(Z)mによって置換されたフェニルを表し、
R11は、メチルを表し、
R12は、メチル又はエチルを表し、
Zは、ハロゲン原子、シアノ、ニトロ、C1~C4アルキル、トリフルオロメチル、メトキシ、トリフルオロメトキシ、トリフルオロメチルチオ又はフェニルを表し、mが2以上を表す場合には、各々のZは互いに同一であっても又は互いに相異なっていてもよく、さらに、2つのZが隣接する場合には、隣接する2つのZは-CH=CH-CH=CH-を形成することにより、それぞれのZが結合する炭素原子と共に6員環を形成してもよく、
mは、1、2又は3の整数を表す。]
(iv)下記式(I)による少なくとも1種の化合物を含む場合
(式中、
Xは、窒素およびC-Halから選択され、
Yは、窒素およびC-Halから選択され、
R1は、水素、ハロゲン、Halで置換されているC1-C6アルキル、Halで置換されているC2-C6アルケニル、Halで置換されているC3-C6シクロアルキル、ハロゲン、シアノ、およびアルコキシの群から選択される1つ以上の置換基で置換されているフェニルから選択され、
R2は、ヒドロキシ、C1-C6チオアルキル、C1-C6アミノアルキル、ハロゲン、シアノ、C1-C6アルコキシ、C1-C6アルキル、C1-C6アルキルカルボニルの群から選択される1つ以上の置換基で置換されているC1-C6アルコキシ、ハロゲン、シアノ、アルコキシ、C1-C6アルキル、アルキルアミノ、ホルミル、C1-C6アルコキシ、C1-C6アルキルカルボニル、C1-C6アルコキシカルボニルの群から選択される1つ以上の置換基で置換されているフェノキシ、シアノ、ハロゲン、C1-C6アルキル、C1-C6アルコキシ、C1-C6アルキルカルボニルの群から選択される1つ以上の置換基で置換されているアニリンから選択され、
Halは、ハロゲンである。)
(v)リン酸一水素二カリウム、リン酸二水素カリウム、リン酸カリウム、硝酸カリウム、硫酸カリウム、または塩化カリウムである肥料を含む場合
(vi)下記式(1)で表される化合物を含む場合
(vii)S-5-メチル-2-メチルチオ-5-フェニル-3-フェニルアミノ-3,5-ジヒドロ-4H-イミダゾール-4-オンを含む場合
(viii)プロチオコナゾールを含む場合
(ix)ジノテフランを含む場合
(x)ヒドロキシイソキサゾールおよびチフルザミドを質量比1:5?5:1で含む場合
(xi)ピカルブトラゾクスを含む場合) - (b2)カルボン酸型アニオン界面活性剤が、ポリカルボン酸塩およびポリカルボン酸共重合物ナトリウム塩から選択される少なくとも1種である請求項1に記載の農薬組成物。
- (b3)カリウム塩が、炭酸カリウム、および安息香酸カリウムから選択される少なくとも1種である請求項1または2に記載の農薬組成物。
- (B)助剤は、前記(b1)~前記(b4)から選択される2種以上含む、請求項1~3のいずれか1項に記載の農薬組成物。
- 請求項1~4のいずれか1項に記載の農薬組成物を含む、植物病害に対する防除剤。
- 前記植物病害が、Aphanomyces(アファノマイセス)属菌、Pythium(ピシウム)属菌、Fusarium(フザリウム)属菌、Rhizoctonia(リゾクトニア)属菌、Screlotium(スクレロチウム)属菌、Cochiliobolus(コクリオボルス)属菌、Collletotrichum(コレトトリカム)属菌、Magnaporthe(マグナポルセ)属菌、Rosellinia(ロセリニア)属菌、Sclerotinia(スクレロチニア)属菌のいずれかによって引き起こされる病害である、請求項5に記載の防除剤。
- 請求項1~4のいずれか1項に記載の農薬組成物を栽培土壌または植物へ施用する植物病害防除方法。
- 植物への前記施用が、請求項1~4のいずれか1項に記載の農薬組成物の、植物体または植物種子との接触又は当該植物の作付けに係る栽培土壌への含有又は当該植物の根若しくは地下茎への接触によるものである、請求項7に記載の植物病害防除方法。
- (A)ヒドロキシイソキサゾール又はその塩と、(B)下記(b1)~(b4)から選択される少なくとも1種の助剤と、を植物体へ施用する、防除効果増強方法であって、
(b1)糖エステル型、アルキルアミン型、アルキルフェノール型及びエーテル型からなる群より選択される少なくとも1種の非イオン系界面活性剤、
(b2)カルボン酸型アニオン系界面活性剤、
(b3)炭酸カリウム、安息香酸カリウム、ソルビン酸カリウム、ピロ亜硫酸カリウム、第三リン酸カリウム、フタル酸水素カリウム、ヘキサメタリン酸カリウム、クエン酸三カリウム、乳酸カリウム、および酢酸カリウムから選択される少なくとも1種のカリウム塩、
(b4)メチル-5-ジメチルアミノ-2-メチル-5-オキソペンタン酸メチル、乳酸メチル、乳酸エチル、乳酸エチルヘキシル、および乳酸プロピルから選択される少なくとも1種の溶剤、
前記アルキルフェノール型非イオン系界面活性剤は、POEスチレン化フェニルエーテルおよびPOEトリスチリルフェニルエーテルから選択される少なくとも1種であり、
前記エーテル型非イオン系界面活性剤は、POEラウリルエーテル、POAトリスチリルフェニルエーテル、POEトリデシルエーテル、POEトリスチリルフェニルエーテル、PEGモノラウレート、POEアルキルエーテル、POAアルキルエーテル、POE多環フェニルエーテル、POEイソデシルエーテル、およびPOEアルキルエーテルリン酸から選択される少なくとも1種である、防除効果増強方法。
(ただし、以下の(i)~(xi)の場合を除く。
(i)下記一般式(I)で表されるイミダゾール系化合物を含む場合
(式中、Rは炭素数1~6のアルキル基又は炭素数1~6のアルコキシ基であり、nは1~5の整数である)
(ii)下記一般式(I)で表されるインドール系化合物を含む場合
〔式中、R1及びR2はそれぞれ独立して、C1-4アルキルであるか、又はR1とR2とが一緒になって形成するC4-6アルキレン若しくはC4-6アルキレンオキシであり;Yは水素原子、ハロゲン、シアノ基、ニトロ基、C1-4アルキルスルホニル、C1-4アルキル、C1-4アルコキシ、C1-4アルキルチオ、C1-4ハロアルキル、C1-4ハロアルコキシ又はC1-4ハロアルキルチオであり;R3及びR4はそれぞれ独立して、水素原子、C1-4アルキル、C3-6シクロアルキル、C2-4アルケニル、C2-4アルキニル、C1-4アルコキシ、C1-4アルキルチオ、ハロゲン、C1-4ハロアルキル、ニトロ基、シアノ基、ホルミル基又はC1-4アルコキシカルボニルであり;R5、R6、R7及びR8はそれぞれ独立して、水素原子、C1-4アルキル、C2-4アルケニル、C2-4アルキニル、C1-4アルコキシ、C1-4アルキルチオ、C1-4ハロアルキル、C1-4ハロアルコキシ、C1-4ハロアルキルチオ、C2-4ハロアルケニル、C2-4ハロアルキニル、C1-4アルコキシカルボニル、C1-4アルキルカルボニル、C1-4ハロアルキルカルボニル、C1-4アルキルカルボニルオキシ、C1-4アルキルスルホニル、C1-4ハロアルキルスルホニル、C1-4アルキルスルホキシ、C1-4アルコキシスルホニル、C1-4アルキルスルホニルオキシ、シアノ基、水酸基、ニトロ基、ホルミル基若しくはハロゲンであるか、又はR5、R6、R7及びR8のうちの2つが一緒になって形成するハロゲンで置換されてもよいC1-3アルキレンジオキシ基若しくはC3-6アルキレンである〕
(iii)下記式(I)で表されるオキシム置換アミド化合物、そのN-オキシド又はその塩を含む場合
[式中、G1は、下記のG1-1、G1-2、G1-3、G1-4、G1-5、G1-6、G1-7、G1-8又はG1-9で表される構造を表し、
G2は、下記のG2-1又はG2-2で表される構造を表し、
Wは、酸素原子又は硫黄原子を表し、
X1は、ハロゲン原子、ニトロ、メチル、ジフルオロメチル又はトリフルオロメチルを
表し、
X2は、水素原子を表し、さらにG1がG1-8で表される構造を表し、且つX1がトリフルオロメチルを表す場合には、X2はハロゲン原子を表してもよく、
X3は、水素原子又はメチルを表し、
X4は、水素原子又はハロゲン原子を表し、
X5は、水素原子を表し、
Y1は、水素原子、ハロゲン原子、メチル、トリフルオロメチル又はメトキシを表し、
Y2は、水素原子、ハロゲン原子、シアノ、C1~C6アルコキシ、メチルチオ、メチルスルフィニル又はメチルスルホニルを表し、
Y3は、水素原子、ハロゲン原子、シアノ、C1~C4アルキル、トリフルオロメチル、C2~C4アルケニル、C2~C6アルキニル、R6によって任意に置換された(C2~C6)アルキニル、-OR7a、C1~C4アルキルチオ、-C(R8)=NOR9又はフェニルを表し、
Y4は、水素原子又はハロゲン原子を表し、
Y5は、水素原子を表し、
R1は、C1~C6アルキル、ハロ(C1~C4)アルキル、R10によって置換された(C1~C4)アルキル、C3~C6シクロアルキル、C3~C6アルケニル、ハロ(C3~C4)アルケニル、C3~C6アルキニル又はフェニルを表し、
R2は、水素原子、メチル又はエチルを表し、ただし、G1がG1-1で表される構造を表し、X1が塩素原子を表し、X2、X3及びX5が水素原子を表し、X4が水素原子又は塩素原子を表し、且つG2がG2-1で表される構造を表し、Y3が塩素原子を表し、Y1、Y2、Y4及びY5が水素原子を表す場合には、R2はメチル又はエチルを表し、
R3は、水素原子又はメチルを表すか、或いは、R2とR3とは一緒になってシクロプロピル環を形成してもよいことを表し、
R4は、水素原子、ハロ(C1~C4)アルキルチオ、C1~C4アルキルカルボニル又はC1~C4アルコキシカルボニルを表し、
R5は、メチルを表し、
R6は、ハロゲン原子、C3~C6シクロアルキル、ヒドロキシ(C3~C6)シクロアルキル、C5~C6シクロアルケニル、-OH、-OR7b、C1~C4アルキルカルボニルオキシ、C1~C4アルキルスルホニルオキシ、C1~C4アルキルチオ、トリメチルシリル、-C(R8)=NOR9、フェニル又は(Z)mによって置換されたフェニルを表し、
R7a及びR7bは、各々独立して、C1~C4アルキル、ハロ(C1~C4)アルキル、C1~C4アルコキシ(C1~C2)アルキル、C3~C4アルキニル又は(Z)mによって置換されたフェニルを表し、
R8は、水素原子又はメチルを表し、
R9は、メチル又はエチルを表し、
R10は、シアノ、C3~C6シクロアルキル、C1~C4アルコキシ、C1~C4アルキルチオ、トリメチルシリル、-C(R11)=NOR12、フェニル又は(Z)mによって置換されたフェニルを表し、
R11は、メチルを表し、
R12は、メチル又はエチルを表し、
Zは、ハロゲン原子、シアノ、ニトロ、C1~C4アルキル、トリフルオロメチル、メトキシ、トリフルオロメトキシ、トリフルオロメチルチオ又はフェニルを表し、mが2以上を表す場合には、各々のZは互いに同一であっても又は互いに相異なっていてもよく、さらに、2つのZが隣接する場合には、隣接する2つのZは-CH=CH-CH=CH-を形成することにより、それぞれのZが結合する炭素原子と共に6員環を形成してもよく、
mは、1、2又は3の整数を表す。]
(iv)下記式(I)に表される化合物を含む場合
(式中、
Xは、窒素およびC-Halから選択され、
Yは、窒素およびC-Halから選択され、
R1は、水素、ハロゲン、Halで置換されているC1-C6アルキル、Halで置換されているC2-C6アルケニル、Halで置換されているC3-C6シクロアルキル、ハロゲン、シアノ、およびアルコキシの群から選択される1つ以上の置換基で置換されているフェニルから選択され、
R2は、ヒドロキシ、C1-C6チオアルキル、C1-C6アミノアルキル、ハロゲン、シアノ、C1-C6アルコキシ、C1-C6アルキル、C1-C6アルキルカルボニルの群から選択される1つ以上の置換基で置換されているC1-C6アルコキシ、ハロゲン、シアノ、アルコキシ、C1-C6アルキル、アルキルアミノ、ホルミル、C1-C6アルコキシ、C1-C6アルキルカルボニル、C1-C6アルコキシカルボニルの群から選択される1つ以上の置換基で置換されているフェノキシ、シアノ、ハロゲン、C1-C6アルキル、C1-C6アルコキシ、C1-C6アルキルカルボニルの群から選択される1つ以上の置換基で置換されているアニリンから選択され、
Halは、ハロゲンである。)
(v)リン酸二水素カリウム、硝酸カリウム、硫酸カリウム、または塩化カリウムである肥料を含む場合
(vi) 下記式(1)で表される化合物を含む場合
(vii)S-5-メチル-2-メチルチオ-5-フェニル-3-フェニルアミノ-3,5-ジヒドロ-4H-イミダゾール-4-オンを含む場合
(viii)プロチオコナゾールを含む場合
(ix)ジノテフランを含む場合
(x)ヒドロキシイソキサゾールおよびチフルザミドを質量比1:5?5:1で含む場合
(xi)ピカルブトラゾクスを含む場合)
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