JP7369202B2 - 半導体レーザダイオードおよび半導体レーザダイオードの製造方法 - Google Patents
半導体レーザダイオードおよび半導体レーザダイオードの製造方法 Download PDFInfo
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- 239000004065 semiconductor Substances 0.000 title claims description 318
- 238000004519 manufacturing process Methods 0.000 title claims description 26
- 238000000034 method Methods 0.000 claims description 43
- 229910052751 metal Inorganic materials 0.000 claims description 18
- 239000002184 metal Substances 0.000 claims description 18
- 239000003989 dielectric material Substances 0.000 claims description 14
- 238000005476 soldering Methods 0.000 claims description 5
- 230000031700 light absorption Effects 0.000 claims description 3
- 239000010410 layer Substances 0.000 description 413
- 239000000463 material Substances 0.000 description 57
- 239000000758 substrate Substances 0.000 description 36
- 238000002347 injection Methods 0.000 description 19
- 239000007924 injection Substances 0.000 description 19
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 18
- 238000005253 cladding Methods 0.000 description 16
- 230000015572 biosynthetic process Effects 0.000 description 15
- 230000008569 process Effects 0.000 description 14
- 230000000694 effects Effects 0.000 description 11
- 238000005530 etching Methods 0.000 description 11
- 238000002161 passivation Methods 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 9
- 239000011787 zinc oxide Substances 0.000 description 9
- 230000003287 optical effect Effects 0.000 description 8
- 230000005855 radiation Effects 0.000 description 7
- 229910006404 SnO 2 Inorganic materials 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 3
- 239000002019 doping agent Substances 0.000 description 3
- 230000005670 electromagnetic radiation Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- 229910002704 AlGaN Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000001312 dry etching Methods 0.000 description 2
- -1 for example Chemical class 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000010849 ion bombardment Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 150000002927 oxygen compounds Chemical class 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910002601 GaN Inorganic materials 0.000 description 1
- 229910005540 GaP Inorganic materials 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- 229910017911 MgIn Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910003363 ZnMgO Inorganic materials 0.000 description 1
- 229910007717 ZnSnO Inorganic materials 0.000 description 1
- 229910007709 ZnTe Inorganic materials 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 description 1
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 1
- CFEAAQFZALKQPA-UHFFFAOYSA-N cadmium(2+);oxygen(2-) Chemical compound [O-2].[Cd+2] CFEAAQFZALKQPA-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002800 charge carrier Substances 0.000 description 1
- 230000002925 chemical effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 230000005525 hole transport Effects 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910003465 moissanite Inorganic materials 0.000 description 1
- 238000001451 molecular beam epitaxy Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- SBIBMFFZSBJNJF-UHFFFAOYSA-N selenium;zinc Chemical compound [Se]=[Zn] SBIBMFFZSBJNJF-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000000927 vapour-phase epitaxy Methods 0.000 description 1
- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 description 1
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Description
基板を用意するステップ、
エピタキシャル成長により半導体層列を設けるステップ、
後でコンタクト領域となる領域をマスクで覆うステップ、
コンタクト領域内においてリッジをエッチングするステップ、および/またはコンタクト領域側方で横方向に位置する1つまたは複数のカバー領域をダメージ形成処理するステップ、
マスクを除去するステップ、
特に好ましくは半導体層列のためのp型コンタクトを成すことができる透明導電カバー層を設けるステップ、特に面全体にわたり設けるステップ、
1つまたは複数の金属製コンタクト素子をカバー層上に、かつ/またはカバー層のところに設けるステップ。
2 半導体層列
3 活性層
4 カバー層
5 活性領域
6 光出射面
7 背面
8 光
9 リッジ
10 活性領域を規定する要素
11 コンタクト素子
12 ダメージ形成処理された半導体構造
13 金属製コンタクト層
14 透明導電コンタクト層
18 メサトレンチ
19 誘電体材料
20 上面
21 コンタクト領域
22 カバー領域
31 バッファ層
32、35 クラッド層
33、34 導波路層
41 第1の層
42 第2の層
91 横方向
92 垂直方向
93 長手方向
100 半導体レーザダイオード
Claims (17)
- 半導体レーザダイオード(100)であって、
垂直方向に成長させられた半導体層列(2)と、
該半導体層列上に設けられた透明導電カバー層(4)と
を有し、前記半導体層列(2)は活性層(3)を含み、該活性層(3)は、動作中、長手方向(93)に延在する少なくとも1つの活性領域(5)内で光(8)を生成するように調整されて設けられており、
前記半導体層列は、垂直方向(92)において上面(20)で終端し、該上面は、垂直方向で前記活性領域の上方に配置されたコンタクト領域(21)と、前記垂直方向および前記長手方向に対し垂直な横方向(91)において前記コンタクト領域に直接つながっている少なくとも1つのカバー領域(22)とを有し、
前記透明導電カバー層は、前記コンタクト領域上および前記少なくとも1つのカバー領域上で切れ目なく上面上に設けられており、
前記透明導電カバー層は少なくとも、前記少なくとも1つのカバー領域内で、前記半導体層列の前記上面上に直接設けられており、
前記少なくとも1つの活性領域を規定する少なくとも1つの要素(10)が設けられており、該要素(10)は前記透明導電カバー層によって覆われ、
前記活性領域を規定する前記少なくとも1つの要素(10)は、前記上面の前記コンタクト領域内に形成されたリッジ(9)を有し、該リッジ(9)は、透明導電コンタクト層により形成されており、該透明導電コンタクト層は透明導電酸化物により形成されており、
前記透明導電コンタクト層は第1の透明導電酸化物を有し、前記透明導電カバー層はこれと異なる第2の透明導電酸化物を有し、前記第2の透明導電酸化物は前記第1の透明導電酸化物より屈折率が低い、
半導体レーザダイオード(100)。 - 前記透明導電カバー層は透明導電酸化物を有する、
請求項1記載の半導体レーザダイオード。 - 前記透明導電カバー層において前記半導体層列とは反対側に、金属製コンタクト素子(11)が配置されている、
請求項1記載の半導体レーザダイオード。 - 前記金属製コンタクト素子は、当該半導体レーザダイオードをワイヤボンディングまたは半田付けするためのボンド層である、
請求項3記載の半導体レーザダイオード。 - 前記リッジは、前記活性領域内で生成された光の屈折率導波のためのリッジ導波路構造を成す、
請求項1記載の半導体レーザダイオード。 - 前記リッジは、該リッジにより前記活性領域内で生成された光の屈折率導波がもたされないように低い高さを有する、
請求項1記載の半導体レーザダイオード。 - 前記活性領域を規定する前記少なくとも1つの要素は、ダメージ形成処理された半導体構造(12)を前記少なくとも1つのカバー領域内に有する、
請求項1項記載の半導体レーザダイオード。 - 前記ダメージ形成処理された半導体構造は、前記半導体層列の前記上面に形成されている、
請求項7記載の半導体レーザダイオード。 - 前記上面に直接隣接して前記コンタクト領域内で前記半導体層列の前記上面上に、前記透明導電カバー層によって覆われた金属製コンタクト層または透明導電コンタクト層が配置されている、
請求項1または2記載の半導体レーザダイオード。 - 前記透明導電カバー層は、少なくとも前記コンタクト領域内に第1の透明導電酸化物を備えた第1の層を有し、前記少なくとも1つのカバー領域内に、前記第1の透明導電酸化物とは異なる第2の透明導電酸化物を備えた第2の層を有し、前記第1の層が前記第2の層を前記少なくとも1つのカバー領域内で覆っている、
請求項1記載の半導体レーザダイオード。 - 前記第2の層は、前記少なくとも1つのカバー領域内にのみ配置されている、
請求項10記載の半導体レーザダイオード。 - 前記半導体レーザダイオードには前記上面上に、前記活性領域に作用を及ぼす誘電体材料は設けられていない、
請求項1または2記載の半導体レーザダイオード。 - 前記上面上に複数のコンタクト領域が設けられており、
前記活性層内には動作中、複数の活性領域が存在しており、該活性領域各々の上方で垂直方向にそれぞれ1つのコンタクト領域が配置されており、
該コンタクト領域は、複数のカバー領域のうちのカバー領域によって互いに分離されており、
前記活性領域を規定する複数の要素が設けられており、該要素は前記透明導電カバー層によって覆われる、
請求項1記載の半導体レーザダイオード。 - 前記透明導電カバー層は、複数の前記コンタクト領域および複数の前記カバー領域の上方に切れ目なく配置されている、
請求項13記載の半導体レーザダイオード。 - 前記透明導電カバー層は、互いに分離された複数の区間に分割されており、該区間各々は1つの活性領域に割り当てられている、
請求項13記載の半導体レーザダイオード。 - 前記第2の透明導電酸化物は、前記第1の透明導電酸化物よりも光吸収率が低い、請求項10記載の半導体レーザダイオード。
- 請求項1または2記載の半導体レーザダイオード(100)の製造方法であって、
活性層(3)と、コンタクト領域(21)および少なくとも1つのカバー領域(22)を備えた上面(20)とを有する半導体層列(2)を用意するステップと、
活性領域を規定する少なくとも1つの要素(10)を形成するステップと、
前記透明導電カバー層(4)を、前記コンタクト領域上および前記少なくとも1つのカバー領域上に切れ目なく設けるステップと
を有する、半導体レーザダイオード(100)の製造方法。
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