JP7282739B2 - 抗微生物組成物 - Google Patents
抗微生物組成物 Download PDFInfo
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- JP7282739B2 JP7282739B2 JP2020506322A JP2020506322A JP7282739B2 JP 7282739 B2 JP7282739 B2 JP 7282739B2 JP 2020506322 A JP2020506322 A JP 2020506322A JP 2020506322 A JP2020506322 A JP 2020506322A JP 7282739 B2 JP7282739 B2 JP 7282739B2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing carboxylic groups or thio analogues thereof, directly attached by the carbon atom to a cycloaliphatic ring; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/185—Acids; Anhydrides, halides or salts thereof, e.g. sulfur acids, imidic, hydrazonic or hydroximic acids
- A61K31/19—Carboxylic acids, e.g. valproic acid
- A61K31/20—Carboxylic acids, e.g. valproic acid having a carboxyl group bound to a chain of seven or more carbon atoms, e.g. stearic, palmitic, arachidic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8129—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers or esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers, e.g. polyvinylmethylether
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Epidemiology (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Dermatology (AREA)
- Pharmacology & Pharmacy (AREA)
- Medicinal Chemistry (AREA)
- Cosmetics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicinal Preparation (AREA)
Description
a.ポリビニルアルコールを含む水溶性ビニルポリマー0.01~10重量%と、
b.4.5を超えるpKaを有するカルボン酸0.1~20重量%と、
c.アニオン性界面活性剤1~80重量%とを含む抗微生物組成物に関し、
組成物のpHは4.5~6.5の範囲にある。
組成物は、ポリビニルアルコールを含む水溶性ビニルポリマーを含む。水溶性ビニルポリマーは、界面活性剤などの成分とともに使用される場合、増粘剤、粘度調整剤および複合体形成剤として使用されることが知られている。
本発明の組成物はまた、4.5を超えるpKa値を有するカルボン酸またはその誘導体を0.1~20重量%、好ましくは0.1~15重量%、さらに好ましくは0.2~10重量%、最も好ましくは0.2~5重量%含む。
pKaの値が高いほど、所与のpHでの解離の程度が低くなる。これは、周知のヘンダーソン・ハッセルバルヒ式によって支配される。
本発明の組成物はまた、アニオン性界面活性剤を含む。
溶媒、例えば、エチルアルコール、イソプロパノール、アセトン、エチレングリコールモノエチルエーテル、ジエチレングリコールモノブチルエーテル、ジエチレングリコールモノエチルエーテル;
固形石鹸の場合、乾燥した皮膚を取り除くのを助ける、平均直径が50μmを超える粒子を含有してもよい。理論に拘束されないが、剥離の程度は粒子の大きさおよび形態に依存する。大きくて粗い粒子は通常、非常に手触りが粗く、刺激性である。非常に小さな粒子は効果的なスクラブ剤として機能しない場合がある。当技術分野で使用されるこのようなスクラブ剤には、天然ミネラル、例えば、シリカ、タルク、方解石、軽石、リン酸三カルシウム;種子、例えば、イネ、アプリコットの種子など;砕いた殻、例えば、アーモンドおよびクルミの殻;オートミール;ポリマー、例えば、ポリエチレンおよびポリプロピレンのビーズ、花びらならびに葉;微結晶ワックスビーズ;ホホバエステルビーズなどが含まれる。これらのスクラブ剤には、ミクロンサイズから数mmの範囲の様々な粒径および形態がある。これらはまた、様々な硬さを有する。いくつかの例が、タルク、方解石、軽石、クルミの殻、ドロマイトおよびポリエチレンである。
プロトコル
以下の実施例に示される組成物はいずれも、以下のそれぞれの実施例および手順に示される量(重量パーセント単位)のポリマーおよびカルボン酸を使用して調製した。
(American Standard Test Method2783)に従って、抗微生物効果の評価を行った。トリプトソイ寒天(TAS)プレート上で試験生物を一晩(22±2時間)増殖させた。生物は、元の供給源から3回を超えて継代しなかった。必要な細胞数を達成するのに十分な好適な量の生理食塩水に再懸濁することにより、細胞の光学密度(OD)に基づいて細胞数を調整した。分光光度計を使用して、細胞の620nmでのODを各試験生物の細胞数に標準化した。コンタクトキルアッセイのために生理食塩水中でODを2.0に調整することにより、1×109コロニー形成単位(CFU)/mLの最小最終懸濁液を得た。
5を超えるログ減少はCFUの数が99.99%減少することを意味し、0.5未満のログ減少はCFUの数が減少しないことを意味し、これは、抗微生物効果がないことを意味する。また、5を超えるログ減少は、完全な死滅を意味する。
4-メチルオクタン酸-(pKa=4.93;Aldrich製、カタログ番号W357502)
ヘキサン酸-(pKa=4.88;Aldrich製、カタログ番号153745)
2-エチルヘキサン酸-(pKa=4.72;Aldrich製、カタログ番号538701)
シクロヘキサン酸-(pKa=4.92;Aldrich製、カタログ番号101834)
サリチル酸-(pKa=2.97、Sigma Aldrich製、カタログ番号247588)
クエン酸-(pKa=3.13、Sigma Aldrich製、カタログ番号C83155)
乳酸-(pKa=3.86、Sigma Aldrich製、カタログ番号252476)
リンゴ酸-(pKa=3.4、Sigma Aldrich製、カタログ番号M8304)
グリコール酸-(pKa=3.6、Sigma Aldrich製、カタログ番号V900017)
PVA-ALDRICH、カタログ番号363170、
PVP-SIGMA-ALDRICH製、名称PVP10
PAA-ALDRICH製、カタログ番号523925、
ポリスチレンスルホネート(PSS)-AkzoNobel製、名称FLEXAN(登録商標)IIの下に販売、
カルボキシメチルセルロースナトリウム(SCMC)-ALDRICH製、カタログ番号419273、
ヒドロキシエチルセルロース(HEC)-SIGMA製、カタログ番号09368、および
アルギン酸ナトリウム-Thomas Baker製、カタログ番号142582。
ラウリル硫酸ナトリウム(SLS)、カタログ番号62862、Sigma-Aldrich製。
Claims (12)
- 抗微生物組成物であって、
a.ポリビニルアルコールを含む水溶性ビニルポリマー0.01~10重量%と、
b.4.5を超えるpKaを有するカルボン酸0.1~20重量%と、
c.アニオン性界面活性剤1~80重量%と
を含み、
前記組成物のpHが5~6.5の範囲にあり、
アニオン性界面活性剤が、ラウリル硫酸ナトリウムまたはラウリルエーテル硫酸ナトリウムから選択される抗微生物組成物。 - 前記ビニルポリマーがポリビニルアルコールである、請求項1に記載の組成物。
- 前記カルボン酸が、鎖長C4~C16を有する脂肪族カルボン酸から選択される、請求項1または2に記載の組成物。
- 前記脂肪族カルボン酸が、直鎖または分岐脂肪族カルボン酸、環状脂肪族カルボン酸およびそれらの混合物から選択される、請求項3に記載の組成物。
- 前記脂肪族カルボン酸が、ヘキサン酸、シクロヘキサン酸、2-エチルヘキサン酸、オクタン酸、4-メチルオクタン酸およびそれらの混合物から選択される、請求項4に記載の組成物。
- 化粧品として許容される基剤をさらに含む、請求項1から5のいずれか一項に記載の組成物。
- 請求項1から6のいずれか一項に記載の組成物を表面に適用する工程を含む、表面を洗浄または消毒する非治療的方法。
- 前記組成物がウォッシュオフ組成物の形態であり、前記適用された組成物を少なくとも部分的に除去する追加の工程がある、請求項7に記載の方法。
- 前記組成物を少なくとも部分的に除去する前記工程が、前記基材上に前記組成物を適用する工程の後5分未満以内に実行される、請求項8に記載の方法。
- 抗微生物効果のための、請求項1から6のいずれか一項に記載の組成物の非治療的使用。
- 手指衛生の改善のための、請求項1から6のいずれか一項に記載の組成物の非治療的使用。
- 抗微生物組成物において該組成物の抗微生物効果を改善するための、(a)ポリビニルアルコールを含む水溶性ビニルポリマー0.01~10重量%と、(b)4.5を超えるpKaを有するカルボン酸またはその誘導体0.1~20重量%と、(c)ラウリル硫酸ナトリウムまたはラウリルエーテル硫酸ナトリウムから選択されるアニオン性界面活性剤1~80重量%との組合せの非治療的使用であって、前記組成物のpHが5~6.5の範囲にある前記使用。
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EP17187899.4 | 2017-08-25 | ||
EP17187899 | 2017-08-25 | ||
PCT/EP2018/071043 WO2019038049A1 (en) | 2017-08-25 | 2018-08-02 | ANTIMICROBIAL COMPOSITION |
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JP2020531412A JP2020531412A (ja) | 2020-11-05 |
JP7282739B2 true JP7282739B2 (ja) | 2023-05-29 |
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Country Status (9)
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US (1) | US11278480B2 (ja) |
EP (1) | EP3672408B1 (ja) |
JP (1) | JP7282739B2 (ja) |
CN (1) | CN111065268B (ja) |
CA (1) | CA3072651A1 (ja) |
EA (1) | EA202090535A1 (ja) |
MX (1) | MX2020002022A (ja) |
WO (1) | WO2019038049A1 (ja) |
ZA (1) | ZA202000606B (ja) |
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CN111107744A (zh) | 2017-09-26 | 2020-05-05 | 埃科莱布美国股份有限公司 | 酸性/阴离子抗微生物组合物和杀病毒组合物以及其用途 |
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JP2016510339A (ja) | 2013-02-04 | 2016-04-07 | スリーエム イノベイティブ プロパティズ カンパニー | 抗菌性組成物、ワイプ、及び方法 |
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US11278480B2 (en) | 2022-03-22 |
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CN111065268B (zh) | 2022-01-25 |
EP3672408A1 (en) | 2020-07-01 |
EP3672408B1 (en) | 2021-10-13 |
CA3072651A1 (en) | 2019-02-28 |
EA202090535A1 (ru) | 2020-06-03 |
BR112020001901A2 (pt) | 2020-08-04 |
CN111065268A (zh) | 2020-04-24 |
JP2020531412A (ja) | 2020-11-05 |
US20200246235A1 (en) | 2020-08-06 |
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