JP7262392B2 - コンフォーマルグラフェン分散によるナノ構造リチウムイオンバッテリ電極複合材料 - Google Patents
コンフォーマルグラフェン分散によるナノ構造リチウムイオンバッテリ電極複合材料 Download PDFInfo
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- JP7262392B2 JP7262392B2 JP2019542529A JP2019542529A JP7262392B2 JP 7262392 B2 JP7262392 B2 JP 7262392B2 JP 2019542529 A JP2019542529 A JP 2019542529A JP 2019542529 A JP2019542529 A JP 2019542529A JP 7262392 B2 JP7262392 B2 JP 7262392B2
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/184—Preparation
- C01B32/19—Preparation by exfoliation
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/194—After-treatment
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0404—Methods of deposition of the material by coating on electrode collectors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0416—Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Dispersion Chemistry (AREA)
- Composite Materials (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762464167P | 2017-02-27 | 2017-02-27 | |
| US62/464,167 | 2017-02-27 | ||
| PCT/US2018/019965 WO2018217263A2 (en) | 2017-02-27 | 2018-02-27 | Nanostructured lithium-ion battery electrode composite materials via conformal graphene dispersion |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2020508541A JP2020508541A (ja) | 2020-03-19 |
| JP2020508541A5 JP2020508541A5 (enExample) | 2021-03-04 |
| JP7262392B2 true JP7262392B2 (ja) | 2023-04-21 |
Family
ID=63355355
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019542529A Active JP7262392B2 (ja) | 2017-02-27 | 2018-02-27 | コンフォーマルグラフェン分散によるナノ構造リチウムイオンバッテリ電極複合材料 |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US11088392B2 (enExample) |
| EP (1) | EP3586388A4 (enExample) |
| JP (1) | JP7262392B2 (enExample) |
| KR (1) | KR102520522B1 (enExample) |
| CN (1) | CN110832681B (enExample) |
| WO (1) | WO2018217263A2 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20230299330A1 (en) * | 2017-02-27 | 2023-09-21 | Northwestern University | Graphene-functionalized composites for battery anodes, forming methods and applications of same |
| WO2018217263A2 (en) * | 2017-02-27 | 2018-11-29 | Northwestern University | Nanostructured lithium-ion battery electrode composite materials via conformal graphene dispersion |
| JP2021063002A (ja) * | 2019-10-11 | 2021-04-22 | ハリマ化成株式会社 | 単層グラフェンの製造方法、単層グラフェン分散体の製造方法及び単層グラフェン分散体 |
| JP6885487B1 (ja) * | 2020-03-30 | 2021-06-16 | 住友大阪セメント株式会社 | リチウムイオン二次電池用正極材料、リチウムイオン二次電池用正極及びリチウムイオン二次電池 |
| EP4147284A4 (en) * | 2020-05-04 | 2025-01-15 | Northwestern University | Conformal pickering emulsion graphene coatings for electrode materials and forming methods applications of same |
| US20230335730A1 (en) * | 2020-10-05 | 2023-10-19 | Northwestern University | Composites with surface refining and conformal graphene coating, electrodes, and fabricating methods of same |
| US12406996B2 (en) * | 2021-04-27 | 2025-09-02 | Northwestern University | Composite material with conformal graphene coating, fabricating methods and applications of same |
| CN113830755B (zh) * | 2021-09-14 | 2023-08-08 | 广西师范大学 | 一种一步法电化学制备钴单质-石墨烯插层化合物的方法 |
| KR102657695B1 (ko) * | 2021-09-29 | 2024-04-16 | 경상국립대학교산학협력단 | 아연-이온 전지용 집전체 및 음극재, 이의 제조방법 및 아연-이온 전지 |
| KR102651481B1 (ko) * | 2021-11-10 | 2024-03-27 | 한국과학기술연구원 | 단일 및 다성분계 나노입자 고밀도화, 고균일화 및 그 제조방법 |
| CN114914560B (zh) * | 2022-04-02 | 2024-12-13 | 武汉理工大学 | 一种双层分布的锂离子电池极片中导电剂比例的确定方法 |
| CN115986092B (zh) * | 2023-02-23 | 2025-08-29 | 贵州梅岭电源有限公司 | 一种锂离子电池的制备方法 |
| WO2024242976A1 (en) * | 2023-05-22 | 2024-11-28 | Northwestern University | Lithium-ion battery electrode materials with graphene-cellulose composite coatings and applications of same |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120064409A1 (en) | 2010-09-10 | 2012-03-15 | Aruna Zhamu | Graphene-enhanced anode particulates for lithium ion batteries |
| JP2012219010A (ja) | 2011-04-06 | 2012-11-12 | Samsung Electro-Mechanics Co Ltd | ナノ複合素材及びその製造方法並びにこれを含むエネルギ貯藏装置 |
| JP2013054958A (ja) | 2011-09-05 | 2013-03-21 | Hitachi Maxell Energy Ltd | 非水電解質二次電池用負極材、リチウムイオン二次電池及び電気化学キャパシタ |
| JP2013067543A (ja) | 2011-09-26 | 2013-04-18 | Asahi Glass Co Ltd | ケイ酸化合物、二次電池用正極および二次電池の製造方法 |
| US20150044564A1 (en) | 2013-08-08 | 2015-02-12 | Yanbo Wang | Anode containing active material-coated graphene sheets and lithium-ion batteries containg same |
| US20150044556A1 (en) | 2013-08-08 | 2015-02-12 | Yanbo Wang | Cathode active material-coated discrete graphene sheets for lithium batteries and process for producing same |
| US20150072162A1 (en) | 2011-04-22 | 2015-03-12 | Northwestern University | Methods for preparation of concentrated graphene ink compositions and related composite materials |
| JP2015527707A (ja) | 2012-07-20 | 2015-09-17 | アカデミア シニカAcademia Sinica | グラフェンを被覆した電極 |
| CN105047917A (zh) | 2015-06-25 | 2015-11-11 | 中国航空工业集团公司北京航空材料研究院 | 一种磷酸铁锂电池正极材料的制备方法 |
| JP2016189294A (ja) | 2015-03-30 | 2016-11-04 | 東ソー株式会社 | リチウムイオン2次電池用負極活物質およびその製造方法 |
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| US6159636A (en) * | 1996-04-08 | 2000-12-12 | The Gillette Company | Mixtures of lithium manganese oxide spinel as cathode active material |
| CN102917981B (zh) * | 2010-05-14 | 2016-01-20 | 巴斯夫欧洲公司 | 用石墨烯包封金属和金属氧化物的方法以及这些材料的用途 |
| US8691441B2 (en) | 2010-09-07 | 2014-04-08 | Nanotek Instruments, Inc. | Graphene-enhanced cathode materials for lithium batteries |
| US20120088151A1 (en) * | 2010-10-08 | 2012-04-12 | Semiconductor Energy Laboratory Co., Ltd. | Positive-electrode active material and power storage device |
| CN102087921B (zh) * | 2011-01-21 | 2014-01-01 | 清华大学 | 一种自支撑超级电容器电极材料及其制备方法 |
| US9079764B1 (en) | 2011-04-22 | 2015-07-14 | Northwestern University | Methods for preparation of concentrated graphene compositions and related composite materials |
| US9902866B2 (en) | 2011-04-22 | 2018-02-27 | Northwestern University | Methods for preparation of concentrated graphene ink compositions and related composite materials |
| KR102706790B1 (ko) | 2015-10-14 | 2024-09-12 | 노쓰웨스턴유니버시티 | 그래핀-코팅된 금속 산화물 스피넬 캐소드 |
| CN105932296B (zh) * | 2016-05-26 | 2018-04-27 | 宁波维科电池股份有限公司 | 一种高分散性石墨烯复合浆料的制备方法 |
| CN106340653B (zh) * | 2016-09-29 | 2018-10-30 | 叶盛 | 一种褶皱状石墨烯复合导电剂及制备方法 |
| WO2018217263A2 (en) * | 2017-02-27 | 2018-11-29 | Northwestern University | Nanostructured lithium-ion battery electrode composite materials via conformal graphene dispersion |
-
2018
- 2018-02-27 WO PCT/US2018/019965 patent/WO2018217263A2/en not_active Ceased
- 2018-02-27 US US15/906,776 patent/US11088392B2/en active Active
- 2018-02-27 KR KR1020197023314A patent/KR102520522B1/ko active Active
- 2018-02-27 CN CN201880012170.8A patent/CN110832681B/zh active Active
- 2018-02-27 EP EP18805721.0A patent/EP3586388A4/en active Pending
- 2018-02-27 JP JP2019542529A patent/JP7262392B2/ja active Active
-
2021
- 2021-07-07 US US17/369,058 patent/US11876168B2/en active Active
-
2023
- 2023-11-07 US US18/387,509 patent/US12381252B2/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120064409A1 (en) | 2010-09-10 | 2012-03-15 | Aruna Zhamu | Graphene-enhanced anode particulates for lithium ion batteries |
| JP2012219010A (ja) | 2011-04-06 | 2012-11-12 | Samsung Electro-Mechanics Co Ltd | ナノ複合素材及びその製造方法並びにこれを含むエネルギ貯藏装置 |
| US20150072162A1 (en) | 2011-04-22 | 2015-03-12 | Northwestern University | Methods for preparation of concentrated graphene ink compositions and related composite materials |
| JP2013054958A (ja) | 2011-09-05 | 2013-03-21 | Hitachi Maxell Energy Ltd | 非水電解質二次電池用負極材、リチウムイオン二次電池及び電気化学キャパシタ |
| JP2013067543A (ja) | 2011-09-26 | 2013-04-18 | Asahi Glass Co Ltd | ケイ酸化合物、二次電池用正極および二次電池の製造方法 |
| JP2015527707A (ja) | 2012-07-20 | 2015-09-17 | アカデミア シニカAcademia Sinica | グラフェンを被覆した電極 |
| US20150044564A1 (en) | 2013-08-08 | 2015-02-12 | Yanbo Wang | Anode containing active material-coated graphene sheets and lithium-ion batteries containg same |
| US20150044556A1 (en) | 2013-08-08 | 2015-02-12 | Yanbo Wang | Cathode active material-coated discrete graphene sheets for lithium batteries and process for producing same |
| JP2016189294A (ja) | 2015-03-30 | 2016-11-04 | 東ソー株式会社 | リチウムイオン2次電池用負極活物質およびその製造方法 |
| CN105047917A (zh) | 2015-06-25 | 2015-11-11 | 中国航空工业集团公司北京航空材料研究院 | 一种磷酸铁锂电池正极材料的制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US12381252B2 (en) | 2025-08-05 |
| US20210344036A1 (en) | 2021-11-04 |
| CN110832681B (zh) | 2023-03-03 |
| WO2018217263A2 (en) | 2018-11-29 |
| WO2018217263A3 (en) | 2019-02-21 |
| KR102520522B1 (ko) | 2023-04-12 |
| KR20190114994A (ko) | 2019-10-10 |
| CN110832681A (zh) | 2020-02-21 |
| EP3586388A2 (en) | 2020-01-01 |
| EP3586388A4 (en) | 2020-12-23 |
| JP2020508541A (ja) | 2020-03-19 |
| US20180254517A1 (en) | 2018-09-06 |
| US11088392B2 (en) | 2021-08-10 |
| US20240079637A1 (en) | 2024-03-07 |
| US11876168B2 (en) | 2024-01-16 |
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