JP7122254B2 - スルホニルペンダント基を有するフッ素化コポリマー及びイオノマーの製造方法 - Google Patents

スルホニルペンダント基を有するフッ素化コポリマー及びイオノマーの製造方法 Download PDF

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JP7122254B2
JP7122254B2 JP2018546900A JP2018546900A JP7122254B2 JP 7122254 B2 JP7122254 B2 JP 7122254B2 JP 2018546900 A JP2018546900 A JP 2018546900A JP 2018546900 A JP2018546900 A JP 2018546900A JP 7122254 B2 JP7122254 B2 JP 7122254B2
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copolymer
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formula
fluorinated
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JP2019511598A5 (OSRAM
JP2019511598A (ja
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ディー.ダールケ グレッグ
デュシェーヌ デニス
ヒンツァー クラウス
ハー.ロッホハース カイ
タラー アルネ
ツェー.ツィップリース ティルマン
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3M Innovative Properties Co
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1039Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • C08F214/26Tetrafluoroethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14Monomers containing only one unsaturated aliphatic radical
    • C08F216/1466Monomers containing sulfur
    • C08F216/1475Monomers containing sulfur and oxygen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621Binders
    • H01M4/622Binders being polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8663Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers
    • H01M4/8668Binders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88Processes of manufacture
    • H01M4/8825Methods for deposition of the catalytic active composition
    • H01M4/8828Coating with slurry or ink
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1004Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M2008/1095Fuel cells with polymeric electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0082Organic polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Inert Electrodes (AREA)
  • Fuel Cell (AREA)
JP2018546900A 2016-03-07 2017-03-06 スルホニルペンダント基を有するフッ素化コポリマー及びイオノマーの製造方法 Active JP7122254B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662304425P 2016-03-07 2016-03-07
US62/304,425 2016-03-07
PCT/US2017/020895 WO2017155862A1 (en) 2016-03-07 2017-03-06 Fluorinated copolymer having sulfonyl pendant groups and method of making an ionomer

Publications (3)

Publication Number Publication Date
JP2019511598A JP2019511598A (ja) 2019-04-25
JP2019511598A5 JP2019511598A5 (OSRAM) 2020-04-16
JP7122254B2 true JP7122254B2 (ja) 2022-08-19

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JP2018546900A Active JP7122254B2 (ja) 2016-03-07 2017-03-06 スルホニルペンダント基を有するフッ素化コポリマー及びイオノマーの製造方法

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US (1) US20190027769A1 (OSRAM)
EP (1) EP3426701B1 (OSRAM)
JP (1) JP7122254B2 (OSRAM)
CN (1) CN108779209A (OSRAM)
TW (1) TW201805316A (OSRAM)
WO (1) WO2017155862A1 (OSRAM)

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* Cited by examiner, † Cited by third party
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EP3353221B1 (en) 2015-09-23 2023-06-07 3M Innovative Properties Company Method of making a copolymer of tetrafluoroethylene having sulfonyl pendant groups
EP3896052A1 (en) 2017-05-19 2021-10-20 3M Innovative Properties Co. Methods of making a polyfluorinated allyl ether and compounds relating to the methods
US11377510B2 (en) 2017-09-14 2022-07-05 3M Innovative Properties Company Fluorinated copolymer and compositions and articles including the same
US20210071039A1 (en) * 2018-01-22 2021-03-11 W. L. Gore & Associates Gmbh Compositions for forming antistatic coatings and articles coated with the compositions
JP7556359B2 (ja) * 2019-10-21 2024-09-26 Agc株式会社 フルオロスルホニル基含有含フッ素ポリマーおよびその製造方法、スルホン酸基含有含フッ素ポリマーおよびその製造方法、固体高分子電解質膜、膜電極接合体ならびに固体高分子形燃料電池
WO2021130626A1 (en) 2019-12-23 2021-07-01 3M Innovative Properties Company Process of making fluoroolefins by thermal decomposition of fluorinated ionomers
CN111138596B (zh) * 2019-12-23 2022-09-30 珠海冠宇电池股份有限公司 聚合物电解质及包括该聚合物电解质的锂离子电池
WO2021198808A1 (en) 2020-03-30 2021-10-07 3M Innovative Properties Company Fluoropolymer comprising pendent groups with ionic bis(sulfonyl)imide moiety and perfluoroether terminal group
US20230090482A1 (en) * 2020-04-09 2023-03-23 3M Innovative Properties Company Composite including fluorinated polymer and salt nanoparticles and articles including the same
CN111718452A (zh) * 2020-06-24 2020-09-29 深圳市信宇人科技股份有限公司 用于锂离子电池干法电极粘结剂的制备方法及其粘结剂

Citations (5)

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JP2013509467A (ja) 2009-10-29 2013-03-14 ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア スルホニルフルオリドポリマーの単離方法、およびそれによって得られるポリマー
JP2013181128A (ja) 2012-03-02 2013-09-12 Asahi Glass Co Ltd ポリマーの製造方法、固体高分子形燃料電池用電解質膜および膜電極接合体
JP2014529636A (ja) 2011-08-04 2014-11-13 スリーエム イノベイティブプロパティズカンパニー 低当量重量ポリマー
WO2017053563A1 (en) 2015-09-23 2017-03-30 3M Innovative Properties Company Method of making a copolymer of tetrafluoroethylene having sulfonyl pendant groups
JP6640863B2 (ja) 2015-02-12 2020-02-05 スリーエム イノベイティブ プロパティズ カンパニー ペンダントスルホニル基を有するテトラフルオロエチレン/ヘキサフルオロプロピレンコポリマー

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US6653379B2 (en) * 2001-07-12 2003-11-25 3M Innovative Properties Company Fluoropolymers resistant to stress cracking
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EP1699829A1 (en) * 2003-12-30 2006-09-13 3M Innovative Properties Company Fluoropolymer coagulation method and composition
JP4969126B2 (ja) * 2005-07-07 2012-07-04 富士フイルム株式会社 固体電解質フィルム及びその製造方法、製造設備並びに電極膜複合体及び燃料電池
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JP5540681B2 (ja) * 2009-07-14 2014-07-02 株式会社豊田中央研究所 改質電解質及びその製造方法、並びに、改質剤
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JP2013509467A (ja) 2009-10-29 2013-03-14 ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア スルホニルフルオリドポリマーの単離方法、およびそれによって得られるポリマー
JP2014529636A (ja) 2011-08-04 2014-11-13 スリーエム イノベイティブプロパティズカンパニー 低当量重量ポリマー
JP2013181128A (ja) 2012-03-02 2013-09-12 Asahi Glass Co Ltd ポリマーの製造方法、固体高分子形燃料電池用電解質膜および膜電極接合体
JP6640863B2 (ja) 2015-02-12 2020-02-05 スリーエム イノベイティブ プロパティズ カンパニー ペンダントスルホニル基を有するテトラフルオロエチレン/ヘキサフルオロプロピレンコポリマー
WO2017053563A1 (en) 2015-09-23 2017-03-30 3M Innovative Properties Company Method of making a copolymer of tetrafluoroethylene having sulfonyl pendant groups

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EP3426701A1 (en) 2019-01-16
EP3426701B1 (en) 2022-08-10
WO2017155862A1 (en) 2017-09-14
CN108779209A (zh) 2018-11-09
TW201805316A (zh) 2018-02-16
JP2019511598A (ja) 2019-04-25
US20190027769A1 (en) 2019-01-24
EP3426701A4 (en) 2019-07-31

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